The iron and steel industry is not only one of the most important components of China's national economy, but also a typical resource-and-energy-intensive industry. Under the background of "Carbon Peaking and Carbon Neutrality Goals", it is of great significance for the iron and steel industry to improve the green closed-loop supply chain and develop circular economy. From the perspective of green supply chain, this paper puts forward the three-level network structure of waste steel reverse logistics based on the present situation of waste steel recycling in China, and uses k-means clustering algorithm and accurate center of gravity method to select locations for the primary and secondary nodes. The purpose of this paper is to provide a basis for iron and steel enterprises to carry out network optimization of reverse logistics.