Rossby Wave Breaking (RWB) propels stratospheric ozone (O3) into the troposphere resulting in an augmentation of tropospheric ozone levels and leading to subsequent alterations in the tropospheric chemistry. Given the profound implications, it is crucial to understand RWB-induced ozone variations comprehensively beyond localized production and transport, particularly over densely populated Indian subcontinent. In this context, we investigated the role of RWB on tropospheric ozone variability followed by its relative contribution at the lower levels by leveraging the data from Atmospheric Infrared Sounder (AIRS) onboard Aqua satellite, along with Copernicus Atmosphere Monitoring Service (CAMS) global reanalysis. In this study, we used 232 RWB events for the period 2004-2021, revealing an enhancement of ozone concentration from the daily mean of corresponding RWB days in a climatological aspect. We examine the fraction of events that allows the stratospheric ozone transport till lower troposphere by analyzing the presence of significantly increased stratospheric ozone tracers (SOT) obtained from CAMS over the Indian subcontinent at various pressure levels during RWB days. Additionally, we subjectively examine stratospheric ozone intrusions till the lower troposphere using SOT and ozone from CAMS on a centroid based relative domain. Our findings reveal that only 46% of the total RWB events facilitate stratospheric ozone transport up to the surface level. Further, analysis reveals an enhancement of ozone before and after the maximum breaking, primarily in upper atmospheric levels. Our results also showed that the intrusion intensity yields diverse increments in various tropospheric layers (e.g., 150-250 ppbv at 100-250 hPa layers). Lower tropospheric ozone variations (850 hPa) to RWB correlates with intrusion intensity, resulting in anomalous changes of about 10-20 ppbv. It is observed that the upper-level positive potential vorticity anomalies catalyze ozone intrusion from the stratosphere, descending to lower levels on intense breaking days through downward transport. These findings deepen our understanding of RWB-induced tropospheric ozone variability and its relative contribution to the ozone changes over the subcontinent.
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