Clay Materials Research Articles

Optimized enhanced energy absorption in polymer nanocomposites reinforced with nano-clay, nano-silica, and diethylenetriamine

In today’s world, where various industries face ever-increasing developments, improving people’s lives and preserving their property and lives are important issues in industrial production. One of the most unpleasant events in life is a collision while using the vehicle. Therefore, in recent decades, the high importance of this issue has attracted the attention of many researchers. The present study investigates the energy absorption of polymer nanocomposites with cylindrical and conical structures with different percentages of clay and silica nanoparticles to determine the various effects of nanomaterials and the effect of structure geometry on energy absorption under quasi-static tests. This experiment has been designed with the help of Design Expert software and the Box-Benken method. Also, nanomaterials between changes of 0-0.4% and diethylenetriamine material with weight% 1,3,5 have been used. From the results, it can be depicted that with the increase of the nanomaterial in this range, energy absorbed by the addition of nano silica up to the central point, i.e., 0.2%, an increase has been witnessed and after that, its intensity has decreased. Within this range, there is an observed significant rise of up to 0.4% for the nano clay material, while its trend keeps up with the previous intensity after the central point. However, in diethylenetriamine material, the highest energy absorption at the central point was 0.2%, after which a downward trend was observed. Also, in the investigation of the geometry of the structure, it was found that cone-shaped structures have higher energy absorption.

Synergy Between Woody Peat and Bentonite Alters Stability of Soil Organic Carbon in Coarse Soil by Enhancing Capacity for Soil Aggregation and Hydro‐Physical Properties

ABSTRACTCoarse soil has a poor structure and is susceptible to wind and water erosion, thereby making it difficult to maintain the soil organic carbon (SOC) content. Woody peat (WP) is an organic material that can increase the SOC content of the soil, while clay materials can rapidly enhance the capacity for soil aggregate formation. In order to explore the synergistic effects of WP and clay materials (bentonite and red clay) on the aggregate structure and hydro‐physical properties of coarse soil, as well as the mechanism associated with SOC mineralization (ΔSOC), we conducted an incubation study using lou soil (L0) and loessial soil (H0) with three treatments: addition of WP alone (LW, HW), mixture of WP and bentonite (LWB, HWB), and mixture of WP and red clay (LWR, HWR). The three treatments enhanced the proportion of macroaggregate (> 2 mm) and aggregate stability of the two soils, and optimized the water retention and ventilation performance. The highest aggregate stability of LWB and HWB can be attributed to the positive synergistic effect of WP and bentonite, and bentonite was more effective than red clay due to its crystal structure. The results also showed that the ΔSOC values were significantly lower under LWB and HWB than those under WP addition alone and adding the mixture of WP and red clay (p < 0.05). Moreover, partial least squares path modeling analysis showed that the hydro‐physical properties of the two improved soils inhibited SOC mineralization (p > 0.05), whereas particulate organic carbon (POC) content significantly accelerated SOC mineralization (p < 0.01). The synergistic effect of clay materials increased mineral‐associated organic carbon (MAOC), which was beneficial to maintain the long‐term effectiveness of WP. Overall, our results demonstrated that the synergistic use of WP and bentonite enhanced the aggregate stability and hydro‐physical properties of coarse soil and improved SOC storage capacity. These results provide scientific and theoretical guidance to facilitate the rapid improvement of coarse soil through engineering measures in arid and semi‐arid areas with water and fertilizer limitations.

Progress on clay swelling inhibitors: a comprehensive review

Relevance. It is known that swelling of a well wall due to the presence of water negatively affects drilling operations, causing a significant increase in their material costs. The use of various inhibitors prevents this effect and the drilling mud reacting on wellbore narrowing. In this sense, the problems of developing polymer, amino-, ionic liquid and shale inhibitors of surfactants considered in the article are very relevant and of practical interest to oil engineers in terms of the prospects for fundamental and applied researches of these issues. Aim. To study the possibilities of existing approaches and methods that determine the characteristics of the main clay swelling inhibitors, the regularities of changes in the properties of traditional and non-traditional clay materials, as well as the mechanisms of clay swelling with the identification of the most characteristic group of these inhibitors. Object. Processes of minimizing the effect of wall narrowing as a result of exposure to inhibitors. Methods. Systematic, critical and comprehensive analysis of modern data on clay swelling inhibition in the field of drilling muds. Results. The authors have carried out the detailed analysis of clay swelling. The paper discusses the characteristics of inhibitors required to prevent swelling, in the structure of which nitrogen and ionic liquids are contained. It is noted that a high-quality clay swelling inhibitor should include in its base a water-soluble bulk molecule with a distinct hydrophobic and hydrophilic structure; have characteristics, which allow replacing the hydrated cations of the intermediate layer with some hydrophobic cations, such as ammonium ions instead of sodium ions; differ in the ability to disperse multiple cations well. It was found that functional groups that support inhibitor binding to the siloxane groups of the clay are able to significantly expand clay swelling.

Railway embankment failure trends and monitoring – lessons learned from the Anglia route

UK railways were constructed with little consideration of engineering practice and with climate change and the associated greater frequency of extreme weather events, comes the impact on earthworks stability and risk to public safety. Many embankments on Network Rail’s Anglia route have shown a gradual degradation through their steep upper slopes and progressive failure within predominantly clay embankment material and underlying soft deposits. A regional wholistic view allows identification of common geotechnical trends and risk categorisation to better enable prioritisation of asset management. Understanding when to intervene is crucial and monitoring the behaviour of earthworks is a vital asset management tool to control risk and extend lifespan. To be a wise investment, slope instrumentation must be properly thought out in line with a detailed interrogation of the site and alongside a well-developed conceptual model. Automated monitoring can bring greater control and allow more accurate evaluation of intervention but must be assessed in line with prioritising large areas with limited budgets. Correct targeting of ground investigation and ensuring sufficient and reliable data can optimise mitigation and provide confidence the solution has provided resilience to railway infrastructure.

Synthesis and Applications of Nanocomposites in Food Packaging Industry: A Review

The current review focuses on the applications of polymer nanocomposites in the packing industry. Nanocomposite fabrication may be carried out through several synthetic techniques based on the type of material required. Basically, it is the composite formation of polymeric matrix and a reinforcing nanofiller. The nanoclay used for the modification of nanocomposites acts as a reinforcement or filler. Montmorillonite (MMT) is the most frequently used clay material to obtain the desired properties of nanocomposite. Clay reinforcement enhances the food packing properties of the material because of its properties as flame retardant, tensile features, barrier properties, and biodegradability. Among bottom-up and top-down techniques, sol-gel synthesis, self-assembly, and polymerization are the most common techniques used for the synthesis of nanocomposites. Nanocomposites derived from bio-polymers make the material biodegradable which, in turn, is one of the most desirable features for their future use. Owing to improved characteristics, clay nanocomposites form a superior class of materials for food packaging, yet much finer dispersion of nanofillers and compatibility may be devised.

Evaluation of Clayey Raw Materials and Ceramic Masses from Ceramic Building Material Companies Located in Northeastern Brazil

The challenge of improving the quality of ceramic products is faced worldwide, especially in areas where artisanal production is common and the need for in-depth knowledge about raw materials, together with inefficient production processes, limits the advancement of the ceramic industry. Scientifically, detailed investigation of ceramic masses’ physical, chemical and mechanical properties can provide essential insights to optimize production, contribute to developing more advanced and sustainable techniques, and increase competitiveness. This study evaluated raw clay materials and ceramic masses obtained from northeastern Brazilian, focusing on their chemical composition, mineralogical phases, thermal behavior, and particle size distribution. Rectangular samples (80 mm × 20 mm × 7 mm) prepared using uniaxial pressing (25 MPa by 30 s) were fired at different temperatures (950 and 1050 °C) and linear shrinkage, flexural strength, water absorption, and apparent porosity measurements were taken. The results showed that the companies still need to improve the production process to meet the minimum strength requirement of 1.5 MPa according to the Brazilian standard NBR 15270.

Evolution of mechanical properties of organic-rich shale during thermal maturation

Accurate assessment of the mechanical properties of organic matter, clay matrix, and bulk shale during maturation remains a challenge. Here, we aim to assess the mechanical properties of organic-rich shale during maturation using a combination of nanoindentation methods and various geochemical analyses, i.e., mineral composition, mass loss rate, chemical structure of organic matter, and Rock-Eval analyses. Results show that the evolution of mechanical properties of organic matter in shale during maturation can be divided into: the main oil-generation stage, and the condensate oil and gas generation stage. The stiffening of organic matter in the shale is mainly due to increased aromaticity and condensation of aromatic groups. The clay matrix experiences a slight decrease in hardness and Young’s modulus at low maturity levels due to the generation of liquid hydrocarbons. However, overall, the clay matrix becomes stiffer as the shale matures due to shale dehydration, expulsion or cracking of liquid hydrocarbons, transformation of clay minerals, and hardening of organic matter. The Young’s modulus and hardness of bulk shale generally increase with increasing maturity. This is closely related to the hardening of organic matter and clay matrix, as well as the development of the more compact and dense microstructure in the shale.

Effects of Acid Modified Mineral Materials on Soil Cadmium Pollution and Plant Remediation

In response to the problem of soil heavy metal pollution, acid modified mineral materials were used to study the changes in adsorption performance, surface charge, and other indicators of four clay mineral materials, vermiculite, arsenic sandstone, shale, and zeolite, under acid modified conditions. The changes in soil physicochemical properties, heavy metal content, and plant growth before and after remediation were analyzed. The study showed that the introduction of acid modified adsorption materials increased the specific surface area and cation exchange capacity, enhanced adsorption performance, and provided theoretical reference for the mechanism and effect of remediation of cadmium contaminated soil. To optimize the application amount of remediation materials and develop cheap, effective, and scalable heavy metal remediation materials, it has important practical significance. Bangladesh J. Bot. 53(3): 803-809, 2024 (September) Special

Regeneration and Single Stage Batch Adsorber Design for Efficient Basic Blue-41 Dye Removal by Porous Clay Heterostructures Prepared from Al13 Montmorillonite and Pillared Derivatives.

Porous clay heterostructures are a hybrid precursor between the pillaring process and organoclays. In this study, the organoclay was substituted by an aluminium intercalated species clay or pillared alumina clays. A porous clay heterostructure was successfully achieved from an aluminium intercalated species clay, due to the easy exchange of the aluminium species by the cosurfactant and silica species. However, using alumina pillared clays, the porous clay heterostructures were not formed; the alumina species were strongly attached to clay sheets which made difficult their exchange with cosurfactant molecules. In this case, the silica species were polymerized and decorated the surface of the used materials as indicated by different characterization techniques. The specific surface area of the porous clay heterostructure material reached 880 m2/g, and total pore volume of 0.258 cc/g, while the decorated silica alumina pillared clays exhibited lower specific surface area values of 244-440 m2/g and total pore volume of 0.315 to 0.157 cc/g. The potential of the synthesized materials was evaluated as a basic blue-41 dye removal agent. Porous clay heterostructure material has a removal capacity of 279 mg/g; while the other materials exhibited lower removal capacities between 75 mg/g and 165 mg/g. The used regeneration method was related to the acidity of the studied materials. The acidity of the materials possessed an impact on the adopted regeneration procedure in this study, the removal efficiency was maintained at 80% of the original performance after three successive regeneration cycles for the porous clay heterostructure. The Langmuir isotherm characteristics were used to propose a single-stage batch design. Porous clay heterostructures with a higher removal capacity resulted in a decrease in the quantities needed to achieve the target removal percentage of the BB-41 dye from an aqueous solution.

Depositional and diagenetic controls on the reservoir quality of marginal marine sandstones: An example from the Early Devonian subbat member, jauf formation, northwest Saudi Arabia

The reservoir quality of marginal marine sandstones can vary significantly across different depositional lithofacies. This variation is primarily due to differences in depositional processes and subsequent diagenetic alterations occurring during various stages of burial. To address this issue, this study focuses on the Early Devonian Subbat sandstones of the Jauf Formation, which serve as an important analogue for subsurface gas reservoirs and have potential for CO2 sequestration. An integrated approach was employed, including field observations, petrography, geochemical analyses, and petrophysical analyses, to investigate the impact of depositional and diagenetic processes on reservoir quality. The findings indicate that the sandstones range from poorly to well sorted, very fine to medium-grained arkosic and quartz arenites that were deposited in a range of environments including shoreface-to-offshore transition zones, wave-dominated deltas, fluvial and tidal estuarine channels. The sandstones experienced both shallow and deep burial diagenesis, while key diagenetic events affecting reservoir quality include compaction, carbonate cementation, the formation of authigenic clays (kaolinite, illite, and chlorite), quartz overgrowth, and the dissolution of unstable feldspar and mica grains. Authigenic pore-filling cements and grain-coating clays significantly influence reservoir quality. The effect of quartz cementation was minimal where illite and/or chlorite coatings are well-developed. Mechanical compaction is more pronounced in the shoreface-to-offshore transition compared to the estuarine channels likely due to the higher detrital matrix content (21.7–35%, avg. 26.7%). The well-sorted fluvial to estuarine channel sandstones exhibit the best reservoir quality, with porosity ranging from 15.9% to 25.5% (average 20.4%) and permeability between 433.8 mD and 1261.2 mD (average 720 mD). This high reservoir quality is attributed to the low detrital matrix content (0–1%, average 0.2%) and limited pore-filling cements. In comparison, the moderately sorted, wave-dominated delta sandstones have lower porosity (5.3–11.2%, average 8.2%) and permeability (17.8–80 mD, average 42.8 mD), despite a relatively higher detrital matrix content (0–11.5%, average 2.8%). The poorly sorted shoreface-to-offshore transition sandstones exhibit the lowest reservoir quality, with porosity ranging from 1% to 2% (average 1.5%) and permeability between 0.3 and 1.1 mD (average 0.7 mD). These variations in reservoir quality among different depositional facies are primarily linked to depositional factors (sorting and detrital clay matrix) and shallow to deep burial diagenetic processes (compaction and cementation). A comprehensive understanding of these processes can enhance reservoir quality prediction in the Jauf Formation and similar reservoirs elsewhere.

Development of free flowing granular hybrid functionalized clay sorbent filters for chromium removal from waste water

Chromium (VI) contamination in water resources at industrial sites poses significant environmental and health risks. Conventional sorbents often suffer from limitations such as clogging, back pressure, poor kinetics, and challenges in coupling with flow systems and regeneration. This study focuses on developing, characterizing, and applying free-flowing granular (FFG) amidoxime-functionalized montmorillonite (Mt) clay sorbents (AO-Mt-H-C) to enhance chromium (VI) removal from contaminated waste water. Batch adsorption experiments demonstrated that AO-Mt-H-C outperformed montmorillonite clay modified with quaternary ammonium alone (Mt-H-C), achieving a Cr (VI) removal efficiency of 50.6 mg g−1 compared to 44.3 mg g−1, due to the synergistic interactions of quaternary ammonium and amidoxime functionalities. To address the limitations of conventional sorbents, such as clogging and poor kinetics, an FFG filter column was developed and tested, showing effective Cr (VI) removal across various water sources with minimal interference in drinking and groundwater. In industrial wastewater with higher matrix loads, over 99 % removal efficiency was achieved with a 25 % increase in sorbent dosage. Desorption and reusability assessments confirmed the AO-Mt-H-C's effectiveness across three cycles. Mathematical modelling using Thomas and Yoon–Nelson equations supported the design of customized treatment systems. Scalability was demonstrated by treating 1.6 m3 of textile industrial effluents (100 mg L−1 Cr (VI)) with quantitative removal efficiency (>99.5 %). This study illustrates that the hybrid functionalization and free-flowing granulation of clay sorbent materials significantly enhance Cr (VI) removal, providing valuable insights for advanced water pollution mitigation and environmental sustainability.

Nanoscale Understanding on CO2 Diffusion and Adsorption in Clay Matrix Nanopores: Implications for Carbon Geosequestration.

Carbon capture and storage (CCS) in subsurface reservoirs represents a highly promising and viable strategy for mitigating global carbon emissions. In the context of CCS implementation, it is particularly crucial to understand the complex molecular diffusive and adsorptive behaviors of anthropogenic carbon dioxide (CO2) in the subsurface at the nanoscale. Yet, conventional molecular models typically represent only single-slit pores and overlook the complexity of interconnected nanopores. In this work, finite kaolinite lamellar assemblages with abundant nanopores (r < 2 nm) were used. Molecular dynamics simulations were performed to quantify the spatial distribution correlations, adsorption preference, diffusivity, and residence time of the CO2 molecules in kaolinite nanopores. The movement of the CO2 molecules primarily occurs in the central and proximity regions of the siloxane surfaces, progressing from larger to smaller nanopores. CO2 prefers smaller nanopores over larger ones. The diffusion coefficients increase, while residence times decrease, with the pore size increasing, differing from typical slit-pore models due to the pore shape and interconnectivity. The perspectives in this study, which would be challenging in conventional slit-pore models, will facilitate our comprehension of the CO2 molecular behaviors in the complex subsurface clay sediments for developing quantitative estimation techniques throughout the CCS project durations.

Evaluating the effect of Incorporating Chicken Feather Fibers on the Technological Properties of Eco-Friendly Compressed Earth Bricks

This paper investigates the feasibility of improving the performance of raw bricks by using chemically treated chicken feather fibers as a sustainable reinforcement material. Although numerous studies have already explored the use of chicken feathers in brick composites, this work is distinguished by the application of a novel chemical treatment involving formaldehyde and silane to enhance the fibers' compatibility with the clay matrix. The treated fibers were incorporated into raw brick samples at varying concentrations. The effects of fiber reinforcement on critical properties such as porosity, bulk density, compressive strength, and thermal conductivity were systematically analyzed. The results indicate that incorporating chemically treated chicken feather fibers reduces porosity and bulk density while increasing compressive strength within an optimal concentration range. Additionally, a significant reduction in thermal conductivity was observed, demonstrating the potential of these materials to improve thermal insulation in construction applications. This study highlights the promise of utilizing chicken feather waste, treated with formaldehyde and silane, as reinforcement in the production of eco-friendly bricks, with implications for sustainable construction practices.

КЕРАМИКАЛЫҚ ЖОЛ ТӨСЕНІШТЕРДІ ӨНДІРУДЕГІ КЕРАМИКАЛЫҚ МАССА КОМПОЗИЦИЯСЫН ЖЕТІЛДІРУ

The article presents the results of a study of the chemical and mineralogical composition of the raw material components in the ceramic mass and provides techniques for the technology of laying ceramic material by vibropressing using talc rock in the mass and methods for determining the composition of clay raw materials. Formulations for the production of ceramic road surfaces, taking into account the factors of preference for mixtures to improve the properties of the finished product as a molding, drying and ceramic material, have been studied in two different components. It was found that the introduction of talc into the ceramic composition has an effect on the formation of high-temperature augite and amphibole phases and the intensification of the formation of minerals in clay, on the formation of high-temperature phases - sanidine, ackermanite elements. This process leads to an increase in the physical and mechanical properties of the resulting samples.The main patterns of formation of the structure and phase of ceramic compositions by firing in the temperature range 1000оC-1100оC were studied by isothermal control.In this pattern, sintering processes with solid and solid liquid-phase syntheses were carried out to ensure the phase - mineral composition, the study clarified the production of high-strength and frost-resistant ceramic pavement. In order to be used in the improvement of the city territory (sidewalks, alleys, park areas, playgrounds, etc.), the possibility of obtaining ceramic road surfaces that meet environmental and operational requirements has been proven. It has been established that one of the priority properties of ceramic road surfaces is a significant abundance of their porosity (25-30%), which allows you to quickly absorb moisture from precipitation (rain, sleet, etc.) and filter water through the body into the ground.Such properties of ceramic paving stones prevent the accumulation of moisture on the surface of the roadway and create comfortable conditions during pedestrian movement, reducing the likelihood of ice formation on the surface of the paving stones in the cold season.

Sustainable approach to raw clays for ceramic and refractory applications: insights from updated traditional ternary diagrams

Abstract The study analysed 93 samples from four Serbian clay deposits to determine their suitability for ceramics production. The samples were mainly composed of illite and kaolinite. Ternary diagrams were used to classify the samples and evaluate their applicability. Winkler's diagrams, ternary graphs and mineralogical compositions were analysed. The results showed a broader area in these graphs than previously determined for structural ceramics, as well as the potential of these clays for ceramic production. The study used dry-milled, hydraulically semi-dry, pressed and fired samples to assess water absorption and flexural strength and statistical analysis to determine the key parameters influencing final product quality, including that of refractory, wall and floor tiles. This paper evaluates the raw clay materials’ applicability in ceramic production, promoting sustainable use through rapid initial tests, energy savings through dry milling and ecologically sound principles through resource-efficient evaluation.

Experimental Study of Plastic Bricks Made from Waste Plastics

This study describes the use of municipal plastic waste (MPW) in the construction industry. Plastic is a nonbiodegradable material that takes thousands of years to decompose and causes soil and water pollution. The amount of plastic waste in municipal solid waste (MSW) is increasing rapidly. Usage is estimated to double every decade. Plastic consumption is high and one of the largest plastic wastes is polyethylene (PE). The use of earth-derived clay materials has caused resource depletion and one of these efforts is the efficient use of plastic waste and laterite quarry waste, along with small amounts of asphalt, to meet the growing demand for traditional building materials, which are less absorbent than laterite bricks. The challenge is to develop alternative building materials, such as brick, that have little but sufficient strength. The use of MPW as a building material, especially in brick production, is one of the promising steps towards sustainable resource and waste management. Plastic waste can partially or completely replace one or more raw materials in brick production. Further research based on recent research and a better understanding of the use of waste plastics in bricks is needed to produce high-quality and durable bricks and to achieve an optimal balance in all aspects, especially in terms of cost and functionality.

Adsorption of nickel (II) from aqueous solutions with clay-supported nano-scale zero-valent iron synthesized from green tea extract

Nano zerovalent iron (nZVI) supported adsorbents have been reported as suitable candidates for adsorption of water contaminants. However, the role of and interplay between surface chemistry, functional group density and textural properties has largely been unexplored. In this work, green tea derived nano zerovalent iron (nZVI) supported clay hybrid material (CnZVI) was used as a novel adsorbent for the removal of Ni2+ ions from water. The unmodified natural clay (Arg) and the CnZVI composite were characterized using FTIR, SEM, TGA and BET techniques. Incorporation of nZVI ameliorated the specific surface area from 16.88 to 30.46 m2/g, translating to ∼80 % increase. This translated to ∼69 % increase in maximum adsorption capacity from 8.47 to 14.38 mg/g, respectively. The addition of nZVI in the clay decreased the affinity (KF) for Ni2+ by ∼48 %. The disparity between the percent increase in surface area (∼80 %) and the adsorption capacity (∼69 %) implies the adsorption of Ni2+ was significantly controlled by textural properties compensating for the antagonistic effects of functional group density. The kinetic rates were best predicted by the pseudo-first-order and Elovich’s models for the Arg and CnZVI, respectively, implicit evidence of the role of surface chemistry. A maximum adsorption capacity of 14 mg/g was achieved for 100 mg Ni2+/L in 120 min for CnZVI.

An evaluation of the consistency of data and models for performance assessment: Divalent metal sorption on montmorillonite

A detailed analysis of literature data on the retention of divalent metal by purified montmorillonite or montmorillonite-rich material (e.g. bentonite) was conducted. Data for which sufficient experimental conditions were available were modeled with the 2SPNE SC/CE model available in the literature, and with a “minimalist” model, which uses a minimum number of parameters to reproduce the data.A successful data modeling could only be achieved if considering (i) cation exchange competition with aqueous Ca2+ and Mg2+, originating from the dissolution of the clay mineral itself or accessory minerals and (ii) precipitation, at high pH, of phases incorporating the divalent metal of interest. However, in many studies, the concentration of aqueous Ca2+ and Mg2+ and, more generally, a full characterization of solution composition (e.g., Si, Al, dissolved organic carbon, alkalinity) is not provided, thus impeding accurate data modeling. Further difficulties stem from uncertainties related to the nature of the solids precipitating at high pH and missing or inaccurate thermodynamic data related to mineral solubility.Log KD values cannot be predicted from available literature data with an accuracy better than ±1 log unit, without sorption data obtained on a material representative of in situ conditions. In addition, the most reactive sites, commonly referred to as strong sites, which have been characterized only on some, but not all, reference clay materials, should not be considered in blind predictions based on the mineralogical composition of clay materials.

Feasibility of biochar for low-emission soft clay stabilization using CO2 curing

Use of traditional lime-cement binders on stabilizing soft sensitive clays pose a significant challenge for the construction sector to reach Finland’s carbon neutrality goals by 2030. Traditional stabilization recipes consisting of cement as binders contributing significantly to CO2 emissions (≅ 500 kg CO2 eq./ton in deep mixing alone). This laboratory study explores the feasibility of achieving near carbon-negative stabilization of soft clay leveraging accelerated CO2 curing (ACC) in biochar (BC) enhanced cementitious composites. BC, a by-product of the biofuel industry, is used as partial replacement of cement (0 %, 10 %, and 50 % of binder) in developing precast cementitious piles. One non-carbonated treatment and two ACC treatments are employed to assess their uniaxial compressive strength, thermogravimetric properties and CO2 sequestration capacity. The results demonstrate that synergistic effects of using BC with ACC not only enhances the compressive strength of the composites but also promotes CO2 uptake due to formation of stable carbonates. BC due to its surface functional groups, honeycomb porous structure, and hydrophilicity facilitated uniform CO2 diffusion in the clay matrix and likely improved internal curing. In ACC treated composites, the replacement of 50 % of cement with BC resulted in sufficient load-bearing capacity (≥50 kPa as per Finnish Guidelines) for both shallow and deep clay layers, making a suitable subgrade media for many types of geotechnical applications. The measured bound CO2 increased gravimetrically from 2 % to 41 % when cement was partially replaced by BC. In case of non-carbonated samples, 10 % partial replacement of BC provided high strength (≥200kPa). Life Cycle Assessment (LCA) of a case study of utilizing BC stabilized clay in deep mixing operations can potentially reduce net carbon emissions to −50 kg CO2 eq./ton.

The influence of addition of fly ash from biomass combustion on selected properties of red building ceramics

The paper characterizes waste in the form of fly ash generated in a power plant during the combustion of biomass in a fluidized bed in terms of its possible use in the ceramic building materials industry. This is important from the point of view of environmental protection. In order to assess the possibility of using ash in the production of red ceramics (e.g. bricks), two different clay raw materials (Clay I and Clay II) were selected to prepare the raw material sets. First of all, the investigated fly ash was subjected to thermogravimetric TG-DTG analysis and its basic chemical composition was determined. Then the specific density was determined for all the raw materials, XRD analysis was also performed and finally characteristic temperatures were determined by means of a high-temperature microscope. The basic raw material sets included clayey raw material and fly ash in various contents: 5 wt%, 10 wt% and 15 wt%. Samples were pressed from the ready sets and fired at the temperature of 1000℃. Afterwards, the obtained samples were subjected to XRD and microstructural tests, then selected physical properties were determined, i.e. water absorption, porosity, apparent density, and compressive strength. Based on the research and analysis of the results, it was found that the introduction of fly ash from biomass combustion into the raw material set in the range of 5–15 wt% has a positive effect on the insulating properties of red ceramics. In addition, the density of the red ceramics decreases with the increase in the addition of fly ash, while its porosity and water absorption increase. Furthermore, the addition of fly ash decreases the compressive strength and visually brightens the microstructure of the products.