Differences of magnetic field flows of “+” and “−” polarities, i.e. the imbalance of magnetic fields for 26 years—from January 1, 1977, to September 30, 2003—are investigated,. The synoptic maps of the longitudinal vector of Sun’s magnetic field strength obtained at the Kitt Peak National Observatory (United States) and kindly given to us by Dr. J. Harvey have served as the initial material. The imbalance of magnetic fields’ cyclicity features and the deviations from the dipole structure of Sun’s magnetic field are determined. The contribution of latitude zones and fields of various strength into the general magnetic flux from the Sun is found. The latter characteristic was compared with the Sun’s mean magnetic field (MMF) obtained from the observations of the Sun as a star (Kotov et al., 2002; Kotov, 2008). The obtained results testify that the imbalance is one of physical characteristics of the Sun. The confirmations of this conclusion are the strict regularities of the Sun’s dipole structure changing; the complicated character of the imbalance cyclicity, i.e., the multiplicity of cycles; the solar nature of MMF changing; and the distinction between two classes of magnetic fields in the imbalance characteristics.