Citrus Limetta Peel Research Articles

Preliminary studies into polypropylene composites reinforced with fruit waste biomass: a choice towards sustainability

Abstract The development of polypropylene (PP) composites filled with a biomass from fruit waste, citrus limetta peel (CLP) fillers is explored in the current study. A polymer matrix consisting of neat polypropylene was filled with 10, 20, and 30% weight percentage (w/w) of CLP. The composite specimens were produced by extrusion followed by injection moulding. In addition to thermal and morphological evaluations, the mechanical properties are determined, including tensile and flexural (both strength and modulus). The primary results demonstrate that, for a 10 weight percent filler content, the inclusion of CLP filler raised the tensile and flexural modulus of the neat PP composites by 20.23% and 14.33%, respectively. All of the composites were found to be thermally stable up to 220 °C through thermal investigation. The burning rate increased with the incorporation of fillers whereas, the dripping effect gets reduced. Filler agglomeration, filler pull out, and poor adherence with increased CLP filler content were observed using scanning electron microscopy. The developed composites have got tremendous potential to be utilized in non-structural applications. The consequences of plastic burden on the environment can also be reduced.

Label-free detection of ampicillin in milk and water using fluorescence carbon dots synthesised from Citrus Limetta peel

Label-free detection of ampicillin in milk and water using fluorescence carbon dots synthesised from Citrus Limetta peel

The Anti-ulcer Potential of Weissella cibaria Assisted Bio-fermented Product of Citrus limetta Waste Peel in Wistar Albino Rats.

There are patents available related to fermented food and beverages which enhance to human health. Citrus limetta (Mosambi) has a high content of flavonoids and exhibits antioxidant activity, which could stimulate the digestive system and be useful for gastroprotective activity. It supports digestion by neutralizing the acidic digestive juices and reducing gastric acidity. This study explored the potential of using waste peel extract from Citrus limetta to prevent ulcers. The study specifically sought to assess the anti-ulcer properties of fermented and non-fermented extracts and compare them. Further, the study looked at the potential benefits of treating or preventing ulcers with Citrus limetta waste peels and whether fermentation affected the efficacy of the treatment. Thirty female Wistar albino rats were equally distributed into five different groups. Group 1 received distilled water (20 ml/kg/b.w); Group 2 received indomethacin (mg/kg/b.w); Group 3 received omeprazole (20 mg/kg/b.w); Group 4 received aqueous extract of Mosambi peel (400 mg/kg/b.w) and Group 5 received fermented product of extract of Mosambi peel (400 mg/kg/b.w). Findings explored that, compared to non-fermented citrus fruit juice, biofermented exhibited less gastric volume (1.58 ± 0.10 ml vs. 1.8 ± 0.14 ml), reduced MDA levels (355.23 ± 100.70 μmol/mg protein vs. 454.49 ± 155.88 μmol/mg protein), and low ulcer index (0.49 ± 0.07 vs. 0.72 ± 0.14). The results suggest that the bio-fermented product of Citrus limetta peel has better anti-ulcer potential against peptic ulcer induced by indomethacin in Wistar albino rats compared to non-fermented.

Enhancing Jatropha oil biodiesel by using Citrus Limetta peels as a biocatalyst: A sustainable way to reduce emissions and enhance the efficiency of CI engine

Biodiesel has become one of the promising alternative fuel resources for petro-diesel. Biodiesel is obtained by mixing oil and alcohol through transesterification reaction. A catalyst (base or acid) is typically added to accelerate the transesterification reaction and yield the maximum biodiesel production. The use of the traditional catalyst has problems like catalyst separation, soap formation, high reaction time, more energy consumption and environmental pollution. Literature shows that the addition of a catalyst from organic sources can overcome these problems. Biocatalysts were produced from different bio-waste like animal bones, plant leaves, fruit and vegetable peels, but there is no work found on the effects of Citrus Limetta peel waste for the biodiesel production. In this work, the feasibility of using Citrus Limetta peel ashes as an eco-friendly biocatalyst was investigated for the biodiesel production from Jatropha oil. The biocatalyst was obtained from Citrus Limetta peel waste after drying, pulverizing and calcination. XRD, SEM and EDX were used for the characterization of the biocatalyst. The biodiesel was tested for conformance with Euro standards. Then, three biodiesel blends (JT90, JT80 and JT70 with 10, 20 and 30 % biodiesel) were tested for determining the engine performance and emission characteristics in a Kirloskar 4-stroke CI diesel engine. SEM and EDX indicated a substantial concentration of potassium (26.8 %) and calcium (71.59 %) in the biocatalyst. The maximum biodiesel yield was achieved with 2 wt% biocatalyst, 15:1 Jatropha-to-methanol molar ratio, 60 °C reaction temperature and 1 h reaction time. Engine performance study showed that the JT80 blend demonstrated a BTE improvement of 1.2 % with a significant BSFC reduction of 11 % when subjected to full load conditions, surpassing that of pure diesel. Emissions study revealed that the JT80 blend demonstrated a substantial decrease in emissions compared to pure diesel. Specifically, there was a noteworthy 10.3 % reduction of carbon monoxide (CO), 14 % of carbon dioxide (CO2), 11 % of unburnt hydrocarbon (HC) and 3 % of nitrogen oxides (NOX), but with an increase of 2 % in smoke emissions.

Utilization of waste citrus limetta peel for the green synthesis of iron catalyst and its subsequent application in fluidized-bed Fenton-like process for environmental sustainable treatment of organic pollutant

This work focuses on the environmental friendly synthesis of an iron-based catalyst utilizing extract from waste citrus limetta peels. The main objective is to encourage the sustainable use of bio-waste materials in catalytic processes. This innovative method demonstrates the efficacy of bio-derived materials in catalysis by removing the need for hazardous chemicals. The green-synthesized catalyst was analyzed using many characterization methods, including X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). These analyzed results give insightful information on the physicochemical properties of green-synthesized catalysts. Furthermore, the prepared catalyst was utilized in a fluidized-bed reactor to facilitate the Fenton degradation of dye effluent, with a specific focus on the commonly used Eosin yellow (EY) dye. The iron catalyst derived from plant-based waste material accomplished an impressive 98% degradation of EY within a 90-minute time frame under optimized working conditions, using a minimal quantity of catalyst. An in-depth analysis was conducted to study the kinetics and process mass transfer in order to improve the comprehension of catalytic processes occurring in the fluidized-bed reactor. The Fenton decomposition of dye effluent is likely to be explained by first-order reaction kinetics. Additionally, confirmed enhanced catalytic durability and decreased deactivation of surface sites of the prepared catalyst after three consecutive oxidation cycles. These findings underscore the potential of this approach in sustainable wastewater treatment, highlighting both its efficiency and cost-effectiveness.

Valorisation of Citrus limetta peel for Aspergillus terreus FP6 mediated pectinase fermentation and application in grape juice clarification

ObjectivesThe present investigation highlights the process parameters influencing the pectinase fermentation by a newly isolated Aspergillus terreus using valorised agro-wastes and determination of the efficacy of the pectinase in grape juice clarification. MethodsThe fungal pectinase was produced under submerged fermentation with the optimisation of carbon and nitrogen sources, initial pH of the medium, inoculum load, incubation time and effect of agitation. The pectinase was later used for the clarification of grape juice and improvement of its total phenolic content. Results and ConclusionsMedium supplemented with sweet lime peel and yeast extract (1 % w/v), at initial pH 6.0, when incubated for 72 h under agitated conditions favoured the highest pectinase production by the fungal culture. Following the pectinase action for 1 and 3 h, the grape juice clarification percentages and total phenolic content were 34.21 %, 69.54 %, 3004, and 3484 mg GAE/L, respectively. The results highlight the valorisation of sweet lime peel for the industrial production of fungal pectinase. The study pronounces the cost-effective pectinase fermentation due to the fungi’s non-fastidious nutritional requirement and ubiquitous nature. The increase in the grape juice clarification and total phenolic content following the A. terreus FP6 pectinase treatment was significantly superior to similar commercial enzyme formulations. The result advocates the candidature of the enzyme in the beverage industry, where it can help mediate a greener approach for fruit juice clarification.

Fabrication and characterization of a composite material from polymer matrix using citrus limetta fiber

Natural fibers, known for their excellent mechanical properties, non-abrasiveness, affordability, high specific strength, environmental friendliness, and biodegradability, are increasingly being considered as potential replacements for synthetic fibers like glass and carbon. This study investigates the use of Citrus limetta peel fibers to develop and characterize a polymer matrix composite. The fibers were extracted, purified, and coated with epoxy resin, then developed into composites using the hand layup method and cured in an oven. Mechanical tests, including hardness, impact, tensile strength, and compression strength, were conducted to assess the composites. The results showed that fiber reinforcement significantly enhanced mechanical stability, with compression strength and ultimate tensile strength reaching 231.39 MPa and 22.68 MPa, respectively. Microstructural analysis using scanning electron microscopy (SEM) and moisture absorption tests were also performed. Additionally, Ansys workbench software was utilized for further analysis. The study concludes that Citrus limetta peel fibers are a viable reinforcement material for polymer matrix composites, offering enhanced mechanical properties. This research is relevant for applications in industries seeking sustainable and high-performance composite materials.

Biodiesel Synthesis from Coconut Oil Using the Ash of Citrus limetta Peels as a Renewable Heterogeneous Catalyst

Biodiesel Synthesis from Coconut Oil Using the Ash of Citrus limetta Peels as a Renewable Heterogeneous Catalyst

Ca-doped ZnO nanoparticles for MB dye degradation and adsorptive removal of tinidazole.

Industrial dye degradation involves several processes by which dyes are broken down, ideally into innocuous products. Methylene blue (MB) is one of the most commonly employed dyes in the textile industry and is released into water in routine industry processes. These discharges lead to creating a nocuous nature for humans and animals. Drugs are also discharged into water bodies from various pharmaceutical industries. In these two contexts, in the present work, the green synthesis of calcium-doped zinc oxide nanoparticles (Ca-doped ZnO NPs) is achieved using the aqueous peel extract of Citrus limetta by the solution combustion technique. The structural, morphological, and optical properties of the synthesized Ca-doped ZnO NPs are investigated using XRD, FTIR, SEM, EDX, and UV-visible spectroscopy. The prepared NPs were subjected to photocatalytic degradation of MB dye under visible-light illumination, which shows ~ 95% dye degradation. The synthesized Ca-doped ZnO NPs were also employed to adsorb tinidazole (TDZ), a nitroimidazole antibiotic, from water samples. An excellent adsorptive capacity of the NPs was observed for selectively adsorbing the TDZ ~ 96.2%. The drug TDZ was found to have pseudo-second-order kinetics. The catalyst recycling proved its repeatability; removal of the dye reached up to 92% after three successive usages. Therefore, using waste Citrus limetta peel extract, the multifunctional Ca-doped ZnO NPs were synthesized, which maintained effective adsorption potential and photocatalytic abilities and could be used as an effective material for environmental remediation.

Elucidating the scale-up potential of biogenic magnetized nanocatalyst towards intensified biodiesel production

The current investigation delved into biodiesel synthesis from castor oil (CO) employing a magnetic nanocatalyst contrived from waste Citrus limetta peel ash (CLPA@Fe3O4). SEM, TEM, EDAX, XRD, XPS, VSM, and FTIR were used meticulously to analyze the synthesized catalyst. The catalyst’s core–shell arrangement kept its regulated size and shape and enhanced its surface properties, significantly increasing its stability. The optimal biodiesel yield of 97.92 % was accomplished utilizing CLPA@Fe3O4 catalyst through transesterification under the ideal reaction conditions of 30 wt% methanol concentration, the catalyst of 6 wt%, 60 °C temperature, and 3 h reaction time. The thermodynamics study advocated the transesterification process to be endothermic and nonspontaneous, while the kinetic tests were revealed to obey pseudo-first-order kinetics. The transesterification of CO employing the current catalyst was found to have an activation energy of 33.138 kJ mol−1. Nevertheless, an extraneous magnet could recover the prepared magnetic iron oxide-supported nanocatalyst from the reactor, as the catalyst showed a strong magnetization of 31.56 (emu/g). The catalyst showed excellent reusability up to 80 % for 6 consecutive cycles. The turnover frequency of the catalyst was ascertained to be 0.011 mol g−1.h−1, which measures the ability to drive biodiesel synthesis. The conversions from CO to biodiesel were validated via FTIR and GC–MS analysis. It is essential to highlight that biodiesel’s key fuel properties align with the standards set by ASTM D6751, indicating promising prospects for its future industrial use. The life cycle cost analysis of the catalyst and biodiesel, i.e., USD 0.533/kg and USD 1.005/L, indicates excellent potential for commercialization. Lastly, using creative bibliometric analysis to identify the gaps in the literature, the study made recommendations for the synthesis of biodiesel utilizing nanocatalyst.

Biosynthesis and screening of cobalt nanoparticles using citrus species for antimicrobial activity

Abstract The synthesis of the nanomaterial is crucial for its characteristics, as well as physiological features. Green nanoparticle production, which reduces metal ions using natural extracts rather than industrial chemical agents, has been created to lower costs, minimize pollution, and improve environmental and human health safety. An aqueous and methanolic extract of a combination of Citrus sinensis and Citrus limetta peel was utilized for the green synthesis of cobalt nanoparticles. UV–Visible, Fourier-transform Infrared, X-ray diffraction (XRD), scanning of electron microscopy (SEM) and other techniques were employed to describe the prepared cobalt nanoparticles. The crystal structure of cobalt nanoparticles was revealed by XRD study. The SEM images of the cobalt nanoparticles revealed the usual subdivision dimensions of 20–30 nm. Using the well diffusion method, the antibacterial activity of the crude extract derived from the combination of the two plants mentioned above and the biosynthesized cobalt nanoparticles was assessed. The result showed that the crude extract and cobalt nanoparticles exhibited antibacterial activity and cobalt nanoparticles exhibited much higher activity than the crude extract. Overall, these findings revealed that formulated cobalt nanoparticle treatment considerably prevented the development of different micro-organisms.

Influence of reaction parameters on biofuels derived from solvothermal liquefaction of Citrus limetta fruit wastes

Citrus limetta or sweet lime is a widely consumed fruit worldwide. The wastes generated from their processing are enormous and are discarded without any value-addition. Biomass liquefaction in hydrogen-donor solvent is an effective thermochemical conversion technique to produce value added products such as biocrude and biochar from wet biomasses directly. Thus, liquefaction studies of Citrus limetta peel and pulp were conducted using solvent methanol at temperatures of 240 °C–280 °C, 30 min residence time as well as 1:2, 1:3 and 1:4 ratios of biomass to solvent. The impact of temperature as well as biomass to solvent ratio on yield of biocrude and biochar were investigated herein. Biocrude produced from Citrus limetta peel at 240 °C and 1:3 ratio of biomass to solvent is maximum (12.5 wt. %). At reaction parameters of 280 °C and 1:4 ratio of biomass to solvent, biocrude from Citrus limetta pulp showed higher heating value of 27.18 MJ kg−1 which was the maximum obtained in this study. The gas-chromatography mass-spectrometry (GC-MS) indicated presence of alcohols, phenols, alkanes, ketones, ethers, esters and fatty acid methyl esters as major compounds. The characteristics and energy content of biochar demonstrated their potentiality for bioenergy applications.

Citrus limetta peels derived carbon dots as highly active carbocatalyst for carbon–carbon bond formation

Citrus limetta peels derived carbon dots as highly active carbocatalyst for carbon–carbon bond formation

Sustainable removal of Pb (II) from aqueous medium by using chitosan functionalized Citrus limetta peels biomass

In this investigation, chitosan functionalized Citrus limetta peel biomass (ChCLP) was synthesized for adsorption of Pb (II). Results of energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopic (XPS) confirmed the chitosan coating and adsorption of Pb (II). Functional groups like -NH2, C-H and -OH groups were present on the ChCLP surface. The surface of ChCLP was observed to be rough and porous. Langmuir isotherm was best fitted in the adsorption data. This indicated toward the monolayer adsorption of Pb (II) onto the homogeneous surface of the adsorbent. The suitability of pseudo-second order (PSO) kinetic model indicated chemisorption of Pb (II) onto ChCLP. Thermodynamic study revealed endothermic and spontaneous Pb (II) adsorption. Values of the diffusion coefficient and dimensionless numbers indicated that Pb (II) adsorption was mix diffusion and transfer controlled. It was found that both the experimental and predicted values for ChCLP was close to each other showing a high R 2 value in the range of 0.94 − 0.98. Results showed that ChCLP has high Pb (II) removal capacity (99.8%) at 100 mg/L and 10 g/L ChCLP dosage. ChCLP adsorbent showed a high regeneration capacity in five consecutive adsorption-desorption cycles.

Adsorption characteristics of magnetized biochar derived from Citrus limetta peels

Agro-industrial waste is an alarming issue that needs to be addressed. Waste valorization is an effective technique to deal with such effectively. Synthesis of biochar from fruit waste is one of the emerging approaches for adsorption, energy storage, air purification, catalysis, and biogas production trending these days. Magnetized Citrus limetta biochar (MCLB) was synthesized from Citrus limetta peels and was magnetized using iron oxide. Magnetization of biochar increases its functionalities as well as makes its separation easy. The removal of Methylene Blue (MB) dye from an aqueous solution is achieved through the use of MCLB. Methylene Blue is a prominent and widely used cationic-azo dye in the textile and printing industries. The accumulation of MB in wastewater is the major problem as MB is reported as a carcinogenic agent. The removal of MB dye with MCLB was analyzed by adsorption studies, wherein the effect of factors influencing adsorption such as initial concentration of MB dye, MCLB dosage, the effect of pH, contact time, and adsorption isotherms were studied. Characterization of MCLB was carried out using various techniques, such as FTIR, VSM, XRD, SEM, RAMAN, and Zeta potential. The adsorption isotherm mechanism was well explained with the non-linear Langmuir isotherm model resulting in a good adsorption capacity (qe = 41.57 mg/g) of MCLB when MB (co = 60 mg/L, pH ~ 6.8, T = 273K). The thermodynamics analysis revealed that MB's spontaneous and endothermic adsorption onto the MCLB surface followed pseudo-second-order kinetics. The results obtained from this study suggest that the magnetized biochar derived from Citrus limetta peels has a wide range of potential applications in the treatment of dyeing wastewater.

Bio-functionalized, elongated hexagonal bi-pyramidal, citrus limetta/ZnO nanostructures as potential photocatalytic and seed germinating agents

In this research, the photocatalytic and seed germination potentials of bio-functionalized, as-synthesized zinc oxide (ZnO) nanoparticles (NPs) were investigated. ZnO NPs were created by reducing zinc acetate hexahydrate with a citrus limetta (C. limetta) peel extract. The hexagonal wurtzite crystal was observed in C. limetta/ZnO NPs, with crystallite diameters ranging from 50 to 60 nm and an energy-band gap of 3.08 eV. Fourier-transform infrared spectrum confirmed the presence of phytochemicals from C. limetta on the surface of the resultant ZnO. The unique, elongated hexagonal bi-pyramidal nanostructures were spread evenly across a vast region, as validated by High-resolution transmission electron microscopy and field emission scanning electron microscope. The highly porous microstructure of C. limetta/ZnO and its large specific surface area of 80.72 m2 g−1 were established by Brunauer–Emmett–Teller analysis. The catalytic performance of C. limetta/ZnO for the decomposition of the industrial reactive yellow 18 dye (RY18) was examined. Under UV light, RY18 dye could be broken down by more than 98% in 100 min. With a minimal energy consumption of 4.34 × 1022 J mol−1, the C. limetta/ZnO NPs demonstrated excellent performance (a quantum yield of 1.79 × 10−4Ϣ and a figure-of-merit of 2.92 × 10−10 mol l J−1g−1h−1). The seed germinating capability of C. limetta/ZnO was investigated first time for the Brassica juncea crop. The germination and development of Brassica juncea seed were greatly enhanced by priming with C limetta/ZnO. Hence, C. limetta/ZnO NPs are identified as photocatalytic and seed-germinating agents with remarkable efficiency.

Suitability evaluation of Citrus limetta peel powder as a filler in fiber-reinforced plastics

Suitability evaluation of Citrus limetta peel powder as a filler in fiber-reinforced plastics

Extraction of bio-fillers from natural solid wastes (citrus limetta peel) and characterization of the physical, mechanical, and tribological performance of sustainable biocomposites

Extraction of bio-fillers from natural solid wastes (citrus limetta peel) and characterization of the physical, mechanical, and tribological performance of sustainable biocomposites

Enhanced shelf-life of peach fruit in alginate based edible coating loaded with TiO2 nanoparticles

This study was conducted to determine the effects of nanoparticle based edible coatings on post-harvest quality of peach fruits during 7 days storage at ambient temperature. The edible coatings consisted of sodium alginate (SA) supplemented with green synthesized titanium dioxide (TiO2) nanoparticles and mousami peel extract (MPE). TiO2 nanoparticles with diameters ranging from 5 nm to 20 nm were synthesized with Citrus limetta (mousami) peel extract. The structural analysis of TiO2 nanoparticles were studied by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and Transmission electron microscopy (TEM). The optical properties were studied by UV-VIS spectroscopy which confirmed the anatase phase of TiO2 nanoparticles. Different nanoemulsion coatings of SA, SA-TiO2 nanoparticles (SA-NT) and SA-NT-MPE were developed to study various post-harvest quality attributes of peaches. Coating treatment significantly reduced percent weight loss, retained antioxidant activity and ascorbic acid content than control samples. The coating had a significant (p<0.05) impact on polyphenol oxidase activity, titratable acidity and firmness of peach samples during storage. Similarly, coated peach samples retained color index and slowed down the yeast and mold count during the storage period. At the end of the storage period, coated samples with coating solutions containing TiO2 nanoparticles and MPE exhibited the lowest yeast and mold counts (4.17 ± 0.12 log10 cfu g−1) whereas uncoated peach samples showed the highest yeast and mold counts (7.15 ± 0.09 log10 cfu g−1). Therefore, this study demonstrated the ability of nanoemulsion as coating agent in maintaining the quality and extending the self-life of peach fruit for up to 7 days at ambient temperature.

Potential of Citrus limetta peel powder (CLPP) for adsorption of hazardous Congo red dye from wastewater

Abstract In this study, Congo red anionic dye was removed from an aqueous solution using powdered Citrus limetta peel. The adsorbent was evaluated with the use of FTIR and SEM. The highest dye removal was achieved when the operating parameters were optimized, including pH = 6.0, adsorbent dose = 0.4 g, contact time = 90 min, initial adsorbate conc. = 10 ppm, and temperature = 60 °C. The pseudo-second-order model was investigated to have the best fit for the kinetics of the process, with R2 = 0.9918 and Qe(cal) = 0.206 mg g-1, which is very close to the experimental Qe(exp) = 0.191 mg g-1. These two models’ plots showed that both physical and chemical adsorption were feasible. ΔG and ΔH being negative suggest that the adsorption was thermodynamically favorable and spontaneous. Testing the suggested technique with groundwater resulted in an 82% CR adsorption efficiency. Due to the incredible removal capacity of CR dyes from industrial effluents, research suggests that CLPP can be used as substitute adsorbents for the treatment of wastewater from the weaving and dyeing industries.