Choice Of Feedstock Research Articles

Assessing the environmental footprint of alternative green biorefinery protein extraction techniques from grasses and legumes

The significant grasslands of Europe and its member states represents a significant feedstock opportunity for circular bioeconomy development. The development of green biorefineries (GBR), to supply protein for the feed industry from grass, could help many European member states to address significant deficits in protein availability and reduce imports. The current study assesses the environmental footprint of alternative GBR protein extraction techniques from grasses and legumes using life cycle assessment. The focus is on comparing feedstock and technology pathways that could displace soya bean imports. The study finds that leaf protein concentrate (LPC) produced from grass had an improved environmental performance when compared to soya bean meal (SBM), across the assessed feedstock (perennial ryegrass or grass-clover mixtures) and technology pathways (one-stage maceration versus multi-stage maceration). For example, in the case of Climate Change the emission intensity for LPC was 57–85 % lower per tonne of crude protein (CP) compared with SBM. Acidification burdens were 54–88 % lower, and Eutrophication: Freshwater burdens were 74–89 % lower. Some scenarios of GBR produced LPC with a larger Energy Resources: Non-Renewable burden than SBM, though this could be mitigated with higher renewable energy (biogas and wind energy) integration within the scenario. Grass-clover scenarios generally achieved a lower intensity of emissions compared to ryegrass scenarios, particularly in the category of Climate Change, where feedstock cultivation represented a significant contributor to impacts. Overall, GBR can produce high quality protein with a lower environmental burden than SBM, but choice of feedstock and system design are critical factors for overall environmental performance.

Biodiesel production and characteristics from waste frying oils: sources, challenges, and circular economic perspective.

Biodiesel serves as a viable alternative to traditional diesel due to its non-toxicity, biodegradability, and lower environmental footprint. Among the diverse edible and inedible feedstocks, waste frying oil emerges as a promising and affordable feedstock for biodiesel production. Commonly waste frying oils include those derived from palm, corn, sunflower, soybean, rapeseed, and canola. The primary challenge related to biodiesel production technologies is the high production cost, which poses a significant barrier to its widespread adoption. Thus, refining the production techniques is essential to enhance yield, reduce capital expenditure, and curtail raw material expenses. An examination of the research focusing on feedstock availability, production, hurdles, operational expenditures, and future potential is pivotal for identifying the most economically and technically viable solutions. This paper critically reviews such research by exploring feedstock availability, production techniques, challenges, and costs intrinsic to biodiesel synthesis. It also underscores the economic feasibility of biodiesel production, shedding light on the pivotal factors that influence profitability, especially when leveraging waste frying oils. Through an in-depth understanding of these considerations, optimal production and feedstock choices for biodiesel production can be identified. Addressing cost and production bottlenecks could potentially enhance the economic viability of waste frying oil-based biodiesel, thus fostering both environmental sustainability and more extensive adoption of biodiesel as an environmental-friendly fuel in the future.

Cellulose nanofibre films as a substitute for plastic packaging: A comparative environmental life cycle assessment

Accumulation of synthetic food packaging in the natural environment has increased considerably in last few decades, posing serious concerns to human and aquatic life. Hence, substituting synthetic packaging with biobased packaging is one viable option. Cellulose nanofibres can easily be transformed into films, which could be a suitable alternative for petroleum-derived packaging. However, production of these films consumes a significant amount of energy as compared with the synthetic packaging. The main contributors for this high energy consumption are associated with the treatment of pulp, production of fibres and drying of films. This study analyzes the environmental impacts (in terms of energy and water) of spray deposited cellulose nanofibre films and its key drivers through an attributional cradle-to-gate life cycle assessment. Different scenarios were formulated and studied in terms of waste feedstock choice, solid content, forming composite of cellulose nanofibres, and location (Australia, China, Germany, Great Britain and United States of America). The results indicate that the environmental impacts of spray deposited cellulose nanofibre films based on a baseline scenario for a large-scale production were still higher as compared with petroleum-based synthetic packaging. However, establishing a recommended scenario from the studied scenarios could lower the environmental impacts significantly (two to five times) in comparison to synthetic food packaging. This life cycle assessment model has the potential to support the reduction of the environmental impact of the studied green chemistry option and to accelerate the transition towards more sustainable packaging.

Feedstock and pyrolysis temperature influence biochar properties and its interactions with soil substances: Insights from a DFT calculation

The use of biochar for soil improvement and emission reduction has been widely recognized for its excellent performance. However, the choice of feedstock and pyrolysis temperature for biochar production significantly affects its surface parameters and interactions with soil substances. In this study, we retrieved 465 peer-reviewed papers on the application of biochar in reducing greenhouse gas emissions and nutrient losses in soil and analyzed the changes in biochar physicochemical parameters from different feedstock and pyrolytic temperatures. Molecular simulation computing technology was also used to explore the impacts of these changes on the interaction between biochar and soil substances. The statistical results from the peer-reviewed papers indicated that biochar derived from wood-based feedstock exhibits superior physical characteristics, such as increased porosity and specific surface area. Conversely, biochar derived from straw-based feedstock was found to contain excellent element content, such as O, N, and H, and biochar derived from straw and produced at low pyrolysis temperatures contains a significant number of functional groups that enhance the charge transfer potential and adsorption stability by increasing surface charge density, charge distribution and bonding orbitals. However, it should be noted that this enhancement may also activate certain recalcitrant C compounds and promote biochar decomposition. Taken together, these results have significant implications for biochar practitioners when selecting suitable feedstock and pyrolysis temperatures based on agricultural needs and increasing their understanding of the interaction mechanism between biochar and soil substances.

Improving acid-stressed anaerobic digestion processes with biochar - towards a combined biomass and carbon management system

Abstract Interest in biochar as an additive to enhance anaerobic digestion (AD) has grown in the context of biomass cascading use and the 2050 net-zero goal. However, few studies have investigated the effects of biochar on AD from a biochar production perspective, including biomass feedstocks and pyrolysis temperatures. To valorise biomass and better understand the mechanisms and environmental implications of using biochar in AD, we investigated the effects of distinct biochar types on AD under acid stress-induced process inhibition using batch tests. The results demonstrated that biochar can mitigate acid stress and enhance the methane production rate. The kinetic rate constant of methane production is positively related to the buffer capacity of the tested biochars (R2 = 0.88). The choice of feedstocks is a crucial factor (P = 0.003), particularly the best-performing biochars derived from raw grass silage. In contrast, the pyrolysis temperature effect was less significant (P = 0.18). Furthermore, the analysis of biochar indicates that the alkali (K) and alkaline earth (Ca, Mg) metals contained in biochar may be one of the important factors contributing to buffer capacity (R2 = 0.82 to 0.86). Hence, buffer capacity is a crucial quality criteria when evaluating biochar for AD applications. Raw grass silage biochars are promising for acid stress mitigation due to their high buffer capacity, while carbon-rich woody biochars have high CO2 sequestration potential. A compromise between mitigating acid stress and sequestering carbon is the use of pre-treated grass biochar. Overall, the use of biochar-enriched digestate offers a potential way to close material loops and complete the biomass-to-biochar value chain.

Characterization and Remediation Potential of Sorghum and Rice Straw-Derived Biochars on Incubated Spent-Oil Contaminated Soil

The volume and spread of spent lubricants that are indiscriminately let into the environment in developing countries are prohibitive for soil health and productivity, adversely altering soil structure, permeability and microbiota. These result to loss of arable lands and low vegetation cover, thereby contributing significantly to food insecurity and global warming. Biochars possess sustainable soil amendment potentials that depend on the choice of feedstocks. This study used suitable analytical techniques to characterize biochars derived from sorghum and rice straw after slow pyrolysis at 550°C for three hours and investigated their effects on the physicochemical properties of spent oil-contaminated soil in an incubation experiment. Both sorghum biochar (SB) and rice biochar (RB) have pH in the alkaline range (˃ 8.0), similar O/C ratio (0.24), and significant proportions of carbon (53.87–57.57%). Scanning electron microscopy of SB and RB surfaces revealed presence of porous structures. Fourier Transform Infrared Spectroscopy revealed presence of carboxyl, hydroxyl, halogens, and sulphur on the surfaces of SB and RB which are responsible for heavy metal adsorption. Compared with control, increasing biochar amendment at 1, 2 and 3% significantly increased the porosity, water holding capacity and pH of the soil. Besides, soil Fe increased while the extractable content of heavy metals decreased. From this study, the properties of SB and RB and corresponding application in spent oil-contaminated soil indicate their suitability for soil enrichment and amendment.

Sveobuhvatni pregled potencijala proizvodnje biogasa od biomase u Šri Lanci

Biogas has emerged as a renewable energy option that offers a wide range of advantages. This study assesses the appropriateness of a range of biomass feedstock choices, encompassing energy crops, bio-waste, materials derived from both animals and plants, as well as organic residues produced within the food production sector. The aim is to determine their potential as viable substrates for agricultural biogas plants in Sri Lanka. Nevertheless, administrative obstacles and inefficiencies within the existing facilities impede the complete utilization of this potential. In parallel, it is of paramount importance to develop and enhance cost-effective technologies for converting agricultural biomass into energy, all while avoiding conflicts with the food and animal feed industries. Consideration should be given to judiciously utilizing disputed resources like fresh fruits and vegetables as raw materials. When employing biomass for energy generation, factors like economic viability, resource availability, and storage need to be meticulously assessed. Additionally, this review proposes that conducting a life cycle assessment within Sri Lanka's energy sector is both feasible and essential for comparing the energy potential of biomass-based sources with conventional fossil fuels. Such an evaluation can offer invaluable insights into sustainable energy choices for the nation's future.

Activation methods increase biochar's potential for heavy-metal adsorption and environmental remediation: A global meta-analysis

Removal of heavy metals (HMs) by adsorption on biochar's surface has shown promising results in the remediation of contaminated soil and water. The adsorption capacity of biochar can be altered by pre- or post-pyrolysis activation; however, the effect of activation methods on biochar's adsorption capacity varies widely. Here, we conducted a meta-analysis to identify the most effective methods for activation to enhance HM removal by biochar using 321 paired observations from 50 published articles. Activation of biochar significantly improves the adsorption capacity and removal efficiency of HMs by 136 and 80 %, respectively. This study also attempts to find suitable feedstocks, pyrolysis conditions, and physicochemical properties of biochar for maximizing the effect of activation of biochar for HMs adsorption. Activation of agricultural wastes and under pyrolysis temperatures of 350–550 °C produces biochars that are the most effective for HM adsorption. Activation of biochars with a moderate particle size (0.25–0.80 mm), low N/C (<0.01) and H/C ratios (<0.03), and high surface area (> 100 m2 g−1) and pore volume (> 0.1 cm3 g−1) are the most desirable characteristics for enhancing HM adsorption. We conclude that pre-pyrolysis activation with metal salts/oxides was the most effective method of enhancing biochar's potential for adsorption and removal of a wide range of HMs. The results obtained from this study can be helpful in choosing appropriate methods of activations and the suitable choice of feedstocks and pyrolysis conditions. This will maximize HM adsorption on biochar surfaces, ultimately benefiting the remediation of contaminated environments.

Rheology, crystallization, and process conditions: The effect on interlayer properties in three-dimensional printing

Semicrystalline polymers are an attractive feedstock choice for material extrusion (MatEx)-based three-dimensional printing processes. However, the printed parts often exhibit poor mechanical properties due to weak interlayer strength thereby limiting the widespread adoption of MatEx. Improved interlayer strength in the printed parts can be achieved through a combination of process parameter selection and material modification but a physics-based understanding of the underlying mechanism is not well understood. Furthermore, the localized thermal history experienced by the prints can significantly influence the strength of the interlayer welds. In this work, a combined experimental and modeling approach has been employed to highlight the relative impact of rheology, non-isothermal crystallization kinetics, and print geometry on the interlayer strength of printed parts of two semicrystalline polymers, namely, polylactic acid (PLA) and polypropylene (PP). Specifically, the print properties have been characterized as a function of print temperature and print speed. In the case of single road width wall (SRWW) PLA prints, the total crystalline fraction increases due to the broadening of the crystallization window at higher print temperatures and lower print speeds. The results are substantiated by the constitutive modeling results that account for the effects of quiescent crystallization. However, SRWW PP prints display a reduction in the interlayer properties with temperature likely due to significant flow-induced crystallization effects, as suggested by the model. Interestingly, in the case of multilayer PP prints, the repeated heating/cooling cycles encountered during printing counteracts the flow-induced effects leading to an increase in mechanical properties with print temperature consistent with SRWW PLA prints.

Plasma spraying porous thermal barrier coatings with high deposition efficiency: A solvable dilemma?

In addition to the selection of suitable materials, another way to lower the thermal conductivity and improve thermal cyclic performance of ceramic thermal barrier coatings is to produce microstructures with high porosity reaching up to 20 vol%, sometimes even more. The way to achieve this is by selecting suitable process parameters for plasma spraying, e.g. a low plasma enthalpy or a large spraying distance. The choice of the powder feedstock also plays a role. This attempts to melt the powder particles only partially, so that voids are not completely filled between the deposited splats. Hereby, the desired porosity is formed in the layer. Naturally, however, this is typically associated with losses in deposition efficiency. This dilemma is difficult to solve.In this work, spraying experiments were performed in which several process parameters were varied. An argon‑hydrogen mixture was used as plasma gas for the cascaded three-cathode torch. Porosities were obtained by image analysis and, for some samples, also by mercury intrusion; deposition efficiencies were determined gravimetrically. The resulting porosities and deposition efficiencies were combined in an evaluation function to compare different process parameters with respect to their effects on these two target parameters. The results show that the dilemma of optimizing porosity and deposition efficiencies simultaneously could only be solved well to a limited extent. This makes a systematic approach all the more important in order to identify optimum parameter sets within the bounds of what is possible.

Biochar for Supercapacitor Application: A Comparative Study.

Biochar is a carbon-rich solid that can be prepared through heat treatment of biomass under an inert atmosphere. In the present work, biochar prepared from different feedstocks, namely, Litchi chinensis (Litchi) seeds, Syzygium cumini (Jamun) seeds, and pine cone, were evaluated for charge storage in the form of supercapacitors. The physicochemical and electrochemical properties of the biochar were highly dependent on the preparation temperature and the choice of feedstock. Among the three feedstocks, Litchi seed-derived biochar showed the highest specific capacitance of 190 F g-1 at 1 A g-1 in a symmetric cell configuration. N and O heteroatom functionalities in the Litchi seed-derived biochar, higher specific surface area, and pore volume for electrolyte adsorption were responsible for its superior capacitive performance as compared to Jamun seeds and pine cone biochar.

Features of obtaining metallurgical products in the solid-state hydride synthesis conditions

A scientific substantiation of solid-phase feedstock choice and preparation has been carried out, and the thermodynamic and kinetic aspects of solid-state hydride synthesis (SHS) of metal products have been analyzed using the nickel dichloride reduction as an example. The preliminary dehydration modes and methods for controlling the complete removal of crystalline water from chloride raw materials and Olenegorsk superconcentrate, which is natural oxide raw material, are described. Conditions, including initial solid chloride particle sizes, are established under which diffusion complications of reduction to metal in methyldichlorosilane vapor are minimized. Thermodynamic estimates of nickel chlorides and oxides reduction possibility, iron and copper with ammonia and methane at temperatures of 400-1000 K in equilibrium conditions have been carried out. It has been shown that the stoichiometric coefficients of the nickel dichloride in ammonia overall reduction reaction calculated by thermodynamic modeling are in agreement with experimental data. In contrast to the copper dichloride reduction, for nickel dichloride the formation of metal monochloride at the intermediate stage is uncharacteristic, which is associated with a higher thermal stability of nickel dichloride. The main kinetic regularities of the reduction of nickel, copper, and iron to metal under SHS conditions in ammonia, monosilane, and methane, as well as the nickel dichloride with methyldichlorosilane vapor and methane successive reduction, are considered. Approximation of experimental data by topochemical equations in a linear form showed that for reduction degrees a up to 0.7-0.8, these data are satisfactorily described by the Roginsky – Schultz equation. For a &gt; 0,8 the “shrinking sphere” model works better, which confirms the localization of the solid-state reduction reaction at the interface, moves deep into the crystal with the formation of a of interlocked metal germs. The importance and prospects of the results obtained for the theory development of metallurgical processes, deep complex processing of natural iron oxide raw materials, metal products and new generation materials production, including superhydrophobic ones, are discussed. The relevance of the study from the point of view of applying the method of physical and chemical analysis to the study of complex heterogeneous metallurgical processes is noted.

Anaerobic Co-Digestion of Human Feces with Rice Straw for Biogas Production: A Case Study in Sunyani

The choice of feedstock for biogas production should not only be limited to organic waste like agricultural products, food, and animal waste. Human feces could also be considered a source of biogas production. The ever-increasing cost of fossil fuels and environmental pollution threats are forcing the search for alternative energy sources. Several types of research have to unlock the mysteries behind the difficulties of producing biogas from human feces, especially the production of more HN3, which is a greenhouse gas because of its low C:N ratio. This research experimentally investigated how to reduce their amount using rice straw with a high C:N ratio. Several combinations were made between the human waste and the rice straw at different ratios during the experiment. The result shows that the optimal outcome for methane production fell on the 50% HF and 50% RS combination due to the actions of both aerobic and anaerobic processes.

Conversion of Reactive Carbon Solutions into CO at Low Voltage and High Carbon Efficiency.

Electrolyzers are now capable of reducing carbon dioxide (CO2) into products at high reaction rates but are often characterized by low energy efficiencies and low CO2 utilization efficiencies. We report here an electrolyzer that reduces 3.0 M KHCO3(aq) into CO(g) at a high rate (partial current density for CO of 220 mA cm–2) and a CO2 utilization efficiency of 40%, at a voltage of merely 2.3 V. These results were made possible by using: (i) a reactive carbon solution enriched in KHCO3 as the feedstock instead of gaseous CO2; (ii) a cation exchange membrane instead of an anion exchange membrane, which is common to the field; and (iii) the hydrogen oxidation reaction (HOR) at the anode instead of the oxygen evolution reaction (OER). The voltage reported here is the lowest reported for any CO2 to CO electrolyzer that operates at high current densities (i.e., a partial current density for CO greater than 200 mA cm–2) with a CO2 utilization efficiency of greater than 20%. This study highlights how the choice of feedstock, membrane, and anode chemistries affects the rate and efficiency at which CO2 is converted into products.

A new bioenergy model that simulates the impacts of plant‐microbial interactions, soil carbon protection, and mechanistic tillage on soil carbon cycling

AbstractAdvancing our predictive understanding of bioenergy systems is critical to design decision tools that can inform which feedstock to plant, where to plant it, and how to manage its production to provide both energy and ecosystem carbon (C) benefits. Here, we lay the foundation for that advancement by integrating recent developments in the science of belowground processes in shaping the C cycle into a new bioenergy model, FUN‐BioCROP (Fixation and Uptake of Nitrogen‐Bioenergy Carbon, Rhizosphere, Organisms, and Protection). We show that FUN‐BioCROP can approximate the historical trajectory of soil C dynamics as natural ecosystems were successively converted into intensive agriculture and bioenergy systems. This ability relies in part on a novel tillage representation that mechanistically models tillage as a process that increases microbial access to C. Importantly, the impacts of tillage and feedstock choice also influence FUN‐BioCROP simulations of warming responses with no‐till perennial feedstocks, miscanthus, and switchgrass, having more C that is unprotected and susceptible to warming than tilled annual feedstocks like corn–corn–soybean. However, this susceptibility to warming is balanced by a greater potential for increases in belowground C allocation to enhance soil C stocks in perennial systems. Collectively, our model results highlight the importance of belowground processes in evaluating the ecosystem C benefits of bioenergy production.

A short review on approach for biodiesel production: Feedstock’s, properties, process parameters and environmental sustainability

Over the past few decades, an increase in industrialization and the population have been indicated as being critical to the need for energy. Higher pollution levels and rising fuel prices go hand in hand with the increasing demand for renewable energy. Apart from global warming, research interests were encouraged to develop sustainable fuels such as biodiesel, which is a renewable and sustainable substitute for petroleum diesel fuel. Biodiesel is produced from either oil derived from vegetables or animal fats via a catalytic transesterification process. Biodiesel has a few important advantages, such as stronger lubricity, a low level of toxicity, being derived from renewable feedstock, bio-degradability, low sulphur content, and lower levels of exhaust emissions than petroleum diesel fuel. In this comprehensive review, the approach to the biodiesel production process is discussed. This paper also described the benefits and drawbacks of biodiesel, the choice of different feedstock’s, factors (process parameters) that affect biodiesel yield, and research conducted on various aspects of biodiesel properties in various regions around the world. Additionally, it explains the various biodiesel blends, economic and sustainable development, and future challenges associated with biodiesel production.

Recycled Paper as a Source of Renewable Jet Fuel in the United States

Converting biomass into jet fuel involves more than the core chemical process. The overall process includes the logistics of harvesting and transporting the biomass, handling and preparing the material for processing, and processing and disposal of waste. All of these activities contribute to cost. Controlling cost involves more than developing efficient process chemistry. Choice of feedstock also has a significant impact on process economics. We consider chemical conversion of paper from municipal solid waste as a feedstock for the production of jet fuel and diesel. Paper has a significantly higher cellulose content than raw lignocellulosic biomass such as corn stover, so it requires less pretreatment to convert it into hydrocarbons than lignocellulosic biomass. Our techno-economic analysis showed that the cost of converting paper waste into jet fuel is about $1.00/gal less than jet fuel produced from corn stover. Although the cost of recycling paper into jet fuel is less than producing it from corn stover, the process is not competitive with petroleum. We estimated a minimum selling price of $3.97/gal for paper-derived jet fuel. Our sensitivity studies indicated that the biggest economic obstacle is the cost of cellulose hydrolysis. Direct hydrogenation of paper to sugar alcohols combined with increased economy of scale could make recycling paper jet fuel competitive.

Microbial hosts for metabolic engineering of lignin bioconversion to renewable chemicals

This review discusses the use of engineered microbes for bioconversion of lignin from plant biomass to produce renewable chemicals. Existing bacterial hosts for lignin bioconversion are discussed, such as Pseudomonas putida KT2440 and Rhodococcus jostii RHA1, and case studies where they have been engineered to generate aromatic and non-aromatic products are described, and the different types of lignin substrates used for these studies. Other bacteria identified as lignin degraders are described, and the prospects for using other bacteria as hosts for metabolic engineering of lignin degradation are discussed. Recent advances in genetic modification of fungi are also discussed, which could lead to the metabolic engineering of lignin-degrading fungi for bioproduct formation from lignin. Prospects and challenges in this field are discussed, as the field moves from the laboratory to industrial application, including: choice of chassis organism, choice of lignin feedstock, the complexity of polymeric lignin breakdown, and considerations for scale-up and choice of bioproduct.

Risk Analysis on PMMA Recycling Economics.

Poly(methyl methacrylate) (PMMA) is a versatile polymer with a forecast market of 4 Mtons/y by 2025, and 6 USD billion by 2027. Each year, 10% of the produced cast sheets, extrusion sheets, or granules PMMA end up as post-production waste, accounting for approximately 30 000 tons/y in Europe only. To guide the future recycling efforts, we investigated the risks of depolymerization process economics for different PMMA scraps feedstock, capital expenditure (CAPEX), and regenerated MMA (r-MMA) prices via a Monte-Carlo simulation. An analysis of plastic recycling plants operating with similar technologies confirmed how a maximum 10 M USD plant (median cost) is what a company should aim for, based on our hypothesis. The capital investment and the r-MMA quality have the main impacts on the profitability. Depending on the pursued outcome, we identified three most suitable scenarios. Lower capital-intensive plants (Scenarios 4 and 8) provide the fastest payback time, but this generates a lower quality monomer, and therefore lower appeal on the long term. On 10 or 20 years of operation, companies should target the very best r-MMA quality, to achieve the highest net present value (Scenario 6). Product quality comes from the feedstock choice, depolymerization, and purification technologies. Counterintuitively, a plant processing low quality scraps available for free (Scenario 7), and therefore producing low purity r-MMA, has the highest probability of negative net present value after 10 years of operation, making it a high-risk scenario. Western countries (especially Europe), call for more and more pure r-MMA, hopefully comparable to the virgin material. With legislations on recycled products becoming more stringent, low quality product might not find a market in the future. To convince shareholders and government bodies, companies should demonstrate how funds and subsidies directly translate into higher quality products (more attractive to costumers), more economically viable, and with a wider market.

A relative assessment of chromatographic and spectroscopic based approaches to predict engine fuel properties of biodiesel

Biodiesel produced from renewable sources is known to reduce carbon footprint compared to fossil diesel and thus, has a more significant potential for compression ignition engine applications. Unlike diesel, biodiesel can be produced from various sources and, thereby, subjected to composition variability. A priori knowledge of engine fuel properties of biodiesel would allow a careful feedstock choice for producing biodiesel for automotive and stationary engine applications. Regression models to predict engine fuel properties of biodiesel from its composition using Chromatographic and Spectroscopic-based approaches are explored in the present study to develop the most suitable method. Regression models are developed using composition and Fourier Transform Infrared spectra of seventy biodiesel samples. The composition of the seventy biodiesel samples measured using gas chromatography is correlated with the properties using multilinear regression. In the Spectroscopic-based approach, the seventy biodiesel samples' mid-infrared spectra are correlated with the properties using partial least square regression. The developed regression models based on Chromatographic and Spectroscopic approaches are validated using 33 external validation biodiesel samples. The results obtained show that the calorific value, cetane number, density, and kinematic viscosity of biodiesel samples are predicted with a mean absolute percentage error of 1.16%, 4%, 0.76%, and 2.6%, respectively, using the Chromatographic approach while it is 3.17%, 4.59%, 0.73%, and 3.66%, respectively with Spectroscopic method. The chromatographic approach, which resulted in better prediction than the Spectroscopic method, also captures biodiesel composition variations on the engine fuel properties.