Chloride Permeability Research Articles

Assessment of the self-healing capacity of PVA fiber-reinforced composites by chloride permeability and stiffness recovery

This paper investigates the intrinsic ability of PVA fiber-reinforced cementitious composites to re-establish the durability properties of the uncracked state. Comparative chloride penetration tests are used as a direct measure to quantify the effect of self-healing on the chloride penetration resistance after cracking. Two different composites with cement to fly ash ratios of 1:1.5 and 1:2.0 were studied under the influence of healing periods of up to 28 days. After inducing cracks between 100 and 120 μm, samples were exposed to chlorides for 72 h and the resulting chloride penetration depth was compared to the unhealed state. Based on this procedure, a durability recovery index was proposed to quantify the material’s ability to re-establish its function as a protective layer after cracking. Results show that after 14 days of self-healing, chloride penetration through cracks was reduced between 81% and 99%. An extended healing period of 28 days leads to further reduction of the penetration depth to 84%–100%, indicating that most of the reaction takes place within the first 14 days of healing. While the stiffness recovery analysis showed that increasing cement content by 20% correlated with the formation of stronger healing products, no significant difference was found regarding crack closure.

Prediction Model for the Chloride Ion Permeability Resistance of Recycled Aggregate Concrete Based on Machine Learning

The chloride ion permeability resistance of recycled aggregate concrete (RAC) is influenced by multiple factors, and the prediction model for this resistance based on machine learning is still limited. In the paper, six impact factors (IFs), including the carbonation of recycled coarse aggregates (YN), the replacement ratio of recycled coarse aggregates (r), the bending load level (L), the carbonation time (t) and temperature (T) of RAC, and the replacement ratio of carbonated recycled fine aggregates (f), were considered to conduct a chloride penetration test on RAC. Based on the experimental data, four algorithms, including artificial neural network (ANN), support vector machine (SVM), random forest (RF) and extreme gradient boosting (XGBoost), were adopted to establish the machine learning prediction models and study the relationships between the electric flux of RAC and the IFs. The results showed that the predicted values of all four models were in good agreement with the experimental values, and the XGBoost model had the best prediction performance on the testing set. Based on the XGBoost model, the LIME method was adopted to solve the interpretability problem in the prediction process. The importance ranking of IFs on the electric flux was r > t > f > T > L > YN. A graphical user interface (GUI) was developed based on Python 3.8 software to facilitate the use of machine learning models for the chloride ion permeability resistance of RAC. The research results can provide an accurate prediction of the electric flux of RAC.

Experimental study on chloride ion permeability of carbonated recycled aggregate concrete considering the effects of multiple factors

The chloride ion permeability is an important index of durability of carbonated recycled aggregate concrete (CRAC), but the resistance to chloride ion permeability of CRAC is affected by many factors and has yet been fully explored, which needs further systematic study. Considering the effects of the replacement ratio of carbonated recycled coarse aggregate (CRCA), the carbonation time of CRAC, the bending load level, the carbonation temperature of CRAC, and the replacement ratio of carbonated recycled fine aggregate (CRFA), the resistance to chloride ion permeability of CRAC was investigated by conducting tests in this paper. The results indicated that, compared with the non-carbonated recycled aggregate concrete (NCRAC), the electric flux of CRAC decreased by 9.14% to 37.34%. An increase in the replacement ratio of CRCA could reduce the resistance to chloride ion permeability of CRAC, while an increase in CRAC carbonation time had a significant effect on improving the resistance to chloride ion permeability. When the replacement ratio of CRCA was 100%, as the carbonation time increased from 0 to 14 days, the maximum reduction in electric flux of CRAC was 31.66%. With the same replacement ratio of CRCA, as the bending load level increased, the decrease in electric flux of CRAC showed an increasing trend compared to that of NCRAC. The resistance to chloride ion permeability of CRAC could be improved with an increase in carbonation temperature. Compared with the CRAC with carbonation temperature of 20 °C, the electric flux of the CRAC with carbonation temperature of 40 °C decreased by 11.03%. When the replacement ratio of CRFA was in the range of 0 to 20%, the resistance to chloride ion permeability of CRAC could be improved by incorporating CRFA, but the improvement effect was not significant. Therefore, compared with the NCRAC, the resistance to chloride ion permeability of CRAC is enhanced, and the research results can provide data support for the engineering application of CRAC.

Effects of Na2SiO3/NaOH ratio in alkali activator on the microstructure, strength and chloride ingress in fly ash and GGBS based alkali activated concrete

In this study, the impact of alkaline solutions composed of various Na2SiO3/NaOH ratio and NaOH molarity on the strength, chloride ingress and chloride binding capacity of fly ash (FA) and ground granulated blast furnace slag (GGBS) based alkali activated concrete (AAC) was investigated. The microstructural properties of alkali activated binders (AAB) composites was also studied to understand its influence on the chloride permeability of AAC. Chloride permeability of concrete was tested by using the rapid chloride penetration test (RCPT) and by immersing concrete in NaCl solution (ASTM C1556). The compressive strength, chloride ingress and chloride binding capacity of AAC was compared with Portland cement-based concrete (OPC). Results showed that higher Na2O/SiO2 ratio in alkaline solutions resulted in a weak microstructure with, low strength and high chloride ingress. Concrete activated by alkaline solutions with Na2O/SiO2 molar ratio =1 (+3), exhibited greater compressive strength and resistance to chloride ion penetration. The increase of SiO2 concentration in alkaline solution greatly reduces the binding capacity of AAC while the bound chlorides increased with the NaOH molarity. No chemical chloride binding was observed in AAC but for OPC concrete, calcium salts formed in the microstructure after immersion in NaCl solution. Compared to OPC concrete, AAC showed superior performance in terms of strength and chloride diffusion making it a potential candidate for application in marine structures.

Effect of Waste PET Fiber on the Mechanical Properties and Chloride Ion Penetration of Emergency Repair Concrete for Road Pavement.

This study evaluated the effects of adding waste PET fibers on the mechanical properties and chloride ion penetration of latex-modified ultra-rapid hardening cement concrete used for emergency road pavement repairs. The primary experimental variable was the content of waste PET fibers. The mechanical properties of the concrete were evaluated through compressive strength, flexural strength, and splitting tensile strength tests. Its durability was evaluated through chloride ion penetration, surface resistivity, and abrasion resistance tests. The experimental results were compared with the quality standards for emergency repair concrete set by the Korea Expressway Corporation. As a result, this study has enhanced the strength and resistance to chloride ions of latex-modified concrete by incorporating waste PET fibers. In the mixture with 3.84 kg/m3 of waste PET fibers, the compressive strength was 29.9 MPa at 4 h and 42.5 MPa at 28 curing days. The flexural strength was 6.0 MPa at 4 curing hours and 7.0 MPa at 28 days, and the splitting tensile strength was 4.5 MPa at 28 days of curing. The chloride ion permeability amount and abrasion depth were 1081C and 0.82 mm, respectively. The mixture with 3.84 kg/m3 of waste PET fibers has superior compressive strength, flexural strength, splitting tensile strength, chloride ion penetration, and surface resistivity compared to the mixture with 7.68 kg/m3. This result means that the waste PET fibers caused poor dispersion and fiber-balling within the concrete, leading to loose internal void structures when incorporated at 3.84 kg/m3. However, the abrasion resistance test showed better results for the mixture with 7.68 kg/m3 of waste PET fibers than the 3.84 kg/m3 mixture. Therefore, the test results indicated that 3.84 kg/m3 of waste PET fibers is the most effective for latex-modified concrete used in emergency road pavement repairs.

Investigating the influence of various metakaolin combinations with different proportions of pond ash and Alccofine 1203 on ternary blended geopolymer concrete at ambient curing.

This paper explores the use of a ternary blended geopolymer concrete (TBGPC) incorporating metakaolin (MK), pond ash (PA), and Alccofine 1203 (AF). Three combinations of MK (25%, 50%, and 75%) with varying proportions of PA and AF were prepared, validating against M30 grade cement concrete (CC). TBGPC was prepared with an 8 molarity sodium hydroxide, sodium silicate to sodium hydroxide ratio of 2.0, liquid to binder ratio of 0.5, and an ambient curing mode. For CC, a water to cement ratio of 0.42 and water curing mode were adopted. The mechanical properties and durability behavior of TBGPC and CC specimens were evaluated through compressive strength, rapid chloride penetration test, permeability test, sorptivity test, and water absorption test. The M50P35A15 mix demonstrated remarkable compressive strength improvements, showing a 203% increase over the CC mix at 1day and 250% by 3days. This trend continued with a 155% increase at 7days, 68% at 28days, and 52% at 90days, consistently outperforming the CC mix. Additionally, microstructure characteristics of the M50P35A15 mix were analyzed through SEM studies, providing validation for the observed strength development. Notably, M50P35A15 mix demonstrated substantially higher early and later strength gain. This enhancement in strength was attributed to the gradual densification of the microstructure over time and the formation of additional NASH and CASH gel in M50P35A15 mix. At 28days, the M50P35A15 mix exhibited excellent durability characteristics, with a Coulomb value of 1008, permeability of 10mm, sorptivity of 0.45mm/√min × 10-4, and water absorption of 1.07%. This study demonstrates the potential of MK, PA, and AF as viable materials for sustainable geopolymer concrete, offering a low-carbon alternative to traditional cement concrete with superior strength and durability aspects.

Response tests on the effects of particle size of waste glass sand and glass powder on the mechanical and durability performance of concrete

To investigate the effect of waste glass material particle sizes on the mechanical and durability properties of concrete, a two-phase experimental approach was conducted. First, comprehensive tests were performed to examine the effects of glass sand and glass powder of different particle sizes on concrete performance. Subsequently, based on the experimental results, an orthogonal test was designed to optimize the replacement amounts of composite particle sizes. The results indicated that an appropriate amount of glass sand can enhance the mechanical properties and durability of concrete, while excessive amounts or larger particle sizes may have adverse effects. The pozzolanic effect of glass powder also contributes to performance improvement, but the replacement rate should be limited to 20%. Under composite particle size conditions, the compressive, tensile, and shear strengths of concrete increased by 35.56%, 21.74%, and 13.79%, respectively, while durability significantly improved, with water absorption reduced by 20.73% and chloride ion permeability decreased by 63.10%. At a total replacement rate of 20%, the optimal proportions were determined to be 2.86% for 0.6 mm glass sand, 1.43% for 1.18 mm glass sand, 8.57% for 50–60 μm glass powder, and 7.14% for 60–70 μm glass powder. The incorporation of composite particle sizes improved the microstructure of concrete, thereby enhancing its mechanical and durability properties.

A New Performance-Based Test for Assessing Chloride-Induced Reinforcement Corrosion Resistance of Geopolymer Mortars.

The widespread adoption of geopolymer concretes in the industry has been slow, mainly due to concerns over their long-term performance and durability. One of the main causes of concrete structures' deterioration is chloride-induced corrosion of the reinforcement. The reinforcement corrosion process in concrete is composed of two main stages: the initiation phase, which is the amount of time required for chloride ions to reach the reinforcement, and the propagation phase, which is the active phase of corrosion. The inherent complexities associated with the properties of precursors and type of activators, and with the multi-physics processes, in which different transfer mechanisms (moisture, chloride, oxygen, and charge transfer) are involved and interact with each other, have been a major obstacle to predicting the durability of reinforced alkali-activated concretes in chloride environments. Alternatively, the durability of alkali-activated concretes can be assessed through testing. However, the performance-based tests that are currently available, such as the rapid chloride permeability test, the migration test or the bulk diffusion test, are only focusing on the initiation phase of the corrosion process. As a result, existing testing protocols do not capture every aspect of the material performance, which could potentially lead to misleading conclusions, particularly when involving an electrical potential to reduce the testing time. In this paper, a new performance-based test is proposed for assessing the performance of alkali-activated concretes in chloride environments, accounting for both the initiation and propagation phases of the corrosion process. The test is designed to be simple and to be completed within a reasonable time without involving any electrical potential.

The screening effect of coarse aggregate on the air void structure and durability of air-entrained concrete

The control of air void structures introduced by air-entraining agents (AEAs) has long been a crucial problem. However, the mechanism through which the air void structure is refined by the extrusion of the slurry and the cutting of the aggregate remains insufficiently studied. This study aims to investigate the screening effect of coarse aggregate on the air void structure. The gradations of coarse aggregates were controlled by the fractal dimension (D). For casting air-entrained concrete, multiple continuously graded aggregates with D of 2.1, 2.3, 2.5 and 2.7 as well as two single graded aggregates with D=1.8 and 3.0 were used. Various parameters such as air content, air void structure, freeze-thaw durability, chloride ion permeability and water absorption were measured. Various air void structure parameters were compared to macroscopic properties. To evaluate the screening effect of coarse aggregate, the bubble rising and splitting behavior when passing through a single simulated aggregate (SA) and SA layer were observed. The findings indicate that finer and continuously graded coarse aggregates lead to higher air content and promoted air bubble trapped rate, which suggests a stronger screening effect. This results in a smaller bubble spacing coefficient and stronger frost resistance.

Novel approaches to improving gas separation: Ionic liquids coated coke/ NH2-UiO-66-based mixed matrix membranes for CO2/N2 separation

Permeability and separation efficiency of mixed matrix membranes (MMMs) are two important aspects. Polymeric membranes offer excellent mechanical and physical properties; however, they have a low permeability. To enhance the permeability and separation performance of polyvinyl chloride (PVC) membranes, Cholinium amino acid-based (IL) were impregnated with activated coke/ NH2-UiO-66 (Zr) (AC/MOF) composite and then IL@AC/MOF filler was incorporated into PVC matrix. FTIR spectroscopy, TGA, SEM, EDX, and Brunauer-Emmett-Teller (BET) surface area measurement were used to characterize the MMMs prepared. The porous structure of MMMs nanocomposites causes AC/MOF composite to effectively accelerate gas the diffusion in the PVC matrix. The permeability measurements for CO2 and N2 were made at 288.15, 298.15, 308.15, and 318.15 K at pressure 3 bar The outcomes indicates that the incorporation of the IL@AC/MOF filler increased the permeability of the PVC/AC/MOF MMMs compared to the pure polymeric membrane. The mixed matrix membranes exhibit superior gas separation performance, surpassing the 2008 Robson's Upper Bound.

Analysis of waste glass as a partial substitute for coarse aggregate in self-compacting concrete: An experimental and machine learning study

With the growing environmental burden to minimize debris and recycle, the concrete industry has replaced wasted glass with concrete composition elements in multiple ways. This study provides a comprehensive analysis of integrating waste glass aggregate (WGA) at various proportions (0 %, 5 %, 10 %, 15 %, and 20 %) as substitutes for coarse aggregates along with a consistent 20 % silica fume (SF) as cement replacement in self-compacting concrete (SCC). In addition to determining the mechanical, durability and microstructural properties of SCC, this research also uses advanced machine learning (ML) techniques to predict the mechanical properties accurately. By employing slump flow, j-ring flow and v-funnel time the rheology of fresh SCC was evaluated. Mechanical properties were assessed through the evaluation of compressive, splitting tensile, and flexural strength, whereas electrical resistivity, water permeability, rapid chloride permeability (RCPT), and accelerated mortar bar test (AMBT) were employed to evaluate durability. The microstructure was further examined using scanning electron microscopic (SEM) and energy-dispersive X-ray spectroscopy (EDS) analysis. The replacement of WGA with a constant SF in SCC improved flowability while lessening its passing ability. Furthermore, the study indicated that adding 5 % WGA along with 20 % SF to SCC resulted in a slight decrease of 4.53 % in compressive strength and 3.61 % in flexural strength compared to the reference mix containing 0 % WGA and 20 % SF after 28 days, which yields a favorable outcome. Findings from further assessments revealed that SCC's durability characteristics were enhanced by adding WGA and SF. Expansion of the Ca/Si ratio observed in EDS analysis significantly impacts the strength, while voids and cracks patterns detected in SEM analysis, result in an inferior microstructural performance with the incorporation of WGA. Notwithstanding both the ML models exhibiting excellent regression coefficients (R2), the random forest model showed superior accuracy and reliability in its results.

Effect of steam curing on strength, durability and microstructure of concretes with and without mineral admixtures

This research explores the effect of steam curing on the strength, durability and microstructure of concretes with and without mineral admixtures of fly ash (FA) and ground granulated blast-furnace slag powder (SL). Two types of C55 strength grade concretes (one was pure cement concrete, the other was a concrete made by replacing part of the cement with 12% FA and 18% SL) were prepared and their compressive strength, chloride diffusion coefficient and carbonation depth under standard and steam-curing conditions were measured and compared. The phase composition and microstructure of the concretes under the two curing conditions were tested by X-ray diffraction, scanning electron microscopy and mercury intrusion porosimetry. The results showed that, on the one hand, compared with standard curing, steam curing is beneficial to the early strength, but not conducive to the later strength development and chloride permeability resistance of both types of concretes. Furthermore, for the steam-cured concrete, the 28 days carbonation depth of the forming surface is higher than that of the bottom surface. In addition, steam curing can reduce the carbonisation resistance of pure cement concrete and improve the carbonisation resistance of concrete mixed with FA and SL. On the other hand, composite mineral admixtures of FA and SL reduce the early strength and the carbonisation resistance of concrete cured by standard curing, but improve the later strength, the carbonisation resistance and chloride permeability resistance of concrete cured by steam curing. FA and SL are thermally activated under steam curing and can react with the calcium hydroxide formed by cement hydration in the early stage, which produces a larger amount of secondary hydration products to improve the pore structure and interfacial microstructure of the concrete with FA and SL. In this way, the adverse effects of steam curing on later strength and durability of concrete are significantly restrained by composite mineral admixtures of FA and SL.

Predictive and experimental assessment of chloride ion permeation in concrete subjected to multi-factorial conditions using the XGBoost algorithm

Chloride ions infiltrate concrete structures, causing corrosion of the steel reinforcement, which creates concrete spalling and decreases load-bearing capacity, ultimately leading to structural failure. Thus, it is essential to comprehend the diffusion process of chloride ions in concrete. Current models used to predict the chloride ion diffusion in concrete are hindered by poor accuracy due to their simplistic consideration of variables and the complex interplay of environmental and material factors affecting key parameters such as surface chloride concentration (Cs) and the chloride diffusion coefficient (D). These influences are challenging to capture with simple linear or non-linear relationships, and traditional machine learning models often overfit training data and underperform with new data. To address these challenges, this study presents physical model experiments conducted to explore the diffusion process of chloride ions under multi-field coupling conditions, examining chloride ion concentrations across different concrete layers under varying environmental temperatures (T), humidities (h), erosion times (t), water-cement ratios (W/C), and volumes of coarse aggregates (v). This study reveals the distribution patterns of chloride ions within concrete layers. An XGBoost machine learning predictive model was developed using environmental temperature, humidity, erosion time, water-cement ratio, and coarse aggregate volume as input variables, with Cs and D as output variables. The results show that when the water-cement ratio reaches 0.5 in high humidity, the SHAP value rises to 0.015, enhancing chloride diffusion. As erosion time exceeds 200 days and temperature surpasses 38 °C, the SHAP value peaks at 0.02. Additionally, when coarse aggregate volume is between 0.45 and 0.60, temperature changes have little effect on Cs. Additionally, a graphical user interface was developed for modeling Cs and D to enhance practical usability.

The role of low-quality calcined clay in enhancing the performance of cement mortar exposed to normal and aggressive media

This study focuses on the role of low-quality calcined Fanja (FNJ) clay in enhancing the behavior of cured cement mortar (CM) and its resistivity to chloride and sulfuric acid attack. Ordinary Portland cement was replaced with different quantities (10%, 25%, 35%, and 50% by weight) of FNJ, which was calcined at different temperatures (620 °C, 760 °C, and 900 °C). After 28 days of curing, all the hardened mortars were immersed in 5% sulfuric acid for up to 12 weeks. Additionally, a rapid chloride permeability test was conducted on the 91-day cured CM and CM-FNJ samples to evaluate the affinity of calcined FNJs to retard the chloride diffusion into CM. The results showed that all samples containing FNJ900 showed better physical and mechanical properties than the control sample, while CM with NFJ760 recorded nearly similar performance as CM-NFJ900. In contrast, the CM-FNJ620 mixtures showed lower properties than those of other mixtures. In addition to the pozzolanic reactivity of the calcined clay, the presence of hematite in the calcined clay strongly contributed to increasing the mechanical properties of the hardened mortar through forming calcium ferrosilicate hydrate binding phase, as confirmed by X-ray diffraction. Moreover, the existence of hematite increased the resistivity of CM against sulfuric acid attack as it acts as a buffer for an acidic medium. Compared with CM-FNJ900, the CM-FNJ760 is recommended for use as it exhibited a higher strength activity index and comparable resistance to accelerated chloride diffusion and sulfuric acid accompanied by lower energy demand and lower CO2 emission, achieving the concept of ‘sustainability’.

Carbonation and chloride penetration performance of self-compacting concrete with masonry and concrete wastes

In this research, masonry and concrete construction and demolition wastes (CDWs) were used as supplementary cementitious material (25% vol. residue of masonry, RM) and recycled coarse aggregate (RCA) in increasing levels (0%, 50% and 100% vol. residue of concrete), respectively, in the development of self-compacting concrete (SCC). The performance of SCC mixtures was evaluated in terms of fresh properties, compressive strength, resistance to both accelerated (1% CO2, 65% R.H. and 23 °C temperature) and natural carbonation as well as chloride penetration. Experimental results showed a monotonic workability reduction associated to the incorporation of increasing levels of RCA. In compressive strength, the SCC with RCA showed the greatest increase in this mechanical property after 28 days of accelerated exposure in the carbonation chamber, when compared to its water-cured counterpart. Yet, at 360 days of accelerated carbonation exposure, all SCCs showed compressive strength reductions compared to their water-cured counterparts. On the other hand, the chloride permeability resistance of the SCCs was low and very low at the ages evaluated. Thus, the findings of this study indicate that the use of CDW can generate SCCs with adequate fresh properties, compressive strength and carbonation and chloride penetration performance, which offers benefits for the environment.

The effect of Dolomite powder and Fly ash on durability properties of self-compacting concrete

Abstract This study aims to assess the effectiveness of dolomite mineral admixture in the production of self-compacting concrete (SCC). The characteristics of concrete at 7 and 28 days of hardening were evaluated. SCC mixtures with different amounts of dolomite powder and fly ash (FA) at a constant composition were made. It has been noted that the flow ability of SCC mixes gets better with increasing percentages of dolomite. In addition to its mechanical characteristics, the durability of mixes containing SCC has been studied, including water absorption, sorptivity, and permeability to chloride ions and acid attack. After 28 days, a strength of 61 MPa was achieved with a 20% DP replacement level mixture, which is 31.38% higher than the control SCC mix. Along with the compressive strength of SCC, parameters affecting the durability of SCC such as Rapid chloride penetration test (RCPT), Sorptivity, water absorption and hydrochloric acid attack were also studied at 28 days. The utmost resistance to permeability of chloride ions was attained.

Chloride permeation resistance of sulphoaluminate cement-based composite characterized by both alternating current section and RCM methods

Sulphoaluminate cement (SAC) was widely used for rapid repair and strengthening of building structures due to its excellent quick hardening and high early strength behavior. This study developed a SAC-based engineering cement composites (ECC) with ultra-high molecular weight polyethylene (UHMWPE) and investigated its mechanical properties. Chloride ion permeability coefficient were evaluated by new alternating-current sectioning and rapid chloride migration (RCM). The mechanism of the SAC-ECC against chloride erosion were quantified using nitrogen isothermal adsorption. The results show that the fracture energy, tensile strength and strain of SAC-ECC samples are higher than that of normal ECC. The polyethylene (PE) fiber could significantly improve the flexural strength and toughness with PE fiber content of 0.75 % by volume. The hydration products generated could react with chloride ion to make it chemically stabilized, leading to reduce the chloride ion diffusion coefficient significantly. Based on microscopic analysis (SEM), the pore structure in SAC-ECC composite improved remarkedly while the volume of harmful pore decreased evidently as well. SAC-ECC developed in this paper could be poetically applied to strengthening and repair of marine concrete structures.

Workability, mechanical, durability, and microstructural investigation of sustainable concrete utilizing secondary treated wastewater, fly ash, and sodium nitrite

ABSTRACT This study explored the use of secondary treated wastewater (STW) from three secondary-level wastewater treatment plants, along with fly ash (FA) and sodium nitrite (SN), to produce sustainable concrete, comparing it to concrete made with tap water. Key properties examined included workability (slump cone), strength (compressive, split tensile, and flexural), and durability (rapid chloride permeability and efflorescence). Scanning electron microscopy (SEM) analysis was performed to investigate the concrete's microstructure. The results indicated that FA and SN content had a notable influence on the workability, mechanical strength, and durability of the concrete mixtures. However, the type of water (STW or tap water) used in the concrete preparation showed no significant impact. Durability tests revealed that the penetrability of the mixtures ranged from low to moderate, signifying good quality, and no efflorescence was observed. Ultimately, the study concluded that concrete made with STW, when supplemented with 10% FA and 2% SN, demonstrated comparable performance to that made with tap water across key properties, offering a viable option for sustainable concrete production.

Study on the influence of early frost attack on the performance of cement mortar

The loss of strength and durability caused by early frost attack is the macro performance of internal microstructure deterioration. Understanding the influence mechanism of early frost attack at the micro level is necessary to avoid or minimize the early frost attack to macro performance. In this study, the influence of early frost attack on the strength, water sorptivity, chloride permeability, and microstructure of cement mortar was investigated. The fresh mortars were pre-cured for 10, 12, 14, and 16 h and then frozen at −10 °C for 7 days to simulate an early frost attack. After freezing, the standard curing (20 °C) was carried out until the testing. It is found that after standard curing of 28 days, the strength of early-frozen mortar can reach more than 95 % of the 28-day strength of unfrozen mortar. Interestingly, the sorptivity coefficient and total charge passed of early-frozen mortar are much higher than the level of unfrozen mortar, and the loss of resistance to water penetration and chloride ion penetration exceeds 20 %, indicating that early frost attack causes more severe damage to the durability than to the strength of mortar. Mercury intrusion porosimetry (MIP) results show that early frost attack can increase the pore volume of >50 nm and coarsen the pores within 10–50 nm. Correspondingly, key pore parameters (critical pore diameter, threshold pore diameter, and tortuosity) that affect the durability of mortar are also negatively affected. Energy dispersive spectroscopy (EDS) analysis also shows that after suffering early frost attack, the interfacial transition zone (ITZ) thickness of mortar is increased from 4 to 10 μm to 8–13 μm, and the probability of high Ca/Si ratios (4–10) in the ITZ is also increased. Finally, it is concluded that the coupling effect of pore structure coarsening and ITZ degradation leads to more severe durability loss.

Experimental investigation of using Ultra-High-Performance Concrete coating for anti-corrosion protection of reinforced concrete induced by chloride ions

The emergence of Ultra High-Performance Concrete (UHPC) is one of the latest developments in concrete technology. Repairing and rehabilitating damaged structures by applying a thin layer of several centimeters on conventional concrete (with or without reinforcement) has been one of the applications of UHPC. Due to its very small porosity and excellent permeability, UHPC has extremely high durability against the penetration of destructive substances such as water, chloride ions, oxygen, etc. In this work, we investigated the durable effect against external aggressive corrosive substances by coating a 2.5 cm thickness layer of UHPC on conventional concrete. The desired composite concrete consists of a conventional concrete core with a compressive strength of 40 MPa and a coating with a thickness of 2.5 cm of UHPC cover. Then, this concrete went through oxygen penetration, Rapid Chloride Permeability Test (RCPT), and electrical resistance tests. Finally, to verify the results of the durability tests, two sets of comparison reinforced concrete specimens with 5 cm as their covers were exposed to an accelerated corrosion test. It is found that the substitution of a 2.5 cm layer of UHPC instead of the conventional concrete resulted in a 30-times increase in resistance against water penetration, 41 times against chloride ion penetration, 307 times against oxygen penetration, and 8 times in its electrical resistance. Based on corrosion acceleration test results, after 30 days of applying a current with a voltage of 31 volts, the control specimens with a 5 cm cover started to corrode after one week. After 30 days, 47 % corrosion was observed. Even though after 365 days, no signs of corrosion were found in the UHPC-coated specimens.