Chemical Characteristics Of Water Research Articles

Physical and chemical characteristics of plasma-activated water generated by hybrid dielectric barrier discharge and gliding arc discharge

This research explores the synergistic application of Dielectric Barrier Discharge (DBD) and Gliding Arc Plasma Jet (GAPJ) in a Hybrid Plasma Discharge (HPD) setup for enhanced water activation. The HPD system demonstrated balanced and sustained generation of reactive oxygen and nitrogen species (RONS), maintaining efficiency at higher specific input energy (SIE) values. Comparative analyses with DBD and GAPJ systems highlighted the superior performance of the HPD system in generating RONS and modifying water’s molecular structure. Key observations included a decrease in water’s pH and an increase in oxidation-reduction potential, total dissolved solids, and conductivity, stabilizing beyond 5 l min−1 airflow and 10 min of treatment. UV−Vis spectroscopy identified nitrites, nitrates, hydrogen peroxide, and nitrous acid, while Raman spectroscopy captured shifts in vibrational modes, particularly in librational and O–H stretching bands. These changes correlated with alterations in reactive species concentrations and pH levels. Overall, the HPD system emerged as a versatile and efficient approach for generating plasma-activated water, suitable for applications in microbial deactivation, surface sterilization, and electrocatalytic process optimization, offering stable and continuous production of reactive species across a range of SIE values.

Chemical characteristics, formation mechanisms, and geological evolution processes of high-salinity coal reservoir water in the Binchang area of the southern Ordos Basin, China

The chemical characteristics of coal reservoir water are important for studying the formation and enrichment of biogenic coalbed methane (BCM). Based on geological and sampling test data, this paper studied the geochemical characteristics and formation mechanisms of high-salinity coal reservoir water (CRW) in the Jurassic Yan'an Formation of the Binchang area in the southern Ordos Basin. The results show that the TDS contents of the CRW in the Binchang area are between 7577.38 and 15,138.61 mg/L (av. 13,268.95 mg/L), which is high-salinity brackish water. The ion types of CRW are mainly Na+, Cl− and HCO3−, and the correlations between TDS and Na+ and Cl− are close to 1. The Piper trilinear diagram indicates that the evolution direction of the CRW is deep concentrated brine, and the hydrochemical type is the NaCl type. The 127I concentrations of CRW are between 285 and 484 μg/L, which are much higher than the values of 55.88 μg/L for seawater. The results of 129I dating show that the minimum age of the CRW in the study area is between 6.7 Ma and 39.97 Ma, which is much younger than the actual geological age of the Yan'an Formation. The hydrogen and oxygen isotope results show that the CRW in the study area experiences an apparent oxygen drift, indicating that the coal reservoir of the Yan'an Formation has good sealing and a long retention time for the CRW. The hydrodynamic factors show that the hydrodynamic conditions of the coal reservoir are weak, and the primary ions in the CRW originated from the dissolution of salt rocks. The main ion differentiation indices show that high-salinity coal seam water is mainly formed by evaporation, and the ion exchange between CRW and the surrounding rock and the alternating adsorption of cations in water are very weak. Evaporation and diagenesis lead to an increase in the contents of Na+, Cl− and I+ in coalbed water, which in turn leads to an increase in the total dissolved solids contents of CRW and its evolution toward concentrated brine. The genesis and evolution of the CRW in the study area are affected by the combination of the relationships among the paleoclimate, aquifers and aquifuges, and tectonic evolution processes. The CRW in the study area has experienced five evolution stages, i.e., sedimentary water and diagenetic water, high-salinity infiltration water, primary mixed water, paleoatmospheric precipitation recharge water, and secondary mixed water. The above understanding can provide a basis for studying the formation period and accumulation mechanism of BCM and provide a hydrogeological basis for water resource utilisation and pollution prevention and the control of high-salinity water.

Hydrochemical and isotopic characteristics of water sources for biological activity across a massive evaporite basin on the Tibetan Plateau: Implications for aquatic environments on early Mars

Covered by vast eolian landforms, gravel deposits, and playas, the worldwide typical evaporite deposit land, Qaidam Basin, in northwestern China is analogous to early Mars when the aridification process had lasted for millions of years since the end of a wetter climate. This study aims to investigate the chemical and isotopic characteristics of waters in an evaporite-rich environment, as well as the habitable conditions therein, that have undergone a transformation similar to early Mars. In May 2023, a total of 26 water samples were collected across the representative central axis of a longitudinal aridity gradient in the Qaidam Basin, including categories of meteoric water, freshwater, standing water accumulated after precipitation, salty lacustrine water, and hypersaline brines to inspect compounds made up of carbon, nitrogen, phosphorus, sulfur, halogen, and metallic elements. As evaporation intensified, the salt types transformed from HCO3-Ca·Na to Cl·SO4-Na or ClMg. The dominance of carbonate will gradually be replaced by sulfate and chloride, leaving much more dilute and less detectable contents. The presence of trace ClO4−, ClO3−, ClO2−, and BrO3− was confirmed in a few of the sampled Qaidam waters, indicating the preservation of oxyhalides in waters within an arid region and possibly the presence of relevant microbial enzymes. The isotopes of water, carbonaceous, and nitrogenous compounds provide valuable references for either abiogenic or biogenic signatures. With undetectable amount, phosphorus was found to be the limiting nutrient in evaporative aquatic environments but not necessarily antibiosignatures. Overall, these results suggest that the paleo-lacustrine environments on Mars are more likely to preserve biosignatures if they feature the dominance of carbonate minerals, bioavailable nitrate, phosphorus, and organic carbon, the presence of thermodynamically unstable oxyhalides, and isotope ratios that point to the involvement of biological activity.

Hydrochemical characterization and comprehensive water quality assessment of groundwater within the main stream area of Yishu River.

To gain a comprehensive understanding of the hydrochemical characteristics, controlling factors, and water quality of groundwater in the main stream area of Yishu River (MSYR), a study was conducted using water quality data collected during both the dry and wet seasons. Through statistical analysis, hydrochemical methods, fuzzy comprehensive evaluation, and health risk evaluation modeling, the water chemical characteristics of the main stream area of Yishu River were studied, and the water quality of the area was comprehensively evaluated. The findings indicate that HCO3- and Ca2+ are the predominant anions and cations in the MSYR during the dry and wet seasons, respectively. Moreover, anion concentration in groundwater follows HCO3- > SO42- > NO3- > Cl-, while cations are ranked as Ca2+ > Na+ > Mg2+ > K+. Overall, the groundwater manifests as weakly alkaline and is predominantly classified as hard-fresh water. During the wet season, there is greater groundwater leaching and filtration, with rock and soil materials more readily transferred to groundwater, and the concentrations of main chemical components in groundwater are higher than those during the dry season, and the hydrochemical types are primarily characterized as HCO3-Ca·Mg and SO4·Cl-Ca·Mg types. These results also suggest that the chemical composition of the groundwater in the MSYR is influenced mainly by water-rock interaction. The primary ions originate from the dissolution of silicate rock and carbonate rock minerals, while cation exchange plays a critical role in the hydrogeochemical process. Groundwater in the MSYR is classified mostly as class II water, indicating that it is generally of good quality. However, areas with high levels of class IV and V water are present locally, and NO3- concentration is a crucial factor affecting groundwater quality. In the wet season, more groundwater and stronger mobility lead to greater mobility of NO3- and wider diffusion. Therefore, the risk evaluation model shows that nitrate health risk index is higher in the wet season than it is in the dry season, with children being more vulnerable to health risks than adults. To study groundwater in this area, its hydrochemical characteristics, water quality, and health risk assessment are of great practical significance for ensuring water safety for residents and stable development of social economy.

Integration of geoelectrical, hydrochemical and geothermal data to identify the origin of thermal water in the foothills of the Tlemcen mountains, Northwestern Algeria

In previous studies, the mean geothermal gradient of the Tlemcen region has been estimated as low (3.7°C/100m). The existing boreholes in the Remchi plain (North of the Tlemcen Mountains) reveal thermal waters (26-48°C) and a remarkable artesianism. To understand the hydrodynamics and origin of thermalism of this groundwater, we merged geophysical and physical-chemical data. Geophysical data allowed us to improve the resolution of the fault network, to estimate the thickness of various sandstone beds connected with the thermal reservoir and to delimit the productive aquifer. Chemical characteristics of waters have been used for a statistical analysis, which displayed two independent water clusters resulting from two hydrodynamic patterns throughout the aquifer. The hydrothermal analysis identifies the depth reached by water and the relationship between water circulation and the fault network. Comparison with previous studies allowed us to build a schematic geological model, which explains hydrodynamics, origin and role of this structure in the groundwater flow.

Study on Hydrochemical Characteristics and Interactions between Groundwater and Surface Water in the Dongting Lake Plain

The Dongting Lake Plain is a major ecological reserve for river and lake wetlands in the Yangtze River Basin, with complex river and lake relationships and frequent water flow exchange. Studies on the hydrochemical characteristics and the mechanism of interaction between groundwater and surface water will actively promote the scientific management, utilization of water resources, and protection of the ecological environment in the Dongting Lake Plain. Based on hydrogeochemical statistics, Gibbs diagrams, ion ratios, rock weathering end-element diagrams, hydrogen–oxygen isotope relationship diagrams, and other technical methods, the chemical characteristics, ion sources, and the distribution of hydrogen–oxygen isotopes of groundwater and surface water in “the Three Inlets” and “the Four Rivers” water system areas as well as the Dongting Lake water were analyzed. Additionally, the interactions between groundwater and surface water and the proportions of these contributions were discussed. The results show that both groundwater and surface water in the Dongting Lake Plain are weakly acidic or alkaline, and the anions are mainly HCO3−, the cations are mainly Ca2+and Mg2+, with the hydrochemical types being mainly HCO3−Ca−Mg and HCO3−Ca. The chemical characteristics of groundwater and surface water are mainly affected by the interaction between water and rock; the ions in surface water mainly come from the weathered dissolution of carbonate and silicate rocks, while the ions in groundwater mainly come from the weathered dissolution of carbonate and silicate rocks, with the dissolution of evaporite rocks locally. Groundwater and surface water are mainly distributed near the local meteoric water line (LMWL), and the slope of the local evaporation line is less than that of the LMWL, which indicates that atmospheric rainfall is an important recharge source for groundwater and surface water and that at the same time, it is affected by evaporation to a certain extent. Part of the groundwater in the Dongting Lake Plain is discharged into the surface rivers in “the Three Inlets” and “the Four Rivers” water system areas, and the other part is directly discharged into Dongting Lake. According to the mass balance relationship of isotopes, the proportions of surface water in “the Three Inlets” and “the Four Rivers” water system areas contributing to Dongting Lake’s water are 18.48% and 60.38%, respectively, and the proportion of groundwater in the lake plain contributing to Dongting Lake water is 21.14%.

Hydrochemical Characteristics and Control Factors of Shallow Groundwater in Anqing Section of the Yangtze River Basin

Shallow groundwater is the main source of water for living and industrial and agricultural production in Anqing City, which is an important basic guarantee to maintain the sustainable development of the social economy and regional ecological environment. In order to further study the water chemical characteristics and controlling factors of shallow groundwater in Anqing City, 196 groups of shallow groundwater samples were collected. A Piper diagram graph, Gibbs chart, ion ratio, and mathematical statistics were comprehensively used to study the water chemical characteristics and controlling factors of groundwater in Anqing City, and the contribution of different sources to the water chemical components of groundwater was quantitatively evaluated. The results showed that the shallow groundwater in Anqing City was weakly alkaline, with pH values ranging from 5.84 to 8.38, with an average value of 7.21. The TDS ranged from 47 to 1 620 mg·L-1, with an average of 324.21 mg·L-1. HCO3- and Ca2+ were the main anions, and the water chemical type was HCO3-Ca type. The chemical components of groundwater were affected by rock weathering leaching, cation alternating adsorption, mineral dissolution and precipitation, and human activities. Ca2+, Mg2+, and HCO3- were mainly derived from the weathering dissolution of carbonate and silicate; Na+, Cl-, and SO42- were affected by industrial activities and domestic sewage discharge; and K+ and NO3- were affected by agricultural activities. The APCS-MLR receptor model analysis further revealed that the chemical components of groundwater were mainly geological factors, industrial factors, agricultural factors, and unknown sources, and their contribution rates were 45.35%, 14.19%, 25.38%, and 15.08%, respectively. Geological factors were important sources of hydrochemical components of shallow groundwater, and human activities aggravated the evolution of groundwater hydrochemistry.

Investigation on water inrush fracture mechanics model based on fracture mechanics and microseismic monitoring

North China coalfield is one of the most severe coal fields threatened by Ordovician limestone water (buried depth exceeding 1000 m). In this paper, the hydraulic mechanism of Ordovician limestone water in the complex geological structure are studied. An interesting phenomenon was found in the study, the water inrush from Ordovician limestone has a “latent period” and presents lag water inrush law. The hydrochemical characteristics of the early stage in Xingdong coal mine is non-Ordovician limestone water chemical characteristics, the later stage gradually shows the Ordovician limestone water with the continuous outflow. Meanwhile, the hyperbolic contour distribution characteristics are also observed in the spatial distribution law of microseismic in the floor working face. The minimum damage area is in the layer at the hyperbolic apex, which is the critical breakthrough point of water inrush. Furthermore, the water inrush fracture mechanics model (WIFM) of concealed fault with high confined water is established based on the fracture mechanics theory. The results show that the critical values of the length and angle of the water inrush of the conceal fault are about 50 m and 40°. It should be pointed out that the longer and larger angle conceal faults indicate the longer of the fracture expansion at the tip of the fault, and the probability of water inrush increases. Special attention should be paid to such concealed faults and methods such as grouting should be adopted to avoid the water inrush disaster caused by the activation of faults. This model provides a theoretical basis for the mechanical mechanism of the coal seam floor water inrush process.

Novel Method on Mixing Degree Quantification of Mine Water Sources: A Case Study

After a mine water inrush occurs, it is crucial to quickly identify the source of the water inrush and the key control area, and to formulate accurately efficient water control measures. According to the differences in water chemical characteristics of four aquifers in the Fenyuan coal mine, the concentrations of K+~Na+, Ca2+, Mg2+, Cl−, SO42−, and HCO3− were taken as water source identification indexes. A decision tree classification model based on the C4.5 algorithm was adopted to visualize the chemical characteristics of a single water source and extract rules, and intuitively obtained the discrimination conditions of a single water source with Mg2+, Ca2+, and Cl− as important variables in the decision tree: Mg2+ < 39.585 mg/L, Cl− < 516.338 mg/L and Mg2+ ≥ 39.585 mg/L, Ca2+ < 160.860 mg/L. Factor analysis and Fisher discriminant theory were used to eliminate the redundant ion variables, and the discriminant function equations of the two, three, and four types of mixed water sources were obtained successively in turn. This paper puts forward MSE, RMSE, and MAE as the evaluation indexes of the water source mixing degree calculation models and obtains the ranking of the pros and cons of the mixed water source mixing degree calculation models. The results show that the minimum inscribed circle analytical method is the optimal model for the calculation of the mixing degree of two types of water sources, and the MSE, RMSE, and MAE are 0.17%, 4.13%, and 4.13%, respectively. The minimum inscribed circle clustering method is the optimal model for the calculation of the mixing degree of three types of water sources, and the minimum distance method is the optimal model for the calculation of the mixing degree of four types of water sources. The method of mine water source identification based on the decision tree C4.5 algorithm and mixing degree calculation has the characteristics of a simple calculation process, high efficiency, objective accuracy, and low cost, which can provide a scientific basis for the development of stope water control measures.

Study of the features of hydrochemical characteristics and development of zooplankton in the area of water-air curtain type fish protection structure in the cooling reservoir of the SDPP

PURPOSE. Study of the features of hydrobiological characteristics of zooplankton development under operating conditions of a fish protection structure similar to a water-air curtain (WAC) at an energy facility.METHODS. Hydrobiological material was collected, processed and analyzed on the physical and chemical characteristics of water and on the qualitative and quantitative composition of zooplankton in the water intake area of the Zainskaya State District Power Plant. A comparative analysis of our own research and literature data on the characteristics of water in the area of a water-air curtain fish protection structure was carried out. The material was processed using generally accepted hydrobiological methods in the laboratory of the Department of Aquatic Bioresources and Aquaculture of Kazan State Energy University.RESULTS. It is shown that a fish protection device of the water-air curtain type is a multifunctional technical solution, which during operation changes the physical and chemical characteristics of the state of the ecosystem, especially in the bottom layer. It was revealed that a fish protection structure (FPS) like a water-air curtain does not reduce the species diversity of zooplankton. In the area where the WAC operates, the maximum abundance and biomass of zooplankton were noted compared to control stations. The basis of the number and biomass of zooplankton were crustaceans: cladocerans accounted for 50.2% of the total biomass, copepods accounted for 46.1%.CONCLUSION. Observations of the state of the ecosystem in the area of operation of the water-air curtain and assessment of water quality based on hydrobiological indicators revealed high water quality in the area where the WAC operates, and an improvement in the environmental situation.

Study of Physical and Chemical Properties of Drinking Water Sources on the Citarum River Irrigation Area in Karawang, West Java, Indonesia

Citarum River in West Java has been named as the most polluted river in the world. The irrigation stream plays an important role in society as the source of agricultural and drinking water. However, the increasing number of industries and population density along the river have made this river dirtier. This study aims to determine the physical and chemical characteristics of water in the Citarum River irrigation area. There were 33 samples that were taken for every 1,5 km. The physical chemical water parameters were tested at DLHK Karawang Water Laboratory. The water surface has a sharper color and smell when entering the industrial areas. This finding indicates that several chemical wastes are dumped directly into the water. The turbid color of the river water exceeds the set threshold. In addition, the dissolved iron content was above the standard. The results of this research can be implemented in the fields of water management, environment, and public health. Moreover, the results can be used as a basis for the government to make regulations. In addition, this can be used for other researchers in the development of science.

The role of turnover in structuring subterranean aquatic communities in Southeastern Brazil.

Similarly to other animal communities, the diversity of subterranean aquatic fauna is influenced by several factors and processes, such as habitat fragmentation, dispersion, environmental heterogeneity, and physical and chemical water characteristics. Here, we studied cave aquatic communities of the Alto Ribeira hydrographic basin, regarding troglobitic and non-troglobitic species, located in a single karst area to evaluate the influence of sub-basins in fauna differentiation. We investigated how abiotic variables (flow, electrical conductivity, temperature, pH, and substrate) influence the fauna composition and the contribution of beta diversity components (nestedness and turnover) in explaining communities' dissimilarities. Fauna composition differed between sub-basins, as most species did not co-occur in different caves. Caves with higher flow and substrate diversity were the richest. In addition, each cave community was influenced by a unique set of abiotic variables. Dissimilarity among caves was mainly explained by turnover, and our findings suggest the restricted species distribution could be due to ecological (e.g., limited dispersion capacity, tolerance to abiotic variables), hydrogeological (e.g., dispersion barriers, isolation of sub-basins), and historical (e.g., colonization, paleoclimatic events) factors and processes. Therefore, different elements are responsible for determining the composition of cave aquatic communities in different sub-basins, reflecting the variability within a single karst area.

Geochemical characterization and implications of soil gas and geothermal fluids in the fault zone of Xiongan new area

This study investigates the geochemical characteristics and implications of soil gas and geothermal fluids in the fault zone of Xiongan New Area (XNA). Spatial distribution analysis reveals high soil gas concentrations along the fault zone, prompting the establishment of measurement lines along specific fault segments, such as Niudong fault, with a vertical burial trend. The measured average Rn flux ranges from 71.44 to 335.35 mBq m−2s−1, while CO2 flux ranges from 25.96 to 78.23 g m−2d−1. Furthermore, the average Rn and CO2 concentration intensities range from 0.91 to 2.30 and 1.13 to 2.61, respectively, indicating significant degassing in the fault zone.Geothermal well samples are collected from the deep reservoir in XNA, displaying a predominance of Cl–Na composition. Analysis of the Na–K–Mg equilibrium diagram suggests that the chemical characteristics of deep geothermal water are a result of interactions with rocks and mixing with shallow cold water in XNA. Isotopic analysis indicates the atmospheric precipitation origin of the deep geothermal water with extensive lateral recharge from underground runoff, emphasizing strong water-rock interactions. Comparison with other tectonic units in the region reveals that the Niudong Fault Zone serves as a regional geothermal control structure, facilitating deep fluid convection.In the eastern part of XNA, the geochemical analysis reveals concentrated degassing and a relatively high proportion of mantle-derived sources near the Niudong Fault Zone. This observation suggests the fault zone serves as a primary conduit for deep gases and geothermal fluids. The findings of this research provide valuable scientific references for future urban planning, energy utilization, and geologic hazard monitoring in XNA. Continued monitoring efforts are crucial for understanding the nature of fault activity and resource distribution in the region.

Palatability Assessment of Subsurface Water in South India: An Experimental and Numerical Study

Monitoring the quality of groundwater is crucial and important for the environment, the human health and agriculture practices. This study focused on evaluating the physical and chemical characteristics of subsurface water of different selected places in Coimbatore. This study was also aimed for identifying the influence of sampling location to its characteristics. Twenty-five subsurface water samples were taken from distinct places and sources. The tests were conducted as per Indian standards. The findings indicate that temperature, available and residual chlorine, and pH are nearly identical for all groundwater samples; turbidity, electrical conductivity, total dissolved solids, sulphates and iron change significantly depending on where the source was located. To determine the appropriateness of ground water samples for drinking purposes, findings were compared with Indian (IS 10500:2012) and WHO (2006) standards. It was determined that results for all parameters are within the acceptable limit. The statistical analysis was conducted using SPSS software to know the significance of the predicted results and it has been found that the results were statistically significant.

Comparative study of the quality of water produced by a solar distiller and by reverse osmosis

Freshwater is a vital resource for human well-being, accounting for about 2.5% of the water on our planet. However, the growing demand for freshwater puts its quality at risk. For meeting the water needs, desalination is a crucial solution, but it needs to be ensured that the water quality meets the international standards. In this article, we will compare the physical and chemical characteristics of water produced by solar distillation and reverse osmosis, using the same source water. We started with saline water with a pH ranging from 7.70 to 7.80, conductivity ranging from 49.5 to 51 ms/cm, and bicarbonate ion concentration ranging from 125 to 145 mg/l. We used a solar distiller and reverse osmosis to obtain distilled water with a pH of 7 to 7.20, conductivity of 0.2 to 1.6 ms/cm, and bicarbonate ion concentration of 14 to 28.5 mg/l. The results we obtained were found to comply with international drinking water standards.

Ecological and statistical models to configure flow regime for environment benefit in highly engineered rivers: a case study in the MacKenzie River, Southeast Australia.

Ecological and statistical models were developed using freshwater algal assemblages to assess water quality and ecological health of a regulated river. These models were used to inform configuration of flows to maintain or improve environmental conditions of the waterway whilst meeting consumptive water supply commitments. The flow regime of the MacKenzie River, western Victoria, Australia, has been substantially modified since the construction of a water supply reservoir on its upper reach in 1887. Water is withdrawn at several locations downstream of the reservoir, creating a substantially modified flow regime, impacting key environmental values of the river. To assess the impact of the different flow regimes on river health and ecosystem function, ten sites were repeatedly sampled along the river between February 2012 and April 2014. Physical and chemical characteristics of water, including pH, temperature, turbidity, electrical conductivity, dissolved oxygen, total nitrogen, total phosphorous, cations, and anions, were measured. Biological properties of the algal periphyton communities, including dry mass, ash-free dry mass, chlorophyll-a concentration, and species composition, were also measured. Exploration of the algal assemblage and water chemistry data using the computationally unconstrained ordination technique such as principal component analysis principal component analysis (PCA), correspondence analysis (CA), detrended correspondence analysis (DCA), and canonical correspondence analysis (CCA) indicated two strong gradients in the data sets. Furthermore, the quantitative ecosystem response models have been developed as the prototype tool to assist in the future configuration of flows in this river. The empirical data and models showed the lower reaches of the river to be in poor condition under low flows, but this condition improved under flows of 35 ML/day, as indicated by the reduction in green algae and cyanobacteria and improvement. Finally, the results are presented to tailor discharge and duration of water volume by amalgamation of consumptive and environmental flows to improve the condition of the stream thereby supplementing the flows dedicated to environmental outcomes.

GEOMORPHOLOGICAL, HYDROGEOLOGICAL AND GROUNDWATER QUALITY ANALYSIS IN KARST SYSTEMS OF THE CENTRAL-WESTERN PART OF METALIFERI MOUNTAINS

This scientific study focuses on the relatively lesser-known karst areas in the central-western part of Metaliferi Mountains. These surfaces display pronounced spatial fragmentation, forming limestone klippes with well-defined karst systems of geomorphic and hydrogeological complexity. Using GIS and statistical methods, the study highlights the morphological and distributional traits of the identified karst forms. Additionally, the area was analysed from a hydrogeological standpoint to explore the connections between the identified insurgences and exsurgences, and the impact of the karst environment on the chemical characteristics of karst waters. The geomorphological analysis reveals a clustered and non-uniform arrangement of depression forms, as shown by the nearest neighbour index, with a quasi-circular shape highlighted by the Circularity Index. From a hydrogeological perspective, there is an increase in carbonate ions (HCO3-) and calcium ions (Ca2+), along with a decrease in Fe and Al ions, indicating possible alluvium presence as a filter. The comparison of these values with legal thresholds demonstrates a high water quality in the analysed karst exurgences.

The Chemical Weathering of Rocks and Its Carbon Sink Effect in the Naqu River Basin of the Nujiang River Source Area, Southwest China

Carbon plays an important role in global climate change. The mechanisms of carbon sources and carbon sinks have also received wide attention from society, and the physical and chemical characteristics of riverine ions can reflect the chemical weathering of rocks and carbon sink capacity of river basins. Based on the data on river, rainwater, and rock samples from 2019, this study used various methods, such as ion ratio diagrams and ternary diagrams, to analyze the chemical characteristics of water; the chemical weathering and carbon sink effects of rocks were also calculated while assuming three scenarios based on the main sources of ions in the Naqu River. The results showed that for the whole catchment, the main ion sources in the river were: carbonate rock chemical weathering > silicate rock chemical weathering > evaporite dissolution > atmospheric precipitation input. According to the calculations, in the three scenarios, the carbonate weathering rates were 16.84, 11.32, and 14.08 t/km2/yr, and the carbon sink capacities were 66.47, 121.13, and 93.80 mol/km2/yr, respectively; the evaporite weathering rates were 2.20, 9.63, and 5.92 t/km2/yr, respectively. The silicate chemical weathering rate and carbon sink capacity did not change significantly in either scenario, with 6.82 t/km2/yr and 248.6 mol/km2/yr, respectively. This study quantified the ion sources in the Naqu River basin and accurately analyzed their chemical genesis, which helps in understanding the role of the rivers of the Qinghai–Tibet Plateau in the global carbon cycle and global climate change, in addition to providing a reference for the scientific development of the Nujing River.

Dynamics of dissolved Fe content in tributaries of Lake Teletskoe, depending on solar activity indicators

Relevance. The need to expand and deepen the understanding of the influence of solar radiation indicators on chemical characteristics of surface water, since the dependence of hydrochemical processes on periodic changes in solar activity has so far been studied extremely poorly. In addition, special attention is paid worldwide to the study of iron content in waters of rivers and lakes. Iron increased concentrations are one of the reasons for the "brownification" of surface waters in a significant part of the Northern Hemisphere. Aim. To establish a relationship between iron content and dynamics in the waters of the tributaries of Lake Teletskoe with indicators of solar activity (sunspots number, F-index). Methods. Water samples from the tributaries of Lake Teletskoe were collected into clean new polyethylene bottles in the estuaries of the rivers, from a depth of 0.5 m during the spring-summer high water and autumn low water, in 2016–2020. Content of total and dissolved Fe in the waters was determined by the ISP-MS method and by the AAS method. We used the data on solar activity indicators from the Belgian Observatory, which are freely available. Results. The total Fe content in the rivers of Lake Teletskoe basin for the period from 2016 to 2020 changes from 5 to 340 µg/l. Concentrations of dissolved iron (4 to 200 µg/l) do not exceed Russian standards, but they are often noticeably higher than the global average for river waters established abroad. The highest iron content, as well as the proportion of its soluble forms in the tributaries of Lake Teletskoe and in lake waters, was noted in 2016. It is probably due to the highest rates of solar activity. They cause certain changes in the environment – such as an increase in air temperature and water evaporation, and decrease in river flow, which accompanied by growth in concentrations of chemical elements in surface waters. Since 2016, there has been a steady decrease in dissolved iron concentration in surface natural waters of Lake Teletskoe basin, which may be a consequence of a decrease in solar radiation intensity in recent years.

Investigating limnological processes and modern sedimentation at Lake Żabińskie, northeast Poland: a decade-long multi-variable dataset, 2012–2021

Abstract. Here, we present a dataset of a decade-long monitoring project of Lake Żabińskie, a hardwater eutrophic lake in northeast Poland. The lake contains annually laminated (varved) sediments that form a unique archive of past environmental variability. Regular measurements of the lake water physical and chemical characteristics were done using a multiparameter sonde and a set of temperature sensors deployed in the water column. Seasonal variability in sediment fluxes was documented by a sediment trap. Field sampling provided information about the hydrochemistry of incoming streams and of the lake outflow. The overall monitoring program was designed to assess relationships among meteorological conditions, limnological processes, and modern sedimentation and to answer the question of whether meteorological and limnological phenomena can be precisely tracked with varves. However, this dataset can also be used for modeling physical and biogeochemical processes in lakes. The dataset is archived at https://doi.org/10.34808/w8w7-9x34 (Tylmann et al., 2023).