Chemical Remanent Magnetization Research Articles

Possible Eoarchean Records of the Geomagnetic Field Preserved in the Isua Supracrustal Belt, Southern West Greenland

AbstractRecovering ancient records of Earth's magnetic field is essential for determining the role of the magnetosphere in protecting early Earth from cosmic radiation and atmospheric escape. We present paleomagnetic field tests hinting that a record of Earth's 3.7‐billion‐year (Ga) old magnetic field may be preserved in the northeastern Isua Supracrustal Belt as a chemical remanent magnetization acquired during amphibolite‐grade metamorphism in the banded iron formation. Multiple petrological and geochronological lines of evidence indicate that the northernmost part of Isua has not experienced metamorphic temperatures exceeding 380°C since the Eoarchean, suggesting the rocks have not been significantly heated since magnetization was acquired. We use “pseudo” baked contact tests (intrusions emplaced 3.26–3.5 Ga ago) and a fold test (folding 3.6 Ga ago) to demonstrate that some samples preserve a ca. 3.7 Ga record of the magnetic field. We recover a field strength of >15 µT. This suggests that Earth's magnetic field may have been weak enough to enhance atmospheric escape during the Archean.

Contrasting Recording Efficiency of Chemical Versus Depositional Remanent Magnetization in Sediments

AbstractHow and when sedimentary rocks record Earth's magnetic field is complex. Most studies assume a time‐progressive lock‐in mechanism during sediment deposition called depositional remanent magnetization (DRM). However, magnetic minerals can also form in situ, recording a chemical remanent magnetization (CRM) that is discontinuous in time. Disentangling the two mechanisms represents a major hurdle, and differences in their recording efficiencies remain unexplored. Here, our theoretical solutions demonstrate that CRM intensities exceed DRM by a factor of six when acquired in the same magnetic field. Novel experiments growing greigite (Fe3S4) in sediments and subsequent redeposition under identical magnetic field conditions confirm the predicted difference in recording efficiency. Thus, if left unrecognized, CRM leads to overestimated paleointensity and deserves more attention when interpreting Earth's magnetic history from sedimentary records. Recognition of fundamental differences between CRM and DRM characteristics provide a way forward to distinguish the recording mechanisms through routine laboratory protocols.

Remagnetization of magnetite-bearing rocks in the Eastern Qiangtang Terrane, Tibetan Plateau (China): Mechanism and diagnosis

Remagnetization is a common yet notorious phenomenon that interferes with paleogeographic reconstruction. Classical paleomagnetic field tests are helpful in detecting remagnetization but their diagnostic power is limited: remagnetization may occur before folding, the tilting age may be ambiguous, or protracted remagnetization may yield dual polarities. Rock magnetic information can provide other constraints on our understanding of the origin of natural remanent magnetization (NRM). Here we focus on the rock magnetic properties of acknowledged remagnetized limestones and unremagnetized rocks of the Zaduo area in the Eastern Qiangtang Terrane, Tibetan Plateau (China). Chemical remanent magnetization is suggested as a more frequent mechanism than the thermoviscous resetting of the NRM. The secondary NRM resides in authigenic magnetite of stable single domain and superparamagnetic (SP) size which grew during post-depositional burial processes. Both high-field and low-field thermomagnetic runs reveal the alteration of existing iron sulfides to magnetite in the remagnetized limestones. NRM decay curves show that the maximum unblocking temperature of the remagnetized samples is significantly lower than that of the unremagnetized samples. Component analysis of acquisition curves of the isothermal remanent magnetization (IRM) reveals a hard component that represents SP magnetite in remagnetized limestones. This component is absent in unremagnetized rocks. End-member modelling reveals a convex curve in the coefficient of determination versus the number of end-members plot for the unremagnetized limestones, whereas the remagnetized rocks exhibit both near-linear and convex shapes. In addition, quantitative analysis of the hysteresis loop shape for different lithologies indicates its validity in detecting remagnetization. Furthermore, we show the differences in the hysteresis data distributions of the two rock types on the Day plot, the Néel diagram, the Borradaile diagram, and the Fabian diagram. Our research emphasizes that rock magnetic properties can serve as tools to diagnose remagnetization in magnetite-dominated rocks. We recommend a comprehensive rock magnetic study to discriminate remagnetization, involving the Day plot, Fabian diagram, thermal demagnetization curves, IRM component analysis and end member modelling.

Remagnetization of the Upper Permian–Lower Triassic limestones in the western Lhasa Terrane and its tectonic implications

SUMMARY The drift history of the Lhasa terrane plays an essential role in understanding the tectonic evolution of the Bangong-Nujiang Tethyan Ocean and the Neo-Tethyan Ocean, as well as the evolutionary history of the Tibetan Plateau. Here, a combined rock magnetic, petrographic, and palaeomagnetic study is performed on the Upper Permian–Lower Triassic limestones (∼259–251 Ma) in the western Lhasa terrane. The site-mean direction for the 28 sites is Dg = 32.1°, Ig = 50.3°, kg = 47.9 and α95 = 4.0° in situ and Ds = 342.9°, Is = 32.7°, ks = 43.2 and α95 = 4.2° after tilt-correction, yielding a palaeopole at 68.9°N, 314.4°E with A95 = 4.3°, corresponding to a palaeolatitude of 18.0° ± 4.3°N. The fold tests are not significant because the sampling section shows monoclinic features with minor variations in their bedding attitudes. The palaeopoles for the directions before and after tilt-correction are compared with reliable Late Permian–Palaeogene palaeopoles obtained from the Lhasa terrane. Based on these comparisons, the studied limestones were remagnetized prior to tilting and this remagnetization most likely occurred during the Early Cretaceous. The depositional environment of the limestones may have changed from anoxic to suboxic and oxic during the Early Cretaceous, leading to the oxidation of iron sulphide to authigenic magnetite. Meanwhile, the Late Jurassic–Early Cretaceous convergence between the western Lhasa and Qiangtang terranes may have resulted in tectonic fluid migration and the formation of calcite veins and stylolites in the limestones. This is supported by the presence of small calcite veins and stylolites in some samples, as well as the fact that the framboidal oxides were formerly sulphides (mostly pyrite), implying that the majority of the iron oxides observed in the limestones were authigenic. These processes indicate that chemical remanent magnetization caused by the growth of magnetic minerals related to tectonic fluid migration was most likely the mechanism for the limestone remagnetization.

Thermal and Structural History of Impact Ejecta Deposits, Ries Impact Structure, Germany

AbstractThe Ries impact structure (Germany) contains well‐preserved ejecta deposits consisting of melt‐free lithic breccia (Bunte Breccia) overlain by suevite. To test their emplacement conditions, we investigated the magnetic properties and microstructures of 26 polymict breccia clasts and a stratigraphic profile from the clasts into the suevite at the Aumühle quarry. Remanent magnetization directions of the Bunte Breccia clasts fall into two groups: those whose directions mostly lie parallel to the reversed field during impact carried mostly by magnetite, and those whose directions vary widely among each clast carried by titanohematite. Basement clasts containing titanohematite acquired a chemical remanent magnetization (CRM) during the ejection process and then rotated during turbulent deposition. Clasts of sedimentary rocks grew magnetite after turbulent deposition, with CRM directions lying parallel to the paleofield. Suevite holds a thermal remanent magnetization carried by magnetite, except for ∼12 cm from the contact with the Bunte Breccia, where hematite concentrations increase due to hydrothermal alteration. These observations lead us to propose a three‐stage model of (a) turbulent deposition of the melt‐free breccia with clast rotation <580°C, (b) deposition of the overlying suevite, which acted as a semi‐permeable barrier that confined hot (<300°C) oxidizing fluids to the permeable breccia zone, and (c) prolonged hydrothermal activity producing further alteration which ended before the next geomagnetic reversal. Basement outcrops have significantly different magnetic properties than the Bunte Breccia basement clasts with similar lithology. Two basement blocks situated near the inner ring may have been thermally overprinted up to 550°C.

Tracing titanomagnetite alteration with magnetic measurements at cryogenic temperatures

SUMMARY Titanomagnetite containing up to 0.6–0.7 Ti atoms per formula unit is a primary magnetic mineral phase in submarine basalts and in some terrestrial volcanic rocks. On a geological timescale, it often undergoes alteration, forming new magnetic phases that may acquire (thermo)chemical remanent magnetization. The initial stage of this natural process can be modelled by prolonged laboratory annealing at moderately elevated temperatures. In this study, our goal is to characterize the alteration products resulting from annealing a submarine basalt containing homogeneous titanomagnetite Fe3−xTixO4 (x ≈ 0.46) at temperatures of 355, 500 and 550 °C for up to 375 hr, by examining their magnetic properties over a wide range of temperatures. The effect of extended annealing is most apparent in the low-temperature magnetic properties. In the fresh sample, a magnetic transition is observed at 58 K. Below the transition temperature, the field-cooled (FC) and zero-field-cooled (ZFC) saturation isothermal remanent magnetization (SIRM) curves are separated by a tell-tale triangular-shaped area, characteristic for titanomagnetites of intermediate composition. The room-temperature SIRM (RT-SIRM) cycle to 1.8 K in zero field has a characteristic concave-up shape and is nearly reversible. For the annealed samples, the magnetic transition temperature shifts to lower temperatures, and the shape of the curves above the transition changes from concave-up to concave-down. The shape of the RT-SIRM cycles also progressively changes with increasing annealing time. The SIRM loss after the cycle increases up to ∼30 per cent for the samples annealed for 375 hr at 355 °C, and for 110 hr at 500 and 550 °C. The Curie temperatures of the newly formed magnetic phases exceed the Curie temperature of the fresh sample (205 °C) by up to 350 °C. While this effect is most commonly attributed to extensive single-phase oxidation (maghemitization), the behaviour observed at cryogenic temperatures appears incompatible with the known properties of highly oxidized titanomaghemites. Therefore, we propose that, at least in the initial stage of the ‘dry’, that is, not involving hydrothermalism, alteration of titanomagnetite, temperature- and time-controlled cation reordering is the primary mechanism driving changes in both low- and high-temperature magnetic properties.

Evaluating the Compatibility of Hematite (U‐Th)/He Data and Hematite‐Carried Secondary Magnetizations: An Example From the Colorado Front Range

AbstractAncient magnetization(s), often recorded by hematite (Fe2O3), provide key paleomagnetic constraints on plate interactions through time. Primary remanent magnetizations may be modified or overprinted by secondary processes that complicate interpretations of paleomagnetic data. Hematite (U‐Th)/He (hematite He) dating has the potential to resolve when secondary magnetizations were acquired. Here, we compare hematite He data and paleomagnetic results in Paleoproterozoic crystalline rocks, meters below a major nonconformity in the Colorado Front Range, USA. Prior work and new rock magnetic data indicate that pervasive hematite alteration records a secondary chemical remanent magnetization (CRM) during the Permo‐Carboniferous Reverse Superchron, coincident with the Ancestral Rocky Mountain orogeny. We target minor hematite‐coated faults cutting basement for (U‐Th)/He analyses because they are of sufficient hematite purity to yield geologically meaningful dates. Two samples yield overlapping and scattered individual hematite He dates ranging from ∼138 to 27 Ma (n = 33), significantly younger than the age of the late Paleozoic CRM. Scanning electron microscopy, electron probe microanalysis, and Raman spectroscopy indicate that aliquots have variable grain size distributions and fluorocarbonate impurities. Thermal history models support hematite on fault surfaces mineralized coeval with CRM acquisition during the late Paleozoic, and hematite He data scatter reflects variable He loss during Mesozoic burial owing to differences in grain size distribution from fault slip comminution and in chemistry among aliquots. Our results underscore the differences in temperature sensitivity and sampling requirements between paleomagnetic and hematite He investigations and illustrate that hematite He dates will usually be younger than preserved remanent magnetizations.

Self‐Reversed Magnetization in Sediments Caused by Greigite Alteration

AbstractMultipolarity remanence in greigite‐bearing sediments has long been recognized, but the cause of this anomalous remanence behavior is not well understood. Here, we use electron microscopic and magnetic analyses to investigate the origin of such multipolarity in Miocene greigite‐bearing sediments from the Pannonian Basin (Hungary). We find a magnetic softening and partial transformation of iron sulfides to magnetite and pyrrhotite from “single‐polarity” to “multi‐polarity” samples. The inward alteration of sulfide grains is topotactic and is size‐dependent with higher alteration in smaller grains. We propose a multi‐phase self‐reversal chemical remanent magnetization (CRM) mechanism in altered greigite: the neoformed magnetite/pyrrhotite shell acquires a CRM coupled in the opposite direction to the primary CRM of the greigite core, likely through magnetostatic interactions or interfacial exchange interactions between the closely contacting core and shell. This new greigite self‐reversal model can explain the commonly observed antiparallel polarities and has broad geochronological, tectonic and paleoenvironmental implications.

Estimating Paleointensities From Chemical Remanent Magnetizations of Magnetite Using Non‐Heating Methods

AbstractMany meteorites experienced aqueous alteration on their parent body. During this process, magnetite usually forms and acquires a chemical remanent magnetization (CRM) if growing in the presence of a magnetic field. The epoch of aqueous alteration on planetesimals encompasses the lifetime of the solar nebula. Therefore, magnetite‐bearing meteorites are potential sources of invaluable data regarding the intensity of the solar nebula magnetic field and its influence on planetary accretion. The major limitation encountered in meteorite paleomagnetic studies is the lack of an empirical law relating a CRM characterized using non‐heating methods and the magnetizing field intensity. This issue is usually bypassed using the empirical law for non‐heating methods calibrated for thermoremanent magnetizations (TRM), resulting in poorly constrained paleointensities. Here, we determine such an empirical law through a series of CRM acquisition experiments. Magnetite is grown in weakly magnetic sedimentary rocks and synthetic samples in a magnetic field while heated at 350°C for 5 hr in an argon atmosphere. All samples exhibit a high‐coercivity magnetization parallel and proportional to the field applied, identified as a CRM carried by magnetite. We determine the CRM empirical law by retrieving the applied field intensity using non‐heating methods. The empirical coefficients differ from the TRM ones by a factor of 1.9–3.2 depending on the method. We use these coefficients to revisit the paleointensities published for the CM chondrite Murchison and the C2 ungrouped Tagish Lake. This empirical law opens the door to the study of numerous magnetite‐bearing meteorites potentially carrying a CRM.

Effects of Hydrothermal Alteration and Mineralization on the Paleomagnetic Properties of Rocks from IODP Expedition 376 at Brothers Volcano

AbstractThe 3-D subseafloor architecture of submarine hydrothermal systems is largely unknown, particularly at arc volcanoes. The alteration of volcanic rocks in these systems produces dramatic changes in their magnetic properties. Here, we present the first comprehensive study of paleomagnetic measurements from oriented samples of hydrothermally altered dacites from Brothers volcano (Kermadec arc), drilled during International Ocean Discovery Program (IODP) Expedition 376. These data have enabled insight into the progressive evolution of magnetic minerals in subseafloor volcanic rocks affected by variable types and degrees of hydrothermal alteration in response to varying fluid temperatures, chemistry, and associated mineralization; from initial chloritization typical of relatively low-temperature interaction with seawater to extremely altered rocks affected by higher-temperature, very acidic magmatic fluids.Hydrothermally altered samples show a significant reduction in natural remanent magnetization intensity (10–4 to 10–2 A/m) compared with unaltered samples (1–10 A/m), suggesting that primary titanomagnetite grains are destroyed during the hydrothermal alteration process. Except for a small region in proximity to the mineralized stockwork zone, no chemical remanent magnetization is observed in association with hydrothermal alteration, consistent with the widespread formation of diamagnetic and/or paramagnetic minerals such as pyrite, rutile, and leucoxene, which do not carry any natural remanent magnetization.Demagnetization experiments show that most of the oriented samples possess a stable characteristic remanent magnetization induced by the residual primary magnetic minerals formed at the time the rocks cooled on the sea floor. Partially chloritized dacites, however, are characterized by large magnetic susceptibilities, low Koenigsberger ratios, and very low magnetic coercivities, consistent with initial dissolution of smaller, singledomain magnetic grains, indicating that intensely hydrothermally altered rocks are better paleomagnetic indicators than initially chloritized samples at the periphery of the hydrothermal systems.The significant magnetic contrast between fresh and hydrothermally altered rocks, in addition to a thick layer (>300 m) of demagnetized rocks observed at Brothers volcano, confirms the empirical results that magnetic anomalies are important geophysical tools to determine the geometry of hydrothermal systems at submarine arc volcanoes.

Remagnetization Under Hydrothermal Alteration of South Tibetan Paleocene Lavas: Maghemitization, Hematization, and Grain Size Reduction of (Titano)magnetite

AbstractThe Paleocene lavas from Dianzhong Formation (E1d) in Linzhou basin of southern Lhasa terrane are a key target for paleomagnetic investigations into the timing and paleolatitude of the initial India‐Asia collision. Controversy exists, however, on whether these rocks preserve a primary remanent magnetization. Here we reanalyze previously published thermal demagnetization data and report detailed rock magnetic results and petrographic observations of these rocks. We find that the original magnetic carrier, a magmatic multidomain Ti‐poor titanomagnetite, underwent significant grain size reduction and was variably reacted to single‐domain maghemite and nano‐hematite. Such strong alteration may have resulted from successive hydrothermal events: a first event related to the ∼52 Ma dike intrusions into the E1d that accompanied a massive ignimbrite eruption deposited above the E1d producing heating up to 300°C; and a secondary event related to the 42–27 Ma southward overthrusting of the basin, heating the E1d up to 130–145°C. Unblocking/inversion temperature spectra of the authigenic maghemite and nano‐hematite overlap with those of the titanomagnetite, implying that the primary remanence of the E1d lavas has been contaminated or replaced by thermoviscous and chemical remanent magnetizations. Thus the isolated characteristic remanent magnetization from these rocks, whether slightly or completely altered, cannot be considered primary and should not be used for paleolatitudinal determination. Our study confirms that hydrothermal alteration can seriously jeopardize the remanence carried by titanomagnetite and thus should be tested for paleomagnetic investigations of rock units from tectonically active areas.

Using Preisach Theory to Evaluate Chemical Remanent Magnetization and Its Behavior During Thellier‐Thellier‐Coe Paleointensity Experiments

AbstractThe behavior of grain‐growth chemical remanent magnetizations (gCRM) are investigated for different coercivity and magnetostatic‐interaction‐field distributions and acquisition conditions using a thermally activated Preisach model for assemblages of interacting single‐domain grains. A new growth‐rate dependent equation was derived, from which it was found that gCRM intensity is over 10% more sensitive to growth rate than previously modeled. We compare the gCRM results to the behavior of thermoremanences (TRM). gCRMs are two times more sensitive to changes in coercivity distribution, whereas TRMs are four times more sensitive to changes in magnetostatic interactions. The Thellier‐Thellier‐Coe paleointensity protocol was simulated in Preisach space, and gCRMs were found to produce concave‐up Arai plots with pTRM checks which plot to the left of the Arai plot and positive partial‐TRM tail checks that increase with magnetostatic interactions. This often leads to the failure of selection criteria, but high‐temperature segments can pass the criteria for weakly interacting gCRMs; these estimates can underestimate the field by up to 66%.

Paleomagnetic study of impactites from the Karla impact structure suggests protracted postimpact hydrothermalism

AbstractWe present a paleomagnetic study of the ~10 km diameter Karla impact structure in Russia. We sampled the target carbonate rocks, and a yet undocumented fragmental melt‐bearing lithic breccia layer. This impact breccia, which contains carbonate melt, is enriched in stoichiometric magnetite by a factor of ~15 compared to the target lithologies, and carries a stable natural remanent magnetization. The weak remanent magnetization and the presence of both normal and reverse polarities down to the centimeter scale indicate that the breccia does not carry a thermoremanent magnetization (TRM), but rather a chemical remanent magnetization (CRM). The presence of stoichiometric magnetite and the absence of TRM suggest that the magnetite was formed during relatively low‐temperature postimpact hydrothermalism that affected the porous impact breccia layer. During this process, the breccia acquired a CRM. The paleomagnetic direction is compatible with a Cenozoic age for the impact event, but cannot bring more precise constraint on the age because of the stable position of the Eurasian plate over the last 60 Myr. However, the presence of both polarities indicates that mild hydrothermalism took place over a period of time long enough to span at least one reversal of the geomagnetic field, that is, over a time scale of the order of 100 kyr. This confirms that protracted hydrothermal systems associated with impact craters are long lived, even in relatively small craters such as Karla, and are key features of the geologic and environmental effects of impacts on Earth.

Unraveling the complex burial history of the Antrim formation in Michigan basin using paleomagnetism, rock magnetism and geochemistry

This paper presents an integrated paleomagnetic, rock magnetic and geochemical study of the Devonian Antrim shale in the Michigan Basin. Specimens were obtained from two unoriented vertical cores (named St. Chester and Krocker) and sampled relative to a master specimen orientation line. Alternating field (AF) demagnetization experiments isolated a lower coercivity component (LC) from 0 to ∼60 mT in the Krocker core and corresponds to a Jurassic (170 Ma ± 25) magnetization. Higher coercivity components (HC) in the Krocker core are unblocked from ∼60 to 120 mT and unlike LC components, occasionally exhibit stable unblocking temperature ranges (e.g., 150–450°C) and higher AF demagnetization ranges (∼60–120 mT). HC components in the Krocker core are unique to certain members within the Antrim shale with a poorly resolved Middle Permian/Late Triassic magnetization in the Paxton member and Late Pennsylvanian (305 Ma ± 10) component in the Norwood. The St. Chester well exhibited a LC component among all specimens with a slightly older (205 Ma ± 10) than the Krocker core. Rock magnetic parameters indicate the magnetization resides in PSD/SD magnetite in both HC and LC components. Overall, the magnetizations are interpreted to be chemical remanent magnetizations (CRMs) with the HC component residing in SD magnetite which formed during hydrothermal activity in both cores. The LC component likely resides in PSD/MD magnetite and is interpreted to have formed in response to fluid flow associated with tectonic uplift and/or hydrocarbon migration. Petrographic observations indicate mineral assemblages consistent with hydrothermal mineralization (e.g., baroque dolomite). Depleted δ18O data from carbonate fractures are consistent with a hydrothermal fluid magnetization mechanism. Consistent anisotropy of magnetic susceptibility (AMS) lineations indicates either a long-lived paleocurrent direction or far-field tectonic shortening originating from the neighboring Acadian orogeny. Inorganic geochemistry indicate that paramagnetic Fe-rich clays carry the AMS signal. Lastly, an evaluation of the origin of chalcopyrite and monazite is performed through provenance analysis. These minerals are attributed to hydrothermal mineralization however, strong evidence suggests that some fraction of these grains were sourced from the Michigan Peninsula.

Greigite (Fe3S4) Formation in Artificial Sediments via Solid‐State Transformation of Lepidocrocite

AbstractGreigite (Fe3S4) is a ferrimagnetic iron‐sulfide mineral that forms in sediments during diagenesis. Greigite growth can occur diachronously within a stratigraphic profile, complicating or overprinting environmental and paleomagnetic records. An important objective for paleo‐ and rock‐magnetic studies is to identify the presence of greigite and to discern its formation conditions. Greigite detection remains, however, challenging and its magnetic properties obscure due to the lack of pure, stable material of well‐defined grain size. To overcome these limitations, we report a new method to selectively transform lepidocrocite to greigite via the intermediate phase mackinawite (FeS). In‐situ magnetic characterization was performed on discrete samples with different sediment substrates. Susceptibility and chemical remanent magnetization increased proportionally over time, defining two distinct greigite growth regimes. Temperature dependent and constant initial growth rates indicate a solid‐state FeS to greigite transformation with an activation energy of 78–90 kJ/mol. Low and room temperature magnetic remanence and coercivity ratios match with calculated mixing curves for superparamagnetic (SP) and single domain (SD) greigite and suggest ∼25% and ∼50% SD proportions at 300 and 100 K, respectively. The mixing trend coincides with empirical data reported for natural greigite‐bearing sediments, suggesting a common SP endmember size of 5–10 nm that is likely inherited from mackinawite crystallites. The average particle size of 20–50 nm determined by X‐ray powder diffraction and electron microscopy accords with theoretical predictions of the SP/SD threshold size in greigite. The method constitutes a novel approach to synthesize greigite and to investigate its formation in sediments.

Importance of Hematite Self‐Reversal in Al‐Rich Soils Magnetostratigraphy: Revisiting the Damei Red Soil Sequence in the Bose Basin, Southern China

AbstractUnderstanding the acquisition of chemical remagnetization that commonly takes place in sedimentary red beds is crucial not only to assess the stability of primary chemical remanent magnetization (CRM) but also to evaluate the impact of diagenesis on the paleomagnetic record. The inconsistency between the magnetostratigraphy and the 0.803 Ma age of tektites within the upper vermiculated unit of a red soil sequence (Damei) in southern China strongly suggests pervasive remagnetization. This remagnetization has previously been interpreted as a CRM lock‐in. However, our recent study suggests that the upper soil units of this section above the tektite‐bearing layer have experienced milder weathering than the underlying layer. It seems that CRM lock‐in has not completely overprinted the primary remanence of this section. To investigate the exact remagnetization mechanism, the magnetostratigraphy of the Damei sequence was revisited and the oriented samples were subjected to progressive thermal demagnetization up to 680°C (instead of 585°C in our previous study) by using a newly designed oven with ultralow magnetic field noise. The new demagnetization results for vermiculated and red clay samples document a high‐temperature (HT) remanence component above 630°C with some above 525°C, and a self‐reversal medium temperature (MT) component between 300 and 585°C. The magnetic polarities of most HT components are consistent with the tektite age. The self‐reversal MT component is carried by Al‐substituted hematite transformed from Al‐substituted maghemite. Self‐reversal likely occurred during the maghemite to hematite transformation process. Additional attention should be paid when using magnetostratigraphy to date highly weathered aluminum‐rich red sediments.

Tectonics, cooling rates and temperatures during emplacement of the Rajmahal traps, India

Paleomagnetism is used to decipher the emplacement setting of the Rajmahal traps. Sampling was restricted to flows with known age. Three magnetic minerals are identified, titanomaghemite, Ti-poor magnetite, and possibly Mg–Al-rich titanomagnetite. Detailed analysis of thermomagnetic curves revealed that the emplacement temperature for Rajmahal traps was lower than 600 °C. Two magnetization components are distinguished. The low coercivity component, probably chemical remanent magnetization, is erased in fields up to 3.1 mT. In contrast, the high coercivity thermal remanent magnetization is more stable, sometimes throughout the demagnetization. The paleomagnetic results show that the sites have suffered up to 11° of clockwise and 17° of counter-clockwise rotation. As there is no field evidence of faulting and pervasive deformation, we propose that this rotation is probably due to penecontemporaneous joints or faults. These structures could have acted as conduits for fluids that increased the cooling rate.

Seafloor Magnetism Under Hydrothermal Alteration: Insights From Magnetomineralogy and Magnetic Properties of the Southwest Indian Ridge Basalts

AbstractTitanomagnetites in mid‐ocean ridge basalt (MORB) experience variable post crystallization alterations associated with seafloor tectonic and environmental processes. Compared to low‐temperature oxidation, seafloor hydrothermal alteration is thought to be more destructive but its magnetic aftermaths are insufficiently documented. Here we present comprehensive rock magnetic and electron microscopic analyses of fresh and hydrothermally‐altered MORBs dredged from the Longqi and Yuhuang hydrothermal fields, Southwest Indian Ridge. We observe large variations in magnetic properties of fresh MORBs, originated from relative proportions of nano‐scale single‐domain to vortex state and micron‐scale vortex to multi‐domain state dendritic titanomagnetites. Progressive hydrothermal alteration produces secondary magnetite through recrystallization of exsolved and dissolved Fe from primary titanomagnetite. Exsolution is evident by a dual Verwey transition signature and coexisting Ti‐poor titanomagnetites and sphenes in partially chloritized basalts. A schematic model is proposed to explain the variations in magnetomineralogy and magnetic properties with progressive hydrothermal alteration. Intermediate hydrothermal alteration products retain a secondary chemical remanent magnetization (CRM) which is related to the long‐term magnetization variations in oceanic basalts. The established framework allows characterizing MORB hydrothermal alteration and ultimately contributes to resolving the complexity of seafloor magnetism.

Post-Depositional Fluid Flow in Jurassic Sandstones of the Uncompahgre Uplift: Insights From Magnetic Fabrics

The anisotropy of magnetic susceptibility (AMS) in sedimentary rocks results from depositional, diagenetic, syn- and post-sedimentary processes that affect magnetic grains. Some studies have also shown the potential role played by post-depositional fluid flow in detrital and carbonate formations. Here we present a new case study of Middle-Upper Jurassic sandstones where secondary iron oxides, precipitated from fluids that migrated through pores, give rise to the AMS. These sandstones are well exposed in the Uncompahgre Uplift region of the Central Colorado Trough, Colorado. The magnetic foliation of these undeformed, subhorizontal strata consistently strike NE-SW over a large distance with an average 45° dip to the SE. This steep AMS fabric is oblique with respect to the regional subhorizontal bedding and therefore does not reflect the primary sedimentary fabric. Also, outcrop-scale and microscopic observations show a lack of post-depositional plastic (undulose extinction) or pressure-solution (stylolites) deformation microstructures in these sandstones, hence precluding a tectonic origin. The combination of magnetic hysteresis, isothermal remanent magnetization, and thermal demagnetization of the natural remanent magnetization indicate that these rocks carry a chemical remanent magnetization born primarily by hematite and goethite. High-field magnetic hysteresis and electron microscopy indicate that detrital magnetite and authigenic hematite are the main contributors to the AMS. These results show that post-depositional iron remobilization through these porous sandstones took place due to the action of percolating fluids which may have started as early as Late Cretaceous along with the Uncompahgre Uplift. The AMS fabric of porous sandstones does not systematically represent depositional or deformation processes, and caution is urged in the interpretation of magnetic fabrics in these types of reservoir rock. Conversely, understanding these fabrics may advance our knowledge of fluid flow in porous sandstones and may have applications in hydrocarbon exploration.

Chronology of serpentinization: Paleomagnetic evidence for 20 Ma serpentinization of the Oeyama ophiolite, Wakasa, Southwest Japan

Serpentinization of mantle peridotite generates magnetite that is able to acquire a remanent magnetization parallel to the ambient geomagnetic field. The paleomagnetic direction of serpentine provides insights as to the timing of serpentinization. This study examines paleomagnetic properties of serpentine in the Paleozoic Oeyama ophiolite in Wakasa (35.39°N, 134.39°E), Southwest Japan. Reversed polarity magnetizations with clockwise deflections from the south were observed in the serpentine in the high temperature component (HTC) magnetization with an unblocking temperature (Tub) of ∼580°C. The mean reversed polarity direction was D = 226.0°, I=−37.8°, α95=5.9°, and n=30. The remaining samples with an HTC of Tub between 400-450°C show the present-day geomagnetic field direction. Rock magnetism reveals that the reversed direction is carried by single-domain (SD) grains of magnetite, whereas multi-domain (MD) magnetite grains carry the present-day geomagnetic field direction. Magnetite grains originated from olivine during serpentinization grew to SD size and acquired the chemical remanent magnetizations during a reversed polarity interval. As serpentinization progresses, SD magnetite grains increased to MD magnetite grains and/or were subjected to maghemitization. The mean reversed direction yielded a paleomagnetic pole at 47.4°N, 230.3°E (A95 = 5.7°), which overlaps with the 20 Ma segment of the apparent polar wander path for SW Japan. We conclude that serpentinization occurred in the Oeyama ophiolite at approximately 20 Ma during the clockwise rotation of SW Japan.