Characterization Of Biodiesel Research Articles

Experimental studies of thermal behavior, engine performance and emission characteristics of biodiesel / diesel / 1 pentanol blend in diesel engine

The present study investigates the significance of the utilization of biodiesel derived from waste cooking oil in diesel engines and its impact on engine output and environmental pollution after blending with diesel and 1-pentanol. The higher values of the ignition index and comprehensive performance index of 4.34 ×10−4mass/min°C2 and 13.71×10−6 mass2/min2 °C3, respectively, for D70B20P10 (70 % diesel, 20 % biodiesel & 10 % 1-pentanol by volume) indicate superior combustion performance. At full load, carbon monoxide and unburned hydrocarbon emissions from 1-pentanol blended fuels decrease significantly, ranging from 40 % to 52 % and 30.76–46.15 % compared to diesel. The D70B20P10 also showed an improved thermal efficiency of 28.68 % among all tested fuels at full load but slightly lower than diesel (29.56 %). Diesel demonstrated superior in-cylinder pressure (ICP) of 77 bar and heat release rate (HRR) of 41.1 J/ºCA owing to its excellent combustion characteristics. Introducing 5–10 % 1-pentanol in blend improved combustion, elevating ICP and HRR, attributed to enhanced fuel atomization and oxygen content. The sustainable process index value obtained for a global index per person is 0.002×10−4cap Litre-1, which lies between 0 and 1, indicates sustainability and compatibility of biodiesel production demonstration by universal biofuels (Andhra Pradesh).

Experimental Analysis of Cycle Tire Pyrolysis oil Doped with 1-decanol + TiO2 additives in Compression Ignition Engine using RSM Optimization and Machine Learning Approach

This study investigates the effect of TiO2 nano additives in conjunction with 1-decanol on the performance and emission characteristics of biodiesel. The analysis involves four different blends: 90D7TO3DO+25 ppm TiO2 (90% Diesel+7% Tire oil + 3% decanol and 25 parts per minute Titanium dioxide), 80D14TO6DO+50 ppm TiO2 (80% Diesel+14% Tire oil + 6% decanol and 50 parts per minute Titanium dioxide), 70D22TO8DO+75 ppm TiO2, (70% Diesel+22% Tire oil + 8% decanol and 75 parts per minute Titanium dioxide), and 100TO+100 ppm TiO2.( 100% Tire oil + 100 parts per minute Titanium dioxide), (DOE), design of experiments approach is used in this analysis. BTE is high for 90D7TO3DO+25 ppm TiO2 (36.12%), compared to Diesel (30%), i.e. 90D7TO3DO+25 ppm TiO2 possesses 20.67% higher than diesel. The blend 90D7TO3DO+25 ppm TiO2 exhibited the lowest fuel consumption (0.25 kg/kWh), compared to diesel (0.28 kg/kWh), i.e. it was 12% less than diesel. Inline cylinder pressures were optimal at 70 bar for the blend 90D7TO3DO+25 ppm TiO2, indicating favorable combustion properties. In terms of emissions, diesel emits NOx (1850 ppm), and the blend 100TO+100 ppm TiO2 achieved the lowest NOX emission of 1550 ppm, representing a 16.3% reduction compared to diesel. The RSM model's coefficient of determination (R-squared) for all the parameters considered was remarkably high (nearly 0.98), meaning that it accounts for 98.00% of the variability in the parameters. The corrected R-squared value validates the model's robustness. The results of the coefficient of determination (R2) for Bayesian Ridge regression clearly illustrate that the method is capable of making accurate predictions across the majority of the measurements as compared to Random Forest (RF).

Response surface methodology optimization of characteristics of biodiesel powered diesel engine and its effective integration to autonomous microgrid

An optimum diesel engine load condition with higher thermal efficiency and energy management has been the foremost challenge in the renewable energy research field. Modern trends involve nano additives for obtaining high performing biodiesel blends. Considering the above-mentioned factors, an experimental study along with statistical analysis has been performed with variation of compression ratio (16, 17.5 & 18), ZrO2 nano additive (50, 100 & 150 ppm) and load (50, 75 & 100 %). The optimization was accomplished by diminishing the BSFC, NOx, HC, CO, and increasing the BTE, CO2 using the approach of desirability. From the obtained results, the optimum operating conditions of the engine were found to be 75 % load, 18:1 compression ratio, and 150 ppm ZrO2 nano additive. The actual values at optimized conditions are obtained as BSFC (0.27 kg/kWh), BTE (33.37 %), CO (0.71 %), CO2 (8.69 %), NOx (1270 ppm), HC (62 %) and Smoke (25.20 %) with error less than 5 %. It has been observed that the BSFC of the proposed biodiesel-diesel blend is lower than that of pure diesel in all levels of power output. The biodiesel fuelled diesel engine is integrated as backup power in autonomous microgrid with main power as solar PV system operated at MPPT mode. A hybrid power system based on solar PV and biodiesel generator set up is the better alternative to emission-intensive fossil fuel and intermittent renewable.

Boosting biodiesel production from waste vegetable oil water using Acid-Base Sequential Catalysis

<p>The use of active and recyclable catalysts is advantageous for catalytic biodiesel synthesis from waste vegetable oils which is in demand owing to frequent calls on environmental pollution and for clean renewable energy production. For this study, homogenous catalysts are effective at converting single-origin feedstocks low in free fatty acids (FFA) and water into biodiesel. Biodiesel production based on waste vegetable oil was carried out to establish an optimal catalyst régime. Acid-catalyzed transesterification and sequential base catalysis were used to convert waste vegetable oil to biodiesel at varying amounts of catalyst (0.46-0.58%) and different contact times (1-2 hr). Optimal yields were obtained at 2 hrs contact time and 0.50% amount of catalyst. Characterization tests conducted were specific gravity (0.8718-0.8935), flash point (117-1370C), viscosity (4.29-6.09mm2/s) and cetane index (40-43) values were within biodiesel specifications. The study, therefore, confirmed that acid-base sequential catalysis holds a lot of promise for the creation of affordable, environmentally friendly technologies. The biodiesel's characteristics were also in good agreement with American (ASTM D6571) fuel specifications. Therefore, the work recommends the utilization of acid (H2SO4) and base (NaOH) catalysis in the technologically enhanced conversion of waste vegetable oil into biodiesel.</p>

Effect of antioxidants on CI engine characteristics of safflower biodiesel with varying fuel injection pressures

A product of microorganisms, crop plants, and animal-based oil, biodiesel holds excellent promise as a sustainable energy resource and a solution to the world's rising energy issues. Biofuel resembles the qualities of fossil diesel, while it is also proven to be a greener fuel and viable alternative. To enhance the properties of biodiesel, the additives, mainly antioxidants, were added to the 20 % blend of safflower biodiesel (B20) at various injection pressures (190, 200, and 210 bar). At a concentration of 1000 ppm, the antioxidants, namely BHA (butylated hydroxy anisole) and BHT (butylated hydroxytoluene), were added to the B20 blend of higher IP. Investigation on the effects of antioxidants with biodiesel on the performance and emission characteristics were tested in CI diesel engines at different injection pressures (IP). The findings from this study indicate that antioxidants added to biodiesel significantly improved the engine's performance. Higher IP resulted in higher BTE (1.6 %) with lesser emissions of CO (33.33 %), HC (10 %) and smoke (19.5 %) than diesel. But it emits higher NOx emissions (2.5 %). The addition of the antioxidant BHA showed a decrease in NOx emissions by 5 % to higher IP. Thus, the safflower biodiesel B20 added with antioxidant BHA will likely be a tremendous alternate fuel for the CI engine.

Obtaining and characterization of biodiesel by transesterification from sunflower oil

Obtaining and characterization of biodiesel by transesterification from sunflower oil

Enhancement of biomass productivity and biochemical composition of alkaliphilic microalgae by mixotrophic cultivation using cheese whey for biofuel production

The growth of microalgae under alkaline conditions ensures an ample supply of CO2 from the atmosphere, with a low risk of crashing due to contamination and predators. The present study investigated the mixotrophic cultivation of two alkaliphilic microalgae (Tetradesmus obliquus and Cyanothece sp.) using cheese whey as an organic carbon source. The variation in cheese whey concentration (0.5–4.5% (v/v)), culture pH (7–11), and NaNO3 concentrations (0–2 gL−1) was evaluated using central composite design in response to biomass productivity and the contents of lipids, total proteins, and soluble carbohydrates. Both investigated microalgae effectively utilized cheese whey as an organic carbon source. The optimum conditions for simultaneously maximizing biomass and lipid productivity in T. obliquus were 3.5% (v/v) whey, pH 10.0, and 0.5 g L−1 NaNO3. Under these conditions, the biomass, lipid, soluble carbohydrate, and protein productivities were 48.69, 20.64, 7.02, and 10.97 mg L−1 day−1, respectively. Meanwhile, Cyanothece produced 52.78, 11.42, 4.31, and 7.89 mg L−1 day−1 of biomass, lipid, carbohydrate, and protein, respectively, at 4.5% (v/v) whey, pH 9.0, and 1.0 g L−1 NaNO3. The lipids produced under these conditions were rich in saturated fatty acids (FAs) and monounsaturated FAs, with no polyunsaturated FAs in both microalgae. Moreover, several biodiesel characteristics were estimated, and results fell within the ranges specified by international standards. These findings indicate that the mixotrophic cultivation of alkaliphilic microalgae could open new avenues for promoting microalgae productivity through low-cost biofuel production.

Harnessing waste glycerol to mitigate salinity constraints in freshwater microalgae cultivation for enhanced biodiesel recovery

The current study investigated the synergistic effect of waste glycerol and salinity on Scenedesmus obliquus cultivation for enhanced biomass and biodiesel production. Optimal glycerol concentration was identified at 0.08 M supplementation, resulting in 23.1 % significant increase in biomass productivity. However, higher glycerol concentrations resulted in growth retardation. Salinity of +200 % NaCl showed positive impact on the growth, with the highest recorded dry weight of 1.76 g/L and biomass productivity of 0.206 g/L.day. However, further increases in salinity resulted in 53.4 % reduction in biomass yield at +800 % NaCl compared to +200 % NaCl. The combined treatment of the optimum glycerol concentration at different salinities (Glyc + Salin) showed superior growth performance up to +600 % NaCl, which confirmed mitigation of salinity inhibitory effects. Glyc + Salin exhibited the highest recorded nitrogen and phosphorus removal efficiencies (98.1 % and 96.6 %, respectively at day 8), dry weight (2.02 g/L), and biomass productivity (0.231 g/L.day). Notably, lipid content increased to 240.4 mg/g dw, and lipid productivity reached 56.0 mg/L.day, representing 76.1 % improvement over the control. Biodiesel characteristics, including cetane numbers and iodine values, showed also improvement, confirming the potential of Glyc + Salin for sustainable microalgal cultivation and biodiesel production.

Unleashing the power of non-edible oil seeds of Ipomoea cairica for cleaner and sustainable biodiesel production using green Molybdenum Oxide (MoO3) nano catalyst

This research aims to conduct a thorough analysis of the novel and cost-effective use of Ipomoea cairica L. seeds as a potential feedstock for green energy technologies. Ipomoea cairica L. seeds (42 % oil, 0.67 % free fatty acid content) were used as a promising source for producing sustainable biodiesel using novel green Molybdenum Oxide (MoO3) nanocatalyst. The Ipomoea cairica seeds utilized in this study serve a dual purpose: they provide feedstock for the future energy mix, and their seed shells (considered waste) are used as a starting material for synthesizing green nanocatalysts. The highest biodiesel yield of 95 % was achieved under optimal reaction conditions of 1:15 oil to methanol molar ratio, 50 °C, 120 min, and 0.4 (wt.%) catalyst loading. In order to evaluate the quality and characteristics of the resultant biodiesel and synthesized nanocatalyst, a detailed examination was conducted utilizing analytical techniques such EDX, XRD, FTIR, SEM, NMR (1H, 13C) and GC–MS analysis. The phytofabricated nanocatalyst unveils highest recyclability (up to 5 cycles), reactivity, stability and efficiency during transesterification operations. The produced biodiesel was also optimized using response surface methodology (Box-Behnken Design). When compared to conventional diesel, the biodiesel made from Ipomoea cairica L. seed oilshowed better oxidative stability and reduced viscosity, suggesting that it might be a viable replacement for conventional fuel without compromising engine performance. Moreover, using untamed, uncultivated, and non-edible seed plants to produce biodiesel presents a chance to move toward a more sustainable and environmentally friendly energy plan.

Production and Characterization of Ackee Apple (Blighia sapida) Seeds and African Star Apple (Chrysophyllum albidum) Seeds Oil Mixtures and their Biodiesel

This paper focused on the characterization of oils and biodiesels derived from Ackee apple seeds and African star apple seeds obtained from local markets. The oils from individual seeds and their mixtures at varying ratios were characterised for relative density, free fatty acid, acid, iodine, and saponification, which yielded 0.91 g/cm3, 1.06 mg-KOH/g, 2.12 mg-KOH/g, 38.36mg-iodine/100g, and 195.74 mg-KOH/g of ackee seed oil, respectively. And 0.89 g/cm3, 2.105 mg-KOH/g, 4.2 mg-KOH/g, 52.49 mg-iodine/100 g, and 227.7 mg-KOH/g of African star apple seed oil, respectively. The highest relative density of 0.9064 g/cm3 and free fatty acid of 3.73 mg-KOH/g were achieved from the mixture of ackee apple and African star apple seeds’ oils at 80 and 20%, respectively, while the highest saponification of 221.264 mg-KOH/g and iodine of 49.66 mg-iodine/100 g were obtained from the oil mixture of 20 and 80%, respectively. Also, the oils extracted from the seeds, were subjected to a transesterification process to produce biodiesel. 144°C flash point, 206°C fire point, and 2.8°C cloud point were obtained from the biodiesel of the oil mixture of 20 and 80%, respectively. Further analysis of the mixtures showed low volatility and high resistance to fire due to their high flash and fire points. The highest value recorded for the flash point is lower when compared with some other seed oils flash points; however this value is higher than the standard flash point for biodiesels .Highest boiling point of 64°C was attained at an oil mixture ratio of 60 and 40%, respectively. This value is too low compared to the normal boiling point range of 315-350°C for biodiesels, and the high acid values recoded for the mixtures make the oils inedible. The oils, however, have advantages over other edible seed oils as they will serve as valuable ingredients in the soap-making industries since they are not competing with food resources.

Analysis of biodiesel and fatty acids using state-of-the-art methods from non-edible plants seed oil; Nicotiana tobaccum and Olea ferruginia

The long-term socioeconomic and environmental alternative to fossil fuels is biodiesel. Current biodiesel manufacturing research has developed competitive, sustainable methods. The study validates and explains biodiesel benefits while increasing output. Physicochemical characterizations, gas chromatography-mass spectrometry (GCMS), Fourier transform infrared (FTIR), elemental analysis (EA), inductively coupled plasma atomic emission (ICP-OES), and nuclear magnetic resonance (NMR) are studied. In this study, we discovered two inedible plant seeds, specifically Olea ferruginea (OF) and Nicotiana tobaccum (NT), which exhibited significant oil contents of 30–49% by weight; both seeds had minimal amounts of free fatty acids contents of 1.1% and 0.9%, and biodiesel yield 96.4–97.9% after an optimization process, i.e., methanol/ oil ratio (6:1), KOH concentration (0.32), temperature (65 °C), stirring rate (700 rpm), and time (60 mins). A comprehensive analysis was performed to investigate and contrast the physical, chemical, and compositional attributes of the FAMEs with those of mineral diesel. Gas chromatography determined biodiesel's chemical composition and detected various fatty acid methyl esters (FAMEs) i.e. palmitic (9.7–14.0), stearic (1.8–3.2), oleic (25.5–47.2), linoleic (8.5–32.2), α-Linolenic (3.6–1.1), arachidic (2.4–0.8), and gondoic acid was (48.5–0.5%), respectively. In novel biodiesel characterization, NMR spectroscopy defines and assigns sample chemical structures to identify and quantify unsaturated long-chain alkyl esters. NMR spectroscopic biodiesel methanol quantification is an alternative to official methods. 1H NMR revealed the molecular hydrogen nuclei. This study examines all biodiesel purity and transesterification performance parameters. Producing cost-effective and optimal biodiesel requires the intent of these properties. Inedible seeds can be cultivated in infertile terrain to improve biodiesel production and solve the energy dilemma.

The Combustion and Emission Characteristics of Corn Oil Biodiesel with Titanium Oxide (TiO2) Nano-additive

This experiment produced biodiesel from corn oil through transesterification. Fuel mixture proportions were changed to assess engine performance and reduce fossil fuel emissions. This study examined brake power, mean effective pressure, mechanical efficiency, brake thermal efficiency and indicated thermal efficiency, and emissions such as hydrocarbons, carbon monoxide and NOx. 20% of corn oil was blended with diesel to make biodiesel. The fuel characteristics of the corn oil methyl ester matched ASTM standards. Experimental results were obtained by operating a single-cylinder four-stroke diesel engine under various load conditions. Titanium oxide nanoparticles in the biodiesel reduced HC and CO engine emissions whereas, there was an increase in CO2 and NOx emissions. Combustion parameters such as cumulative net heat release rate and fuel line pressure decreased whereas, cylinder pressure and net heat release rate increased; the sample BD20 + 100 ppm TiO2 sample exhibited appreciable results.

Exploring the efficiency and emission characteristics of hydroxy-boosted canola biodiesel in comparison to traditional diesel fuels

In this research, we experimentally examined how incorporating HHO into blends of 20% canola biodiesel with 80% diesel and 40% canola biodiesel with 60% diesel impacts the engine’s performance and its emission traits. Canola oil, widely used in Europe, served as the biodiesel base. The addition of HHO, recognized for its potential to improve combustion efficiency and reduce emissions which were deteriorated by biodiesel addition. The findings revealed decrement on fuel consumption as 5.74% and 4.43% and rise in thermal efficiencies as 3.92% and 3.97% with HHO addition compared to B20 and B40, respectively. Besides that, CO emissions were reduced significantly up to 35.43%, while CO2 emissions decreased moderately up to 14.93% compared to diesel fuel. On the other hand, biodiesel and HHO addition increased NOx emissions as 49.80%. Utilization of biodiesel and HHO in diesel engines offers a straightforward way to reduce emissions and enhance fuel efficiency, addressing environmental issues and promoting sustainable transportation.

Characteristics of Biodiesel Produced from Crude Palm Oil through Non-Alcohol Synthesis Route Using Dimethyl Carbonate and Immobilized Eco-Enzyme Catalyst

Biodiesel, an alternative to traditional diesel, is essential for the sustainability of long-term energy supplies and often synthesized through a non-alcoholic route called interesterification. The described synthesis method facilitates the modification of oil and fat by exchanging acyl radical groups between triglyceride and alcoholic acid (alcoholysis), fat (acidolysis), or ester (transesterification). Therefore, this research aimed to determine the effect of the reactant ratio between crude palm oil (CPO) and dimethyl carbonate (DMC), along with the use of an eco-enzyme catalyst, on biodiesel characteristics. The CPO:DMC ratio was 1:1.5, 1:2, 1:2.5, and 1:3, while the immobilized eco-enzyme catalyst was 2%, 3%, 4%, 5%, and 6% of CPO mass. The results showed that interesterification with a 1:3 reactant ratio using a 4%wt catalyst was the best procedure, producing biodiesel yield of 73.65%, density of 0.860 g/mL, viscosity of 4.63 mm2/s (cSt), flash point of 113 °C, calorific value of 34.454 MJ/kg, and cetane number of 70.6%.

Physical-Chemical Properties of First-Generation Biofuel Aiming Application in Diesel Locomotive

Theoretical framework: A biodiesel fuel is made from long-chain fatty acids derived from vegetable oil or animal fat. Similarities between physical-chemical characteristics of diesel and biodiesel make their mixture feasible. Environmental benefits achieved by using biofuels to drive machines has increased their contribution in energetic matrixes. Objective: The aim of this research is to produce soybean and sunflower biodiesel in the laboratory using a transesterification reaction and to examine the biodiesel specifications for utilization in compression ignition engines. Method: The physical-chemical properties of the biodiesel measured in the present work are density, viscosity, cetane index, flash point, pour point, and cloud point. Results and conclusion: For soybean and sunflower biodiesel, density (867 kg/m³, 860 kg/m³), viscosity (5.29 mm²/s, 5.30 mm²/s), Centane index (53.88, 55.66), flash point (187°C and 135.6°C) are reported respectively. Regarding the pour point, cloud point, were only determined for sunflower biodiesel, respectively, -2°C and 13°C. The results indicate that these properties, density, kinematic viscosity, flash point, as determined from the soybean and sunflower biodiesel are within the limits established by The Brazilian National Agency of Petroleum, Natural Gas and Biofuels, Resolution No. 45 of the ANP of 08/25/2014 – DOU 08/26/2014. These values are, respectively, 850-900 kg/m³, 3-6 mm²/s, at least 100°C.The produced biodiesel presented behavior similar to diesel S10 proving its viability of use. Research implications: As a result of such thorough research, we are able to compare many characteristics of soybean and sunflower biodiesel with commercial diesel S10. This research is critical to the performance evaluation of a compression ignition engine and the potential reduction in greenhouse gas emissions associated with conventional diesel.

Experimental investigation and gray relational optimization of engine parameters to improve the output characteristics of an ammonia biodiesel powered dual fuel combustion engine

An innovative approach to this research is to evaluate the effects of different concentrations of biodiesel with premixed ammonia energy in a dual-fuel combustion engine and determine the best operating conditions for optimal engine responses. Experimental results of a 40% ammonia energy premixing fraction with direct injection of a biodiesel blend of 30% (40%AEPF + B30) at 80% load improved brake thermal efficiency (BTE) by 8.42% while reducing brake specific energy consumption (BSEC) by 13.28%. It also reduces the hydrocarbon (HC) emission by 16.8%, the carbon monoxide (CO) emission by 15.06%, and the smoke opacity by 26.8%. As opposed to this, carbon dioxide (CO2) and nitrogen oxide (NOx) emissions are elevated by 21.5% and 16.54%, respectively, relative to the 40% ammonia energy premixing fraction with direct injection of diesel (40%AEPF + Diesel). Thereafter, the ANOVA technique is also utilized to analyze the impact of operational parameters, and the findings show that the responses are statistically significant. Additionally, the results are utilized in a grey relational analysis (GRA) based optimization process to determine the appropriate operational variables. According to optimization results, 40%AEPF + B30 at 80% load provides the most efficiency and fuel economy. It is capable of being used as an alternate fuel instead of conventional diesel.

Manufacturing Biodiesel from Cooking Oil Teaching Factory Products Using Bentonite Catalyst with Non-Alcohol Route Method

This research investigates an eco-friendly approach to biodiesel production through non-alcoholic pathways using heterogeneous catalysts. The study examines various ratios of methyl acetate to cooking oil and temperatures, revealing that the optimal conditions for biodiesel production are a 1:4 ratio, utilizing a bentonite catalyst (0.75 g), operating at 60°C for 120 minutes. Fourier Transform Infrared Spectroscopy (FTIR) analysis confirms the presence of ester groups, the primary component of biodiesel. Most biodiesel characteristics align with quality standards, including density (0.8844 kg/m3), cetane number (61.9), and acid number. However, the biodiesel flash point falls below the minimum standard, suggesting a potential area for improvement. This research underscores the potential of using methyl acetate as a heterogeneous catalyst for biodiesel production, with most biodiesel characteristics meeting established quality standards, although further work may be needed to address the flash point issue.

Biodiesel production and exploring properties of Datura stramonium L. oil with its optimization using combined approaches-Taguchi, grey relational analysis, and response surface methodology.

Biodiesel production through the synthesis of Datura stramonium L. oil is studied to explore the most efficient approaches to suggest an alternate feedstock for biodiesel production. The main objective of this work is to optimize the process variables of biodiesel synthesis by using some statistical approach (Taguchi method, grey relational analysis (GRA), and response surface methodology (RSM) analyzing three parameters, i.e., alcohol-to-oil molar ratio, catalyst (NaOH) concentration, and process temperature for achieving maximum biodiesel derived from Datura stramonium L. oil. The transesterification process is applied by using an ultrasonic-assisted technique. Grey relational analysis (GRA) was successfully applied with the Taguchi method resulting in the optimum combination of A2B1C1. Based on the findings, the best operating conditions for transesterifying are attained with the RSM approach consisting of a 5.697:1 molar ratio (level 2), 0.3 (wt.%) NaOH concentration (level 1), and 70 °C process temperature (level 1). With a value of 87.02%, these ideal operating conditions produce the maximum yield as compared to grey relational analysis (GRA) yields 83.99%. The obtained results have been verified through the characterization of oil and biodiesel as well. Also, the fuel qualities of DSL biodiesel were identified and assessed. DSL oil was found 137.6 degrees of unsaturation during fatty acid profile analysis. DSL biodiesel was found the best kinematic viscosity (4.2 mm2/s) and acid value (0.49) when compared to Karanja and palm biodiesel. D. stramonium L. was recognized as a suitable species for biodiesel feedstock according to the findings.

Production of Biodiesel from Candlenut Seed Oil (Aleurites Moluccana Wild) Using a NaOH/CaO/Ca Catalyst with Microwave Heating

Oil fuels derived from fossils are non-renewable, so over time, they will run out and have a negative impact on air pollution. To overcome this, there is a need for environmentally friendly alternative fuels from renewable sources such as biodiesel. This research used microwave heating with a CaO catalyst. NaOH-impregnated snail shells and active carbon support. This research aims to determine the effect of power on the conversion of candlenut seed oil into biodiesel using the NaOH/CaO/CA catalyst both in terms of compliance with the SNI 7182-2015 standard and analysis using GC-MS (Gas Chromatography-Mass Spectrometry). The synthesis of the NaOH/CaO/CA catalyst was carried out through wet impregnation and calcination at a temperature of 500°C and analyzed using gas sorption analysis (GSA). Then proceed to the transesterification process, where the power for microwave heating was varied to 300, 450, and 600 watts with a mole ratio of esterified oil and methanol, namely 1:10 for 3 minutes. The analysis results of the NaOH/CaO/CA catalyst using the GSA instrument have a surface area of 9.306 m2/g, pore volume of 0.033 cc/g, and pore diameter of 14.043 nm. Meanwhile, the results of the biodiesel analysis showed that the optimum biodiesel yield was 85.625% at 600 watts of power and had a kinematic density and viscosity that met the SNI 7182-2015 biodiesel standards. Analysis of biodiesel characteristics using GC-MS showed that the three most optimum biodiesel components were hexadecanoic acid, methyl ester (22.664%), 9,12-Octadedecadienoic acid (Z,Z)-, methyl ester (30.176%) and 9-Octadecenoic acid (Z)-, methyl ester (38.656%).

Characterization and optimization of waste-derived biodiesel utilizing CNT/MgO nanocomposite and water emulsion for enhanced performance and emission metrics

Efficiently managing agricultural plant residues is a growing concern, leading to a focus on converting waste materials into valuable resources. The Rutaceae family, especially Citrus maxima peel oil (CMPO), has potential for biofuel production, but research on its use remains limited, especially in terms of fuel modification. This study aims to extract biofuel from Citrus maxima peel and characterize its chemical components. To enhance efficiency and align with environmental goals, the study suggests integrating water and a nanocomposite into CMPO. An eco-friendly method was employed to synthesize a carbon nanotube (CNT)-induced magnesium oxide (MgO) nanocomposite that was extensively characterized. Fuel combinations were derived using a Box-Behnken design matrix, and optimization followed, emphasizing performance and emission parameters. Analysis of the elemental composition and free fatty acid profile of extracted CMPO highlights its potential as an alternative fuel. Optimal concentrations of CMPO, water, and nanocomposite in diesel fuel were found to be 27.6%, 12.2%, and 64.9 ppm, respectively. Confirmation tests validated improved performance and emission outcomes under these optimal conditions. Projected performance and emission parameters closely align with experimental findings. The proposed fuel combination is expected to achieve a significant 40% reduction in the demand for petroleum derivatives.