Characteristics Of Groundwater Research Articles

Groundwater Characteristics’ Assessment for Productivity Planning in Al-Madinah Al-Munawarah Province, KSA

In recent times, drilling groundwater wells for irrigation, domestic, and industrial uses is increasing at a high rate in Saudi Arabia, meaning that groundwater is becoming a primary water resource. In the study region, over-exploitation and unsustainable performance severely deteriorate groundwater. Therefore, it is important to monitor the groundwater levels and quality as well as to detect the hydraulic parameters in order to plan and maintain groundwater sustainability. Knowledge of aquifer hydraulic parameters and groundwater quality is essential for the productivity planning of an aquifer. Therefore, this study carried out a thorough analysis on measured depth to groundwater data (2017 and 2022), borehole pumping test records, and chemical analysis of the collected water samples, especially in the presence of overexploitation and scarcity of recharge scale. To accomplish this aim, measurements of 113 groundwater wells (including 103 water samples) and analysis of 29 pumping tests between step and long-duration tests were made of all aquifer characteristics. These parameters consist of well loss, formation loss, well efficiency, specific capacity, transmissivity, hydraulic conductivity, resulted drawdown, and physiochemical parameters. Thematic maps were generated for all parameters using the geographic information system (GIS) and diagrams to strategize the groundwater productivity in Al-Madinah Al-Munawarah Province. The estimated hydraulic parameters are highly variable. Four distinct portions were identified for aquifer potentiality based on these varying ranges. Both the north and east of the region are good for groundwater productivity due to good aquifer materials, whereas the southwestern and western portions have relatively poor values. The analyzed groundwater was categorized as fresh to slightly salty water, with two primary chemical types identified showing a prevalence of mixed NaCl and Ca-Mg-SO4/Cl water. Finally, groundwater productivity assessment predicts that the aquifers can support the Al-Madinah Al-Munawarah Province demand for several years if certain well distributions are adopted and for a few hours/day of pumping rate. The maps that have been created can be examined to aid in making decisions related to hydrology.

General Hydrogeochemical Characterization of Groundwater in Coastal Aquifers of Kilwa Kisiwani Oceanic Island, South East Tanzania

General Hydrogeochemical Characterization of Groundwater in Coastal Aquifers of Kilwa Kisiwani Oceanic Island, South East Tanzania

Demystifying Heavy Metals and Physicochemical Characteristics of Groundwater in a Volcano-Tectonic Region of Middle Awash, Ethiopia, for Multipurpose Use

Demystifying Heavy Metals and Physicochemical Characteristics of Groundwater in a Volcano-Tectonic Region of Middle Awash, Ethiopia, for Multipurpose Use

Framework for mapping large-scale nature-based solutions for drought mitigation: Regional application in Flanders

Droughts are classified as the most expensive climate disasters as they leave long-term and chronic impacts on the ecosystem, agriculture, and human society. The intensity, frequency, and duration of drought events have increased in the past and are expected to continue rising at global, continental, and regional scales. Nature-based solutions (NBS) are highlighted as effective solutions to cope with the future impacts of these events. Despite this, there has been limited comprehensive research on the effectiveness of NBS for drought mitigation, and existing suitability mapping frameworks often overlook drought-specific criteria. To address this gap, a new framework is proposed to identify areas suitable for two drought-coping NBS types at a regional scale: detention basins and managed aquifer recharge. Two multi-criteria decision-making techniques (MCDM), i.e. Boolean logic and Analytic- Hierarchy Process (AHP), were used to map suitable large-scale NBS. The new framework accounts for unique criteria to specifically address drought conditions. By incorporating climate change scenarios for both surface and groundwater, recharge, and different groundwater characteristics, it identifies suitable and sustainable locations capable of managing extreme drought events. Executed through Boolean logic at a regional scale in Flanders (Belgium), the framework's strict approach yields significant potential areas for detention basins (298.7 km²) and managed aquifer recharge (867.5 km²). Incorporating AHP with the same criteria introduces a higher degree of flexibility for decision-makers. This approach shows a notable expansion across Flanders, varying with the level of suitability. The results underscore the highly suitable potential for detention basins (2552.2 km²) and managed aquifer recharge (2538.7 km²), emphasizing the adaptability and scalability of the framework for addressing drought in the region. The comparison between potential recharge volume due to detention basin and groundwater use in the region indicated that the detention basins could partially compensate for the high water demand. Therefore, creating a framework targeting drought is vital for the sustainable management of water scarcity scenarios.

Hydrochemical Characteristics of Groundwater and Its Influencing Factors in Yuanzi River Basin, Shuozhou, Shanxi, China

Hydrochemical Characteristics of Groundwater and Its Influencing Factors in Yuanzi River Basin, Shuozhou, Shanxi, China

Hydrogeochemical characteristics of shallow groundwater and salinization evaluation in the coastal aquifers of Cangzhou, China

To investigate the hydrogeochemical characteristics of shallow groundwater and evaluate groundwater salinization state in Cangzhou, China, two sampling campaigns have been conducted. In summer, 33 groundwater samples, 3 seawater samples and 5 river water samples were collected. In winter, 22 groundwater samples were collected. The hydrochemical type was determined by the Piper diagram. Evolution mechanisms of groundwater were analyzed by the Gibbs diagram. The trend of de-salinization or salinization of groundwater was determined by the hydrochemical facies evolution diagram. The groundwater salinization grade was evaluated by both the seawater intrusion groundwater quality index (GQISWI) and the attribute recognition model based on entropy weight (ARMEW). The Piper diagram shows that Na+ is the dominant cation and Cl- is the dominant anion in shallow groundwater, and the groundwater in this area is mainly of Cl-Na type followed by Cl-Ca·Mg type. The evaporation-crystallization process has significant influence on the evolution of saline groundwater. In summer, most brackish groundwater exhibit compositions of the freshening stage with direct cation exchange, and most saline groundwater is mainly at the seawater intrusion stage with reverse cation exchange. In winter, compared to the summer season, more groundwater samples in the middle of study area exhibit intrusion trend, and without obvious Na-HCO3 facies. In summer, values of GQISWI range from 20.47 to 75.38 with an average of 59.31. The GQISWI gradually increases from east to west, denoting the degree of groundwater salinization is alleviated from coast to inland. In winter, values of GQISWI range from 54.47 to 79.09 with an average of 66.00, slightly higher than that in summer. The proportion of no salinization (Grade I), minor salinization (Grade II) and serious salinization (Grade III) of groundwater samples in Cangzhou identified by ARMEW is 3.0%, 21.2% and 75.8% in summer, respectively. In winter, the proportion is 9.1% for Grade II and 90.9% for Grade III. The GQISWI index shows the largest area of Grade II, and ARMEW presents the largest area of Grade III in both seasons. Compared with GQISWI index, ARMEW model gives more conservative evaluation results of groundwater salinization. The results provide useful information on the groundwater salinization status for the local area, and help for the management of groundwater resources in Cangzhou.

Origin and Geochemical Characterization of Groundwater from Coal Seam: A Case Study of Balasu Coalfield, Ordos Basin.

The hydrochemical characteristics of groundwater are of great significance for studying the source, development, and utilization of groundwater. This study investigated the characteristics of anions and cations, total dissolved solids (TDS), hydrochemical types, and hydrogen and oxygen isotopes of surface water and groundwater in the Balasu coalfield. By conducting experiments using inductively coupled plasma emission electron spectrometry, ion chromatography, acid-base titration, and gravimetric analysis, the characteristics of ion concentration and TDS in different aquifers were analyzed to determine the possible source of groundwater in C2 (number 2 coal seam in Yan'an Formation). The Piper trilinear diagram was used to determine the hydrochemical types of aquifers, and the source of groundwater was determined based on the stable isotope characteristics of hydrogen and oxygen. The changes in ion, TDS, hydrogen, and oxygen isotopes of surface water and groundwater were analyzed, and the groundwater differences between the two sets of coal seams were compared. The research results indicate that the groundwater in C2 (number 2 coal seam in Yan'an Formation) is caused by the original sedimentary water and the infiltration of Zhiluo Formation and A1 (strata at the top of the Yan'an Formation to number 2 coal seam). However, C4 (number 3 coal seam in Yan'an Formation) is hindered by the well-developed mudstone in A3 (bottom of number 2 coal seam to the top of number 3 coal seam), which hinders the infiltration of groundwater. The study emphasizes that the overlying strata can have a significant impact on the coal seam when the moisture content is high and there is a lack of overlap, thereby promoting changes in the moisture content of the coal seam. This study provides some insights into the safety of coal mines, especially in mining areas with a high coal seam moisture content.

Sustainable water–ecosystem management using the Bayesian network and variable relationship analysis

ABSTRACT Under the pressures of global climate change and human activities, the carrying capacity of water and soil resources in agricultural lands has decreased, and the traditional models of agricultural development are no longer sustainable. Land degradation, groundwater quality reduction and ecosystem instability are the consequences of agricultural development without considering sustainability indicators. This article aims to investigate the use of variable relationship analysis and Bayesian network methods to analyze and investigate the relationship between irrigation in agriculture and the sustainability of the groundwater ecosystem. Descriptive statistics of agriculture including cultivation pattern, time, precipitation, irrigation, and land slope were analyzed and combined with the simulated characteristics of groundwater including specific yield, hydraulic conductivity and hydrodynamic diffusion coefficients. Five crops of wheat, barley, paddy, alfalfa, and potato were studied to evaluate the effect of plants on the pattern of nitrate release due to irrigation and fertilization in agriculture. The results showed that managing the amount of fertilizer and the volume of irrigation can positively affect the nitrate distribution pattern in the groundwater even in a short period of time.

Groundwater assessment for sustainable development in the Wadi Al-Hamd Basin, Al-Madinah Al-Munawarah, KSA

This study relied on well monitoring many drilled wells data in the Wadi Al-Hamd Basin to determine water level and chemical properties from field measurements. The characteristics of groundwater must be assessed in terms of present and future eases and stresses to ensure sustainable development. Hydrogeological, hydrochemical, groundwater quality indices and Geographic Information Systems (GIS) data sets have been integrated to assess the groundwater aquifer in the study area. To implement this work, we measured the depth to the water table from eighty-eight drilled wells. Also, the major ions were determined from 82 water samples to evaluate the physicochemical properties, groundwater facies, and controlling mechanisms using diagrams such as the modified Piper proposed by Chadha, Total Ionic Salinity (TIS), and Gibbs. In this study, five irrigation water quality indicators (IWQI), including total dissolved solids (TDS), sodium adsorption ratio (SAR), potential salinity (PS), magnesium hazard (MH), and residual sodium carbonate (RSC) have been determined to assess the suitability of groundwater for irrigation. Based on the findings of this study, groundwater flows from the southeast and northwest to the west and south, respectively. In this basin, 56% of water samples have TDS greater than 2000 mg/L, while 62% of water points are categorised as Na–Cl water type, which indicates that evaporation and rock–groundwater interaction influenced groundwater quality evolution. Almost 87% of samples were rated good to excellent for irrigation use with respect to SAR. On the other hand, all water points are suitable for irrigation based on RSC. Likewise, groundwater is suitable for irrigation purposes despite the relatively high PS levels (>5 meq/L in about 49% of samples) and some small spots with high levels of MH (>50% in about 12% of samples), especially in the southern and central portions of the studied basin.

Hydrochemical characteristics and sources of groundwater pollution in Soubré and Gagnoa counties, Côte d’Ivoire

For many years, groundwater has been widely used to meet a variety of human needs. As a result of increased urbanization, industrial use, and agriculture, groundwater is inextricably affected by various threats, resulting in groundwater pollution. This current study was carried out to determine the hydrochemical characteristics of groundwater in Gagnoa and Soubré counties as well as the main sources of pollution and their impact on groundwater chemistry and quality. A total of thirty (30) groundwater samples were collected from boreholes in September 2020. The following physicochemical and chemical parameters were analyzed: Na, Ca, K, Mg, SO4, NO3–N, HCO3, Cl, pH, EC and TDS. The results showed that groundwater was acidic with a pH range from 5.22 to 6.84, fresh and moderately mineralized with a TDS range from 55.96 to 744.46 mg/l. Hydrogeochemical characterization based on the Piper diagram and Gibbs plot was used to identify the groundwater types and the main mechanism controlling the groundwater mineralization. Five (5) water types were identified with the dominance of hydrogen carbonate facies and showed the presence of silicate weathering and carbonate dissolution in the area. This is consistent with the results inferred from Gibbs plot showing that groundwater chemistry is governed by rock-water interaction. The spatial distribution map of major ions showed the different locations where each ion is dominant.According to WHO standards, the parameters show values within the threshold limit except for some of them of which their values exceed the limit. Principal component analysis and ionic ratio plots showed that the high values of nitrate as nitrogen and sulfate observed are due to the influence of natural sources such as carbonate dissolution and anthropogenic activities such as sewage-manure and chemical fertilizers.Therefore, mitigation measures should be adopted to reduce the impact of human activities contributing to groundwater pollution to protect the groundwater quality and human health.

Appraisal of groundwater suitability and hydrochemical characteristics by using various water quality indices and statistical analyses in the Wadi Righ area, Algeria

ABSTRACT This assessment research focuses on the hydrochemical characteristics and groundwater suitability in the Wadi Righ region, in southern Algeria. The statement of the problem revolves around determining water quality using various indices including Permeability Index (PI), Residual Sodium Carbonate (RSC), Water Quality Index (WQI), Sodium Percentage (Na%), Sodium Adsorption Ratio (SAR), Canadian Council of Ministers of the Environment's Water Quality Index (CCME WQI), Magnesium Hazard (MH), Irrigation Water Quality Index (IWQI), and Kelly Index (KR). Additionally, statistical methods were utilized to establish correlations between these indices and chemical elements. The working method involved investigating hydrochemical parameters in Wadi Righ's groundwater and analyzing 52 samples. The results indicate that water quality, as assessed by the water quality indices, was categorized as very poor and unsuitable overall, with lower quality observed particularly in the central and southern regions. However, groundwater demonstrated excellence and suitability for irrigation purposes. Qualitatively, the findings suggest that there are significant relationships among irrigation suitability indices, as indicated by Pearson correlation analysis. These relationships stem from shared inputs and hydrogeochemical characteristics of groundwater. This analysis reinforces the quantitative findings and provides insights into the underlying factors influencing groundwater quality and suitability for irrigation in the Wadi Righ region.

Hydrochemical characterization and comprehensive water quality assessment of groundwater within the main stream area of Yishu River.

To gain a comprehensive understanding of the hydrochemical characteristics, controlling factors, and water quality of groundwater in the main stream area of Yishu River (MSYR), a study was conducted using water quality data collected during both the dry and wet seasons. Through statistical analysis, hydrochemical methods, fuzzy comprehensive evaluation, and health risk evaluation modeling, the water chemical characteristics of the main stream area of Yishu River were studied, and the water quality of the area was comprehensively evaluated. The findings indicate that HCO3- and Ca2+ are the predominant anions and cations in the MSYR during the dry and wet seasons, respectively. Moreover, anion concentration in groundwater follows HCO3- > SO42- > NO3- > Cl-, while cations are ranked as Ca2+ > Na+ > Mg2+ > K+. Overall, the groundwater manifests as weakly alkaline and is predominantly classified as hard-fresh water. During the wet season, there is greater groundwater leaching and filtration, with rock and soil materials more readily transferred to groundwater, and the concentrations of main chemical components in groundwater are higher than those during the dry season, and the hydrochemical types are primarily characterized as HCO3-Ca·Mg and SO4·Cl-Ca·Mg types. These results also suggest that the chemical composition of the groundwater in the MSYR is influenced mainly by water-rock interaction. The primary ions originate from the dissolution of silicate rock and carbonate rock minerals, while cation exchange plays a critical role in the hydrogeochemical process. Groundwater in the MSYR is classified mostly as class II water, indicating that it is generally of good quality. However, areas with high levels of class IV and V water are present locally, and NO3- concentration is a crucial factor affecting groundwater quality. In the wet season, more groundwater and stronger mobility lead to greater mobility of NO3- and wider diffusion. Therefore, the risk evaluation model shows that nitrate health risk index is higher in the wet season than it is in the dry season, with children being more vulnerable to health risks than adults. To study groundwater in this area, its hydrochemical characteristics, water quality, and health risk assessment are of great practical significance for ensuring water safety for residents and stable development of social economy.

Assessment of physicochemical, minerals and microbiological qualities of borehole and well water: A case study of Akure Metropolis, Nigeria

Groundwater constitutes a substantial reservoir of fresh water utilized for agricultural irrigation and drinking, emphasizing the critical importance of safeguarding its availability and quality. Contamination of groundwater can arise from chemical, physical, or microbiological sources, each contributing to various health-related issues. In the region of FUTA Southgate, Southwest Nigeria, an assessment was conducted on the physicochemical and microbiological characteristics of groundwater from hand-dug wells and boreholes to ascertain its suitability for human consumption. The analysis indicated that parameters such as BOD, DO TS, TH, and nitrate content were within the acceptable limits set by the World Health Organization (WHO) and the Nigerian Standard for Drinking Water Quality (NSDQ). However, the presence of heavy metals like Fe, Cu, Cr, Pb, Mn, Cd, and Zn was detected using an atomic absorption spectrometer, revealing a slight level of contamination in both water sources. Furthermore, microbiological examination identified Total Coliform Counts of 382 cfu and 159 cfu in hand-dug wells and boreholes, respectively, indicating fecal contamination. The findings suggest that inadequate sewage systems and improper waste disposal practices contribute to the compromised water quality and elevated nitrate levels in hand-dug wells, rendering the shallow aquifer groundwater unsafe for drinking purposes across all evaluated parameters. Consequently, appropriate treatment and disinfection measures are imperative before utilizing the contaminated borehole and groundwater wells for human consumption or industrial purposes.

Health risk assessment of nitrates and fluorides ingestion and geochemical evaluation of groundwater characteristics in semi-arid regions

Health risk assessment of nitrates and fluorides ingestion and geochemical evaluation of groundwater characteristics in semi-arid regions

Triple isotopes (δD, δ18O, δ17O) characteristic of river water and groundwater in an arid watershed from Qaidam Basin, Northwestern China: implications for hydrological cycle

Combining traditional stable isotopes (δD and δ18O) and triple oxygen isotope (δ17O) is conducive to tracing hydrological cycle processes. The application of triple oxygen isotopes primarily focuses on precipitation, which is lacking in river water and groundwater. In this study, the spatial variations of δD, δ18O, δ17O, d-excess and 17O-excess of river water and groundwater in the Golmud River basin as well as the correlation between them were investigated to elucidate water origin and assess the evaporation influence on water bodies during flood season. Spatial changes in δD, δ18O and δ17O of river water exhibit a decrease-increase-stability pattern contrary to that observed for d-excess, 17O-excess has no distinct trend but is higher at both the source and downstream regions. The results show that river water and groundwater originate from precipitation in the mountainous area, and the meltwater in the source region also contribute to the river water with high d-excess and 17O-excess during flood season. The combination of d-excess and 17O-excess reveal that river water is also affected by evaporation and mixing of river water in tributaries. It was found that the river water is recharged in the mountains, undergoes evaporation in the upstream region and leaks into groundwater in the midstream region, which is recharged by the groundwater and evaporated again in the downstream region. This study could provide a more comprehensive understanding of the potential and value of triple oxygen isotopes in the hydrological cycle.

Study on Hydrochemical Characteristics and Interactions between Groundwater and Surface Water in the Dongting Lake Plain

The Dongting Lake Plain is a major ecological reserve for river and lake wetlands in the Yangtze River Basin, with complex river and lake relationships and frequent water flow exchange. Studies on the hydrochemical characteristics and the mechanism of interaction between groundwater and surface water will actively promote the scientific management, utilization of water resources, and protection of the ecological environment in the Dongting Lake Plain. Based on hydrogeochemical statistics, Gibbs diagrams, ion ratios, rock weathering end-element diagrams, hydrogen–oxygen isotope relationship diagrams, and other technical methods, the chemical characteristics, ion sources, and the distribution of hydrogen–oxygen isotopes of groundwater and surface water in “the Three Inlets” and “the Four Rivers” water system areas as well as the Dongting Lake water were analyzed. Additionally, the interactions between groundwater and surface water and the proportions of these contributions were discussed. The results show that both groundwater and surface water in the Dongting Lake Plain are weakly acidic or alkaline, and the anions are mainly HCO3−, the cations are mainly Ca2+and Mg2+, with the hydrochemical types being mainly HCO3−Ca−Mg and HCO3−Ca. The chemical characteristics of groundwater and surface water are mainly affected by the interaction between water and rock; the ions in surface water mainly come from the weathered dissolution of carbonate and silicate rocks, while the ions in groundwater mainly come from the weathered dissolution of carbonate and silicate rocks, with the dissolution of evaporite rocks locally. Groundwater and surface water are mainly distributed near the local meteoric water line (LMWL), and the slope of the local evaporation line is less than that of the LMWL, which indicates that atmospheric rainfall is an important recharge source for groundwater and surface water and that at the same time, it is affected by evaporation to a certain extent. Part of the groundwater in the Dongting Lake Plain is discharged into the surface rivers in “the Three Inlets” and “the Four Rivers” water system areas, and the other part is directly discharged into Dongting Lake. According to the mass balance relationship of isotopes, the proportions of surface water in “the Three Inlets” and “the Four Rivers” water system areas contributing to Dongting Lake’s water are 18.48% and 60.38%, respectively, and the proportion of groundwater in the lake plain contributing to Dongting Lake water is 21.14%.

Influence of Selected Soil Properties on Groundwater Flow around Ariaria Dumpsite, Aba, Southeast, Nigeria

A study on the analysis of soil and groundwater characteristics due to municipal waste is indispensable to the sustenance of the environment and human health. This study is to evaluate the “Influence of selected Soil properties on groundwater flow around Ariaria dumpsite, Aba Southeast, Nigeria using Particle Size Analysis and Vertical Electrical Sounding (VES) configurationˮ. The sieve analysis shows that the soil samples collected consist of 11.95% of Silt, 83.62% of Sand and 4.42% of little Gravel. The mean permeability of the study area ranges from 0.19 (cm/sec) to 0.49 (cm/sec), the mean infiltration rate ranges from 6840mm/hr to 31320mm/hr. The Longitudinal conductance and Transmissivity values range from 0.0060 to 0.0284Ω-1 and 3.8165 to 16.85892/day. The values of longitudinal conductance and transmissivity indicates that the aquifer has poor protection capacity rating and its classification of well is from very low potential to low potential. The soil samples of the study area are well sorted and the movement of leachate from the dumpsite into the subsurface is very fast because the Permeability (K) is good, Coefficient of uniformity (Cu) and Coefficient of curvature classified the soil samples collected from the area as well graded soil. From the geophysical survey (VES) results, the groundwater depths (upper and lower aquifers) within the study area ranges from 30m (98ft) to 60m (197ft) at average depth of 45m(147ft). The curve types are AHA, HKA and AKA. The SWL of the study area ranges from 12m to 19m deep. The recommend drill depth to groundwater of is 50m (164) for domestic and consumption purpose.

Groundwater Characterization Studies Using Electric Resistivity Survey (ERS) in Kirana Hills, District Chiniot, Pakistan

This study demonstrates an application of resistivity surveys to understand local hydrological conditionsand basement configuration in Kirana Hills region of District Chiniot. Schlumberger configuration has been applied toacquire vertical electrical sounding (VES) data. The apparent resistivity curves were calibrated with theoretical curvesto compute true resistivity and depth of different layers. Maps of true resistivity at various depths were generated tostudy the lateral resistivity variation in the area. VES sounding data were compared with available lithological columnsto establish relationship of lithology and resistivity. Resistivity values are laterally variable due to lithology and qualityof water. Very low resistivity values were observed within alluvial sediments close to the Kirana Hills due to presenceof high Total Dissolved Solids in water. Resistivity value layers in unconsolidated sediments increases in the southernand western parts of the area where relatively better quality of groundwater occurs. In the northern and eastern parts ofthe study area very high resistivity (greater than 100 Ωm) is recorded at depth greater than 40m that indicates hard rockbasement. The resistivity survey in the area is useful to differentiate zones of low and high Total Dissolved Solidsgroundwater and also determine the zones where subsurface basement is shallow. Therefore, resistivity survey inKirana Hill regions is helpful in solving hydrological issues of the study area.

Hydrogeochemical characterization and assessment of factors controlling groundwater salinity in the Chamwino granitic complex, central Tanzania

Chamwino district, central Tanzania is a semi-arid granitic complex province, where groundwater is the major source of water for domestic and other uses. However, groundwater in the area is affected by salinity, thus, lowering the availability of potable water for various uses, decrease in crop production, taste less, wastage of soap, and abnormal pain. Due to this, this study sought to characterize groundwater using hydrogeochemical facies and signatures in order to identify the factors influencing the distribution of salt water in the Chamwino Granitic Complex. A total of 141 groundwater samples were collected from wells spatially distributed within the study area from January 2023 to April 2023, (a season of relatively low rainfall). All samples were subjected to in situ analyses of physicochemical parameters pH, temperature (T), total dissolved solids (TDS), electrical conductivity (EC), and salinity using a multi-parameter water analyzer and analyses of major ions (Ca2+, Mg2+, K+, Na+, Cl−, SO42−, HCO3−, and NO3−). The study revealed that the dominant cations in the groundwater are Na+ > Ca2+ > Mg2+, and the anions are Cl− > HCO3− > SO42. Five geological formations (granodiorite, tonalitic orthogenesis, migmatite, tonalite, and alluvium) were identified, and each is characterized by its unique groundwater facie. In the areas that are dominated with granodiorite, the major hydrogeochemical facies were Ca–HCO3, Na–Cl, Ca–Na–HCO3, Ca–Mg–Cl, and Ca–Cl water types; tonalitic orthogenesis was dominated by Ca–HCO3, Na–Cl, Ca–Mg–Cl, and Ca–Cl water types; migmatite was dominated by Ca–HCO3, Na–Cl, Ca–Mg–Cl, and Ca–Cl water types; tonalite was dominated by Na–Cl, Ca–Mg–Cl, and Ca–Cl water types; and alluvium was dominated by Na–Cl and Ca–Mg–Cl and Ca–Cl water types. The common hydrogeochemical facies in all five geological units are Na–Cl, Ca–Mg–Cl, and Ca–Cl water types. It is revealed that the groundwater in the study area is alkaline in nature and slightly saline with salinity level between 0.2 mg/L (fresh water) and 2.8 mg/L (brackish water) with mean 1.07 mg/L (of 141 samples). The factors controlling groundwater salinity distribution are mainly rock-water interaction and ion exchange reactions. Groundwater salinity in the study area is largely attributed to the abundance of Na+, Ca2+, Cl− and SO42−. Abundance of Na+ and Ca2+ is the results of both, weathering of feldspar minerals particularly plagioclase (Na–Ca feldspars) which are the major mineral in granites, and evaporation crystallization cycles of evaporates in semi-arid areas such as Chamwino. Also, such evaporation crystallization cycles account for the abundance of Cl− and SO42− especially in areas dominated by alluvium. However, anthropogenic activities as evidenced by elevated nitrate up to 212.6 mg/L in congested areas are also likely to contribute in area) to the elevated Cl− and SO42−. In other geological units such as tonalitic orthogneiss, migmatite and granodiorite, there was an ostensible mixing of saline water with fresh water from local recharge as indicated by the abundance of HCO3− ions. Nonetheless, the hydrogeochemical characterization of groundwater in the Chamwino granitic complex suggests that there is little possibility for groundwater to evolve to a carbonate water type (fresh water) because the groundwater salinity is mainly geogenic, unless artificial recharge through rainwater harvesting is applied.

Groundwater characteristics using geophysical, geospatial, and hydrogeological studies in Peshawar Basin, Pakistan

Groundwater characteristics using geophysical, geospatial, and hydrogeological studies in Peshawar Basin, Pakistan