Characteristics Of Deposits Research Articles

Application of Aeromagnetic Survey in Detecting Potential Mineralization Zones Around Dongzhongla Deposit, Gangdese Metallogenic Belt

The Dongzhongla deposit is a skarn-type lead–zinc ore deposit located in the eastern segment of the Gangdese metallogenic belt, situated in the Xizang province, China. The high-altitude mountainous terrain of the region poses significant challenges to ground-based exploration. To facilitate more accurate mineral exploration in the deposit and its surrounding area, a high-resolution airborne magnetic survey was conducted over the mining area and its periphery. The airborne magnetic data were processed using derivative and Euler deconvolution methods, yielding results that reflect the geological structural features of the study area. By integrating the geological characteristics of the ore deposit, we inferred that the areas of magnetic anomaly extensions and the peripheries of other magnetic anomalies are favorable zones for mineralization, providing positive leads for further mineral exploration.

Study of the features of using the spectral remote sensing method to detect geological features of mineral deposits

В настоящее время ГИС продемонстрировала свое удобство в разведке полезных ископаемых, принимая за основу метод дистанционного зондирования Земли, включающий в себя различные измерения отраженных и поглощенных электромагнитных колебаний от удаленных объектов, состоящих из различных сред, таких горная порода, минералы, земельный и растительный покров. Спектральные спутниковые снимки с использованием бортовых дистанционных датчиков позволяют обнаружить перспективные участки месторождений полезных ископаемых. Программа ГИС (ARGIS) имеет возможность создавать прогнозную карту полезных ископаемых без выезда в поле, находясь в камеральных условиях. Это обусловлено тем что, дистанционное зондирование Земли может различать спектральные признаки горных пород и минералов, а программа ГИС способна интегрировать различные источники данных по геологии, что позволяет различать типы геологических минералов Қазіргі уақытта ГАЖ Жерді қашықтықтан зондтау әдісін негізге ала отырып, пайдалы қазбаларды барлауда өзінің ыңғайлылығын көрсетті, оған әртүрлі ортадан тұратын алыс объектілерден шағылысқан және сіңірілген электромагниттік тербелістердің әртүрлі өлшемдері кіреді тау жыныстары, минералдар, жер және өсімдік жамылғысы. Борттық қашықтықтағы датчиктерді қолданатын спектрлік спутниктік суреттер пайдалы қазбалар кең орындарының перспективалы учаскелерін анықтауға мүмкіндік береді. ГАЖ бағдарламасы (ARCGIS) камералдық жағдайда далаға шықпай-ақ пайдалы қазбалардың болжамды картасын жасау мүмкіндігіне ие. Бұл жерді қашықтықтан зондтау тау жыныстары мен минералдардың спектрлік белгілерін ажырата алатындығына байланысты, ал ГАЖ бағдарламасы геология бойынша әртүрлі деректер көздерін біріктіре алады, бұл геологиялық минералдардың түрлерін ажыратуға мүмкіндік береді Currently, GIS has demonstrated its convenience in mineral exploration, taking as a basis the method of remote sensing of the Earth, which includes various measurements of reflected and absorbed electromagnetic vibrations from remote objects consisting of various media such as rock, minerals, land and vegetation. Spectral satellite images using on-board remote sensors make it possible to detect promising areas of mineral deposits. The GIS program (ARCGIS) has the ability to create a forecast map of minerals without going into the field, while in office conditions. This is due to the fact that remote sensing of the Earth can distinguish the spectral features of rocks and minerals, and the GIS program is able to integrate various data sources on geology, which makes it possible to distinguish types of geological minerals

Ore-forming fluid characteristics of Jiaodong-type gold deposits in the North China Craton: constraints from the geochemistry of auriferous pyrite

Ore-forming fluid characteristics of Jiaodong-type gold deposits in the North China Craton: constraints from the geochemistry of auriferous pyrite

Genesis of the Bailugou Vein-Type Zinc-Lead-Silver Deposit, Eastern Qinling Orogen, China: Constraints from Ore Geology and Fluid Inclusions

The Bailugou vein-type zinc-lead-silver deposit is located in the Eastern Qinling Orogen, China. There has been a long-standing debate about whether its formation is related to magmatism or metamorphism. To determine the origin of ore-forming materials and fluids, we conducted a geological and fluid inclusion investigation of the Bailugou. Field surveys show that the vein-type orebodies are controlled by faults in the dolomitic marbles of the Mesoproterozoic Guandaokou Group, and they are distal to the regional Yanshanian intrusions. Four ore stages, i.e., quartz–pyrite ± sphalerite (Stage 1), quartz–polymetallic sulfides (Stage 2), dolomite–polymetallic sulfides (Stage 3), and calcite (Stage 4), are identified through microscopic observation. The homogenization temperatures of measured fluid inclusions vary in the range of 100 °C to 400 °C, with the dominating concentration at 350 °C to 400 °C, displaying a descending trend from early to late stages. The estimated formation depth of the Bailugou deposit varies from 2 km to 12 km, which is deeper than the metallogenic limit of the epithermal hydrothermal deposit but conforms to the typical characteristics of a fault-controlled deposit. The ore-forming fluid in Stage 1 originates from a fluid mixture and experiences a phase separation (or fluid immiscibility) between the metamorphic-sourced fluid and the fluids associated with ore-bearing carbonate-shale-chert association (CSC) strata. This process results in the transition to metamorphic hydrothermal fluid due to water–rock interactions in Stage 2, culminating in gradual weakening and potential fluid boiling during the mineralization of Stage 3. Collectively, the Bailugou lead-zinc-silver mineralization resembles an orogenic-type deposit formed by metamorphic fluids in the Qinling Yanshanian intracontinental orogeny.

Mining of primary raw materials as the critical foundation of 'sustainable' metals: a wicked problem for technology innovation clusters.

A transition to a more sustainable human-nature system is inextricably linked to raw materials production, if economic growth is to be maintained or increased by the emergence of new, energy- and metal-hungry technology innovation clusters. The dependence on mined raw materials is a wicked problem for societies vulnerable to negative ecological impacts and for global power bases wanting to secure access to an increasing array of feedstocks. We interrogate the issue of what constitutes a sustainable metal from a triple perspective: (i) the characteristics of ore deposits and the primary extractive operations that supply critical raw materials; (ii) the impediments for complex and interacting supply chains to maintain critical (and other) metals in use; and (iii) the lack of transparency in supply chains that makes it challenging for customers to avoid resources that have been produced by unsustainable and poor practices. We examine existing and emerging structures for resource management to explain the limits to the circular economy and what constitutes a meaningful systemic structure for primary production by responsible mining. We call for the inclusion of a standardized statement of the 'natural capital' embodied in R&D for technological materials as a means to create transparency about what constitutes a sustainable metal.This article is part of the discussion meeting issue 'Sustainable metals: science and systems'.

APPLICATION OF SUPPORT VECTOR MACHINE AND ORDINARY KRIGING (SVM-OK) TO SPATIAL INTERPOLATION OF POROSITY ATTRIBUTE OF AGBABU BITUMEN DEPOSIT

The lack of geostatistical modelling of volumetric characteristics of Nigeria's long-discovered heavy oil and bitumen deposits in Agbabu was accountable for the discrepancies in the hydrocarbon-in-place calculations. The absence of spatial variability evaluation in such efforts is responsible for the inconsistency and divergence that define the impacts of the existing attempts to estimate the porosity attribute. Due to its optimum features and simplicity of estimate, Kriging is reported as the most generally used approach to evaluate the connection between variables (inputs and output). However, Kriging reveals that the relationship between variables requires a linear form, which is frequently not the case. Thus, the necessity for a procedure with no fixed shape is built based on information acquired directly from the data. Consequently, support vector regression, a form of the support vector machine, is employed as a choice in contrast to kriging. This research is a comparative application of support vector machine and kriging (SVM-OK) to the spatial interpolation of the porosity property of the Agbabu bitumen field. The porosity values from existing data are trained, cross-validated, and verified with the help of the support vector machine, and they are interpolated by ordinary kriging. The geographical patterns of the predictions have been checked visually using graphs based on these three diagnostics: variance of the error terms and correlation of the error terms. The findings of this study illustrate the performance of the combination of the Support vector machine and conventional kriging in the spatial interpolation of volumetric characteristics in the Agbabu bitumen deposit. The approach exhibited great predictive performance. SVM-kriging will be employed in reservoir characterisation with the least mean absolute error (MAE) and mean squared error (MSE).

Sequence stratigraphic analysis of the late Permian Changhsingian platform marginal reef, Western Hubei, South China

This study presents a comprehensive analysis of the late Permian platform marginal reefs in the Sichuan Basin, focusing on reefal lithofacies and sequence stratigraphic patterns. Field outcrop observations and rock sample analyses from the Jiantianba reef were conducted to establish an evolution model of sponge reef development and spatial distribution. Four stages of marginal carbonate platform were documented: open platform, gently sloping reef, steeply sloping reef, and reef bank system. Distinct lithofacies were identified in these stages, reflecting different depositional environments and growth rates. The gently sloping reef was composed of filled skeleton framestone, filled skeleton bafflestone, and micrite organism limestone, indicating limited reef-building capacity. In contrast, the lithofacies of steeply sloping reefs were composed of open skeleton framestone, open skeleton bafflestone, binding skeleton bafflestone, and benthic organism bindstone, indicating stronger reef-building ability. Based on depositional features and carbon isotopic trends, the reef strata were divided into two sequences. Sequence 1 corresponds to the formation of unit 1, and sequence 2 can be further divided into units 2 and 3. In unit 1, reefs developed in a relatively deeper-water setting. It was characterized by rich micrite limestone, forming a gentle margin. Unit 2 witnessed reef development in shallower waters. Early marine cementation and microbial clots were prevalent, contributing to form a steep margin. In the early stage of unit 3, reefs primarily developed in a tidal-controlled environment. Subsequently, reef strata experienced a transition to a wave-influenced environment, leading to the formation of a reef bank system. In general, sequence 1 mainly formed in a heterozoan-dominated factory, and reefs contributed to a relatively gently sloping platform margin. In contrast, sequence 2 formed in a photozoan-dominated factory, and reefs contributed to a relatively steeply sloping platform margin.

New insights on gravity flow dynamics during submarine canyon flushing events

Millions of tons of material are flushed through submarine canyons during infrequent high-magnitude events, transporting coastal sediment to the deep ocean. However, observations related to individual canyon flushing events are challenging due to the destructive nature and infrequency of flushing events. The impacts of one of the largest gravity flows in the past decade were documented in Kaikōura Canyon, Aotearoa−New Zealand, where >1 km3 of sediment was mobilized by the 2016 CE Kaikōura earthquake (Mw 7.8). We present new high-resolution (<1 m) multibeam data collected with an autonomous underwater vehicle (AUV) along the Kaikōura Canyon axis, together with side-scan sonar and seafloor video imagery. These data sets reveal a wide range of erosional and depositional features that were not previously identified. Eroded bedrock and deep erosional structures are found in the upper canyon, including linear grooves, and rockfall debris (>5-m-diameter boulders). This erosional area transitions downcanyon to coarse-grained depositional bedforms, including cyclic steps and gravel waves (average wavelengths of 250 m and wave heights of ∼20 m), covering the mid- and lower canyon. Our observations provide high-resolution field-based evidence of (1) flow transformation, from a debris flow to a high-density turbidity current; and (2) variations of flow dynamics within turbidity currents both across- and downcanyon, during an infrequent, high-energy canyon flushing event. This research offers new insights into the processes that create and shape nearshore bedrock-incising submarine canyons.

Varying free-gas zone (FGZ) and bottom-simulating reflection (BSR) response across a deep graben off Trujillo, central Peru

The complexity of marine gas hydrate systems at the Peruvian convergent margin has been linked to the post-Miocene history of vertical tectonics and subduction erosion that affected the forearc. Here, multichannel seismic data and published findings reveal that such a complexity has been further extended by the occurrence of the pre-Miocene deep Morsa Norte Graben (MNG) off Trujillo (8°–9° S) in the Central Peru margin. At water depths of 650–750 m in the upper slope, directly above the MNG depocentre (which has a 4–6 km overburden thickness), continuous bottom-simulating reflections (BSRs) and concentrated sub-BSR high-amplitude reflections are confined beneath a layered basin with a low–moderate near-seafloor heat flow (7–33 mW m −2 ). A deeper BSR modelled with a thermogenic gas composition is associated with the enhanced reflections. At a water depth of 900 m, sub-BSR reflections become less frequent in an area with a layered sediment cover defined by a moderate near-seafloor heat flow (15–33 mW m −2 ). At a water depth of 1200 m, where the MNG is relatively thick (3–4 km overburden thickness), faults connect patchy BSRs with a moderate–high near-seafloor heat flow (52–110 mW m −2 ). There, sub-BSR enhanced reflections are scarce. Immediately above the top of the gas hydrate stability zone (GHSZ), the near-seafloor heat flow reaches 81 mW m −2 . Modelling suggests a water depth-dependent transport of heat towards the seafloor with respect to the top of the GHSZ, implying that the closer the seafloor is to the top of the GHSZ, the lower the advection of heat, and vice versa. Recent seafloor-related depositional and structural features amplify such relations in agreement with near-seafloor heat-flow variability. However, towards the area outside the extent of the MNG (<3 km overburden thickness), continuous BSRs are not linked either to a deeper BSR or to sub-BSR enhanced reflections. The continuity of one of these BSRs is deflected upwards beneath a slump, suggesting an incomplete thermal re-equilibration of the GHSZ. Therefore, we conclude that the BSR responds to: (1) the confinement and thickening of the free-gas zone (FGZ) above the MNG depocentre due to the sealing effect of recent sedimentation close to the top of the GHSZ; (2) the seepage of gas-rich fluids from a thinned FGZ above the relatively thick MNG, due to the enabling effect of faults cutting the GHSZ far from the top of the GHSZ; (3) the undisturbed state of the FGZ outside the extent of the MNG; and (4) the disequilibrium state of the base of the GHSZ due to the unloading of sediments in an unstable slope environment prone to failure.

Insight into the 2021 Semeru volcano eruption from rapid monitoring of its pyroclastic deposits using Google Earth Engine and multi-sensor data

The objective of this study is to map the pyroclastic deposits resulting from the Semeru eruption in 2021 and to analyse the process of pyroclastic deposit formation, including the tephra and lithification phases, using multi-sensor data. The distribution of pyroclastic deposits was mapped using machine learning algorithms, Sentinel 2 and Sentinel 1 imagery on Google Earth Engine. Data acquisition in the Semeru volcano area was conducted both prior to and following the 2021 eruption. Additionally, field investigations were conducted to analyse the distribution of pyroclastic deposits, including the characteristics of individual layers, the lithification process of pyroclastic layers, and their relationship with the characteristics of the eruption. The results demonstrate that pyroclastic deposits in the proximal facies are composed of lithic, lapilli tuff, lava and tuff. The mapping results also indicate the presence of volcanic ash deposits in the central facies or summit area of Semeru, exhibiting distinctive characteristics associated with volcanic ash. The 2021 eruption has also resulted in rapid changes to river morphometry, as evidenced by notable shifts in a significant decrease in pixel values for NDVI (−0.0781-0.0625), a significant increase in pixel frequency of EVI (1800–6000), and MNDWI (1700–3000), respectively. The change of pyroclastic fall into consolidated tephra occurred from December 2021 to May 2023, where in May 2023 volcanic ash had changed into tuff and lapilli had changed into lapilli tuff. Furthermore, data from Sentinel-1 indicated that pyroclastic flows could be identified using both vertical and horizontal polarization. It can therefore be concluded that the 2021 eruption of Semeru exhibited distinctive characteristics of pyroclastic deposits, where some of the characteristics of the pyroclastic distribution can be monitored rapidly with Google Earth Engine. Therefore, the use of Google Earth Engine with integration of radar and optical data can be recommended to mapping pyroclastic deposits rapidly.

Evolution of a buried moat-drift system within the Ewing Terrace uncovering highly dynamic bottom currents at the Argentine Margin during Early Oligocene to Middle Miocene

The Ewing Terrace is a relatively flat surface formed by the action of bottom currents and part of a Contourite Depositional System (CDS) at the Argentine continental slope. It is situated in a highly complex oceanographic setting at the Brazil-Malvinas Confluence Zone. Located in water depths of approx. 1000 – 1200 m and incised by the Mar del Plata Canyon, the Ewing Terrace is separated into the Northern Ewing Terrace (NET) and the Southern Ewing Terrace (SET). The long-term variations in ocean circulation led to a complex internal architecture of the terrace. As a result, this region represents a unique archive for studying sedimentary features that were eroded, transported, and deposited by along- and down-slope processes. An in-depth data analysis of high-resolution multichannel seismic profiles exhibits a complex sequence of erosional and depositional contouritic features, namely buried moat-drift systems identified in depths of approx. 370-750 m below the seafloor. They are arranged in migrating sequences and clustered in the Early Oligocene to Middle Miocene. This pattern is probably attributable to the vertical shift of water masses and to a highly dynamic oceanographic setting with spatial changes influenced by the Brazil-Malvinas Confluence Zone over this particular geological time. The moat-drift systems reveal significant lateral changes from north to south. In the southern area of the SET the moats are constructional and the associated separated mounded drifts are well developed. In contrast, the northern area exhibits two types of moats, reminiscent of cut-and-fill structures that mirror the significant and rapid changes in bottom current dynamics. With these new insights, this study contributes to a better understanding of moat-drift systems and improves the knowledge about past oceanographic dynamics and sediment deposition at the northern Argentine margin.

Benthic Foraminifera Biostratigraphy and Sedimentation Fiatures of the Western Sakhalin Upper Eocene

New data on micropaleontological and lithological characteristics of Eocene deposits exposed along the Avgustovka River near the village of Boshnyakovo, Western Sakhalin are presented. For the first time, benthic foraminifera were found in these deposits and it was concluded that they are of middle-late Eocene age. Analysis of the taxonomic composition of the foraminifera assemblage, as well as the material composition of the rocks, allowed us to assume that these strata were formed within a relatively deep-water marine basin, which periodically supplied volcanic material in the form of tuffs.

Characteristics of Rock Avalanche Deposit in Wangjiapo, Ludian Based on UAV Aerial Image Recognition

Rock avalanche disasters in alpine and gorge regions are frequent and large in scale and cause severe damage. The movement of a rock avalanche is complex and has not been fully studied. The deposits of a rock avalanche can provide valuable insights into its movement process, which is crucial in understanding the rock fragmentation mechanism and predicting disaster-affected areas. Taking the Wangjiapo rock avalanche in Yunnan Province of China as an example, the size, shape and distribution characteristics of the deposit were analyzed based on field surveys, unmanned aerial vehicle (UAV) photography and image recognition technology. Initially, 3062 deposited rock blocks were manually measured in the field. Subsequently, the Particles/Pores and Cracks Analysis System (PCAS) was employed to identify 11,357 rock blocks with an area greater than 0.1 m2 from UAV orthophotos. By comparing the characteristics of the rock blocks obtained through image recognition and manual measurement, the statistical analysis of UAV aerial imagery combined with PACS proved feasible in studying the Wangjiapo rock avalanche. The results showed that the rock block movement was accompanied by fragmentation and sorting processes; furthermore, the roundness increased with the migration distance. Small blocks were more prevalent at the foot of the slope, while irregularly shaped, large blocks dominated in source areas. The movement of huge blocks was characterized by significant potential energy-driven features and inertia advantages, allowing them to travel farther than smaller blocks, and they tended to be concentrated in the central area of the deposit. Additionally, affected by the cementation degree of breccia and the topography, the blocks in the eastern and western deposit areas exhibited different fragmentation and deposition characteristics.

Depositional characteristics in the Lower Congo Basin during the Cenomanian-Turonian stage: Insights from fine-grained sedimentary rocks

The Cenomanian-Turonian (C-T) stage, marked by extensive black shales and Oceanic Anoxic Event 2 (OAE 2), is pivotal for deciphering paleoceanographic conditions and the main drivers of hydrocarbon formation. Despite its significant oil and gas potential, the Lower Congo Basin (LCB) in central West Africa, particularly during the C-T stage (Likouala Formation), has been severely understudied, primarily due to limited exploration and a historical preference for other basins. Therefore, understanding the depositional characteristics of the C-T stage in the LCB is essential for elucidating paleoceanographic conditions, evaluating hydrocarbon potential and interpreting environmental changes. Due to the limited availability of published data and samples, we employed a targeted and integrated geological analysis to gain comprehensive insights, encompassing logging, lithofacies identification, thin-section observations, grain size measurements, and geochemical analyses (major, trace, and rare earth elements), to provide a cohesive and confirmatory assessment. Utilizing relative sea-level curves and geochemical indicators, and by comparing with other relevant basins, this study preliminarily identified OAE 2 stratigraphic intervals and attempted to discuss the impact of OAE 2 on organic matter enrichment in the LCB. The results indicate that, during the C-T stage, the LCB featured a restricted sea bay environment with limited terrestrial input and anoxic waters. Multiple geochemical proxies suggest that relative sea-level changes significantly affected paleoproductivity, thereby influencing organic matter enrichment. During the depositional period of Lower Likouala Formation (LLF), a relative sea-level drop resulted in weakly reducing conditions in a marginal restricted sea bay environment, leading to low primary productivity. Conversely, during the depositional period of Upper Likouala Formation (ULF), enhanced aeolian input and sea-level rise increased nutrient supply from the open ocean. This led to elevated surface marine productivity and intensified reducing conditions in the water column, forming a marginal semi-restricted sea bay environment. Enhanced reducing conditions within the lower stratigraphic intervals of the ULF are likely consequences of OAE 2. However, the marginal restricted sea bay environment and limited water exchange may have constrained the enhancement of paleoproductivity by OAE 2. These insights not only significantly enhance our understanding of the organic-rich fine-grained sedimentary rocks in the LCB during the C-T stage, but also contribute to a broader comprehension of the South Atlantic's paleoceanographic conditions and the interplay between regional geological processes and global climate events during the C-T stage.

Impact of Reservoir Heterogeneity on Bitumen Content in the Mackay River Oil Sands, Athabasca (Canada)

AbstractThe Lower Cretaceous Manville Group of Upper McMurray Formation is one of the main bitumen reservoirs in Athabasca. In this study, the relationship between reservoirs heterogeneity and bitumen geochemical characteristics were analyzed through core and microscopic observation, lab analysis, petrophysics and logging data. Based on the sedimentology framework, the formation environment of high‐quality oil sand reservoirs and their significance for development were discussed. The results indicate that four types lithofacies were recognized in the Upper McMurray Formation based on their depositional characteristics. Each lithofacies reservoirs has unique physical properties, and is subject to varying degrees of degradation, resulting in diversity of bitumen content and geochemical composition. The tidal bar (TB) or tidal channel (TC) facies reservoir have excellent physical properties, which are evaluated as gas or water intervals due to strong degradation. The reservoir of sand bar (SB) facies was evaluated as oil intervals, due to its poor physical properties and weak degradation. The reservoir of mixed flat (MF) facies is composed of sand intercalated with laminated shale, which is evaluated as poor oil intervals due to its poor connectivity. The shale content in oil sand reservoir is very important for the reservoir physical properties and bitumen degradation degree. In the context of regional biodegradation, oil sand reservoirs with good physical properties will suffer from strong degradation, while oil sand reservoirs with relatively poor physical properties are more conducive to the bitumen preservation.

Genesis of the Kateba’asu gold deposit, Western Tianshan, China: Constraints from pyrite trace element, sulfur isotope, and quartz H-O isotopes

The Kateba’asu gold deposit, situated in the Western Tianshan of China, is one of the most significant discoveries in the world-class Tianshan gold belt. The deposit features two distinct mineralization styles. The early, subordinate skarn-type copper–gold mineralization occurs in the contact zone between monzogranite, diorite, and Silurian limestone, composed of garnet, diopside, epidote, chalcopyrite, pyrite, and gold. The later, primary lode-gold mineralization is hosted in the altered monzogranite characterized by pervasive quartz-pyrite-sericite-chlorite-K-feldspar alteration and a well-develped veining systems.Pyrite is the dominant sulfide mineral related to gold mineralization in the Kateba’asu gold deposit, with four types identified: Py0 from the early skarn copper–gold mineralization, and Py1 to Py3 from the later lode-gold mineralization. All types of pyrite are homogeneous and contain very low levels of lattice-bound gold. Py0 is euhedral and fine-grained, with relatively high Cu, Au, Co, and Ni contents, and displays a magmatic sulfur isotopic signature with δ34S ranging from 0.8 to 4.3 ‰. Py1 occurs as euhedral to subhedral, coarse-grained crystals within pyrite-quartz veins with higher concentrations of Co and Ni. Py2, which develops in the quartz-pyrite veins, is medium to coarse-grained and contains elevated levels of As, Cu, Zn, and Bi relative to Py1. Py3, found in polymetallic sulfide veins of the main lode-gold stage, is anhedral and medium to fine-grained with higher contents of As, Ag, Cu, Zn, Se, Te and lowest Co and Ni concentrations compared to Py1 and Py2. The positive correlations between Au-Te, Au-Bi, Au-Cu, and Pb-Bi across all pyrite types, along with the presence of visible gold in Py3, indicate that most gold occurs as micro-/nano-sized inclusions and as fissure gold. The δ34S values of Py1, Py2, and Py3 (7.6 to 11.8 ‰, 10.1 to 12.6 ‰, and 9.8 to 12.4 ‰, respectively) were attributed to an initial magmatic source and mixed with external sulfur subsequently from the wall rocks. The H and O isotopic compositions (δDH2O = −84.1 to −93.5 ‰; δ18OH2O = 1.8 to 6.6 ‰) of quartz from the lode-gold mineralization imply that ore-forming fluids were predominantly of magmatic origin, with a additional contribution from meteoric water. Taken together, a two-episode mineralization model was proposed for the formation of the Kateba’asu gold deposit. The early skarn mineralization stage is associated with the emplacement of diorite during the Early Carboniferous. In contrast, the subsequent lode-gold mineralization, occurring between the Late Carboniferous and Permian periods, represents a overprinted magmatic-hydrothermal gold system potentially linked to a deep-seated magmatic intrusion.

A novel meshless method for numerical simulation of fractured-vuggy reservoirs

This paper proposes a novel meshless numerical simulation method for fractured-vuggy reservoirs. Initially, model discretization involves extracting fracture and vug feature nodes along the contours of the reservoir bodies and in alignment with fracture orientations, tailored to the characteristics of the fractured-vuggy oil deposit. Subsequently, a connection element model is established within the influence domain. Based on the seepage equations of the connection system, a computational method for the parameters of the connection elements (connection transmissibility and connection volume) is defined. In addition, a sequential method is employed to solve for the pressure and saturation, achieving rapid prediction of the reservoir's production dynamics. On this basis, an automatic history matching algorithm is utilized for real-time fitting of oil–water dynamic indicators, inverting the characteristic parameters of the connection element model, and quantitatively characterizing the injection–production connection elements. The research findings indicate that the method is capable of rapidly fitting and predicting the dynamics of oil reservoir production. Furthermore, conceptual model examples have substantiated that it achieves comparable computational efficiency and superior computational accuracy when compared to the traditional finite difference (volume) method under the same nodal conditions. Additionally, the node arrangement for fractures and vugs is comparatively flexible, and it can ensure the integrity of the flow paths with a limited number of nodes to enhance predictive accuracy. Therefore, this method can effectively meet the rapid prediction requirements for fractured-vuggy reservoirs and also provides a novel meshless computational approach for the numerical simulation of such reservoirs.

Genesis of the Haopinggou breccia-hosted Au deposit, western Henan Province, China

Breccia-hosted Au deposits within the North China Craton (NCC) exhibit a complex genesis, with some breccias being genetically linked to Au mineralization and others unrelated. Understanding the origin of these breccias is crucial for elucidating the genesis of associated ore deposits and guiding exploration strategies. The Haopinggou deposit in the Xiong’ershan district, on the southern margin of the NCC, comprises quartz-carbonate vein-hosted Ag–Pb–Zn–Au deposits and related breccia pipe in metamorphic rocks of the late Archean to early Paleoproterozoic Taihua Group. The origin of the Haopinggou breccia is crucial to understand the Xiayu Ag-Pb-Zn-Au mineralization (5640 t Ag). In this study, we evaluate the genetic links between breccia and Ag-Pb-Zn-Au mineralization, with new insights obtained from the Haopinggou deposit characteristics, breccia characteristics, breccia-hosted Au mineralization, and isotopic data, which refine our understanding of Haopinggou Ag-Pb-Zn-Au hydrothermal systems and exploration models in discordant breccia pipes. Recent underground tunnel surveys and drill-core logging reveal a close spatial link between the breccia and hidden granite porphyry. Juvenile magmatic clasts (granite porphyry) and cement (K-feldspar and quartz crystallized from granite porphyry) are present in the breccia pipe above a granite porphyry apophysis, indicating that the breccia was formed by phreatomagmatic brecciation caused by emplacement of the granite porphyry. Fluidization at the cm- to 100-m-scale reveals that the movement direction of clasts inside the breccia pipe was from northwest to southeast after crypto-explosion, creating a northwest-trending breccia zone. Anhedral monazite (131.2 ± 7.6 Ma) encapsulated in pyrite from the breccia constrains the upper limit of brecciation. The δ34S values of pyrite in rock powder and hydrothermal cements range from 3.8 ‰ to 5.3 ‰ (mean: 4.8 ‰) and 2.7 ‰ to 7.5 ‰ (mean: 5.2 ‰), respectively, with δ34S-sphalerite in hydrothermal cement ranging from 5.7 ‰ to 6.1 ‰ (mean: 5.9 ‰) and δ34S-chalcopyrite ranging from − 0.9 ‰ to 5.6 ‰ (mean: 2.9 ‰). The S isotope characteristics of vein-hosted and breccia-hosted mineralization zones are consistent, with complete alignment of the sulfide assemblages and alteration features. These pieces of evidence collectively indicate that both vein- and breccia-hosted mineralization zones are products of magmatic activity. The metallogenic model for the Haopinggou breccia pipe underscores its unique formation mechanism, driven by pre-existing northwest-striking structural weaknesses and fluidization, indicative of a predominant northwest–southeast clast movement, and suggesting the potential for deep-seated porphyry-type Au mineralization.

Sulfide trace element enrichments in the metamorphic basement-hosted Xinhua Pb-Zn-Cu vein-type deposit, eastern Guizhou province (SW China)

Cambrian carbonate formations are widespread in the western Hunan-eastern Guizhou (WHEG) region (southwestern China), which hosts many Mississippi Valley-Type (MVT) lead–zinc (Pb-Zn) deposits. Regional Pb-Zn mineralization is well developed in the low-grade metamorphic rocks of the basal Proterozoic Banxi Group. The mineralization is associated with quartz veins and generally distributed along NE-trending fault zones. Moreover, these deposits have an extensive distribution and high grade, and are associated with Cu-Ag endowment. However, geological and geochemical research on these Pb-Zn vein-type deposits is relatively limited, and their relationship with the regional MVT mineralization remains unclear. The representative Xinhua deposit in Danzhai district is selected as the study subject. We conducted in situ trace element analyses on the sphalerite and chalcopyrite from the various metallogenic stages, and compared them with published sphalerite trace element data from the MVT Pb-Zn deposits in the western Hunan-eastern Guizhou metallogenic belt. Seven orebodies in Xinhua Pb-Zn deposit have been discovered so far, with a metal resource of over 120,000 metric tonnes of Zn + Pb. Field geology and microscopic petrography have revealed two mineralization stages: An early-stage black sphalerite (Sp-I) followed by reddish-brown sphalerite (Sp-II) mineralization, which corresponds to the main chalcopyrite mineralization stage, and a later-stage light-yellow sphalerite (Sp-III), Cu ore-barren mineralization.LA-ICPMS data indicate that the sphalerite from Xinhua has similar trace element compositions to those from the MVT Pb-Zn deposits in the region. They are relatively enriched in Ga, Cd, and Ge, while depleted in Fe, Co, and Mn. Critical metal Ge and Ga are particularly enriched in sphalerite, especially in Sp-I (Ge max 937 ppm, Ga max 824 ppm). The substitution mechanism of Ge and Ga in sphalerite are likely 2Cu+ + Ge4+ ↔ 3Zn2+ and Cu+ + Ga3+ ↔ 2Zn2+. Indium and Sn are mainly present in Sp-I and Sp-III. Chalcopyrite contains Zn and Sn both exceeding 100 ppm. Contents of Se, Ag, In, and Sn in chalcopyrite are significantly higher than those in sphalerite. Calculation of the sphalerite trace element geothermometer (GGIMFis) suggests that the average sphalerite ore-forming temperatures are 164 °C (Sp-I), 156 °C (Sp-II), and 205 °C (Sp-III), implying medium- to low-temperature mineralization. This indicates a possible influx of high-temperature, in-bearing fluid during the late-stage mineralization.In summary, the faults-controlled vein-type Pb-Zn deposits (e.g., Xinhua) may have been products of the same Kwangsian orogeny as other strata bound MVT deposits, and the Xinhua deposit features two mineralization stages with multiple ore metal sources. During the ore-forming fluid ascent, some ore-forming materials may have precipitated in the fluid conduits. And exposed after the erosion of the shallower stratiform orebodies and strata. Consequently, the Xinhua Pb-Zn deposit represents the preserved ore-fluid conduit phase (in the basement strata) of the MVT mineralization.

Mineralogy and Geochemical Characteristics of Lateritic Nickel Deposit in Wiwirano District, North Konawe, SE Sulawesi, Indonesia

This research aims to understand the mineralogical and geochemical characteristics of the nickel laterite deposit in the East Sulawesi Ophiolite Belt in Wiwirano District, North Konawe, Southeast Sulawesi, Indonesia. The deposit is analyzed and described to determine the laterization process and supergene enrichment. The geochemical data was obtained from X-ray fluorescence analysis, and mineralogical data from petrography and X-ray diffraction analysis. The minerals in the limonite zone are dominated by goethite and hematite. Minerals found in the saprolite zone include quartz, orthopyroxene, and lizardite, whereas the bedrock is made up of olivine, orthopyroxene, serpentine, and chromite. Fe2O3, Al2O3, and Co contents are high in the limonite zone, SiO2 and MgO have high content in the saprolite zone, and Ni is enriched in the saprolite zone. The distribution of enriched Ni is controlled by bedrock or parent lithology with an average content of 1.3% - 2.4% in saprolite, while in the limonite zone, Ni content is lower with an average content of 0.8% - 1.2%.