Changes In Precipitation Rates Research Articles

Influence of seasonal hydrological regimes on benthic macroinvertebrates in two the Brazilian biodiversity hotspots

Global warming has changed climate patterns worldwide causing an increase of extreme weather conditions that have altered annual seasonal hydrological regimes. These extreme climate-driven shifts modify habitat availability and can influence freshwater communities in disruptive ways. Our study investigates how changes in annual seasonal hydrological regimes affect the community structure and the Functional Feeding Groups (FFG) of benthic macroinvertebrates in two Brazilian biodiversity hotspots, the Brazilian Tropical Savannas (a.k.a., Cerrado) and Atlantic Forest biomes. We investigate whether annual variation in precipitation between biomes influence composition, richness, and abundance of benthic macroinvertebrates and their proportions of FFG. We demonstrate that differences in annual precipitation rates affect the composition and abundance, but not richness of benthic macroinvertebrates. Changes in community structure are related to changes in annual precipitation, which modify stream variables. Our findings suggest that annual seasonal changes in hydrological precipitation modify benthic macroinvertebrate communities, especially in Cerrado, where dry seasons are more pronounced. Therefore, annual changes in precipitation rates may disrupt the benthic macroinvertebrate communities in tropical savannas, potentially leading to biodiversity loss.

Surface Salinity Changes of the Tropical and Subtropical Oceans Since 1970 and Their Relationship With Surface Freshwater Fluxes

AbstractSea surface salinity (SSS) has shown a broad‐scale trend pattern of “salty gets saltier, fresh gets fresher” during the past decades, in line with changes in surface freshwater fluxes (FWFs). Yet, regional SSS changes and their relationship with FWFs are more complex and less appreciated, causing uncertainties in understanding the link between ocean salinity and the global water cycle. Based on the Hybrid Coordinate Ocean Model, we simulated the observed trends of tropical freshening and subtropical salinification since 1970 and gained insight into underlying processes through sensitivity experiments. Albeit with regional differences, changes in precipitation rate are the leading driver for SSS trends in most parts of the tropical and subtropical oceans, with a contribution of typically >60% in six selected regions. The roles of wind‐driven ocean dynamics and evaporation are secondary, contributing by <20% and <30%, respectively. Our results also suggest notable regional contrasts in the SSS‐FWF relationship. Particularly, many regions within the 10°–20° bands show opposite trends in SSS and FWF. Both the climatological and perturbed circulations are essential in this regionality. Specifically, the poleward Ekman transports driven by tropical trade winds act to broaden the SSS‐freshening regions generated by increased tropical rainfall; wind‐driven alterations in the geostrophic circulation cause SSS advection across zonal salinity gradients. These processes drive SSS changes that are opposite in sign to local FWF changes and complicate the regional SSS‐FWF relationship in the long‐term change since 1970.

Seasonal Differences of Precipitation and Microphysical Characteristics over the Asian Monsoon Region Using Spaceborne Dual-Frequency Precipitation Radar

Abstract This study aimed to reveal the seasonal climatic variations in the microphysical properties of precipitation over the Asian monsoon region. We used the Dual-Frequency Precipitation Radar satellite product aboard the Global Precipitation Measurement Mission Core Observatory for 8 years from 2014 to 2021 to statistically analyze the mass-weighted mean diameter (Dm) and frequency of heavy ice precipitation (graupel and hail). The results showed statistically significant seasonal changes. The microphysical characteristics of large Dm and frequent heavy ice precipitation were observed over the Indian subcontinent and Indochina Peninsula in the premonsoon season and over the western Himalayan region in the mature-monsoon season, which can be related to the intense and deeply developed precipitation systems. The relationship between precipitation rate and Dm was also examined. The results indicated that changes in Dm were not caused only by changes in precipitation rate but were probably induced by changes in precipitation characteristics. In terms of the relationship between the microphysical properties, heavy ice precipitation particles in the upper atmosphere above the melting layer were observed more frequently as Dm near the surface increased. We also studied lower-atmospheric instability by investigating the vertical gradients of the dry and moist static energies. The results indicated that instability properties were different; dry and wet instabilities were dominant in the premonsoon and monsoon seasons, respectively, consistent with the results of the precipitation characteristics. Significance Statement The purpose of this study was to reveal seasonal variations in precipitation microphysical characteristics, such as precipitation particle size and the existence of graupel and hail in the upper atmosphere, by climatological analysis over the Asian monsoon region. In previous studies, microphysical characteristics have mainly been addressed using ground-based observations. However, more sampling is needed to expand our understanding of climatological perspectives; therefore, we used recently available satellite observations. As a result, we found that precipitation particles at the surface were larger, and more graupel and hail existed in clouds in the premonsoon season when less precipitation was observed, compared to the mature-monsoon season when precipitation amount and frequency were abundant.

Constraining oceanic carbonate chemistry evolution during the Cretaceous-Paleogene transition: Combined benthic and planktonic calcium isotope records from the equatorial Pacific Ocean

The Mesozoic-Cenozoic transition is a period of biogeochemical cycle perturbations. The strongest of them is the Cretaceous-Paleogene boundary (K-Pg) crisis, characterized by one of the most important extinctions of planktonic marine calcifiers in Earth's history. One of the primary drivers of this biocalcification crisis is thought to be the increase in atmospheric CO2 concentration and ocean acidification triggered by the Chicxulub Impact, and/or Deccan volcanism. Because it reflects changes of the calcium cycle and/or depends on parameters of the carbonate system, the Ca isotope composition of carbonate minerals precipitated from seawater (δ44/40Ca) offers the potential to reconstruct some of the environmental changes that occurred. Here we present new high-resolution planktonic and benthic foraminiferal δ44/40Ca, δ18O, δ13C, and Sr/Ca records across the K-Pg transition from Shatsky rise (Leg 198; ODP Site 1209, Hole C). The δ44/40Ca record displays a succession of rapid shifts of ca. −0.4‰ across the K-Pg transition. They are similar though not identical between the planktonic and benthic records. These shifts took place on a timescale significantly shorter than the residence time of Ca in the oceans and are therefore unlikely to result from global disequilibrium in the oceanic Ca budget. Instead, changes in the fractionation factor between carbonate minerals and seawater in response to changes in precipitation rates may explain the observed δ44/40Ca and Sr/Ca record. The benthic and planktonic δ44/40Ca records show a late Maastrichtian and an early Danian negative excursions best explained by a succession of episodes of ocean alkalinity increase related to increased continental weathering caused by CO2 emissions from Deccan volcanism and the aftermath of the K-Pg biocalcification crisis. Carbonate compensation via carbonate sediment dissolution, biological carbonate compensation via reduction of biocalcification, and/or an increase in continental weathering must have occurred to offset the excess CO2, ultimately resulting in rapid changes in ocean carbonate chemistry, in combination with reduced surface alkalinity export in response to the early Paleogene planktonic biomineralization crisis.

River incision, 10Be production and transport in a source-to-sink sediment system (Var catchment, SW Alps)

Abstract. Detrital 10Be from continental river sands or submarine sediments has been extensively used to determine the average long-term denudation rates of terrestrial catchments, based on the assumption that the rate of cosmogenic nuclide production by the interaction of source rocks with cosmic radiation balances out the loss of these nuclides by surface denudation. However, the 10Be signal recorded in sediments may be affected at the source by the response time of mountainous catchments to high-frequency forcings. In addition, transient sediment storage in piedmonts, alluvial plains and lakes or near the coast may also induce a difference between the erosive signal and its record in the sedimentary sink. Consequently, a significant part of the signal recorded in shallow-water sediments can be lost, as deep marine sediments may simultaneously record a signal coming from newly eroded source rocks along with one coming from the destabilization of previously deposited sediments. In this paper, we use the landscape evolution model Badlands to simulate erosion, deposition and detrital 10Be transfer from a source-to-sink sedimentary system (the Var River catchment, southern French Alps) over the last 100 kyr. We first compare model-based denudation rates with the ones that would be extracted from the 10Be record of local continental sediments (equivalent to river sands) and from sediments deposited offshore over time in order to examine if this record provides an accurate estimate of continental denudation rates. Then, we examine which conditions (precipitation rate, flexure, ice cover) satisfy published measured river incision rates and 10Be concentration in submarine sediments. Our results, based on the Var catchment cosmic ray exposure dating and modelling indicate that, while river sands do accurately estimate the average denudation rate of continental catchments, this is much less the case for deep submarine sediments. We find that deep-sea sediments have a different and often much smoother 10Be signature than continental ones and record a significant time lag with respect to imposed precipitation rate changes, representing the geomorphological response of the margin. A model which allows us to fit both measured 10Be concentration in marine sediments and river incision rates on land involves an increase in precipitation rates from 0.3 to 0.7 m yr−1 after 20 ka, suggesting more intense precipitation starting at the end of the Last Glacial Maximum.

Development of lacustrine primary productivity in the Amazon Basin during the Holocene

The Amazon Basin is one of the most productive regions in the world and an important carbon sink. However, lake productivity has varied throughout the Holocene, as preserved in lacustrine sedimentary records. Concentrations of chlorophyll pigmented derivatives that are mainly derived from phytoplankton and macrophyte populations can be used to infer lake production levels. Here we use the chlorophyll derivatives concentrations analyzed by spectrophotometer in sediment cores from nine lakes distributed throughout the Brazilian Amazon Basin to document the continental-scale changes in lake production during the Holocene. Chlorophyll derivatives have varied with changes in precipitation rate throughout the last 10,000 years, similar to other climate records in tropical South America, including Ti concentration from the Cariaco Basin, δ13C from Lake Titicaca, and refractory black carbon in Nevado Illimani. Increasing precipitation is responsible for increasing the nutrient supply into the lake, which stimulates primary production. Our analysis was compared to climate-related parameters, suggesting an increasing trend of lake production rates during the wetter Late and Early Holocene, while lower production rates characterized the dry phase of the Middle Holocene. Therefore, the chlorophyll derivatives concentrations generally follow precipitation changes in the Amazon Basin during the Holocene.

Did increased flooding during the African Humid Period force migration of modern humans from the Nile Valley?

During the Quaternary period, the eastern Sahara's hydroclimate oscillated between wet and dry intervals. These oscillations caused drastic changes in precipitation rates, often associated with ancient human migrations. In particular, significant migration of riparian populations from the Nile Valley to the west and northwestward of the Sahara occurred during the African Humid Period (AHP), an episode of increased monsoons, which characterized North Africa in response to increasing insolation. Several fossil rivers, now preserved as ridges throughout southern Egypt due to their floodplains' deflation, contain archeological artifacts and thus represent a potentially important record of fluvial activity during this episode of past human dynamics and environmental change. Here we present 14C and Optically Stimulated Luminescence (OSL) ages of sediments preserved in these palaeorivers, which cluster within the AHP and are thus consistent with increased fluvial activity during this distinct humid period. Palaeohydraulic reconstructions based on grain size, channel geometry, and drainage area suggest typical precipitation intensities of 55–80 mm/h during sediment transport events. Given previous annual rainfall estimates, these hydrologic conditions may have lasted, or occurred, during the AHP up to 3–4 times more frequently than before and after this period. Such intense fluvial activity is consistent with monsoon intensification and may have rendered the area inhospitable for human settlements, congruent with population migration out of the Nile Valley during the AHP. These findings highlight links between past human ecodynamics and environmental signals, providing a concrete narrative of human population response to warming with potential echo in the current situation.

Changes in precipitation rates over the last 70 years in Eastern Paraná State, Brazil

Temporal hydrometeorological series may present variations over time. The awareness of these characteristics is important to improve the monitoring of changes that these series may suffer along time. In this regard, the present paper aims to identify the existence of precipitation trends for the east portion of Paraná state, in Brazil, and also investigate the changes in the observed rates over the last 70 years. The statistical tests of Mann-Kendall and Pettitt, and also the Theil-Sen estimator, are applied for series of precipitation from 13 pluviometric stations of eastern Paraná state, Brazil, with 70 years of data records. By the results it was identified long-term linear positive trend for 11 of the precipitation series and also detected medium-term patterns in precipitation over 10 stations, characterizing the Joseph effect. These series have presented a behavior with higher rates in the most recent years in comparison from the first years of the historical data, sectioning the complete series into two shorter stationary periods, and presenting an abrupt change point.

What Controls the Water Vapor Isotopic Composition Near the Surface of Tropical Oceans? Results From an Analytical Model Constrained by Large-Eddy Simulations.

The goal of this study is to understand the mechanisms controlling the isotopic composition of the water vapor near the surface of tropical oceans, at the scale of about a hundred kilometers and a month. In the tropics, it has long been observed that the isotopic compositions of rain and vapor near the surface are more depleted when the precipitation rate is high. This is called the “amount effect.” Previous studies, based on observations or models with parameterized convection, have highlighted the roles of deep convective and mesoscale downdrafts and rain evaporation. But the relative importance of these processes has never been quantified. We hypothesize that it can be quantified using an analytical model constrained by large‐eddy simulations. Results from large‐eddy simulations confirm that the classical amount effect can be simulated only if precipitation rate changes result from changes in the large‐scale circulation. We find that the main process depleting the water vapor compared to the equilibrium with the ocean is the fact that updrafts stem from areas where the water vapor is more enriched. The main process responsible for the amount effect is the fact that when the large‐scale ascent increases, isotopic vertical gradients are steeper, so that updrafts and downdrafts deplete the subcloud layer more efficiently.

Twenty first century changes in Antarctic and Southern Ocean surface climate in CMIP6

AbstractTwo decades into the 21st century there is growing evidence for global impacts of Antarctic and Southern Ocean climate change. Reliable estimates of how the Antarctic climate system would behave under a range of scenarios of future external climate forcing are thus a high priority. Output from new model simulations coordinated as part of the Coupled Model Intercomparison Project Phase 6 (CMIP6) provides an opportunity for a comprehensive analysis of the latest generation of state‐of‐the‐art climate models following a wider range of experiment types and scenarios than previous CMIP phases. Here the main broad‐scale 21st century Antarctic projections provided by the CMIP6 models are shown across four forcing scenarios: SSP1‐2.6, SSP2‐4.5, SSP3‐7.0 and SSP5‐8.5. End‐of‐century Antarctic surface‐air temperature change across these scenarios (relative to 1995–2014) is 1.3, 2.5, 3.7 and 4.8°C. The corresponding proportional precipitation rate changes are 8, 16, 24 and 31%. In addition to these end‐of‐century changes, an assessment of scenario dependence of pathways of absolute and global‐relative 21st century projections is conducted. Potential differences in regional response are of particular relevance to coastal Antarctica, where, for example, ecosystems and ice shelves are highly sensitive to the timing of crossing of key thresholds in both atmospheric and oceanic conditions. Overall, it is found that the projected changes over coastal Antarctica do not scale linearly with global forcing. We identify two factors that appear to contribute: (a) a stronger global‐relative Southern Ocean warming in stabilisation (SSP2‐4.5) and aggressive mitigation (SSP1‐2.6) scenarios as the Southern Ocean continues to warm and (b) projected recovery of Southern Hemisphere stratospheric ozone and its effect on the mid‐latitude westerlies. The major implication is that over coastal Antarctica, the surface warming by 2100 is stronger relative to the global mean surface warming for the low forcing compared to high forcing future scenarios.

Calcium isotopes in deep time: Potential and limitations

Calcium is an essential element in the biogeochemical cycles that regulate the long-term climate state of Earth. The removal of CO2 from the ocean-atmosphere system is controlled by the burial of carbonate sediments (CaCO3), ultimately linking the global calcium and carbon cycles. This fundamental link has driven the development of the stable calcium isotope proxy with application to both ancient skeletal and non-skeletal bulk carbonate sediments. Calcium isotope ratios (δ44/40Ca) have been used to track long-term changes in seawater chemistry (e.g., aragonite vs. calcite seas) and to elucidate short-term climatic perturbations associated with mass extinction events. However, developments in the calcium isotope proxy have shown that δ44/40Ca values in carbonate minerals also are sensitive to changes in precipitation rates, mineralogy and diagenesis, thereby complicating the application of the proxy to the reconstruction of global cycles. First, inorganic carbonate precipitation experiments have demonstrated that carbonate δ44/40Ca values are sensitive to precipitation rates with higher rates generally leading to larger fractionation. Second, δ44/40Ca values are sensitive to carbonate mineralogy with inorganic aragonite and calcite being on average ~ 1.5‰ and ~ 0.9‰ depleted relative to contemporaneous seawater, respectively. The effects of both changes in carbonate mineralogy and precipitation rates affect primary and secondary minerals, but are particularly pronounced during carbonate diagenesis where relatively slow rates of recrystallization and neomorphism can lead to significant changes in bulk sediment δ44/40Ca values. Third, changes in faunal composition expressed in skeletal fossil archives can lead to large changes in carbonate δ44/40Ca values that are decoupled from changes in global cycles. Nevertheless, when these factors are appropriately considered the application of calcium isotopes in ancient carbonate sediments becomes a powerful tool for understanding biogeochemical processes that operate over many scales; from diagenetic changes within the sediment pore-space, to regional changes across ancient carbonate platforms, and to global changes in seawater chemistry through time. Importantly, the processes that contribute to variability in carbonate δ44/40Ca values are likely to impact other carbonate-bound proxies, highlighting the potential for calcium isotopes as a tool to better understand the variability of other isotope systems.

Use of high-resolution seismic reflection data for paleogeographical reconstruction of shallow Lake Yamanaka (Fuji Five Lakes, Japan)

High-resolution seismic profiles, combined with the integration of published drilling data, provide a detailed paleoenvironmental history of Lake Yamanaka (Fuji Five Lakes, Japan). This study presents a detailed analysis of the different depositional stages of the area currently occupied by Lake Yamanaka (floodplain wetland, river and lake). From ca. 5500 cal yr BP to ca. 5050 cal yr BP, the Yamanaka basin was occupied by floodplain wetlands. During that period, the landscape was very stable and erosion on northeastern flank of Mt. Fuji was relatively limited. From ca. 5050 cal yr BP to ca. 3050 cal yr BP, the water level increased and the floodplain wetlands became a lake. From ca. 3050 cal yr BP to ca. 2050 cal yr BP, the water level progressively decreased, leading to a reduction in lake extent. During this lowering of the lake's water level, a 1 km2 mass-transport deposit modified the physiography of the lake floor. From ca. 2050 cal yr BP to ca. 1050 cal yr BP, the lake disappeared and a river flowing towards the northwest occupied the depression. Ponds occupied morphological lows formed by mass-transport deposits. From ca. 1050 cal yr BP to the present day, the lake water level rose again, connecting the ponds with the main lake. Since then, the lake water level has continued to rise to the current level. Lake water level fluctuations are the results of several factors that could be interconnected: (i) changes in precipitation rates; (ii) margin destabilization (the Yamanaka mass-transport deposit), (iii) changes in river inlets and therefore variation in water supplies, (iv) volcanic eruptions (scoria fall-out and lava flows) and (v) changes in vegetation cover. This study highlights the importance of coupling sediment cores and high-resolution seismic reflection profiling to identify lateral variation and modification of sedimentary inputs through time.

Hydrodynamic influence on reservoir sustainability in semi-arid climate: A physicochemical and environmental isotopic study

Water scarcity and increasing water demand require the development of water management plans such as establishing artificial lakes and dams. Plans to meet water needs are faced by uprising challenges to improve water quality and to ensure the sustainability of hydro-projects. Environmental isotopes coupled to water physicochemical characteristics were investigated over a biennial cycle to assess both geomorphological and environmental impacts on the water quality of a reservoir situated in an intensively used agricultural watershed under a Mediterranean semi-arid climate. The particularity of the semi-arid climate and the diverse topography generate a continental and orographic rain effect on the isotopic composition of precipitation and the water recharged sources. The studied reservoir responds quickly to land-use activities and climatic changes as reflected by temporal and spatial variations of water chemistry and isotopic composition. Increasing changes in precipitation rate and dry periods significantly modified the water isotopic composition in the reservoir. During the first year, hydrogen (δD) and oxygen (δ18O) isotopes are depleted by 6 and 2‰ between dry and wet season, respectively. While a shift of −2‰ for δD and −1‰ for δ18O was detected during the second annual cycle. Environmental isotopic compositions demonstrate for the first time the occurrence of groundwater inflow to the central (Cz) and dam (Dz) zones of the Qaraaoun reservoir. The Cz and Dz can be considered as open water bodies subjected to dilution by groundwater inflow, which induces vertical mixing and reverse isotopic stratification of the water column. In the contrary, the river mouth zone acts as a closed system without groundwater intrusion, where heavy water accumulates and may act as a sink for contaminants during dry season. Groundwater influx acts as a dilution factor that renews the hypolimnion, and minimizes the perturbations induced by both internal biogeochemical reactions and external hydrological variations. Attention should be devoted to the hydrogeological location of planned reservoirs, which should take into account the vicinity of shallow water table to insure good water quality and water sustainability.

Modelling the dynamics of total precipitation and aboveground net primary production of fescue-feather grass steppe at Askania Nova according to global climate change scenariosModelling the dynamics of total precipitation and aboveground net primary production of fescue-feather grass steppe at Askania Nova according to global climate change scenarios

This article discusses modelling of Aboveground Net Primary Production (ANPP) of steppe (arid grassland ecosystems) plant species in relation to changes in total precipitation over the previous year at the “Stara” study site, Biosphere Reserve “Askania-Nova”, Khersonregion (Ukraine). To investigate linkages between precipitation and Aboveground Net Primary Production, correlation analysis was chosen and a time series regression analysis was based on the data set for the period 1988–2012. The NPP dependence on quantity of precipitation was found to be more significant for the previous autumn-winter-spring period (AWSP) than for the previous 12 month period. A regression model of ANPP’s dependence on AWSP is proposed. This model was further validated by the authors’ samples of ANPP, collected at the “Stara” study site in 2013–2016. The regression model showed a non-linear (quadratic) dependence of net primary production of zonal and intrazonal plant coenoses and total precipitation for the autumn-winter-spring period for arid grasslands with a coefficient of determination equal to 0.54 and significance level less than 0.05. The non-linear equation for these relations, visualized by a parabola curve, was calculated using the Nonlinear Least-Squares Regression Method. The data set, based on calculated predicted values, using the calculated equation, had a similar dynamic to the historical data on ANPP, but the model could not predict critical values. For this reason, additional studies are required for critical precipitation events. Non-linear response, investigated according to regression analysis, reveals optimal zones of plant growth, depending on the total precipitation level before the vegetation peak. For research areas where the dominant species are the turf grasses Stipa ucrainica P. Smirn., S. capillata L., S. lessingiana Trin. & Rupr., Festuca valesiaca Gaudin, Koeleria cristata (L.) Pers.) the optimal precipitation rates were found to be 350–400 mm during AWSP with ANPP at 350 g/m 2 . On the basis of the regression model and current forecasts of changes in precipitation rates we made a forecast of net primary production of plant communities for four climate change scenarios (RCP2.6, RCP4.5, RCP6, and RCP8.5) described in the Fifth Assessment of Intergovernmental Panel on Climate Change (IPCC). For this purpose, bioclimate projections of 10 major climate models (The Community Climate System Model Version 4 (CCSM4), GISS-E2-R, HadGEM2-AO, HadGEM2-ES, IPSL-CM5A-LR, MIROC-ESM-CHEM, MIROC-ESM, MIROC5, MRI-CGCM3, NorESM1-M), used for preparation of the IPCC report, were analyzed and imported to the geographical information system package QGIS. QGIS modelling software was used for geoanalysis and calculation of GIS-layers for Askania-Nova and adjacent arid grasslands. The results of modelling with the 10 climate models were compared and analyzed for each of the four IPCC scenarios, depending on predicted CO 2 levels. The presented modelling results showed a trend to growth in AWSP precipitation and NPP for all scenarios up to 2040–2060. The scenarios RCP2.6, RCP4.5, RCP6 predicted the optimum precipitation zone for current plant diversity for the period of 2040–2060 and scenario RCP8.5 predicted an optimum zone peak after 2080. The study confirmed the importance of monitoring the productivity of herbaceous communities in dry steppe ecosystems ofUkraine.

Role of climate changes for wind gap formation in a young, actively growing mountain range

AbstractWind gaps in actively growing mountain ranges are unique geomorphological features testifying to the competition between tectonics and fluvial incision. Although it is clear that these landforms reflect the defeat of rivers during sustained rock uplift, the role of climate changes in their formation has never been explored. Here, we use a coupled tectonics–landscape evolution model to show that temporal changes in precipitation rate exert an important control on wind gap formation. In models with a constant precipitation rate, rivers flowing across a growing range are either defeated at an early stage or they abandon their valleys very late, if at all. If precipitation varies, wind gaps form mostly c. 100–200 ka after a transition to drier conditions because of sediment aggradation upstream of the range. Our results suggest that the Pliocene–Quaternary aridification of Central Asia contributed to wind gap formation in active mountain ranges in the foreland of northeastern Tibet.

Magnetic minerals in three Asian rivers draining into the South China Sea: Pearl, Red, and Mekong Rivers

The use of the marine sedimentary magnetic properties, as tracers for changes in precipitation rate and in oceanic water masses transport and exchanges, implies to identify and to characterize the different sources of the detrital fraction. This is of particular importance in closed and/or marginal seas such as the South China Sea. We report on the magnetic properties of sedimentary samples collected in three main Asian rivers draining into the South China Sea: the Pearl, Red, and Mekong Rivers. The geological formations as well as the present climatic conditions are different from one catchment to another. The entire set of performed magnetic analyses (low-field magnetic susceptibility, ARM acquisition and decay, IRM acquisition and decay, back-field acquisition, thermal demagnetization of three-axes IRM, hysteresis parameters, FORC diagrams, and low-temperature magnetic measurements) allow us to identify the magnetic mineralogy and the grain-size distribution when magnetite is dominant. Some degree of variability is observed in each basin, illustrating different parent rocks and degree of weathering. On average it appears that the Pearl River is rich in magnetite along the main stream while the Mekong River is rich in hematite. The Red River is a mixture of the two. Compared to clay mineral assemblages and major element contents previously determined on the same samples, these new findings indicate that the magnetic fraction brings complementary information of great interest for environmental reconstructions based on marine sediments from the South China Sea.

Beryllium-10 concentrations in the hyper-arid soils in the Atacama Desert, Chile: Implications for arid soil formation rates and El Niño driven changes in Pliocene precipitation

Meteoric 10Be concentrations in soil were measured to understand the mechanism, timescale, and climatic dependence of soil formation in the hyper-arid Atacama Desert. The observed systematic decline of soil 10Be concentrations with depth has been reproduced using a simple model that assumes soil matrix, including 10Be, builds up as layers over time while 10Be decays in situ. This suggests a mechanism of soil accumulation via atmospheric deposition, which is in agreement with stable isotopic evidence. The model estimates an age of ∼6.6±0.4Ma for the total soil profile. Small discrepancies between the model and observations are likely mainly due to changes in precipitation rates that can impact 10Be delivery rates and 10Be movement within the profile. Interpreted in this way, the 10Be data suggest drying in the Atacama after ∼4.7Ma, and returning to an insignificant wet period at ∼1Ma, which was possibly connected to El Niño- or La Niña-like climate change.

Investigation of the effects of high atmospheric aerosol pollution on the development of the high-depth cumulonimbus cloud

Considered is a case of the development of the cumulonimbus cloud (Cb) in the southwestern part of Saudi Arabia under the conditions of heavy pollution of atmosphere with natural aerosol. Using the ground-based radar and satellite radiometric instruments, the characteristics of the Cb are obtained for the cloud top height of more than 14 km and maximum reflectivity of 58 dBZ. To measure the precipitation rate using the radar data, the Z-I ratio obtained for the area under study was applied. To compute the precipitation rate, the results of the sounding with the SEVERI radiometer installed on the Meteosat-8 satellite were also used. Carried out are numerical experiments on the simulation of aerosol effects on the evolution of the cloud under study. The development of the cloud at the presence of background aerosol was simulated as well as at high aerosol concentration. Three cases are considered: aerosol is a passive admixture; aerosol has hygroscopic properties; aerosol has ice-forming properties. It is demonstrated that the most considerable effects on the cloud evolution are caused by the intensification of ice formation under the influence of aerosol; not only the time distribution of precipitation rate changes but also the amount of precipitation increases.

Preservation of NOM-metal complexes in a modern hyperalkaline stalagmite: Implications for speleothem trace element geochemistry

We report the first quantitative study of the capture of colloidal natural organic matter (NOM) and NOM-complexed trace metals (V, Co, Cu, Ni) in speleothems. This study combines published NOM–metal dripwater speciation measurements with high-resolution laser ablation ICPMS (LA-ICPMS) and sub-annual stable isotope ratio (δ18O and δ13C), fluorescence and total organic carbon (TOC) analyses of a fast-growing hyperalkaline stalagmite (pH ∼11) from Poole’s Cavern, Derbyshire UK, which formed between 1997 and 2008 AD. We suggest that the findings reported here elucidate trace element variations arising from colloidal transport and calcite precipitation rate changes observed in multiple, natural speleothems deposited at ca. pH 7–8. We find that NOM–metal(aq) complexes on the boundary between colloidal and dissolved (∼1nm diameter) show an annual cyclicity which is inversely correlated with the alkaline earth metals and is explained by calcite precipitation rate changes (as recorded by kinetically-fractionated stable isotopes). This relates to the strength of the NOM–metal complexation reaction, resulting in very strongly bound metals (Co in this system) essentially recording NOM co-precipitation (ternary complexation). More specifically, empirical partition coefficient (Kd) values between surface-reactive metals (V, Co, Cu, Ni) [expressed as ratio of trace element to Ca ratios in calcite and in solution] arise from variations in the ‘free’ fraction of total metal in aqueous solution (fm). Hence, differences in the preservation of each metal in calcite can be explained quantitatively by their complexation behaviour with aqueous NOM. Differences between inorganic Kd values and field measurements for metal partitioning into calcite occur where [free metal]≪[total metal] due to complexation reactions between metals and organic ligands (and potentially inorganic colloids). It follows that where fm≈0, apparent inorganic Kd app values are also ≈0, but the true partition coefficient (Kd actual) is significantly higher. Importantly, the Kd of NOM–metal complexes [organic carbon–metal ratio) approaches 1 for the most stable aqueous complexes, as is shown here for Co, but has values of 24–150 for V, Ni and Cu. This implies that ternary surface complexation (metal–ligand co-adsorption) can occur (as for NOM–Co), but is the exception rather than the rule. We also demonstrate the potential for trace metals to record information on NOM composition as expressed through changing NOM–metal complexation patterns in dripwaters. Therefore, a suite of trace metals in stalagmites show variations clearly attributable to changes in organic ligand concentration and composition, and which potentially reflect the state of overlying surface ecosystems.

Depth and character of rock weathering across a basaltic‐hosted climosequence on Hawai‘i

ABSTRACTUsing field observations and geochemical and digital terrain analyses, we describe the structure and thickness of the regolith across a climosequence on the island of Hawai‘i to gain insight into the relative roles of precipitation and the near‐surface hydrologic structure in determining weathering patterns. In the wet portion of the climosequence, where the long‐term water balance is positive, the regolith thickness reaches an observed maximum of ~40 m and appears limited by the geomorphic base‐level of the landscape. However, even within this thick regolith, distinct units of varying weathering intensity occur; the vertical ordering of which largely reflects differences in the initial permeability structure of the basalt flows rather than a systematic decrease in weathering intensity downwards from the ground surface. In the dry portion of the climosequence, where the long‐term water balance is negative, the regolith thickness is confined to ~1 m, is highly dependent on the inferred permeability structure of the basalt flows, and is independent of geomorphic base‐level. Weathering intensity also varies according to permeability structure and decreases in this thin regolith with distance beneath the ground surface. The abrupt change in regolith depth and character that coincides with the transition from net‐positive to net‐negative long‐term water balance implies that small changes in precipitation rates around a neutral water balance result in large changes in the distribution and depth of weathering. Together our observations indicate that the distribution and depth of weathering in basalts (and probably other lithologies) might be best understood by considering how precipitation interacts with the complicated near‐surface permeability structure over regolith‐forming timescales to weather rock in the vadose zone. Copyright © 2013 John Wiley & Sons, Ltd.