Change In Oscillation Frequency Research Articles

Effect of temporal increase in equivalence ratio on combustion instability of a lean-premixed swirling hydrogen flame

The effect of temporal increase in the equivalence ratio on the combustion instability of a lean-premixed low-swirl hydrogen jet flame in a low-swirl combustor (LSC) is investigated in detail using a high-fidelity Large-Eddy Simulation (LES). The equivalence ratio is linearly increased from 0.3 to 0.5 over a duration of 0.4 s. The results show that the pressure oscillation amplitude in the combustor increases significantly when the equivalence ratio at the combustor inlet (ERCI) exceeds 0.42, and the maximum pressure amplitude and the combustion instability mode exhibit trends consistent with those in a previous experiment and numerical simulation conducted with the same LSC setup at a fixed equivalence ratio of 0.39. Temporal variations in the equivalence ratio and consequently the temperature inside the combustor cause the drastic amplification of pressure oscillation (when the ERCI exceeds 0.42) whose amplitude is larger than that at the fixed equivalence ratio (= 0.39). Prior to the onset of this exceptionally strong combustion instability, a transient irregular oscillation phenomenon comprising instantaneous changes in the pressure oscillation frequency is observed. While the pressure oscillations in the combustor and in the injector channel are in phase after the onset of strong combustion instability, they are in opposite phases during the occurrence of the irregular oscillation phenomenon prior to the onset of strong combustion instability. This irregular oscillation phenomenon predicted by the LES may play a crucial role in the mechanism of transition from stable combustion to combustion instability.

Enhancing sensitivity of trace copper detection based on coupled optoelectronic oscillator

We propose to employ coupled optoelectronic oscillator (COEO) for trace copper detection to achieve an enhanced sensitivity and stability. By replacing the optical source of the traditional OEO with an optical feedback loop, the oscillation frequency is determined by the cavity loop length in conjunction with the laser output wavelength. The sensing head, which is fabricated by inserting a fusion spliced fiber with large lateral offset fusion splicing in a Sagnac loop, act as a wavelength selection component in the laser loop. Hence, the oscillation frequency changes with the varying solution concentration. Benefitting from the matching of the laser loop and the OEO loop, the final oscillation mode is more stable. By comparing the performance of the COEO-based, single-loop and dual-loop OEO-based sensors, the highest sensitivity of 41.1 Hz/(uMol/L) is obtained by the COEO-based sensor. Since the positive feedback of two loops, the single mode oscillation can be implemented without additional devices.

Vertical convection regimes in a two-dimensional rectangular cavity: Prandtl and aspect ratio dependence

Vertical convection is the fluid motion that is induced by the heating and cooling of two opposed vertical boundaries of a rectangular cavity (see e.g. Wang et al., J. Fluid Mech., vol. 917, 2021, A6). We consider the linear stability of the steady two-dimensional flow reached at Rayleigh numbers of O( $10^8$ ). As a function of the Prandtl number, $Pr$ , and the height-to-width aspect ratio of the domain, $A$ , the base flow of each case is computed numerically and linear simulations are used to obtain the properties of the leading linear instability mode. Flow regimes depend on the presence of a circulation in the entire cavity, detachment of the thermal layer from the boundary or the corner regions and on the oscillation frequency relative to the natural frequency of oscillation in the stably temperature-stratified interior, allowing for the presence of internal waves or not. Accordingly, the regime is called slow or fast, respectively. Either the global circulation or internal waves in the interior may couple the top and bottom buoyancy currents, while their absence implies asymmetry in their perturbation amplitude. Six flow regimes are found in the range of $0.1 \leq Pr \leq 4$ and $0.5 \leq A \leq 2$ . For $Pr \lessapprox 0.4$ and $A>1$ , the base flow is driven by a large circulation in the entire cavity. For $Pr \gtrapprox 0.7$ , the thermal boundary layers are thin and the instability is driven by the motion along the wall and the detached boundary layer. A transition between these regimes is marked by a dramatic change in oscillation frequency at $Pr = 0.55 \pm 0.15$ and $A <2$ .

Research on the influence factors of hydraulic oscillator on drag reduction efficiency in horizontal well drilling

The application of hydraulic oscillator can solve the problems of large friction and serious pressure support in the drilling process of extended reach well and long horizontal well, but the conventional hydraulic oscillator parameter setting is not reasonable, high pressure consumption, easy to make the ground machine pump overload operation and failure. Therefore, based on the LuGre dynamic friction model theory, a calculation model for the friction between drill string and rock wall under the condition of longitudinal oscillation is established, and the influence law of hydraulic oscillator oscillation parameters on drag reduction efficiency is studied. The results show that the change of oscillation intensity, oscillation frequency and oscillation amplitude can improve the drag reduction efficiency, and the increase trend of drag reduction efficiency is first increased and then decreased. The selection of each parameter has the optimal value. According to the analysis of orthogonal test results, it is found that the reduction degree of friction between drill string and borehole wall rock by each parameter is in the order of oscillation intensity, oscillation frequency and oscillation amplitude from the largest to the smallest.

Pulsar Timing Array signature from oscillating metric perturbations due to ultra-light axion

Abstract A coherently oscillating ultra-light axion can behave as dark matter. In particular, its coherently oscillating pressure perturbations can source an oscillating scalar metric perturbation, with a characteristic oscillation frequency which is twice the axion Compton frequency. A candidate in the mass range 10(-24,-21) eV can provide a signal in the frequency range tested by current and future Pulsar Timing Array (PTA) programs. Involving the pressure perturbations in a highly nonlinear environment, such an analysis demands a relativistic and nonlinear treatment. Here, we provide a rigorous derivation of the effect assuming weak-gravity and slow-motion limit of Einstein's gravity in zero-shear gauge and show that dark matter's velocity potential determines the oscillation phase and frequency change. A monochromatic PTA signal correlated with the velocity field would confirm the prediction, for example, by cross-correlating the PTA results with the future local velocity flow measurements.

Self-cleaning foulant attachment on near-infrared responsive photocatalytic membrane for continuous dynamic removing antibiotics in sewage effluent environment

Bifunctional photocatalytic nanofiltration (PNF) membrane has become a reliable frontier technique for removing refractory organic micropollutants. However, the active mitigated fouling mechanism from the microscopic perspective during its long-term operation of purifying real micro-polluted water is rarely studied. Herein, with an integrated use of QSense Explorer and confocal laser scanning microscope techniques, self-cleaning foulant attachment on an activated and customized near-infrared responsive polymeric PNF (termed as nPNF) membrane with good service performance for continuous dynamic removing antibiotics in sewage effluent environment was firstly elucidated. Time-dependent changes in dissipation oscillation frequency, sensed mass and the visualized foulant spatial distribution all indicated that there were only sporadic foulant attachment, an extremely low fouling layer thickness and irreversible fouling rate on/of the activated nPNF membrane top surface, thereby endowing it with excellent self-cleaning characteristic. This is probably because the reactive oxygen species (mainly •O2− and •OH) concurrently destroys the integrity of fouling layer and its internal adhesion structure, transforming part of the irreversible fouling on nPNF membrane surface into reversible one that is easy to wash off. These new horizons provided useful insight on the fate of selected antibiotics in the to-be-removed stage and self-cleaning foulant attachment of PNF membrane.

Inductive sensor for measuring linear displacement and velocity – Version with stationary magnetic core

The article describes a displacement sensor designed and manufactured in the Rock Deformation Laboratory of the Strata Mechanics Institute of the Polish Academy of Sciences for cooperation with the GTA-10 triaxial cell. This sensor measures the displacement and velocity of the strength machine's piston.The sensor has the form of a single-layer induction coil made of spring steel with a fixed magnetic core cooperating with the LC oscillator. The coil elongates during measurement without friction, causing oscillation frequency changes, unlike the LVDT sensor, where core movements produce a voltage signal. In this way, a displacement-frequency transducer is realised.The presence of the core linearizes the transducer's displacement-frequency characteristic and increases its sensitivity in this case. Moreover, the core increases the inductance of the sensor, which allows the increase in the capacitance of the resonant circuit and thus, the stability of the oscillations, which are influenced by the parasitic capacitances of the connections. In this way, a resolution of the transducer of less than 500 nm was achieved, with a measuring range of 70 mm (relative resolution 105). The new inductive sensor replaced the resistance displacement sensor, which had been used previously.The article shows the mathematical background of the sensor functioning as a displacement-frequency transducer, its structure and examples of its application.

Acute Effects of Supra- and High-Loaded Front Squats on Mechanical Properties of Lower-Limb Muscles.

Knowledge about the acute effects of supramaximal-loaded resistance exercises on muscle mechanical properties is scarce. Therefore, this study aimed to examine changes in dominant limb biceps femoris and vastus lateralis oscillation frequency and stiffness before and after high- and supramaximal-loaded front squats. Nineteen male handball players participated in the experimental session with a barbell front squat 1RM. The first set was performed at 70% of the 1RM for four repetitions, and the second and third sets were performed at 90%1RM in an eccentric-concentric or an eccentric-only manner at 120% of the 1RM for three repetitions. The handheld myometer was used for the measurement of the biceps femoris and vastus lateralis stiffness and the oscillation frequency of the dominant limb 5 min before and at the 5th and 10th min after front squats. A two-way ANOVA neither indicated a statistically significant interaction (p = 0.335; η2 = 0.059 and p = 0.103; η2 = 0.118), the main effect of a condition (p = 0.124; η2 = 0.126 and p = 0.197; η2 = 0.091), nor the main effect of the time point (p = 0.314; η2 = 0.06 and p = 0.196; η2 = 0.089) for vastus lateralis and biceps femoris stiffness. However, there was a statistically significant interaction (F = 3.516; p = 0.04; η2 = 0.163) for vastus lateralis oscillation frequency. The post hoc analysis showed a significantly higher vastus lateralis oscillation frequency at POST (p = 0.037; d = 0.29) and POST_10 (p = 0.02; d = 0.29) compared to PRE during the SUPRA condition. Moreover, Friedman's test indicated statistically significant differences in biceps femoris oscillation frequency (test = 15.482; p = 0.008; Kendall's W = 0.163). Pairwise comparison showed a significantly lower biceps femoris oscillation frequency in POST (p = 0.042; d = 0.31) and POST_10 (p = 0.015; d = 0.2) during the HIGH condition compared to that in the corresponding time points during the SUPRA condition. The results of this study indicate that the SUPRA front squats, compared to the high-loaded ones, cause a significant increase in biceps femoris and vastus lateralis oscillation frequency.

Inaccuracies due to the frequency warping in simulation of electrical systems using combined state–space nodal analysis

The simulation of electromagnetic transients may suffer from inaccuracies due to a phenomenon known as frequency warping (FW). This paper presents an analysis of the effects of FW on the accuracy of digital simulations, demonstrating that the use of the trapezoidal integration rule (TR), commonly employed in many electromagnetic transients simulators, is the root cause of such inaccuracies. Although FW is considered a major problem in digital signal processing, it is often overlooked when simulating electrical transients. The analysis is carried out in a fourth-order RLC circuit, from which the analytic solution is derived. The circuit is solved using the combined state–space nodal method, considering the TR or recursive convolutions as solution methods for the state–space representation. It was observed that the FW caused a change in the natural oscillation frequency of the system, causing a pulsating behavior of absolute error. The accumulation of errors over time can result in deteriorated solutions when either the time steps are not sufficiently small or the simulation runs for a long enough duration. This paper emphasizes the significance of accounting for the FW phenomenon in digital simulations that rely on integration methods, such as the TR.

Mechanical Photoluminescence Excitation Spectra of a Strongly Driven Spin-Mechanical System

We report experimental studies of a driven spin-mechanical system, in which a nitrogen-vacancy ($\mathrm{N}\text{\ensuremath{-}}$V) center couples to out-of-plane vibrations of a diamond cantilever through the excited-state deformation potential. Photoluminescence excitation studies show that in the unresolved sideband regime and under strong resonant mechanical driving, the excitation spectra of a $\mathrm{N}\text{\ensuremath{-}}$V optical transition feature two spectrally sharp peaks, corresponding to the two turning points of the oscillating cantilever. In the limit that the strain-induced frequency separation between the two peaks far exceeds the $\mathrm{N}\text{\ensuremath{-}}$V zero-phonon linewidth, the spectral position of the individual peak becomes sensitive to minute detuning between the mechanical resonance and the external driving force. For a fixed optical excitation frequency near the $\mathrm{N}\text{\ensuremath{-}}$V transition, $\mathrm{N}\text{\ensuremath{-}}$V fluorescence as a function of mechanical detuning features resonances with a linewidth that can be orders of magnitude smaller than the intrinsic linewidth of the mechanical mode. This enhanced sensitivity to mechanical detuning can potentially provide an effective mechanism for mechanical sensing, for example, mass sensing via measurements of induced changes in the mechanical oscillator frequency.

Chitosan or Cyclodextrin Grafted with Oleic Acid Self-Assemble into Stabilized Polymeric Micelles with Potential of Drug Carriers

Polymeric micelles combining the advantages of biocompatible poly- and oligosaccharides with classical micellar amphiphilic systems represent a promising class of drug carriers. In this work, micelles based on chitosan (or cyclodextrin) and oleic acid with various modification degrees were synthesized-the most optimal grafting degree is 15-30% in terms of CMC. According to NTA data, micelles have a hydrodynamic diameter of the main fraction of 60-100 nm. The inclusion of the antibacterial agents: moxifloxacin or rifampicin in micelles was studied by FTIR spectroscopy and fluorescence spectroscopy using a pyrene label (using monomer-excimer approach). When aromatic molecules are incorporated into micelles, the absorption bands of C-H bonds of the fatty tails of micelles shift towards smaller wavenumbers, indicating a stabilization of the micelles structure, and the microenvironment of the drug molecule changes according to the low frequencies shift and intensity changes in oscillation frequencies of 1450 cm-1 corresponding to aromatic fragment. Loading of moxifloxacin and rifampicin into micelles leads to a change in the fluorescent properties: a shift of the maximum of fluorescence emission to the long-wavelength region and an increase in the fluorescence anisotropy due to a drastic increase in the hydrodynamic volume of the fluorophore-containing rotating fragment. Using the pyrene label, the critical micelle concentrations were determined: from 4 to 30 nM depending on the polymer composition. Micellar systems enhance the effect of the antibiotic by increasing the penetration into bacterial cells and storing the drug in a protective coat. As a part of the supramolecular structure, the antibiotic remains active for more than four days, while in free form, the activity decreases after two days. In pharmacokinetic experiments, in vivo moxifloxacin in micellar systems show 1.7 times more efficiency compared to free form; moreover, two times higher maximal concentration in the blood is achieved. The advantage of polymer micellar systems in comparison with simple cyclodextrins and chitosan, which do not so significantly contribute to the antibacterial and pharmacokinetic parameters, was shown. Thus, polymeric micelles are one of the key approaches to improving the effectiveness of antibacterial drugs and solving the problems of resistant bacterial infections and multidrug resistance.

How certain are El Niño–Southern Oscillation frequency changes in Coupled Model Intercomparison Project Phase 6 models?

AbstractEl Niño–Southern Oscillation (ENSO) is one of the most important modes of climate variability on interannual timescales. We aim to find out whether a change in ENSO frequency can be predicted for the nearer future. We analyse the unforced pre‐industrial control run and the forced 1%/year CO2 increase run for an ensemble of 43 general circulation models that participated in the Coupled Model Intercomparison Project Phase 6 (CMIP6). We assume that the uncertainty of ENSO frequency trend estimates from an ensemble is caused by apparent trends as well as model differences. The part of the uncertainty caused by apparent trends is estimated from the pre‐industrial control simulations. As a measure for ENSO frequency, we use the number of El Niño‐ and La Niña‐like months in a moving 30‐year time window. Its linear decadal trend is calculated for every member. The multimember mean of the trend for both experiments is less than 0.7 events per decade. Given that the standard error is of the same order of magnitude, we consider this a negligible trend. The uncertainties are large in both experiments and we can attribute most of the intermember variability to apparent trends due to natural variability rather than different model reactions to CO2 forcing. This means that the impact of intermodel differences might have been overstated in previous studies. Apparent trends make it very difficult to make reliable predictions of changes in ENSO frequency based on 120‐year time series.

The Effects of the "Sling Shot" Device on Bench Press Performance, Mechanical Properties of Muscle, and Movement Kinematics.

Wojdała, G and Krzysztofik, M. The effects of the "sling shot" device on bench press performance, mechanical properties of muscle, and movement kinematics. J Strength Cond Res 37(4): 780-786, 2023-This study aimed to evaluate the influence of the sling shot support device at various external loads and intensities of effort, taking into account acute changes in power performance, mechanical muscle properties, and bench press kinematics. For this purpose, 12 resistance-trained men (age: 27.1 ± 4.2 years, body mass: 90.3 ± 16.9 kg, bench press [BP] 1 repetition maximum [1RM]: 112.7 ± 23.1 kg) (resistance training experience: 6.9 ± 3.8 years) participated in the study. Each subject completed 2 experimental sessions that differed in the use of the sling shot (SS) or nonuse (CONT) of the SS and an appropriate external load. The 2 experimental sessions consisted of the 1RM test, 3 sets of 2 repetitions of BP with the load increased in each set (50-70-90% 1RM), and a fourth set of the BP efforts to muscle failure with a 70% 1RM load. Before and after each set, the changes in triceps brachii oscillation frequency and stiffness were assessed by means of myotonometry. Results indicated a significant main effect of the SS to increase peak power ( p < 0.0001, η 2 = 0.733). Furthermore, a significantly higher 1RM (129 ± 26 vs. 113 ± 23 kg, p < 0.001, effect size [ES]: 0.63), number of repetitions (15 ± 3 vs. 13 ± 2, p = 0.013, ES: 0.76), and time under tension (34 ± 10 vs. 29 ± 6 seconds, p = 0.017, ES: 0.59) were found during the set to failure for SS in comparison to the CONT condition. Moreover, there was a significant main effect of time to increase oscillation frequency ( p = 0.001; η 2 = 0.666) and stiffness ( p = 0.002; η 2 = 0.613) from pre- to postset measure. In addition, the main effect of the side ( p = 0.034; η 2 = 0.348) was reported to show higher stiffness on the dominant than on the nondominant side in the CONT condition. The results suggest that an independent 1RM measurement and a correspondingly higher workload are required to take full advantage of the SS device. Moreover, the SS can also be used successfully to increase training volume and the involvement of nondominant limbs during a bench press.

Supply less sensitive ring voltage-controlled oscillator for microwave L-band frequencies

PurposeThe primary aim of this paper is to present a novel design approach for a ring voltage-controlled oscillator (VCO) suitable for L-band applications, whose oscillation frequency is less sensitive to power supply variations. In a few decades, with the advancement of modern wireless communication equipment, there has been an increasing demand for low-power and robust communication systems for longer battery life. A sudden drop in power significantly affects the performance of the VCO. Supply insensitive circuit design is the backbone of uninterrupted VCO performance. Because of their important roles in a variety of applications, VCOs and phase locked loops (PLLs) have been the subject of significant research for decades. For a few decades, the VCO has been one of the major components used to provide a local frequency signal to the PLL.Design/methodology/approachFirst, this paper chose to present recent developments on implemented techniques of ring VCO design for various applications. A complementary metal oxide semiconductor (CMOS)-based supply compensation technique is presented, which aims to reduce the change in oscillation frequency with the supply. The proposed circuit is designed and simulated on Cadence Virtuoso in 0.18 µm CMOS process under 1.8 V power supply. Active differential configuration with a cross-coupled NMOS structure is designed, which eliminates losses and negates supply noise. The proposed VCO is designed for excellent performance in many areas, including the L-band microwave frequency range, supply sensitivity, occupied area, power consumption and phase noise.FindingsThis work provides the complete design aspect of a novel ring VCO design for the L-band frequency range, low phase noise, low occupied area and low power applications. The maximum value of the supply sensitivity for the proposed ring VCO is 1.31, which is achieved by changing the VDD by ±0.5%. A tuning frequency range of 1.47–1.81 GHz is achieved, which falls within the L-band frequency range. This frequency range is achieved by varying the control voltage from 0.0 to 0.8 V, which shows that the proposed ring VCO is also suitable for low voltage regions. The total power consumed by the proposed ring VCO is 14.70 mW, a remarkably low value using this large transistor count. The achievable value of phase noise is −88.76 dBc/Hz @ 1 MHz offset frequency, which is a relatively small value. The performance of the proposed ring VCO is also evaluated by the figure of merit, achieving −163.13 dBc/Hz, which assures the specificity of the proposed design. The process and temperature variation simulations also validate the proposed design. The proposed oscillator occupied an extremely small area of only 0.00019 mm2compared to contemporary designs.Originality/valueThe proposed CMOS-based supply compensation method is a unique design with the size and other parameters of the components used. All the data and results obtained show its originality in comparison with other designs. The obtained results are preserved to the fullest extent.

Active control of combustion oscillation with active disturbance rejection control (ADRC) method

This research aims to develop a novel method for the active control of combustion oscillation based on active disturbance rejection control (ADRC). The effectiveness of parameter tuning and the controller in suppressing combustion oscillation was studied by simulation and experiments. The control performance was verified using a Rijke tube and turbulent premixed swirling flame within a model combustor. For the former, the results show that the first-order ADRC can rapidly mitigate the limit cycle oscillation and maintain the effectiveness of the control when the oscillation frequency changes. For the latter, a system identification method based on an acoustic network was adopted. Combining the identification results with a thermoacoustic network, the formation process of the limit cycle oscillation and the effectiveness of the first-order ADRC were simulated by SIMULINK. The experimental results show that the first-order ADRC performs better than the proportional–integral–derivative (PID) controller. At the same time, the first-order ADRC and second-order ADRC achieve good outcomes when the equivalence ratio changes. However, the second-order ADRC exhibits a better pressure-suppression effect and smaller controller output voltage.

Thermally compensated inductive deformation sensor – Mathematical background and practical implementation

The article presents theoretical background and experimental verification of thermal compensation method of inductive displacement sensor. This sensor has the form of single-layer, coreless coil which is the inductance of a resonant LC circuit. Change of coil length causes change in oscillation frequency of Colpitts oscillator.Influence of the sensor temperature on the circuit oscillation frequency was significantly reduced. This was achieved by using the dependence of the sensor resistance on its temperature in a specially modified resonant circuit. The circuit was mathematically modeled. The detectors were made of various metals and their theoretical thermal characteristics were compared with the experimental ones.The sensor has successfully been used for years in rock samples’ deformations measurements during the compressibility test, at hydrostatic pressure up to 400 MPa with temperature changes of several dozen degrees. It replaced resistance strain gauges and LVDT sensors, that were unreliable at high pressures.

Simultaneous Local Capacitance-Voltage Profiling and Deep Level Transient Spectroscopy Using Time-Resolved Scanning Nonlinear Dielectric Microscopy

Abstract Scanning nonlinear dielectric microscopy (SNDM) is a scanning probe technique that measures changes in oscillation frequency between the probe tip and a voltage-biased sample. As the probe moves across the surface of a semiconductor device, the oscillation frequency changes in response to variations in dielectric properties, charge and carrier density, dopant concentration, interface states, or any number of other variables that affect local capacitance. Over the past few years, researchers at Tohoku University have made several improvements in dielectric microscopy, the latest of which is a digital version called time-resolved SNDM (tr-SNDM). Here they describe their new technique and present an application in which it is used to acquire CV, dC/dV-V, and DLTS data from SiO2/SiC interface samples.

Rapid Quantum Squeezing by Jumping the Harmonic Oscillator Frequency.

Quantum sensing and quantum information processing use quantum advantages such as squeezed states that encode a quantity of interest with higher precision and generate quantum correlations to outperform classical methods. In harmonic oscillators, the rate of generating squeezing is set by a quantum speed limit. Therefore, the degree to which a quantum advantage can be used in practice is limited by the time needed to create the state relative to the rate of unavoidable decoherence. Alternatively, a sudden change of harmonic oscillator's frequency projects a ground state into a squeezed state which can circumvent the time constraint. Here, we create squeezed states of atomic motion by sudden changes of the harmonic oscillation frequency of atoms in an optical lattice. Building on this protocol, we demonstrate rapid quantum amplification of a displacement operator that could be used for detecting motion. Our results can speed up quantum gates and enable quantum sensing and quantum information processing in noisy environments.

Regional Differences of Mechanical Properties in a Biceps Brachii Following Eccentric Exercise

PURPOSE: This study aimed to examine the effects of eccentric exercise (ECC) on the indices of mechanical properties together with markers of exercise-induced muscle damage (EIMD) in different sites of the biceps brachii (BB) muscle.METHODS: ECC using an elbow joint was performed in 13 non-trained, college men. Global symptoms of EIMD were identified through changes in muscle soreness and serum creatine kinase (CK) activity, including muscle function following ECC. To evaluate regional EIMD, muscle swelling and tenderness as well as muscular echo intensity were measured at distal (4 cm above the elbow joint) and middle (30% of the distance from the antecubital crease to the acromion) sites within the BB muscle. A handheld myotonometer was used to estimate changes in mechanical properties, that is, oscillation frequency (F), dynamic stiffness (S), and relaxation time (R), of BB muscles after ECC.RESULTS: A significant difference in the major markers of EIMD, such as muscle soreness and serum CK activity, along with parameters of muscle function, was observed after ECC compared to baseline. Although all indirect markers of regional muscle damage demonstrated meaningful differences between before and after ECC, no statistically significant interaction between the distal and middle sites was observed in any of the markers. After ECC, both distal and middle sites showed significant changes in F, S, and R, but no statistical differences in changes in muscle mechanical properties were observed between localized muscle sites within BB muscles.CONCLUSIONS: Changes in mechanical properties, including regional muscle damage, seem to be uniformly influenced by different anatomical locations within the BB muscle, such as elbow flexors, following ECC.

Novel SAW CWA Detector Using Temperature Programmed Desorption

In this article a temperature programmed desorption (TPD) on an uncoated surface acoustic wave (SAW) device has been explored for selectivity studies of chemical warfare agents (CWA). High sensitivity to mass change on SAW device surface was exploited to study desorption patterns in a novel way. CWA Simulants 2-chloroethyl ethyl sulfide (CEES), Methyl Salicylate (MS) and Dimethyl Methyl phosphonate (DMMP) were investigated at different concentrations. SAW device was cooled and exposed to simulant vapours resulting in physical adsorption of gas molecules on device surface and subsequently by ramp heating the device, vapours were desorbed. The change in SAW oscillation frequency, due to desorption, was monitored during the temperature ramping and desorption spectrum was obtained. Desorption spectra were statistically analyzed using Principal Component Analysis (PCA) and our results indicate that all the three compounds investigated produced distinct desorption patterns independent of concentrations. Through this work we aim to develop a reliable methodology for subsequent development of a hand held TDP-SAW detector for field applications.