Changes In Available Energy Research Articles

Energy Status of Stygophilous Amphipod Synurella ambulans as a Promising Biomarker of Environmental Stress in the Hyporheic Zone

The hyporheic zone (HZ) is a sensitive ecotone in river ecosystems because of its biodiversity and susceptibility to human activities. Hyporheic fauna are exposed to multiple stressors that affect the physiology and metabolism of organisms and ultimately ecosystem functioning and biodiversity. This study aimed to quantify adenine nucleotides in the stygophilous freshwater amphipod Synurella ambulans and to evaluate the potential of adenylate energy charge (AEC) as a physiological biomarker of general stress in the HZ of the Sava River at sites with different intensities of environmental and anthropogenic stress. Field studies were conducted seasonally (in December 2018 and April, July, and October 2019) at two sampling sites, one upstream (1-UP) and the other downstream (2-DOWN) of the discharge from the wastewater treatment plant using the standard piston pump. The amphipod population from site 1-UP had significantly higher AEC values than the population from site 2-DOWN in all seasons except summer. Coordinated changes in AEC values with the ATP/ADP ratio indicated differences in energy status between the two populations. However, no changes in the apparent equilibrium constant of adenylate kinase were observed, except in spring at site 1-UP. Multiple linear regression models showed the strongest associations of AEC with Fe and Zn accumulated in amphipods, followed by environmental factors (conductivity, dissolved O2, and concentrations of nitrites and phosphates in the interstitial water). AEC was shown to be a useful index of environmental stress in S. ambulans because it can directly measure the change in available energy and thus the metabolic stress to which the organism is exposed. Finally, seasonal and spatial variations in AEC values reflected ecological status in the HZ.

Assessment of adverse effects of olive mill waste water and olive mill waste contaminated soil on springtail Folsomia candida

In recent years significant attention has been given to the problem of olive mill waste towards the environment. Still, there is a considerable gap in the knowledge of the impact of the olive mill wastewater (OMWW) and the olive mill waste contaminated soil (OMW CS) on non-target soil organisms. Springtails, as an important group of non-target soil organisms, are frequently used in ecotoxicological research. However, information on olive mill waste impact on the model species Folsomia candida is scarce. Therefore, in this study, we determined the effects of OMWW and OMW CS on survival, reproduction, neurotoxicity, oxidative stress, and available energy in springtail F. candida. The exposure to different ratios of OMWW and OMW CS showed higher toxicity of OMW CS in terms of survival (LC50 = 32.34% of OMWW; LC50 = 45.36% of OMW CS) and reproduction (EC50 = 10.10% of OMWW; EC50 = 19.44% of OMW CS). Furthermore, neurotoxicity (AChE induction), oxidative stress (SOD, GST, and MDA induction), and changes in available energy (decrease in lipid and carbohydrate content) have been observed. Those negative effects are likely consequences of the high phenol content specific to OMWW and OMW CS. Obtained results indicate that for the ecotoxicological assessment of various wastes it is essential to consider different tier level biomarkers to have a clear insight into the mechanism of action.

Reduction in human activity can enhance the urban heat island: insights from the COVID-19 lockdown

The COVID-19 lockdowns drastically reduced human activity, emulating a controlled experiment on human–land–atmosphere coupling. Here, using a fusion of satellite and reanalysis products, we examine this coupling through changes in the surface energy budget during the lockdown (1 April to 15 May 2020) in the Indo-Gangetic Basin, one of the world’s most populated and polluted regions. During the lockdown, the reduction (>10%) in columnar air pollution compared to a five year baseline, expected to increase incoming solar radiation, was counteracted by a ∼30% enhancement in cloud cover, causing little change in available energy at the surface. More importantly, the delay in winter crop harvesting during the lockdown increased surface vegetation cover, causing almost half the regional cooling via evapotranspiration. Since this cooling was higher for rural areas, the daytime surface urban heat island (SUHI) intensity increased (by 0.20–0.41 K) during a period of reduced human activity. Our study provides strong observational evidence of the influence of agricultural activity on rural climate in this region and its indirect impact on the SUHI intensity.

The Ability of Soil Pore Network Metrics to Predict Redox Dynamics Is Scale Dependent

Variations in microbial community structure and metabolic efficiency are governed in part by oxygen availability, which is a function of water content, diffusion distance, and oxygen demand; for this reason, the volume, connectivity, and geometry of soil pores may exert primary controls on spatial metabolic diversity in soil. Here, we combine quantitative pore network metrics derived from X-ray computed tomography (XCT) with measurements of electromotive potentials to assess how the metabolic status of soil depends on variations of the overall pore network architecture. Contrasting pore network architectures were generated using a Mollisol—A horizon, and compared to intact control samples from the same soil. Mesocosms from each structural treatment were instrumented with Pt-electrodes to record available energy dynamics during a regimen of varying moisture conditions. We found that volume-based XCT-metrics were more frequently correlated with metrics describing changes in available energy than medial-axis XCT-metrics. An abundance of significant correlations between pore network metrics and available energy parameters was not only a function of pore architecture, but also of the dimensions of the sub-sample chosen for XCT analysis. Pore network metrics had the greatest power to statistically explain changes in available energy in the smallest volumes analyzed. Our work underscores the importance of scale in observations of natural systems.

Performance response of packed-bed thermal storage to cycle duration perturbations

Abstract Packed-bed thermal stores are integral components in numerous bulk electricity storage systems and may also be integrated into renewable generation and process heat systems. In such applications, the store may undergo charging and discharging periods of irregular durations. Previous work has typically concentrated on the initial charging cycles, or on steady-state cyclic operation. Understanding the impact of unpredictable charging periods on the storage behavior is necessary to improve design and operation. In this article, the influence of the cycle duration (or ‘partial-charge’ cycles) on the performance of such thermal stores is investigated. The response to perturbations is explained and provides a framework for understanding the response to realistic load cycles. The packed beds considered here have a rock filler material and air as the heat transfer fluid. The thermodynamic model is based on a modified form of the Schumann equations. Major sources of exergy loss are described, and the various irreversibility generating mechanisms are quantified. It is known that repeated charge-discharge cycles lead to steady-state behavior, which exhibits a trade-off between round-trip efficiency and stored exergy, and the underlying reasons for this are described. The steady state is then perturbed by cycles with a different duration. Short duration perturbations lead to a transient decrease in exergy losses, while longer perturbations increase it. The magnitude of the change in losses is related to the perturbation size and initial cycle period, but changes of 1–10 % are typical. The perturbations also affect the time to return to a steady-state, which may take up to 50 cycles. Segmenting the packed bed into layers reduces the effect of the perturbations, particularly short durations. Operational guidelines are developed, and it is found that packed beds are more resilient to changes in available energy if the store is not suddenly over-charged (i.e. longer perturbations), and if the steady-state cycle duration is relatively long. Furthermore, using the gas exit temperature to control cycle duration reduces the impact of perturbations on the performance, and reduces the time to return to steady-state operation.

Local temperature response to land cover and management change driven by non-radiative processes

Following a land cover and land management change (LCMC), local surface temperature responds to both a change in available energy and a change in the way energy is redistributed by various non-radiative mechanisms. However, the extent to which non-radiative mechanisms contribute to the local direct temperature response for different types of LCMC across the world remains uncertain. Here, we combine extensive records of remote sensing and in situ observation to show that non-radiative mechanisms dominate the local response in most regions for eight of nine common LCMC perturbations. We find that forest cover gains lead to an annual cooling in all regions south of the upper conterminous United States, northern Europe, and Siberia—reinforcing the attractiveness of re-/afforestation as a local mitigation and adaptation measure in these regions. Our results affirm the importance of accounting for non-radiative mechanisms when evaluating local land-based mitigation or adaptation policies. Remote sensing and in situ observations show that non-radiative mechanisms dominate the local climatic response to land cover and land management changes in most regions of the globe for 8 of 9 common land cover and management perturbations.

Towards an Understanding of the Twentieth-Century Cooling Trend in the Southeastern United States: Biogeophysical Impacts of Land-Use Change

Abstract This paper explores the link between the anomalous warming hole in the southeastern United States and a major land-use/land-cover (LULC) change in the region. Land surface and satellite observations were analyzed to estimate the net radiative forcing due to LULC change. Albedo and latent energy were specifically addressed for the dominant LULC change of agriculture to forests. It was assumed that in the energy-limited environment of the region, the partition of changes in available energy due to albedo will mostly impact the sensible heat. The results show that in the southeastern United States, for the period of 1920 to 1992, the changes in sensible (as a result of albedo) and latent energies are in direct competition with each other. In the spring and early summer months, the croplands are in peak production and the latent energy associated with their evapotranspiration (ET) is comparable to that of the forests so the decrease in radiation due to albedo dominates the signal. However, during the late summer and fall months, most major crops have matured, thus reducing their transpiration rate while forests (particularly evergreens) maintain their foliage and with their deep roots are able to continue to transpire as long as atmospheric conditions are favorable. This later influence of latent energy appears to more than offset the increased radiative forcing from the spring and early summer. Overall, a mean annual net radiative forcing resulting from a LULC change from cropland to forests was estimated to be −1.06 W m−2 and thus a probable contribution to the “warming hole” over the Southeast during the majority of the twentieth century.

The adenylate energy charge as a new and useful indicator of capture stress in chondrichthyans.

Quantifying the physiological stress response of chondrichthyans to capture has assisted the development of fishing practices conducive to their survival. However, currently used indicators of stress show significant interspecific and intraspecific variation in species' physiological responses and tolerances to capture. To improve our understanding of chondrichthyan stress physiology and potentially reduce variation when quantifying the stress response, we investigated the use of the adenylate energy charge (AEC); a measure of available metabolic energy. To determine tissues sensitive to metabolic stress, we extracted samples of the brain, heart, liver, white muscle and blood from gummy sharks (Mustelus antarcticus) immediately following gillnet capture and after 3 h recovery under laboratory conditions. Capture caused significant declines in liver, white muscle and blood AEC, whereas no decline was detected in the heart and brain AEC. Following 3 h of recovery from capture, the AEC of the liver and blood returned to "unstressed" levels (control values) whereas white muscle AEC was not significantly different to that immediately after capture. Our results show that the liver is most sensitive to metabolic stress and white muscle offers a practical method to sample animals non-lethally for determination of the AEC. The AEC is a highly informative indicator of stress and unlike current indicators, it can directly measure the change in available energy and thus the metabolic stress experienced by a given tissue. Cellular metabolism is highly conserved across organisms and, therefore, we think the AEC can also provide a standardised form of measuring capture stress in many chondrichthyan species.

Climate‐forced changes in available energy and methane bubbling from subarctic lakes

AbstractStrong correlations between seasonal energy input and methane (CH4) bubbling (ebullition) in northern lakes suggest that energy proxies might provide a constraint on the magnitude of future CH4 emissions. Ebullition is a major pathway for transporting anaerobically produced CH4 from lake sediments to the atmosphere and represents a large unquantified CH4 source. In high‐latitude, postglacial lakes during the ice‐free season, solar shortwave energy input can constrain CH4 productivity via control of sediment temperature. Utilizing long‐term climatic predictors, we calculate CH4 ebullition from three subarctic lakes in northern Sweden over the period of 1916–2079. Using observed energy trends, the seasonal average lake CH4 ebullition is predicted to increase by 80% between the 1916–1926 decade and the 2040–2079 period. Present‐day seasonal average methane ebullition is estimated to have already increased 24% since the 1916–1926 decade.

Little change in global drought over the past 60 years

Drought is expected to increase in frequency and severity in the future as a result of climate change, mainly as a consequence of decreases in regional precipitation but also because of increasing evaporation driven by global warming. Previous assessments of historic changes in drought over the late twentieth and early twenty-first centuries indicate that this may already be happening globally. In particular, calculations of the Palmer Drought Severity Index (PDSI) show a decrease in moisture globally since the 1970s with a commensurate increase in the area in drought that is attributed, in part, to global warming. The simplicity of the PDSI, which is calculated from a simple water-balance model forced by monthly precipitation and temperature data, makes it an attractive tool in large-scale drought assessments, but may give biased results in the context of climate change. Here we show that the previously reported increase in global drought is overestimated because the PDSI uses a simplified model of potential evaporation that responds only to changes in temperature and thus responds incorrectly to global warming in recent decades. More realistic calculations, based on the underlying physical principles that take into account changes in available energy, humidity and wind speed, suggest that there has been little change in drought over the past 60 years. The results have implications for how we interpret the impact of global warming on the hydrological cycle and its extremes, and may help to explain why palaeoclimate drought reconstructions based on tree-ring data diverge from the PDSI-based drought record in recent years.

A combined numerical and semi-analytical collision damage assessment procedure

Ship collisions are increasingly simulated with numerical methods predicting the structural damage, respectively the ships' safety, in such accidental event. The latest analyses techniques can take the non-linear structural behaviour and the motions of the colliding vessels into account, however using time-consuming numerical models. Hence, a single dynamic collision can be analysed with a fair degree of accuracy, but at high computational cost. Therefore, this article presents a combined numerical and analytical procedure to assess ship collision damage with significantly lower computational cost. Numerical quasi-static collision simulations estimate the non-linear structural behaviour for a given vessel colliding at selected vertical locations. This provides the force versus penetration curves, which thus depends on the structural arrangement at the striking location. Hence, the semi-analytical collision analysis is calibrated based on these structural resistance curves in order to estimate the change in available energy for structural deformation considering different longitudinal striking locations and angles. As a result, the collision damage, respectively penetration depth and length, can be estimated for vessels of different dimensions and mass ratio's subjected to various collision situations if the presented procedure is applied.

Sediment response to catchment disturbances

1 IntroductionThe surface of the planet undergoes a constant battle forbalance between uplift and erosion. Plate tectonics causeland to be created and mountains to be born, whileweathering and erosion act to lower the land surface. Riverstransport the products of weathering and erosion to storagepoints, or sinks; the ultimate sink being the deep oceans. Fora given landscape, an equilibrium is reached whereby therates of sediment distribution between sources and sinks arefairly constant. In the case of a river channel, the amount ofwater and sediment moved through a landscape is balancedby the energy available to do this, such that a change ineither of the two generates adjustments in stream power. Achange in environmental conditions often results in aresponse, the magnitude of which is a function of the typeand intensity of “disturbance” to the system. In the case ofthe river channel, this might manifest itself in the form ofchannel aggradation or degradation, whereby sediments areeither deposited or eroded in response to changes in availableenergy or sediment supply.Changestoalandscapearebothnaturalandanthropogenic.In terms of landscapes, we tend to think of a “disturbance”eventasonethatisfairlyextremeandproducesameasureableresponse in the rate or type of processes occurring in thelandscape. Examples of natural disturbances include earth-quakes, volcanic activities and wildfires. Examples ofanthropogenic disturbances include deforestation, intensiveagriculture, urbanization, dam construction and gravel min-ing. Typically, in natural systems, the types of geomorphicresponses to these events include increased rates of sedimentmobilization (i.e., soil erosion, mass movements), transport(i.e., delivery to and within river channel systems) anddeposition (i.e., in floodplains, lakes, estuaries). A goodexample is the 1980 eruption of Mount St Helens volcano,USA, where annual suspended sediment yields after theeruption were as much as 500 times greater than typicalbackground levels. Even 20 years after the eruption, averagesuspendedsedimentyieldsfromthedebris-avalanchedepositsremained 100 times (10

The growing Canadian energy gap: more the can than the couch?

The present study describes the trajectory of the energy gap (energy imbalance) in the Canadian population from 1976 to 2003, its temporal relationship to adult obesity, and estimates the relative contribution of energy availability and expenditure to the energy gap. It also assesses which foods contributed the most to changes in available energy over the study period. Annual estimates of the energy gap were derived by subtracting population-adjusted per capita daily estimated energy requirements (derived from Dietary Reference Intakes) from per capita daily estimated energy available (obtained from food balance sheets). Food balance sheets were used to assess which foods contributed to changes in energy availability. Adult obesity rates were derived from six national surveys. The relationship to the energy gap was assessed through regression analysis. Between 1976 and 2003, per capita daily estimated energy availability increased by 18 % (1744 kJ), and increased energy availability was the major driver of the increased energy gap. Salad oils, wheat flour, soft drinks and shortening accounted for the majority of the net increase in energy availability. Adult obesity was significantly correlated with the energy gap over the study period. The widening energy gap is being driven primarily by increased energy availability. The food commodities driving the widening energy gap are major ingredients in many energy-dense convenience foods, which are being consumed with increasing frequency in Canada. Policies to address population obesity must have a strong nutritional focus with the objective of decreasing energy consumption at the population level.

Maximizing Energy at Coalface for Coalbed-Methane Fracturing

This article, written by Assistant Technology Editor Karen Bybee, contains highlights of paper SPE 114974, "Maximizing Energy at Coalface for Coalbed-Methane- Fracturing Operations," by Abbas Mahdi, SPE, Schlumberger; Mike Yu, SPE, EnCana; Doug Pipchuk, SPE, Craig Wasson, SPE, Jim Nguy, SPE, and Nathan Kathol, Schlumberger, originally prepared for the 2008 CIPC/ SPE Gas Technology Symposium Joint Conference, Calgary, 16–19 June. The paper has not been peer reviewed. Nitrogen coiled-tubing (CT) fracturing is the predominant method for completing and stimulating dry-coalbed-methane (CBM) formations, such as the Horseshoe Canyon in the west-ern Canadian sedimentary basin. Currently, energy that can be delivered to the coalface of these dry-CBM wells has been limited by the frictional pressure loss through CT. The full-length paper discusses the development of a technique that releases a large-volume pressure pulse downhole during the fracturing process to create an order-of-magnitude change in available energy at the fracture face. Introduction The Horseshoe Canyon dry-coal formations have been exploited commercially since late 2000. The Horseshoe Canyon CBM play is a unique CBM play, in that it consists of a dry underpressured coal, which does not require dewatering before production. The coal consists of multiple thin seams, ranging from 10 to 30 seams per well, that are treated individually. Coal-seam thick-ness ranges from 0.1 to 2.5 m. The production rates from these CBM wells dictate that an efficient drilling and completion model be adopted to be economic. The wells are drilled with CT drilling rigs, cased, and cemented. Wireline perforating crews perforate the zones of interest in a rigless operation. The individual coal seams then are stimulated by injection of dry nitrogen at high rates through a CT reel equipped with a fracturing isolation tool. The dry coal has not responded well to any other form of stimulation. To optimize the completion process, high-rate nitrogen-pumping units were developed to reduce the footprint and cost and to increase efficiency of the operation to the point where one and a half to two wells can be stimulated per day. Since the introduction of that change, various optimization initiatives have been attempted. The optimization of nitrogen-pumping rates and pumped volumes has been the focus of these attempts. High rates have been limited by the inside diameter of the CT string. Several CT sizes have been used for this application. Economics and logistics have limited the CT size for CT fracturing to 2 7/8 in. for deeper wells and 3 1/4 in. for shallow wells. The migration to bigger pipe did pro-vide some reduction in frictional pressure loss, but effective pressure at the coalface still was not transported from the surface efficiently.

Efficiencies of thermodynamic processes

When a system is in a state which differs from that of the infinite atmosphere surrounding it, its capacity to do work is measured by the maximum work which the system is capable of producing as it interacts with the infinite sink and eventually reaches the same state as the sink. When the system is subjected to a process there is, in general, a work interaction between the system and the surroundings, together with an exchange of heat with a source or with a sink other than the infinite sink. Here the actual change in available energy is compared with the ideal change in available energy. An efficiency for the process is defined, which will reflect all the losses or irreversibilities in the process. Hitherto, the definition of efficiency for any process from a purely thermodynamic viewpoint has been hampered by using different fundamental relationships in flow and nonflow processes, and for the flow process analysis it has been restricted to adiabatics in which the well-known parameter called `effectiveness' is used as a criterion of efficiency. In the analysis given here the same basic relationships are used independent of the circumstances in which the process takes place. This has been achieved by introducing the concept of `high-grade' energy.

Biochemistry of hyperthyroidism and hypothyroidism.

Summary The thyroid hormones act directly on mitochondria, and thereby control the transformation of the energy derived from oxidations into a form utilizable by the cell. Through their direct actions on mitochondria, the hormones also control indirectly the rate of protein synthesis and thereby the amount of oxidative apparatus in the cell. A rationale for the effects of thyroid hormone excess or deficiency is based upon studies of the mechanism of thyroid hormone action. In hypothyroidism, slow fuel consumption leads to a low output of utilizable energy. In hyperthyroidism, rapid fuel consumption leads to a high energy output, but as efficiency decreases, the utilizable energy produced decreases. Many of the chemical and physical features of these diseases can be reduced to changes in available energy.