Changes In Ozone Concentrations Research Articles

Deciphering multi-temporal scale dynamics in the concentration, sources and processes of near surface ozone over different climatic regions of India.

This study aims to investigate the factors influencing seasonal and long-term (2003-2021) changes in the near surface ozone (850 hpa) concentrations over different climatic sub-regions of India. Detailed comparison of daily (2019-2021) near surface ozone values of ERA-5 and CAAQMS (Continuous Ambient Air Quality Monitoring Stations) ground-based measurements revealed that ERA-5 is temporally in phase with CAAQMS measurements falling indifferent climatic sub-regions of India. ERA-5 near surface ozone shows statistically significant long-term (2003-2021) positive trends [2-4 percent per decade (ppd)] over most of the climatic sub-regions, over Indo-Gangetic Planes (IGPs), Southern and Central India trends are particularly strong. Trends were also estimated for each season separately, which were largely positive (2-6 ppd) over Central and Southern India in the Autumn and Winter seasons. Extensive climatological analysis reveals that the reversal of winds in the Indian monsoonal system plays a vital role in such trend patterns across the Indian subcontinent. South-westerly winds from June through September presumably bring ozone deficit air of marine origin, thus causing a dilution effect while the North-easterly winds during late Autumn and early Winters plausibly bring ozone-rich air from the stratospheric-tropospheric efflux dominated Himalayan region. It allows near surface ozone enhancement over Central and Southern India. Seasonal Principal component analysis (PCA) revealed that precursor gases (CH4 and NO2) and climatic variables especially specific humidity (SH) are the primary drivers of near surface ozone variability in the Winter season, while in Spring, climatic variables like boundary layer height (BLH), temperature (T) and SH have a significant role. Principal component regression (PCR) reveals a long-term increase in near surface ozone levels mostly dominated by precursor concentration over IGPs and Southern sub-regions. Whereas, BLH, T and SH significantly explain near surface ozone trends over North-eastern and Coastal India.

Benefits of air quality for human health resulting from climate change mitigation through dietary change and food loss prevention policy

AbstractFood production, particularly cattle husbandry, contributes significantly to air pollution and its associated health hazards. However, making changes in dietary habits, such as reducing red meat consumption and minimizing food waste, can lead to substantial improvements in both air quality and human health. In this study, we explored the impact of dietary changes on future air quality and human wellbeing. We also assessed the influence of dietary transformation policies in the context of climate change mitigation, with the objective of understanding how policies can effectively complement each other. We used a chemical transport model and an integrated assessment model to determine changes in fine particulate matter (PM2.5) and ozone (O3) concentrations. Then, an exposure model was applied to estimate premature deaths as a consequence of air pollution. Our results showed that dietary changes could play a crucial role in mitigating air pollution, particularly in regions where agricultural activities emit significant quantities of ammonia. In the European Union, for example, dietary changes could lead to a reduction of 5.34% in PM2.5 by 2050. Similarly, in Asia, the models projected a reduction of 6.23% in PM2.5 by 2100. Ground surface O3 levels in Southeast Asia were projected to drop by as much as 12.93% by 2100. Our results further showed that dietary changes could lead to significant reductions in global mortality associated with PM2.5 and O3, with 187,500 and 131,110 avoided deaths per year expected by 2100. A combined approach that integrates dietary changes with climate change mitigation measures could lead to more comprehensive air quality improvements in specific regions. However, careful consideration is needed to address any potential adverse effects on O3 concentrations in some areas.

ТЕОРЕТИЧЕСКИЕ АСПЕКТЫ ВЗАИМОДЕЙСТВИЯ ОЗОНА С ЗЕРНОМ

Despite the popularization of ozone technologies in agriculture, the theoretical aspects of the interaction of an ozone-air mixture with grain material remain under study. The simplified assumption that the change in the amount of ozone absorbed by the grain is proportional to the initial gas concentration does not accurately describe this process. Attempts to analytically determine a certain constant of the rate of ozone absorption by a unit of grain volume were also unsuccessful. The resulting expression was transcendental at that time. Its solution was possible only when performing repetitive calculations, that is, using the iteration method on a personal computer. The use of the modern Matlab application software package made it possible to establish a constant rate of ozone absorption per unit grain volume. However, the experiments have shown that during the experiment this constant changes significantly, including depending on the conditions, therefore this theoretical approach requires clarification. The laws known in physics describing the diffusion process have been adapted to the ozone treatment process. The application of the Langmuir-Schaefer equation for the number of ozone molecules adsorbed on the grain surface and Fick's second law made it possible to determine the rate of ozone diffusion and the change in ozone concentration over time, taking into account the characteristics of the grain pile. A dependence was obtained for the ozone diffusion coefficient, which characterizes the ability of grains to absorb ozone through cell membranes, and the ozone decomposition constants. Under normal storage conditions, these temperature-dependent values can be considered constant. The analytically obtained dependences will allow us to determine the ozone diffusion coefficient and the ozone decomposition constant experimentally.

Contrasting changes in ozone during 2019–2021 between eastern and the other regions of China attributed to anthropogenic emissions and meteorological conditions

Ozone pollution is one of the most severe air quality issues in China that poses a serious threat to human health and ecosystems. During 2019–2021, the maximum daily 8-h average ozone concentrations in eastern China (110–122.5°E, 26–42°N) and the rest of China (ROC) show different decreasing patterns, with ozone concentrations in eastern China decreasing by 14.9 μg/m3, which is much larger than 4.8 μg/m3 in ROC. Here, based on two independent methods, the atmospheric chemical transport model (GEOS-Chem) simulations and the machine learning (ML) model (LightGBM) predictions, the reasons for the differences in ozone changes between eastern China and ROC during the warm season (April to September) are investigated. According to the GEOS-Chem (LightGBM) results, changes in the meteorological conditions contributed to an ozone decrease by 7.3 (6.8) μg/m3 in eastern China due to decreased chemical production and an ozone decrease by 6.8 (7.0) μg/m3 in ROC attributed to the weakened horizontal and vertical advection. With the influence of meteorological factors excluded, the observations show that changes in anthropogenic emissions resulted in an ozone decrease by 7.6 (8.1) μg/m3 in eastern China and an ozone increase by 2.0 (2.2) μg/m3 in ROC, which is primarily induced by the changes in NOx emissions. The surface measurements and satellite retrievals also indicate that the reduction in NOx emissions in ROC is less efficient than that in the more developed eastern China, leading to contrasting changes in ozone concentrations between eastern China and ROC during 2019–2021. Our results highlight the critical need to reduce ozone precursor emissions in the rest regions of China apart from eastern China.

Synergistic degradation levofloxacin through dielectric barrier discharge and sodium persulfate

The release of antibiotics that are difficult to degrade by themselves into the environment have received increasing attention because they have posed great threat to natural ecosystem and human health. Sodium persulfate (PS) is used to treat organic wastewater because of its strong oxidation, but it needs to be activated. Dielectric barrier discharge (DBD) can product stable gas discharge plasma that is suitable for activating PS. The synergistic degradation process of levofloxacin (LFX) by air DBD plasma with PS were investigated. The effects on the degradation ratio and energy efficiency of LFX were studied, including input power, air flow rate, original concentration, discharge spacing, and PS dosage. The degradation kinetics and synergistic factors were calculated under different PS additions. After plasma alone treatment 45 min, the maximum degradation ratio of LFX was 58.74 % and 88.63 % via plasma alone and plasma synergistic with PS under 15 W input power and 50 mg·L−1 LFX original concentration. The energy efficiency, the first-order reaction rate constant and the synergistic factor SI was 0.1532 g·(kW·h)−1, 4.116 × 10−2 min−1 and 1.64, respectively. The change of ozone concentration in the reaction system after adding PS was measured. The effects on the synergistic degradation of LFX of two radical scavengers, methanol (MeOH), and tert-butanol (TBA), were investigated. After calculation, the contribution ratios of ·OH and SO4-· were 48.08 % and 26.97 %, respectively. The intermediate products were analyzed by LC-MS in the decomposition process of LFX, and the probable decomposition pathway of LFX was presented.

친환경 자동차 도입에 따른 지역별 오존 농도 변화 특성 분석

친환경 자동차 도입에 따른 지역별 오존 농도 변화 특성 분석

An Outlier Detection Study of Ozone in Kolkata India by the Classical Statistics, Statistical Process Control and Functional Data Analysis

Air pollution is prevalent throughout the entire world due to the release of various gases such as NOx, PM, SO2, tropospheric ozone (O3), etc. Ground-stage ozone is the predominant issue in smog and is the product of the interplay between sunlight and emissions. The destructive impact on the health of the populace might also still occur in cities with noticeably clean air and where ozone levels hardly ever exceed safe limits. Therefore, the findings of small variations in air quality and the technique of regulating air contamination are thought-provoking. The study employs various techniques to effectively observe and assess strategies for detecting and eliminating outliers in ozone emissions from pollution episodes. This technique helps to describe the sources and exceedance values and enhance the value of monitoring the data. In this study, the data have some missing observations. The method of imputation, the classical statistical technique, the statistical process control (SPC) technique, functional data analysis (FDA), and functional process control help to fill in the data and detect outliers, trend deviations, and changes in ozone concentration at ground level. A comparison study is carried out using these three techniques: classical analysis, SPC, and FDA, and the results show how the statistical process control and functional data methods performed better than the classical technique for the detection of outliers and also in what way this methodology can enable an additional, comprehensive method of defining air pollution control measures and water pollution control measures.

Changes in Stratosphere‐Troposphere Exchange of Air Mass and Ozone Concentration in CCMI Models From 1960 to 2099

AbstractThis study investigates changes in stratosphere‐troposphere exchange (STE) of air masses and ozone concentrations from 1960 to 2099 using multiple model simulations from Chemistry Climate Model Initiative (CCMI) under climate change scenario RCP6.0. We employ a lowermost stratosphere mass budget approach with dynamic isentropic surfaces fitted to the tropical tropopause as the upper boundary of lowermost stratosphere. The multi‐model mean (MMM) trends of air mass STEs are all small over all regions, which are within 0.3 (0.1) % decade−1 for 1960–2000 (2000–2099). The MMM trends of ozone STE for 1960–2000 are 0.3%, −2.7%, 3.4%, −0.9%, and −2.7% decade−1 over the Northern hemisphere (NH) extratropics, Southern hemisphere (SH) extratropics, tropics, extratropics, and globe, respectively. The corresponding ozone STE trends for 2000–2099 are 3.0%, 4.3%, 0.8%, 3.5%, and 4.7% decade−1. Changes in ozone STEs are dominated by ozone concentration changes, driven by climate‐induced changes and ozone‐depleting substance (ODS) changes. For 1960–2000, small changes in ozone STEs in the NH extratropics are due to a cancellation between effects of climate‐induced changes and ODS increases, while the ODS effect dominates in the SH extratropics, leading to a large ozone STE magnitude decrease. Increased ozone transport from tropical troposphere to stratosphere for 1960–2000 is due to increased tropospheric ozone. A decreased global ozone STE magnitude for 1960–2000 was largely caused by ODS‐induced ozone loss that is partly compensated by climate‐induced ozone changes. For 2000–2099, about two‐thirds of global ozone STE magnitude increases are caused by ozone increases in the extratropical lower stratosphere due to climate‐induced changes. The remaining one‐third is caused by ozone recovery due to the phaseout of ODS.

Impact of Atmospheric Circulation Patterns on Ozone Changes in the Pearl River Delta from 2015 to 2020

Based on the ozone observation data and meteorological reanalysis data of the Pearl River Delta (PRD) from 2015 to 2020, the Lamb-Jenkinson weather typing method (LWTs) was used to analyze the characteristics of different circulation types and quantify their contributions to the interannual ozone variation. The results showed that there was a total of 18 weather types in PRD. Type ASW was more likely to occur with ozone pollution, and Type NE was associated with more serious ozone pollution. To better explore the ozone generation mechanism under different weather types, the 18 weather types were merged into five weather categories based on the wind direction change of the 850 hPa wind field and the different positions of the central system. The weather categories with high ozone concentration were the N-E-S directional category[(161±68) μg·m-3] and category A[(122±39) μg·m-3]. The ozone concentrations of these two categories were significantly positively correlated with the daily maximum temperature and the net amount of solar radiation. The N-E-S directional category was the dominant circulation pattern in autumn, whereas category A mostly occurred in spring, and 90% of the ozone pollution events occurring in PRD in spring were related to category A. The contribution of changes in atmospheric circulation frequency and intensity to interannual change in ozone concentration in PRD was 69%, and the contribution of changes in atmospheric circulation frequency alone was 4%. The changes in atmospheric circulation intensity and frequency on ozone-exceeding days contributed comparably to the interannual fluctuations in ozone pollution concentrations.

Potential Impacts on Ozone and Climate From a Proposed Fleet of Supersonic Aircraft

AbstractThere has been renewed interest in developing commercial supersonic transport aircraft due to the increased overall demands by the public for air travel, the aspiration for more intercontinental travel, and the desire for shorter flight times. Various companies and academic institutions have been actively considering the designs of such supersonic aircraft. As these new designs are developed, the environmental impact on ozone and climate of these fleets need to be explored. This study examines one such proposed commercial supersonic fleet of 55‐seater that is projected to fly at Mach 2.2, corresponding to cruise altitudes of 17–20 km, and which would burn 122.32 Tg of fuel and emit 1.78 Tg of NOx each year. Our analyses indicate this proposed fleet would cause a 0.74% reduction in global column ozone (∼2 Dobson Units), which is mainly attributed to the large amounts of nitrogen oxides released in the atmosphere from the supersonic aircraft. The maximum ozone loss occurs at the tropics in the fall season, with a reduction of −1.4% in the total column ozone regionally. The stratospheric‐adjusted radiative forcing on climate from this fleet was derived based on changes in atmospheric concentrations of ozone (59.5 mW/m2), water vapor (10.1 mW/m2), black carbon (−3.9 mW/m2) and sulfate aerosols (−20.3 mW/m2), resulting in a net non‐CO2, non‐contrail forcing of 45.4 mW/m2, indicating an overall warming effect.

Trends and variability of total column ozone in the Third Pole

The Hindu Kush Himalaya and Tien Shan Mountain regions together are called the Third Pole (TP) of Earth, which encompasses ecologically fragile regions of 12 Asian countries. It is the highest mountain chain with the largest reserve of fresh ice mass on the planet outside the northern and southern polar regions. The TP region is experiencing high rate of glacier melting due to climate change for the past few decades, and is a great concern for water security of South Asia. Since changes in ozone concentrations in the atmosphere affect public health, ecosystem dynamics and climate, it is imperative to monitor its temporal evolution in an ecologically sensitive region such as TP. Here, the spatiotemporal characteristics of total column ozone (TCO) in TP and 20 selected cities in and around TP are investigated using a combined long-term data made from the satellite measurements of Ozone Monitoring Instrument (OMI) and Global Ozone Monitoring Experiment (GOME)-2B for the period 2005–2020. The spatial trends in TCO over TP are mostly negative in summer and autumn (from −0.2 DU/yr to −0.6 DU/yr), but positive in winter (up to +0.2 DU/yr). Among the selected 20 urban regions, the highest annual trend −0.42 ± 0.3 DU/yr and the lowest −0.01 ± 0.2 DU/yr are estimated in Xining and Chittagong, respectively. Analysis using a multiple regression model reveals that the ozone variability in TP is mostly driven by tropopause height with a contribution of 24.92%, Quasi-Biennial Oscillation (23.42%), aerosols (16.12%) and solar flux (15.34%). Our study suggests that the observed negative trend is mainly associated with human activities and climate change in TP, which would likely to enhance the surface temperature and thus, melting of glaciers in the region.

Assessing the contribution of open crop straw burning to ground-level ozone and associated health impacts in China and the effectiveness of straw burning bans

In recent years, ozone pollution in China has been shown to increase in frequency and persistence despite the concentrations of fine particulate matter (PM2.5) decreasing steadily. Open crop straw burning (OCSB) activities are extensive in China and emit large amounts of trace gases during a short period that could lead to elevated ozone concentrations. This study addresses the impacts of OCSB emissions on ground-level ozone concentration and the associated health impact in China. Total VOCs and NOx emissions from OCSB in 2018 were 798.8 Gg and 80.6 Gg, respectively, with high emissions in Northeast China (31.7%) and North China (23.7%). Based on simulations conducted for 2018, OCSB emissions are estimated to contribute up to 0.95 µg/m3 increase in annual averaged maximum daily 8-hour (MDA8) ozone and up to 1.35 µg/m3 for the ozone season average. The significant impact of OCSB emissions on ozone is mainly characterized by localized and episodic (e.g., daily) changes in ozone concentration, up to 20 µg/m3 in North China and Yangtze River Delta region and even more in Northeast China during the burning season. With the implementation of straw burning bans, VOCs and NOx emissions from OCSB dropped substantially by 46.9%, particularly over YRD (76%) and North China (60%). Consequently, reduced OCSB emissions result in an overall decrease in annual averaged MDA8 ozone, and reductions in monthly MDA8 ozone could be over 10 µg/m3 in North China. The number of avoided premature death due to reduced OCSB emissions (considering both PM2.5 and ozone) is estimated to be 6120 (95% Confidence Interval: 5320–6800), with most health benefits gained over east and central China. Our results illustrate the effectiveness of straw burning bans in reducing ozone concentrations at annual and national scales and the substantial ozone impacts from OCSB events at localized and episodic scales.

Evaluation of isoprene light response curves for bryophyte-dominated ecosystems and implications for atmospheric composition

Isoprene is emitted from numerous plant species in response to light and temperature and parameterisations of these relationships, based on observations from a few vascular plant species, have been shown to be broadly applicable to many different vegetation types. Here, we investigate their performance when applied to an ecosystem dominated by bryophytes. Over a six-week period, emissions of isoprene were measured above a Scottish peat bog. The light response derived on the basis of both canopy-scale flux and whole-plant enclosure measurements, deviated from the classical response, showing no sign of saturation within the observed range. We attribute this response to the canopy architecture of moss hummocks, which may attenuate light differently compared to a grass canopy. Both existing big-leaf and canopy-level emission algorithms, developed for vascular plants but commonly used for moorland vegetation, failed to replicate the observed fluxes, overestimating at low light intensities (<1000 μmol m−2 s−1 photosynthetically active radiation) and underestimating during daytime clear sky conditions. The light response was optimised for bryophyte-dominated ecosystems using measured fluxes and incorporated into the EMEP4UK chemical transport model and applied exclusively to moorland. The revised parameterisation resulted in a small reduction in the average annual isoprene emissions in the northern latitudes (5%), but peak isoprene emissions and concentrations increased by up to a factor of two. Yet, no significant change in average or maximum surface ozone concentrations was observed, reflecting that the northern latitudes are in a chemical regime that is strongly NOx limited, in part due to the spatial segregation with the urban sources of NO x . We conclude that, the anticipated increase in isoprene emissions from the northern latitudes in response to climate change is unlikely to contribute towards ozone-related air quality issues, as long as NO x pollution does not increase. However, the non-saturating light response may be equally applicable to non-vascular plants elsewhere, including in the tropics.

Impact of Climate Change on Indoor Air Quality: A Review

Climate change can affect the indoor environment due to heat and mass transfers between indoor and outdoor environments. To mitigate climate change impacts and adapt buildings to the changing environment, changes in building characteristics and occupants' behavior may occur. To characterize the effects of climate change on indoor air quality (IAQ), the present review focused on four aspects: (1) experimental and modeling studies that relate IAQ to future environmental conditions, (2) evolution of indoor and outdoor air concentrations in the coming years with regard to temperature rise, (3) climate change mitigation and adaptation actions in the building sector, and (4) evolution of human behavior in the context of climate change. In the indoor environment, experimental and modeling studies on indoor air pollutants highlighted a combined effect of temperature and relative humidity on pollutant emissions from indoor sources. Five IAQ models developed for future climate data were identified in the literature. In the outdoor environment, the increasing ambient temperature may lead directly or indirectly to changes in ozone, particle, nitrogen oxides, and volatile organic compound concentrations in some regions of the world depending on the assumptions made about temperature evolution, anthropogenic emissions, and regional regulation. Infiltration into buildings of outdoor air pollutants is governed by many factors, including temperature difference between indoors and outdoors, and might increase in the years to come during summer and decrease during other seasons. On the other hand, building codes in some countries require a higher airtightness for new and retrofitted buildings. The building adaptation actions include the reinforcement of insulation, implementation of new materials and smart building technologies, and a more systematic and possibly longer use of air conditioning systems in summer compared to nowadays. Moreover, warmer winters, springs, and autumns may induce an increasing duration of open windows in these seasons, while the use of air conditioning in summer may reduce the duration of open windows.

Potential effects of surface ozone on forests in Gangwon Province, South Korea, based on critical thresholds

High hourly concentrations of ozone, a secondary pollutant produced from the photochemical reactions of primary precursors, have been increasing in South Korea, bringing potential adverse effects on vegetation. Deforestation caused by high ozone concentrations has been investigated in China and Japan. Using ozone measurements from East and West, Gangwon Province, South Korea, from 2001 to 2018, this study compared changes in surface ozone concentrations and analyzed the influences of meteorological factors and air pollutants. This study calculated accumulated ozone exposure over a threshold of 40 ppb (AOT40) and investigated the possibility of ozone affecting deforestation. Monthly average surface ozone concentrations increased rapidly in both regions from 2009. Although the daily total insolation (a meteorological factor that significantly impacts photochemical reactions) of West Gangwon and East Gangwon did not differ significantly, the ozone concentration was lower in East Gangwon than in West Gangwon (1.5 times lower from 2001 to 2018) owing to local strong winds. Moreover, there was a negative correlation between nitrogen dioxide and ozone generation. AOT40 in West Gangwon was about twice that in East Gangwon and exceeded 10,000 ppbh, the critical level for forests, every year since 2003. Potential damage from high concentrations of ozone was higher in West Gangwon than in East Gangwon.

Isolating the modulation of mean warming and higher-order temperature changes on ozone in a changing climate over the contiguous United States

Surface ozone is substantially affected by climate change through the modulation of key meteorological parameters such as temperature. While the changes in temperature under a warming climate manifest in changes of both the mean and higher-order statistical moments, their individual role in ozone concentration changes has not been broadly investigated. To address this gap, we use a novel approach to isolate the impacts of mean warming and changes in higher-order moments of temperature on ozone over the southeastern U.S. (SEUS) and western U.S. (WUS) by the mid-21st century based on simulations under Technology Driver Model A1B and B2 scenarios from a regional modeling framework (Weather Research and Forecasting model coupled with Chemistry (WRF/Chem)). Mean warming generally dominates the impacts of climate change on ozone, and higher-order moment temperature changes can also counteract 25% of the ozone exceedance of 70 ppbv over SEUS, and may offset 48% of the mean warming induced increase of ozone exceedance in heat waves during 2046–2055 under A1B. The opposite changes in the higher-order moments over SEUS and WUS lead to opposite impacts on ozone exceedance in the two regions. Our results suggest that improving prediction of both the mean and higher-order temperature changes may be crucial to constraining the future changes in ozone concentration to better inform air quality policy.

Modeling Ground Ozone Concentration Changes after Variations in Precursor Emissions and Assessing Their Benefits in the Kanto Region of Japan

Ozone (O3) is a pollutant of concern in urban areas because of its effects on health, crops, ecosystems, and materials. Despite efforts to meet the Japanese air quality standard for O3 in the Kanto region, the attainment percentage is close to zero. Considering that O3 formation is sensitive to emissions of volatile organic compounds (VOC) and nitrogen oxides (NOx), this study evaluated a range of reductions in the emissions of both precursors using a regional air quality model (ADMER-PRO) and estimated their benefits measured as the economic change due to O3 concentration differences between scenarios. The simulation period was set during the 2016 O3 season. The results showed that O3 concentrations could be reduced using two approaches: significant reduction in VOC levels combined with minor NOx level changes or significant NOx emission reduction. Significant reduction in NOx levels was the most effective strategy for a generalized decrease in the O3 levels in the Kanto region, and the benefit analysis revealed that the most significant economic impacts could be achieved by adopting the latter approach.

Australian Bushfires (2019–2020): Aerosol Optical Properties and Radiative Forcing

In the present study, we present the aerosol optical properties and radiative forcing (RF) of the tropospheric and stratospheric smoke layers, observed by the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) satellite, during the extraordinary Australian biomass burning (BB) event in 2019–2020. These BB layers were studied and analyzed within the longitude range 140° E–20° W and the latitude band 20°–60° S, as they were gradually transported from the Australian banks to the South American continent. These layers were found to be trapped within the Andes circulation, staying for longer time periods in the same longitude region. The BB aerosols reached altitudes even up to 22 km amsl., and regarding their optical properties, they were found to be nearly spherical (particle linear depolarization ratio (PLDR) &lt; 0.10) in the troposphere; while, in the stratosphere, they were more depolarizing with PLDR values reaching up to 0.20. Fine and ultrafine smoke particles were dominant in the stratosphere, according to the observed Ångström exponent, related to the backscatter coefficients obtained by the pair of wavelengths 532 and 1064 nm (Åb up to 3), in contrast to the Åb values in the troposphere (Åb &lt; 1) indicative of the presence of coarser particles. As the aerosols fend off the source, towards North America, a slightly descending trend was observed in the tropospheric Åb values, while the stratospheric ones were lightly increased. A maximum aerosol optical depth (AOD) value of 0.54 was recorded in the lower troposphere over the fire spots, while, in the stratosphere, AOD values up to 0.29 were observed. Sharp changes of carbon monoxide (CO) and ozone (O3) concentrations were also recorded by the Copernicus Atmosphere Monitoring Service (CAMS) in various atmospheric heights over the study region, associated with fire smoke emissions. The tropospheric smoke layers were found to have a negative mean radiative effect, ranging from −12.83 W/m2 at the top of the atmosphere (TOA), to −32.22 W/m2 on the surface (SRF), while the radiative effect of the stratospheric smoke was estimated between −7.36 at the TOA to −18.51 W/m2 at the SRF.

Twenty-first-century Southern Hemisphere impacts of ozone recovery and climate change from the stratosphere to the ocean

Abstract. Changes in stratospheric ozone concentrations and increasing concentrations of greenhouse gases (GHGs) alter the temperature structure of the atmosphere and drive changes in the atmospheric and oceanic circulation. We systematically investigate the impacts of ozone recovery and increasing GHGs on the atmospheric and oceanic circulation in the Southern Hemisphere during the twenty-first century using a unique coupled ocean–atmosphere climate model with interactive ozone chemistry and enhanced oceanic resolution. We use the high-emission scenario SSP5-8.5 for GHGs under which the springtime Antarctic total column ozone returns to 1980s levels by 2048 in our model, warming the lower stratosphere and strengthening the stratospheric westerly winds. We perform a spatial analysis and show for the first time that the austral spring stratospheric response to GHGs exhibits a marked planetary wavenumber 1 (PW1) pattern, which reinforces the response to ozone recovery over the Western Hemisphere and weakens it over the Eastern Hemisphere. These changes, which imply an eastward phase shift in the PW1, largely cancel out in the zonal mean. The Southern Hemisphere residual circulation strengthens during most of the year due to the increase in GHGs and weakens in spring due to ozone recovery. However, we find that in November the GHGs also drive a weakening of the residual circulation, reinforcing the effect of ozone recovery, which represents another novel result. At the surface, the westerly winds weaken and shift equatorward due to ozone recovery, driving a weak decrease in the transport of the Antarctic Circumpolar Current and in the Agulhas leakage and a cooling of the upper ocean, which is most pronounced in the latitudinal band 35–45∘ S. The increasing GHGs drive changes in the opposite direction that overwhelm the ozone effect. The total changes at the surface and in the oceanic circulation are nevertheless weaker in the presence of ozone recovery than those induced by GHGs alone, highlighting the importance of the Montreal Protocol in mitigating some of the impacts of climate change. We additionally compare the combined effect of interactively calculated ozone recovery and increasing GHGs with their combined effect in an ensemble in which we prescribe the CMIP6 ozone field. This second ensemble simulates a weaker ozone effect in all the examined fields, consistent with its weaker increase in ozone. The magnitude of the difference between the simulated changes at the surface and in the oceanic circulation in the two ensembles is as large as the ozone effect itself. This shows the large uncertainty that is associated with the choice of the ozone field and how the ozone is treated.

Characterizing the distinct modulation of future emissions on summer ozone concentrations between urban and rural areas over China

Previous studies on ozone pollution primarily focus on the characterization of ozone on a large regional scale, yet much less attention has been paid towards the contrast between urban and surrounding suburban-rural areas. As anthropogenic emissions are projected to decrease in the coming decades, the evolutions of ozone concentrations over urban and suburban-rural areas are compared using the Community Multiscale Air Quality (CMAQ) model coupled with the Weather Research and Forecasting (WRF). The top 25 city clusters are firstly identified across China based on the amount of NOx emissions and population size. At present, the averages of maximum daily 8-h (MDA8) ozone concentrations over the suburban-rural areas (65.74 ppbv) among these city clusters are higher than the corresponding urban areas (62.00 ppbv). The projections in 2050s depend on the scenarios. Under the Shared Socioeconomic Pathways (SSPs) scenarios such as SSP1-2.6, SSP2-4.5 and SSP5-8.5 indicative of primary decreases in anthropogenic emissions, the mean MDA8 ozone concentrations in suburban-rural areas decrease more than urban areas. In contrast, the gap of higher MDA8 ozone concentrations in suburban-rural than urban areas increases under SSP3-7.0 concomitant with increase in anthropogenic emissions. The strongest response to emission changes is found in SSP1-2.6, in which anthropogenic emission reduction leads to lower MDA8 ozone concentrations in the suburban-rural than urban areas, reversing the present state of higher ozone concentrations in the suburban-rural areas. The feature abovementioned regarding changes of mean MDA8 ozone concentrations is largely reproduced in the response of ozone exceedance. The finding highlights different efficacies of anthropogenic emissions in urban from suburban-rural areas. In a region like China where the population density is much higher in urban than suburban-rural regions, the benefit of ozone reduction due to large emission reductions (e.g., SSP1-2.6) is diminished to some extent because the effect is larger in suburban-rural areas.