The current research addresses the challenges encountered in polyamide 6 carbon fiber composites synthesized by fused deposition modeling. It specifically investigates issues such as inadequate interlaminar bonding and increased void content compared to conventionally manufactured composite components and as-built printed parts. The study focuses on printing pin samples via fused deposition modeling and explores various thermal post-processing methods to reduce void content while preserving dimensional accuracy. To evaluate wear and friction behavior, a pin-on-disc tester was used to test both as-built samples and samples post-heat-treated at 70 °C, 140 °C, and 210 °C. The results indicate that as the applied load increases from 5 to 20 N, both wear rates and friction coefficients increase across all speeds (1–5 m/s). Heating the samples to 70 °C and 140 °C strengthens the interlayer bonding. This significantly improves the maximum wear rates and friction coefficients compared to the as-built samples. However, samples heated to 210 °C do not show much of a change in wear rates or friction coefficients. Samples heated to 210 °C exhibit a decrease in wear rate of 16.87%, 15.82%, and 15.73% for loads ranging from 5 to 20 N, at speeds of 1, 3, and 5 m/s, respectively. This is likely due to pores sealing off and structures binding tightly. The worn surfaces were analyzed using a scanning electron microscope and measured the Shore D hardness of the samples before and after wear testing and documented the results for further analysis. In a scanning electron microscope, samples treated at 210 °C displayed smoother, less worn surfaces. Shore D hardness tests revealed a slightly higher hardness in samples heated to higher temperatures, followed by higher loads and sliding speeds in tribometer tests. This showed that the material was more stable. These post-processing methods significantly advance the development of functional composite elements for superior structural or dynamic performance.
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