This work suggests applying chamfering treatment to the plasma generator of the empty electrode structure. Enhancing the electrodes’ physical structure can significantly improve plasma characteristics without requiring intricate control systems. Experiments have shown that changes in the electrode’s shape can lead to changes in the formation of the atmospheric pressure plasma jet. Specifically, our observations indicate that an increase in the chamfer radius leads to an increase in the ignition voltage and a greater density of reactive species inside the jet. We developed a multi-channel equivalent circuit model to describe the discharge process of a plasma jet. Then, using the mixed layer theory, we investigated the effect of the chamfer radius on the plasma jet. Our findings suggest that chamfering increases the effective discharge area, resulting in more discharge channels in the model. This leads to a higher density of reactive species. Additionally, chamfering improves the mixing of helium and air, increasing the concentration of N2 and O2. This consumes some of the avalanche electrons and raises the ignition voltages, ultimately enhancing the chemical reactivity of the plasma jet. This work provides new ideas for the optimization strategy of atmospheric pressure plasma radiation devices.