The management of soil can be improved by precision agriculture. A way to achieve this is by quantifying NH4+–N and NO3−–N in soil. The sampling of soil for quantifying these N species is a laborious task. Electromagnetic induction (EMI) sensors could ease the task, providing a large quantity of data. The correlation of inorganic N with soil electrical apparent conductivity (ECa) in either single or composite samples is essential to accomplish this. Using an ECa-directed sampling approach, suitable sampling points were identified at four centre pivots. Single and composite samples were collected in 300 mm increments to 600 mm at Hofmeyr and 1500 mm at Douglas, Luckhoff and Empangeni. The samples were analysed for NH4+–N and NO3−–N from which total inorganic N (TIN) was calculated. All three inorganic N fractions were correlated insignificantly to in-field readings of ECa, implicating that EMI sensors are not suitable for inorganic N estimations in these irrigated soils. A comparison between single and composite samples, however, showed a good agreement of NH4+–N concentrations which was not true for NO3−–N or TIN concentrations. Composite samples are recommended for inorganic N measurements with an EMI sensor. Single samples could be used when only NH4+–N is analysed.