Shift Of Center Research Articles

Sedimentation cycles, tectonic phases and progradation trends: Late Pannonian deposition in the Drmno Basin, Serbia

The Drmno Basin is characterized by siliciclastic deposition and coal accumulation during the Late Pannonian and Pliocene, which resulted in the formation of numerous coal seams that lack lateral continuity, challenging traditional research methods. The cyclicity and geometry of the coal seams suggest several phases of peat accumulation, interrupted by the influx of siliciclastic material from the Carpathians. Siliciclastic deposition began in the upper delta plain environment and developed into an alluvial plain with river channels and swamps. The coal seams in the Drmno field within the Kostolac open-cast mine show a northward shift of the peat accumulation centre and, together with the coarsening upward trend in the interburden sediments, indicate a south-northward progradation. Biostratigraphic results confirmed the progradation trend with Prosodacnomya carbonifera indicating an age of 7.5–8 Ma in the southern part of the field and with Prosodacnomya elongata indicating an age of 7.2 Ma in the northern part. The influence of recent tectonic activity in the peri-Pannonian domain is reflected by the presence of compressional tectonic structures observed in the basin fill.

Out-of-plane coordination of iridium single atoms with organic molecules and cobalt-iron hydroxides to boost oxygen evolution reaction.

Advancements in single-atom-based catalysts are crucial for enhancing oxygen evolution reaction (OER) performance while reducing precious metal usage. A comprehensive understanding of underlying mechanisms will expedite this progress further. Here we report Ir single atoms coordinated out-of-plane with dimethylimidazole (MI) on CoFe hydroxide (Ir1/(Co,Fe)-OH/MI). This Ir1/(Co,Fe)-OH/MI catalyst, which was prepared using a simple immersion method, delivers ultralow overpotentials of 179 mV at a current density of 10 mA cm-2 and 257 mV at 600 mA cm-2 as well as an ultra-small Tafel slope of 24 mV dec-1. Furthermore, Ir1/(Co,Fe)-OH/MI has a total mass activity exceeding that of commercial IrO2 by a factor of 58.4. Ab initio simulations indicate that the coordination of MI leads to electron redistribution around the Ir sites. This causes a positive shift in the d-band centre at adjacent Ir and Co sites, facilitating an optimal energy pathway for OER.

China’s Belt and Road Initiative and its Implications on the Global Power Dynamics

This work explores the multifaceted impact of the Belt and Road Initiative (BRI) initiated by China on global power dynamics, economic landscapes, and diplomatic alliances. Beginning with an overview of the BRI's historical context and objectives, the essay delves into its theoretical framework, employing Organski's power transition theory to analyze economic, geopolitical, strategic, and cultural dimensions. The literature review integrates insights from scholars such as Layne, Modelski, Thompson, Huntington, and Nye, providing a nuanced understanding of the BRI's placement within broader historical patterns. The essay then examines the economic impact of the BRI on participating countries, emphasizing infrastructure development, trade facilitation, and technology transfer. A shift in the global economic center of gravity towards Asia is explored, challenging traditional economic power structures. Geopolitical implications and evolving power dynamics are analyzed, highlighting the strategic positioning of China and the formation of new alliances. Global responses to the BRI, particularly from major powers like the United States, Russia, and the European Union, are discussed, reflecting varying perspectives on China's growing influence. The work also addresses challenges and criticisms related to debt sustainability, environmental concerns, transparency, and governance. In conclusion, the paper reflects on the transformative effects of the BRI, emphasizing its role in shaping a multipolar world and challenging existing norms of hegemony.

Sub-10 nm PdNi@PtNi Core–Shell Nanoalloys for Efficient Ethanol Electro-Oxidation

By controlling the structure and composition of Pt-based nanoalloys, the ethanol oxidation reaction (EOR) performances of Pt alloy catalysts can be effectively improved. Herein, we successfully synthesis sub-10 nm PdNi@PtNi nanoparticles (PdNi@PtNi NPs) with a core–shell structure by a one-pot method. The sub 10 nm core–shell nanoparticles possess more effective atoms and exhibit a synergistic effect which can lead to a shift in the d-band center and alter binding energies toward adsorbates. Due to the synergistic effect and unique core–shell structure, the PdNi@PtNi NP catalysts exhibit excellent electrocatalytic performance for ethanol oxidation reactions in alkaline, achieving 9.30 times more mass activity and 7.05 times more specific activity that of the state-of-the-art Pt/C catalysts. Moreover, the stability of PdNi@PtNi NPs was also greatly improved over PtNi nanoparticles, PtPd nanoparticles, and commercial Pt/C. This strategy provides a new idea for improving the electrocatalytic performance of Pt-based catalysts for EORs.

Visible-light assisted peroxymonosulfate process for efficient water treatment via Fe-O embedded ZIF-62

The development of efficient and environmentally friendly water treatment technologies is essential for the treatment of emerging pollutants. In this study, a ZIF-62 catalyst embedded with Fe-O was prepared for the visible-light assisted activation of peroxymonosulfate (PMS) to achieve the removal of bisphenol A by coupling photogenerated carriers with the non-radical pathway. The embedding of Fe-O narrowed the bandgap width (reduced from 3.07 eV to 2.37 eV), enhanced the overall photoresponse performance, and improved the segregation of photogenerated carriers. The upward shift of the d-band center contributes to the adsorption of PMS. The embedding of Fe-O improves the BPA removal kinetics by a factor of 15.4 (increased from 0.00391 min−1 to 0.06005 min−1). Surface-activated complexes played a dominant role in the removal of BPA in this system, and photogenerated holes (h+) and singlet oxygen (1O2) were also involved in the removal of BPA. In addition, the system has good pH adaptability (pH = 3 ∼ 11) and good environmental suitability. Toxicity assessment showed that the overall toxicity of the intermediates tended to decrease. This study provides new insights into visible-light assisted activation of PMS.

АНАЛІЗ ВПЛИВУ КУТА СТРІЛОПОДІБНОСТІ НА ХАРАКТЕРИСТИКИ СТАТИЧНОЇ АЕРОПРУЖНОСТІ КРИЛА НАВЧАЛЬНО-ТРЕНУВАЛЬНОГО ЛІТАКА

The article is dedicated to the analysis of static aeroelastic phenomena in the wing of a trainer aircraft and the general influence of wing sweep on critical speeds. Aeroelasticity studies the interaction between aerodynamic and elastic forces and the impact of this interaction on the aircraft's structure. There are two types of aeroelasticity: static and dynamic. The article reviews and analyzes publications related to this issue. The analysis of the research shows that when designing an aircraft, it is necessary to determine the aeroelastic characteristics of its aerodynamic surfaces. In addition to structural rigidity, the sweep angle also influences these phenomena. The scientific novelty of the study lies in the fact that, unlike the analyzed research, the designed wing structure of a trainer aircraft is considered.For the designed trainer aircraft, the critical speeds of static aeroelastic phenomena were determined. The calculation of the influence of the wing sweep angle on the divergence speeds of the trainer aircraft confirms previously obtained results regarding this influence. When the sweep is increased or decreased for wings with the same span, the torsional rigidity of the wing decreases due to the increase in the length of the line of centers of rigidity. However, the most significant impact on the aeroelastic characteristics is made by the shift of the bending center when the sweep angle changes.With forward sweep, the arm of the aerodynamic forces relative to the bending center increases, thereby reducing the critical divergence speeds. For straight sweep, as the sweep increases, the bending center moves forward, and at a certain point, the bending center is located in front of the aerodynamic center. This means that the wing twist angle decreases as the aerodynamic force increases, which, in the considered planar case, eliminates the occurrence of divergence.The preliminarily determined maximum flight speed does not exceed the critical speeds of divergence and aileron reversal. This result represents the practical value of the study. To achieve higher flight speeds, wings with straight sweep should be used. More precise computational or experimental methods for determining aeroelastic characteristics should be used in the subsequent design stages to prevent aeroelastic phenomena across the entire operational range of speeds and altitudes of the trainer aircraft.

Pola Spasial Pergeseran Pusat Pertumbuhan Desa di Kabupaten Kulon Progo

Kulon Progo is a poorest district and has the highest development inequality in Daerah Istimewa Yogyakarta (DIY) based on Badan Pusat Statistik (BPS) publication. The local government has made various efforts to overcome the problems, one of which is by establishing growth centers since 2003. However, Kulon Progo Regency has experienced rapid development with the existence of Yogyakarta International Airport, which affected the dynamics of regional growth centers. The purpose of this study is to identify the potential Rural Growth Center (PPD) and identify the spatial patterns of PPD shifts in Kulon Progo to see the trickle down effect. This study used descriptive quantitative methods using scalogram index, centrality index, urban network analysis, and gravity index, also moran’s I index and Local Indicator Of Spatial Association (LISA). The results showed that there was a shift in rural growth centers, but the spatial analysis did not show any trickle down effect from rural growth centers that had been formed before. However, new centers were formed that were not related to the previous rural growth centers. These results indicates that the rural growth centers in Kulon Progo cannot have a growth effect on the surrounding area.

Enhanced photocatalytic CO2 reduction to CH4 on oxygen vacancy-rich NiCo2O4 with surface pits: Synthesis, DFT calculations, and mechanistic insights

Unraveling the influence of surface microstructure in materials on their interaction with CO2 remains a critical challenge in achieving efficient and selective CO2 reduction. In this study, we report the engineering of pit structures on the NiCo2O4 surface for efficient photocatalytic reduction of CO2. Characterization results show that calcination temperature affects the distribution of surface pits and oxygen vacancy concentration. Oxygen vacancy sites accompanying surface pits facilitate the generation and movement of photogenerated electrons and holes, preventing their recombination and promoting the conversion of CO2. The CH4 yield from photocatalytic CO2 reduction reaches 52.4 μmol g−1 with the optimal pitted NiCo2O4 catalyst (PNCO2), significantly surpassing the 18.4 μmol g−1 yield of non-pitted NiCo2O4 (NPNCO). Additionally, PNCO2 improves selectivity from 81.8 % for NPNCO to 94.1 %. Density functional theory calculations show that CO2 adsorption on the PNCO2 surface is significantly enhanced as the d-band center shifts toward the Fermi level. The adsorbed CO2 combines with electrons enriched at the Ni sites at the edges of the surface pits, leading to further activation. The reduction of CO2 to intermediate products such as CHO* is analyzed based on in situ diffuse reflectance infrared Fourier transform spectroscopy, and a possible reaction pathway is proposed. This work offers fresh insights into engineering surface pit structures for the design and synthesis of catalysts for photocatalytic CO2 reduction.

The Accelerating Loss of Resilience in Suburban Woodlands Can Largely Be Attributed to the Changes in Urban Precipitation Patterns.

Vegetation resilience holds significant importance for stabilizing ecosystem service functions in a changing climate. While global land surface vegetation resilience changes have been extensively studied, the impact of urbanization on the resilience of suburban woodlands remains inadequately understood. In this study, we utilized two critical slowing down (CSD) indicators, namely lag-one autocorrelation (LOA) and variance (VA), to assess the vegetation resilience, its long-term trends, and influencing factors in suburban woodlands across 1356 cities worldwide. The recovery rates estimated by LOA ( ) and VA ( ) showed close alignment in suburban woodlands with low suburban forest coverage (SFC) areas (correlation coefficient (r) = 0.95). However, a notable divergence was observed in areas with high SFC (r = 0.73). Suburban woodlands with high SFC typically exhibited lower recovery rate estimates, thus indicating greater vegetation resilience compared to areas with lower SFC. From 1986 to 2022, the recovery rates of suburban woodland areas in over 83% of the cities demonstrated a significant upward trend, with an average of 3.23 × 10-3 year-1 for both and , signifying a widespread decline in vegetation resilience. The accelerating pace of urbanization led to higher rising rates of and during 2010-2022 (5.11 × 10-3 year-1) compared to 1986-1999 (0.49 × 10-3 year-1). The notable decrease in resilience of forestland was primarily attributed to reduced precipitation in urban suburbs, which can be explained by urbanization-induced heat island and building barrier effects, causing a shift of precipitation center from urban suburbs to central cities. In summary, this study revealed that urbanization diminishes the vegetation resilience of urban suburban woodlands by altering urban precipitation patterns. These findings underscore the necessity of augmenting water availability in urban suburbs to restore resilience in these woodlands, thereby enhancing their ecosystem service value.

Impacts of Large-Scale Offshore Wind Farms on Tropical Cyclones: A Case Study of Typhoon Hato

Abstract With the rising global demand for renewable energy sources, a great number of offshore wind farms are being built worldwide, as well as in the northern South China Sea. There is, however, limited research on the impact of offshore wind farms on the atmospheric and marine environment, particularly tropical cyclones, which frequently occur in summertime in the South China Sea. In this paper, we employ the Weather Research and Forecasting (WRF) Model to investigate the impacts of large-scale offshore wind farms on tropical cyclones, using the case of Typhoon Hato, which caused severe damage in 2017. Model results reveal that maximum wind speeds in coastal areas decrease by 3–5 m s−1 and can reach a maximum of 8 m s−1. Furthermore, the wind farms change low-level moisture convergence, causing a shift in the precipitation center toward the wind farm area and causing a significant overall reduction (up to 16%) in precipitation. Model sensitivity experiments on the area and layout of the wind farm have been carried out. The results show that larger wind farm areas and denser turbine layouts cause a more substantial decrease in the wind speed over the coast and accumulated precipitation reduction, further corroborating our findings. Significance Statement This study holds significant implications for developing offshore wind farms in tropical cyclone-prone regions like the South China Sea. By focusing on Typhoon Hato as a case study, the research sheds light on the previously understudied relationship between large-scale offshore wind farms and tropical cyclones. The observed decrease in coastal wind speeds and altered precipitation patterns due to wind farm presence highlights the potential for mitigating cyclone-related risks in these regions. Additionally, the study’s sensitivity experiments underscore the importance of careful planning and design in optimizing wind farm layouts for maximum impact reduction. This research contributes vital insights into sustainable energy infrastructure development while minimizing environmental and meteorological risks in cyclone-prone areas.

Platinum modification of metallic cobalt defect sites for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural

Co3O4 possesses both direct and indirect oxidation effects and is considered as a promising catalyst for the oxidation of 5-hydroxymethylfurfural (HMF). However, the enrichment and activation effects of Co3O4 on OH− and HMF are weak, which limits its further application. Metal defect engineering can regulate the electronic structure, optimize the adsorption of intermediates, and improve the catalytic activity by breaking the symmetry of the material, which is rarely involved in the upgrading of biomass. In this work, we prepare Co3O4 with metal defects and load the precious metal platinum at the defect sites (Pt-Vco). The results of in-situ characterizations, electrochemical measurements, and theoretical calculations indicate that the reduction of Co–Co coordination number and the formation of Pt–Co bond induce the decrease of electron filling in the antibonding orbitals of Co element. The resulting upward shift of the d-band center of Co combined with the characteristic adsorption of Pt species synergically enhances the enrichment and activation of organic molecules and OH− species, thus exhibiting excellent HMF oxidation activity (including a lower onset potential (1.14 V) and 19 times higher current density than pure Co3O4 at 1.35 V). In summary, this work explores the adsorption enhancement mechanism of metal defect sites modified by precious metal in detail, provides a new option for improving the HMF oxidation activity of cobalt-based materials, broadens the application field of metal defect based materials, and gives an innovative guidance for the functional utilization of metal defect sites in biomass conversion.

Unlocking Copper-Free Interfacial Asymmetric C-C Coupling for Ethylene Photosynthesis from CO2 and H2O.

Solar-driven carbon dioxide (CO2) reduction into C2+ products such as ethylene represents an enticing route toward achieving carbon neutrality. However, due to sluggish electron transfer and intricate C-C coupling, it remains challenging to achieve highly efficient and selective ethylene production from CO2 and H2O beyond capitalizing on Cu-based catalysts. Herein, we report a judicious design to attain asymmetric C-C coupling through interfacial defect-rendered tandem catalytic centers within a sulfur-vacancy-rich MoSx/Fe2O3 photocatalyst sheet, enabling a robust CO2 photoreduction to ethylene without the need for copper, noble metals, and sacrificial agents. Specifically, interfacial S vacancies induce adjacent under-coordinated S atoms to form Fe-S bonds as a rapid electron-transfer pathway for yielding a Z-scheme band alignment. Moreover, these S vacancies further modulate the strong coupling interaction to generate a nitrogenase-analogous Mo-Fe heteronuclear unit and induce the upward shift of the d-band center. This bioinspired interface structure effectively suppresses electrostatic repulsion between neighboring *CO and *COH intermediates via d-p hybridization, ultimately facilitating an asymmetric C-C coupling to achieve a remarkable solar-to-chemical efficiency of 0.565% with a superior selectivity of 84.9% for ethylene production. Further strengthened by MoSx/WO3, our design unveils a promising platform for optimizing interfacial electron transfer and offers a new option for C2+ synthesis from CO2 and H2O using copper-free and noble metal-free catalysts.

Experimental investigation on the longitudinal stability of the aerodynamically alleviated marine vehicle with multi-steps

To investigate the hydrodynamic performance and motion characteristics of the ultra-high-speed aerodynamically alleviated marine vehicle (AAMV) with multi-steps, a towing tank test scheme was designed and carried out at the China Special Vehicle Research Institute. The study analyzed the effects of canard angle, flap angle, longitudinal center of gravity, and displacement tonnage on the motion stability of multi-stepped AAMV at different speeds. The results indicate that the canard generates an overturning moment that reduces the resistance but brings forward the speed at which porpoising behavior occurs. Additionally, the backward shift of the longitudinal center of gravity causes motion oscillation during the high-speed planing phase, which negatively affects longitudinal stability. On the other hand, the flaps provide aerodynamic lift and restoring moments, improving the lift-drag ratio and enhancing longitudinal stability. Furthermore, while increased mass may result in higher total resistance, it can actually improve resistance performance per unit mass and improve the lift-drag ratio at cruising speed. The computational fluid dynamics (CFD) method was used to analyze the destabilization mechanism of AAMV under extreme conditions in the test. Numerical results indicate that the longitudinal stability of AAMV is directly affected by the relative positions of the center of gravity and the center of pressure. These results demonstrate the changing rules of resistance performance and longitudinal stability of AAMV under different design parameters, thus providing a powerful tool for optimizing AAMV.

Fair Games—Curating New Music

The authors of “Defragmentation: Curating Contemporary Music,” a special issue of the Darmstädter Beiträge zur Neuen Musik published in 2019, considered all aspects of any given artistic event as fair game for curation. They suggested that not only could the choice of pieces, soloists, conductors, and ensembles be (re)tooled (including even site-specific aspects), but the roles of the musicians and audience and even value regimes could be instrumentalized to accord with the artistic demands of the curator. In her introduction to the special issue, Dorothee Richter argued that curation should be a “practice that is deeply involved in the politics of display, politics of site, politics of transfer and translation, and regimes of visibility.” If we understand politics with Jacques Rancière as “giving form to the social,” then Richter suggests that every thinkable manner in which people relate can, and should, be weighed when programming a concert. Curators need to reflect and act upon the way relationships in our world are displayed, the interplay involved on site, the participation or lack thereof of an audience, the participants’ ability to understand, enjoy, and be entertained, and even the audience’s and presenter’s perceived positions in society and how they play out in concert. Writing as a performer-researcher, a cultural-sociologist, and a musicologist, and drawing on previous research in the visual arts, we discuss the impact of the curator within the European new music world. We question the curator’s central role and probe shifts in power relations between festival directors, receptive venues, and performing ensembles. In our view, the rise of the curator in the new music world leads us in at least two distinct directions. First, as in the visual arts world, the individual curator may assume the role of the new protagonist, displacing the performing artists from their throne. When this occurs, curating takes place in a game of mutual competition, distinction, and exploitation, in which illustration of an abstract idea or concept prevails over musical experience. Alternatively, curating may become a collective affair and responsibility along the lines of commoning principles, in which curating returns to its etymological roots as a form of caring for each other and for both the tradition and the future of music.

Spatiotemporal Prediction of Greenhouse Gas Emissions from Rubber Wood Furniture Industry, Taking Hainan as the Case

The rubber wood furniture industry chain, including planting and manufacturing subsystems, emits significant greenhouse gases (GHGs), meanwhile, has huge carbon emission reduction potential. However, quite few studies have taken the whole industry chain GHGs into consideration, especially assessing and modelling those from rubber tree planting to furniture manufacturing. We took the rubber wood furniture of Hainan province as the case, explored its whole life cycle GHGs from cradle-to-gate and predicted the potential GHGs from 2031 to 2062. This study is fully based on field survey and sampling data, including that of the rubber tree planting (40-year cycle) and furniture manufacturing. The results reveal: (1) Whole industry chain of rubber wood furniture emits 3.27×106 kgCO2-eq GHGs per 20,000t rubber logs consuming, where the planting accounts the most (88.20%). Transport and electricity consumption are the main GHGs sources of planting and manufacturing subsystems respectively; (2) The whole life-cycle GHGs of rubber wood furniture in 2023 of Hainan is 2.07×107 kgCO2-eq, which mainly come from Danzhou (24.74%), Haikou (19.55%), and Qiongzhong (15.79%); (3) The total GHGs from the rubber wood furniture industry in Hainan from 2031 to 2062 are 210 MtCO2-eq and 129 MtCO2-eq respectively, without or with felling restriction. The changes of GHGs from 2051 to 2062 are caused by the regional center shift of planting gravity; (4) Improving energy use efficiency and optimizing the location of furniture factories would reduce GHGs. This study can provide empirical support for the low carbon sustainable transformation of the rubber wood furniture industry worldwide.

Strong electronic metal-support interaction of Ni4Mo/N-SrMoO4 promotes alkaline hydrogen electrocatalysis

Ni4Mo electrocatalyst stands out as the promising candidate for hydrogen evolution/oxidation reaction (HER/HOR), yet the intensive hydrogen adsorption leads to sluggish kinetics, decreasing hydrogen catalysis efficiency. Herein, the structure of Ni4Mo nanoparticles anchored on wafer-biscuit-like N-SrMoO4 nanorods (Ni4Mo/N-SrMoO4) is developed to accelerate reaction kinetics by modulating electronic structure. The designed N-SrMoO4 support enables strong electronic metal-support interaction with Ni4Mo, resulting in a downward shift of d-band center and achieving thermally neutral hydrogen adsorption. Ni4Mo/N-SrMoO4 exhibits HER performance with an ultralow overpotential of 15 mV at 10 mA cm−2, superior to Pt/C (η10=18 mV). The outstanding exchange current density of 10.2 mA cm−2 for HOR is three times higher than that of Pt/C (3.5 mA cm−2). Ni4Mo/N-SrMoO4 is further assembled in anion exchange membrane water electrolyzer (AEMWE), resulting in a current density of 100 mA cm−2 at voltage of 1.71 V and the excellent stability of 300 hours. Theoretical calculations and in-situ spectroscopy indicate that the introduction of Sr in N-SrMoO4 effectively enhances electronic metal-support interaction, facilitates the enrichment of adsorbed hydroxyl (OHads) on active sites and weakens hydrogen adsorption on Ni4Mo, thereby accelerating reaction kinetics of hydrogen electrocatalysis.

교육권 개념의 형성과 교사-학부모 관계의 변화

This study sought to understand the depth of the teacher-parent relationship, which has recently been in a state of extreme conflict. Since the ideology of public education spread, the reality of public education has been the government’s domination of education. However, with the emergence of the ‘right to people’s education’and the rise of ‘new public managementism’, the trends of ‘customerism’ were accepted in school education as well. As a result, the state’s power to schools was weakened, and the public education came to be explained under the concept of a ‘contract’ between parents and schools. A series of events that occurred after the democratization of Korean society, such as the launch of the teachers’ union, institutionalization of the school management committee and introduction of the teacher performance-based pay system can be seen as events that brought about significant changes in the decline of teachers’ authority and the shift of center of gravity from the state(schools and teachers) to individuals(parents). The recent phenomenon of deepening tension and conflict between teachers and parents shows that the elements are changing at a fundamental level. Now is the time that a new role of public education and a new relationship between teachers and parents are needed.

Unveiling the development trends of environmental and human health concerns for pesticides: Integrating an intelligent approach and data mining across diverse databases

The impact of pesticide use on environmental and human health has been a persistent global concern. In the era of big data, the scientific literature concerning big data is a significant source of information; however, it is difficult to construct an optimal policy based on traditional insight using keyword searches or a single static-specialized database. In this study, we constructed a new path for data mining across multiple databases to provide a comprehensive picture of the major issues concerning environmental pollution and human health as a result of pesticide use at the global scale. This approach uses a classic unsupervised learning algorithm, Latent Dirichlet Allocation (LDA), in combination with a newly developed dataset of pesticide-associated human health outcomes (PAHHO), including 618 health outcomes classified into 14 types of toxic effects.Our data visualization revealed a shift in the scientific center for pesticide research over the past five decades. The major issues concerning environmental pollutants and health outcomes varied among different countries and in different periods, which was verified in our analysis of several organochlorine pesticides (OCPs) about which people are particularly concerned.A cooccurrence network of adverse health outcomes has gradually increased, suggesting that the impact of pesticides on human health is persistent and cumulative. Our work not only provides a promising research direction related to the most concerning issues in a systematic and visualized way but also provides valuable references to formulate optimal strategies for the goal of the global “One Health” objective in pesticide regulation.

Increasing electrochemical carbon dioxide reduction to methane via a novel copper-based conductive metal organic framework

The development of a new system for the electrochemical carbon dioxide reduction reaction (ECO2RR) to methane (CH4) is challenging, and novel conductive metal organic frameworks (c-MOFs) for efficient ECO2RR to CH4 are critical to this system. Here, we report a novel c-MOF, copper-pyromellitic dianhydride-2-methylbenzimidazole (Cu-PD-2-MBI), in which the introduction of electron-withdrawing 2-methylbenzimidazole (2-MBI) into the copper-pyromellitic dianhydride (Cu-PD) interlayer elevated the valence of copper (Cu) ions, which improved the ECO2RR performance of Cu-PD-2-MBI. Cu-PD-2-MBI was tested in a flow cell, and the Faradaic efficiency of CH4 reached 73.7 %, with a corresponding partial current density of −428.3 mA·cm−2 at −1.3 V, which was higher than those of most reported Cu-based catalysts. Further exploration via theoretical calculations indicated that the intercalated 2-MBI in Cu-PD-2-MBI induced a shift in the d-band center in the Cu sites from −2.63 to −1.86 eV and reduced the formation energy of the *COOH and *CHO intermediates in the process of generating CH4 compared with those of the reference Cu-PD catalyst.

Hydrogen Evolution Reactivity of Pentagonal Carbon Rings and p-d Orbital Hybridization Effect with Ru.

Topological defects are inevitable existence in carbon-based frameworks, but their intrinsic electrocatalytic activity and mechanism remain under-explored. Herein, the hydrogen evolution reaction (HER) of pentagonal carbon-rings is probed by constructing pentagonal ring-rich carbon (PRC), with optimized electronic structures and higher HER activity relative to common hexagonal carbon (HC). Furthermore, to improve the reactivity, we couple Ru clusters with PRC (Ru@PRC) through p-d orbital hybridization between C and Ru atoms, which drives a shortcut transfer of electrons from Ru clusters to pentagonal rings. The electron-deficient Ru species leads to a notable negative shift in d-band centers of Ru and weakens their binding strength with hydrogen intermediates, thus enhancing the HER activity in different pH media. Especially, at a current density of 10 mA cm-2, PRC greatly reduces alkaline HER overpotentials from 540 to 380 mV. And Ru@PRC even exhibits low overpotentials of 28 and 275 mV to reach current densities of 10 and 1000 mA cm-2, respectively. Impressively, the mass activity and price activity of Ru@PRC are 7.83 and 15.7 times higher than that of Pt/C at the overpotential of 50 mV. Our data unveil the positive HER reactivity of pentagonal defects and good application prospects.