The vast ice sheet of Antarctica is isolated geographically but not meteorologically from the rest of the planet. Tropospheric aerosols in or near the accumulation mode size, around a half micron diameter, reside in the atmosphere for tens of days and teleconnect Antarctica with other regions by transport that reaches planetary scales of distances. The aerosol on the ice sheet, therefore, at any time and place represents “memory modules” of events that took place at regions separated from Antarctica by tens of thousands of kilometers. Scientific attention to this collective aerosol system provides insight into long‐range atmospheric transport. Investigations of particles in the ultraclean air over Antarctica were slow to get going mainly because of a failure to recognize the possibility of semiglobal transport of “dust”; as a result, this field is very young, having gone through its “romantic period” of exploratory studies in the late 1960s and entered into a time of synthesis and paradigm building only in the mid‐1970s. An important recent discovery is that the aerosol number concentration (the condensation nuclei (CN)) over this distant ice sheet undergoes a regular, methodical and predictable seasonal variation, nearly disappearing around winter solstice but being relatively robust (i.e., comparable to what one finds over mid‐oceans) in summer. A weakened seasonal modulation of CN is found at coastal sites. Circumstantial evidence indicates that the CN over the ice are produced from gas photolytically. Thus the tiniest particles over Antarctica are products of a slow “chemical” conversion within the atmosphere itself. A major discovery with numerous possible deep geobiological ramifications is that the aerosol over the ice sheet is by mass 70–90% sulfate, in the molecular form of hydrated droplets of sulfuric acid, except during transient events of a few days duration when atmospheric transport forces warm, moist air from the oceans into the interior continental regions. These events are most frequent in late winter‐early spring, accompanying the breakdown of the circumpolar vortex. These “sodium storms” transport large quantities of sea salt to the central ice sheet sporadically. Chemical studies of the submicron ice cap aerosols indicate that there is a uniquely winter and uniquely summer “crustal,” insoluble aerosol that represents <5% of aerosol mass but which has provided an interesting long‐term permanent record of itself going back 2 × 105 years in the ice. In terms of aerosol mass, the aerosol is composed of crustal products (<5%), transported sea‐salt residues (highly variable but averaging ∼ 10%), Ni‐rich meteoric material, and anomalously enriched material with an unknown origin. Most of the Antarctic aerosol, however, is the “natural acid sulfate aerosol” apparently deriving from biological processes taking place in the surrounding oceans.
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