Center Of Gap Research Articles

Dopant effects on the environment-dependent chemical properties of NiO(100) surfaces

NiO is a promising material for applications such as electronic devices and catalysts due to its low cost, environmental friendliness, and optimal chemical and electronic properties. Inclusion of a dopant element into the NiO near surface structure can further tune material properties. Despite extensive studies on doped NiO (M−NiO) materials, there remains a lack of knowledge regarding the connection between dopant, environment-dependent dominant near surface structures, and overall chemical properties. Here, the dopant effects on the near surface structure and electronic properties on M−NiO(100) are systematically examined using a combination of density functional theory (DFT) and ab initio phase diagrams. The simultaneous factors tested include dopant element (Al, Mo, Nb, Sn, Ti, V, W, or Zr), dopant placement (surface or subsurface), Ni/O vacancies (surface or subsurface), and oxygen species (O* or O2*) adsorption. The results reveal the dominant structures and compositions of M−NiO(100) under a wide range of environmental conditions (i.e. varying temperature and pressure). Subsequent electronic analyses of the dominant M−NiO(100) structures show non-uniform changes in charge redistribution, band gap, work function, and d-band center with dopant and near surface structure, emphasizing the role of dopants in tuning M−NiO(100) both geometric and electronic properties. Overall, these multiscale modeling results enable a rapid, effective, and a priori prediction of dominant M−NiO(100) structures with distinct chemical properties, crucial for guiding NiO-based materials design with enhanced performance for advanced electronics, energy storage, and catalytic systems.

Hard Particle Mask Electrochemical Machining of Micro-Textures

The efficient and cost-effective preparation of masks has always been a challenging issue in mask-based electrochemical machining. In this paper, an electrochemical machining process of micro-textures is proposed using hard particle masks such as titanium and zirconia particles. Numerical simulations were conducted to analyze the formation mechanisms of micro-protrusion structures with insulating and conductive hard particle masks, followed by experimental verification of the process. The results indicate that when the hard particles are electrically insulating, metal material preferentially dissolves at the center of the particle gap, and the dissolution then expands over time in depth and towards the particle contact points. Conversely, using the conductive particles as the masks, such as titanium particles, dissolution initially occurs in a ring region centered at the contact point between the hard particle and the anode, with a radius approximately one-quarter of the chosen particle’s diameter (200 μm), and then continues to expand outward.

Hints of Planet Formation Signatures in a Large-cavity Disk Studied in the AGE-PRO ALMA Large Program

Detecting planet signatures in protoplanetary disks is fundamental to understanding how and where planets form. In this work, we report dust and gas observational hints of planet formation in the disk around 2MASS J16120668-301027, as part of the Atacama Large Millimeter/submillimeter Array (ALMA) Large Program “AGE-PRO: ALMA survey of Gas Evolution in Protoplanetary disks.” The disk was imaged with the ALMA at Band 6 (1.3 mm) in dust continuum emission and four molecular lines: 12CO(J = 2–1), 13CO(J = 2–1), C18O(J = 2–1), and H2CO(J = 3(3,0)–2(2,0)). Resolved observations of the dust continuum emission (angular resolution of ∼150 mas, 20 au) show a ring-like structure with a peak at 0.″57 (75 au), a deep gap with a minimum at 0.″24 (31 au), an inner disk, a bridge connecting the inner disk and the outer ring, along with a spiral arm structure, and a tentative detection (to 3σ) of a compact emission at the center of the disk gap, with an estimated dust mass of ∼2.7−12.9 Lunar masses. We also detected a kinematic kink (not coincident with any dust substructure) through several 12CO channel maps (angular resolution ∼200 mas, 30 au), located at a radius of ∼0.″875 (115.6 au). After modeling the 12CO velocity rotation around the protostar, we identified a purple tentative rotating-like structure at the kink location with a geometry similar to that of the disk. We discuss potential explanations for the dust and gas substructures observed in the disk and their potential connection to signatures of planet formation.

Soil Fungal Function Centralization Enhances the Decomposition of Fine Roots at Canopy Gap Borders

Canopy gaps can result in abiotic heterogeneities and diverse niches from gap borders to centers, potentially affecting fine root decompositions mediated by soil fungal communities. Despite extensive discussions on the relationship between soil fungi and fine root decomposition, the mechanism by which gap locations regulate fine root decomposition through the soil fungal community remains elusive. Here, we conducted an in situ field decomposition experiment of Chinese Toon (Toona senensis) fine roots in a low-efficiency weeping cypress (Cupressus funebris) plantation forest across three microhabitats: gap centers, gap borders, and closed canopy areas. Soil fungal communities were determined using internal transcribed spacer (ITS) sequencing after two years of field incubation. Results showed that soil properties and nutrient content in residual roots varied across the three microhabitats, with the gap borders exhibiting the highest decomposition rates. While fungal α-diversity remained relatively consistent, taxonomic compositions differed significantly. Decomposition rates did not show significant correlations with soil properties, observed fungal ASVs, or overall community composition. However, they positively correlated with the relative abundance of saprotrophic Sordariomycetes, which in turn positively correlated with soil total nitrogen (with a highest correlation), peaking at the gap borders. Overall community variations were primarily driven by soil temperature and magnesium content in residual roots. Further analysis revealed high fungal community similarities and low dispersal limitations between the gap borders and closed canopy areas, with more phylogenetically clustered communities at the borders. These results demonstrate that the gap borders possess a high decomposition rate, likely due to the centralization of functions driven by soil fungi such as saprotrophs existing in the “microbial seed bank” or migrating from closed canopy areas. These findings highlight the key role of soil fungi, especially saprotrophic fungi, in fine root decomposition at the gap borders, stressing the importance of soil fungi-driven mechanisms in nutrient cycling, and also informing sustainable forest management practices.

Clonal response of a recalcitrant understory shrub, Labrador tea (Rhododendron groenlandicum Oeder.) to forest gaps

After canopy removing disturbance, recalcitrant understory shrubs can rapidly occupy the forest understory to the detriment of tree regeneration and growth. The expansion of recalcitrant species has been documented following stand replacing disturbances, such as fire and timber harvest. However, there is little information on how these species respond to much smaller canopy gaps created by the senescence and (or) death of single or groups of canopy trees. In this study, we determined the response of Labrador tea ( Rhododendron groenlandicum Oeder.), a recalcitrant ericaceous shrub, to canopy gaps in a late-successional boreal forest in northwestern Ontario, Canada. We evaluated functional traits related to the morphology and regeneration strategy of this plant to elucidate the mechanism of gap filling. We found that R. groenlandicum abundance and vigor were greater at the center of treefall gaps than in gap edges or the forest understory due to aggressive sprouting from buried clonal bud banks. Layering was higher in canopy gaps than in the understory. The composition of ground cover and rooting substrate was more influential on the adventitious rooting of the layered stems than increased light availability in gaps. We found a strong response of R. groenlandicum to small canopy openings, suggesting that the species can form recalcitrant understory layers even in the absence of stand replacing disturbance.

Quantitative Comparison of Ventilation Parameters of Different Approaches to Ventilator Splitting and Multiplexing.

Amid the COVID-19 pandemic, this study delves into ventilator shortages, exploring simple split ventilation (SSV), simple differential ventilation (SDV), and differential multiventilation (DMV). The knowledge gap centers on understanding their performance and safety implications. Our hypothesis posits that SSV, SDV, and DMV offer solutions to the ventilator crisis. Rigorous testing was anticipated to unveil advantages and limitations, aiding the development of effective ventilation approaches. Using a specialized test bed, SSV, SDV, and DMV were compared. Simulated lungs in a controlled setting facilitated measurements with sensors. Statistical analysis honed in on parameters like peak inspiratory pressure (PIP) and positive end-expiratory pressure. Setting target PIP at 15 cm H2O for lung 1 and 12.5 cm H2O for lung 2, SSV revealed a PIP of 15.67 ± 0.2 cm H2O for both lungs, with tidal volume (Vt) at 152.9 ± 9 mL. In SDV, lung 1 had a PIP of 25.69 ± 0.2 cm H2O, lung 2 at 24.73 ± 0.2 cm H2O, and Vts of 464.3 ± 0.9 mL and 453.1 ± 10 mL, respectively. DMV trials showed lung 1's PIP at 13.97 ± 0.06 cm H2O, lung 2 at 12.30 ± 0.04 cm H2O, with Vts of 125.8 ± 0.004 mL and 104.4 ± 0.003 mL, respectively. This study enriches understanding of ventilator sharing strategy, emphasizing the need for careful selection. DMV, offering individualization while maintaining circuit continuity, stands out. Findings lay the foundation for robust multiplexing strategies, enhancing ventilator management in crises.

Deterministic positioning and alignment of a single-molecule exciton in plasmonic nanodimer for strong coupling.

Experimental realization of strong coupling between a single exciton and plasmons remains challenging as it requires deterministic positioning of the single exciton and alignment of its dipole moment with the plasmonic fields. This study aims to combine the host-guest chemistry approach with the cucurbit[7]uril-mediated active self-assembly to precisely integrate a single methylene blue molecule in an Au nanodimer at the deterministic position (gap center of the nanodimer) with the maximum electric field (EFmax) and perfectly align its transition dipole moment with the EFmax, yielding a large spectral Rabi splitting of 116 meV for a single-molecule exciton-matching the analytical model and numerical simulations. Statistical analysis of vibrational spectroscopy and dark-field scattering spectra confirm the realization of the single exciton strong coupling at room temperature. Our work may suggest an approach for achieving the strong coupling between a deterministic single exciton and plasmons, contributing to the development of room-temperature single-qubit quantum devices.

Artificial Intelligence in Emergency Trauma Care: A Preliminary Scoping Review.

This study aimed to analyze the use of generative artificial intelligence in the emergency trauma care setting through a brief scoping review of literature published between 2014 and 2024. An exploration of the NCBI repository was performed using a search string of selected keywords that returned N=87 results; articles that met the inclusion criteria (n=28) were reviewed and analyzed. Heterogeneity sources were explored and identified by a significance threshold of P < 0.10 or an I2 value exceeding 50%. If applicable, articles were categorized within three primary domains: triage, diagnostics, or treatment. Findings suggest that CNNs demonstrate strong diagnostic performance for diverse traumatic injuries, but generalized integration requires expanded prospective multi-center validation. Injury scoring models currently experience calibration gaps in mortality quantification and lesion localization that can undermine clinical utility by permitting false negatives. Triage predictive models now confront transparency, explainability, and healthcare ecosystem integration barriers limiting real-world translation. The most significant literature gap centers on treatment-oriented generative AI applications that provide real-time guidance for urgent trauma interventions rather than just analytical support.

Enhanced performance CdZnTe single crystal with few surface damages via solution based annealing

In this study, heat treatments were employed using a CdCl2 solution as the annealing medium to investigate the evolution of internal defects and photoelectric properties of CdZnTe crystals. It was observed that CdCl2 crystals formed on the surface of the annealed crystals, and their size increased exponentially with prolonged annealing time. It could be a medium for Cl transport. The liquid-phase annealing process was found to be gentle, resulting in minimal damage and the absence of large defects migrating or accumulating dislocations and less nano-defects on the crystal surface than sample annealed in vapor condition. After a 30 hour annealing, the infrared (IR) transmittance reached 55%, and the resistivity increased to 1.36×1010 Ω·cm. The presence of Cd2+ facilitated the filling of Cd vacancies (VCd) defects through diffusion reduction, while the diffusion of Cl- introduced complex defect with extra VCd, causing the Fermi level to approach the center of the band gap. Consequently, a high-resistance CdZnTe material was achieved.

Excited state dynamics of Bi3+ centers in cubic Gd2O3

Photoluminescence characteristics of Gd2O3:Bi are studied in the 4.2–800 K temperature range by the time-resolved spectroscopy methods. Purely cubic structure of Gd2O3:Bi is confirmed by XRD. The luminescence of Bi3+(S6) and Bi3+(C2) centers is found to arise from the electron transitions from the emitting level of the triplet excited state of Bi3+, corresponding to the 3P1 → 1S0 transitions of the free Bi3+ ion. Relaxation processes in the triplet excited state of Bi3+ ions do not result in the population of the lowest-energy metastable level. The absence of the radiative transitions, corresponding to the 3P0 → 1S0 transitions of the free Bi3+ ion, explains the short (0.3–2.0 μs) decay time of the triplet emission of Bi3+ even at 4.2 K. The conclusion is made that the fast luminescence decay cannot be caused by the mixing of the metastable and emitting levels of the triplet excited state of Bi3+ by the magnetic field created at the Bi3+ site by the magnetically ordered Gd3+ sublattice. The electron transfer and recombination processes, resulting in the appearance of the photo- and thermally stimulated electron recombination luminescence of Bi3+(S6) and Bi3+(C2) centers under excitation in the Eexc > 4.3 eV energy region, are also discussed. The energy level positions of the Bi3+(S6) and Bi3+(C2) centers in the band gap of Gd2O3 are estimated.

Flow characteristics of dispersed two-phase flows in an 8 × 8 rod bundle

Two-phase flows in rod bundles or tube bundles appear in heat transfer systems. The bundle-average (or one-dimensional) void fraction is a critical parameter in overall system design, performance evaluation, and safety assessment. Accurate bundle-average void fraction prediction requires a precise interfacial momentum transfer term formulated using the distribution parameter and drift velocity, two essential drift-flux parameters in the drift-flux model. The currently utilized modeling approach is based on the distribution parameter and drift velocity determined together through drift-flux plots. This results in possible compensation errors between the distribution parameter and drift velocity in the model validation process. The independent validation of the constitutive equations for the distribution parameter and drift velocity has been challenging due to experimental difficulty in measuring detailed two-phase flow structures in rod bundles. The present study proposes an approximation methodology to obtain subchannel average two-phase flow parameters using local two-phase flow data measured at two local points: the subchannel center and minimum gap center in a rod bundle. The distributions of subchannel average two-phase flow parameters are invaluable in benchmarking subchannel analysis codes. Comprehensive subchannel average void fraction and gas velocity mappings are given to discuss the effects of gas and liquid velocities, pressure, spacer grid, and developing length on the two-phase flow characteristics in the rod bundle. The bundle-average distribution parameter values calculated by subchannel average two-phase flow parameters are used for independent validation of the constitutive equations of the distribution parameter. The bundle-average drift velocity values back-calculated using the distribution parameter values are also used for independent validation of the constitutive equation of the drift velocity.

Study on the efficient heat transfer mechanism of microchannel pin-fin arrays under low pumping power

The efficient heat transfer with low pressure loss has long been a critical challenge in the microchannel heat sinks (MCHS) design. Further study is required for the quantitative analysis of the longitudinal vortex heat transfer enhancement mechanism. In this research, a microchannel heat transfer experiment and corresponding simulations are conducted. Based on the common Reynolds number range in engineering applications of MCHS, the underlying causes of heat transfer enhancement and pressure loss increase in MCHS with respect to Reynolds numbers is clarified. The results show that when the Reynolds number is 400, the cylindrical wake reduces the synergistic angle between the velocity and the temperature gradient at the streamwise gap, which greatly enhances the heat transfer performance of MCHS. In addition, when the Reynolds number is 900, the early separation of the cylindrical wake vortex leads to a significant reflux near the center of the spanwise gap, which significantly increases the pressure loss. A Different Reynolds number Efficiency Evaluation Criterion (DEEC) is proposed for evaluating the performance of MCHS. It is found that the flow state of cylindrical wake with Reynolds number of 400 has the best heat transfer efficiency. The concept of introducing longitudinal vortices into the pin–fin array can serve as a key guideline in the heat transfer enhancement optimization design of MCHS.

The Determination of the Sensitivity of Refractive Index Sensors

A new approach to determining the sensitivity of refractive index sensors is proposed. It has been shown that relative and absolute sensitivity show different results, and also, for the first time, it is demonstrated that relative sensitivity has advantages over absolute sensitivity. In addition, the influence of the relative width of the photonic band gap and the difference in the refractive indices of the layers on the sensitivity are examined and the corresponding dependences of these parameters are obtained. We propose these parameters as a convenient tool for optimizing the sensitivity of sensors based on defective photonic crystals. Finally, results are obtained regarding the behavior of the defect mode at the center of the photonic band gap of one-dimensional photonic crystals.

Design of highly sensitive temperature sensor based on photonic band gap structure

In this paper, a novel microstrip resonator technique for temperature sensing is proposed, designed, and implemented using a hybrid planar microstrip line and photonic band gap (PBG) structure. To implement the PBG structure of the microstrip line, a microfluidic channel with periodic form is introduced into the substrate and filled with water. The operation principle of the sensor is based on a frequency shift due to the variation in the center of the band gap, which in turn changes with the variation of the permittivity of water, which relates to the temperature. The different empirical expressions describing the complex permittivity with the resonant frequency were carried out. The proposed sensor is simple in design and low cost, which may be applied in different applications at the industrial.

Action mechanism of axial flow on windage loss in open shaft‐type gap with CO2

AbstractThe windage loss in rotor‐stator gap has an important effect on rotating machinery, especially with higher rotational speed and fluid density. However, the mechanism of axial flow on windage loss in open shaft‐type gap is hardly studied in most literature. To clarify it, the influences of axial Reynolds number Reu and rotational Reynolds number Reω on skin friction coefficient Cf are investigated, and flow characteristics are analyzed with different gap geometry, radius ratio η. First, the results reveal that the Cf remains constant when Reu is less than 2.8 × 104 and increases rapidly as Reu when Reu ≥ 2.8 × 104, which indicates that the effect of axial velocity u on Cf is negligible for low Reu. The positive relative deviation Δ suggests that the axial flow makes windage loss and Cf rise. Besides, a larger number of Taylor vortexes fill with gap when the effect of the centrifugal force is larger than that of the inertial force, but they gradually disappear as Reu. Subsequently, the Cf and Δ increase as η, highlighting that the effect of u on windage loss and Cf is more prominent for larger η. The fact that vorticity near walls is larger than that at the center of gap reveals that windage loss arises from the interaction between walls and fluid rather than the dissipation with fluid itself. Finally, the model of Cf in shaft‐type gap is proposed in different Reω ranges based on numerical results, and the maximum sum of squares error of 1.02 × 10−5 and minimal R2 of 0.969 satisfy the requirement of fitting accuracy and indicate that the fitting model can accurately predict Cf. The conclusions significantly help predict windage loss in open shaft‐type gap with axial flow, and further improve the design for generators of supercritical CO2 turbine‐alternator‐compressor unit.

Inclusive Education Practices: Fostering an Accessible Learning Environment for Diverse Learners

Inclusive education, focusing on creating an accessible learning environment for diverse learners, is a crucial aspect of contemporary educational practices. This journal article explores the implementation of inclusive education practices and their impact on fostering a learning environment that accommodates the needs of students with diverse abilities, backgrounds, and learning styles.&#x0D; The background of the research emphasizes the global shift towards inclusive education as an approach to address the diverse needs of learners in mainstream educational settings. The research gap centers around the need for a comprehensive understanding of the practical strategies and interventions that contribute to the successful implementation of inclusive practices.&#x0D; The urgency of this research lies in the importance of providing equitable educational opportunities for all students, regardless of their differences. The article reviews previous studies to identify successful inclusive education models, challenges faced, and the innovative approaches adopted by educators and institutions.&#x0D; The novelty of the article lies in its in-depth analysis of inclusive education practices, shedding light on the pedagogical, social, and institutional factors that contribute to creating an inclusive learning environment. It discusses the role of teacher training, curriculum adaptation, and the use of assistive technologies in promoting inclusivity.&#x0D; The objective of the research is to offer insights into the effective implementation of inclusive education practices and their positive outcomes on diverse learners. The study aims to benefit educators, policymakers, and practitioners by providing evidence-based recommendations for creating inclusive learning environments that foster the holistic development of all students. Overall, the article contributes to the ongoing discourse on inclusive education and its significance in promoting educational equality and social integration.

Improved thermal stability and quantum efficiency of novel cyan phosphors toward full-visible-spectrum lighting

Highly efficient cyan phosphors have been identified as essential components in addressing the cyan gap present in the emission spectra of traditional white light emitting diodes. Here, we report novel Ba4Ca1-yLay(PO4)3Cl:Eu2+ (y = 0–0.15) phosphors with broadband cyan emission based on an efficient and positive cationic heterovalent substitution strategy. Under the near ultraviolet excitation, the quantum yield and thermal stability are progressively enhanced by introducing La3+ to replace the Ca2+ ions, owing to the band gap and killer centers engineering. The Ba3.92Ca0.9La0.1(PO4)3Cl:0.08Eu2+ phosphor exhibits a pronounced emission band in the cyan-green spectral range with a high internal quantum efficiency of 88.0% and an impressive external quantum efficiency of 72.1%. The utilization of Ba3.92Ca0.9La0.1(PO4)3Cl:0.08Eu2+ as the cyan emitting component in the fabrication of white light-emitting diode (WLED) has demonstrated remarkable advancements in the color rendering index value, emphasizing the potential of these phosphors for future implementation in the next generation full-visible-spectrum WLED lighting. Our findings offer evidences that defect engineering techniques effectively enhance the performance of light-emitting diode (LED) phosphors.

Effects of Gap Size on Natural Regeneration in Picea asperata Forests of Northern China

Our study aimed to assess the impacts of varying forest gap sizes on the density, growth, and spatial patterns of seedlings and saplings in spruce (Picea asperata) forests in the Saihanba region, Hebei Province, China. Twenty-four forest gaps were surveyed and categorized into six classes based on the gap size. A one-way ANOVA was used to compare differences in the density, height, and ground diameter of seedlings and saplings among six gap classes. Ripley’s K function was used to explore the spatial patterns of regeneration establishment in each class. The findings of our study indicated that the forest gap size did not significantly influence the density of seedlings or the ground diameter growth of saplings, whereas it significantly influenced the height growth of saplings. In smaller gaps, natural regeneration occurred primarily in the gap edges. As the gap size increased, the natural generation began to shift from the edge areas to the gap centers. Large forest gaps had the highest percentages of random distribution patterns across all spatial scales. Aggregated distributions were observed at distances less than 1 m in all gap size classes, whereas uniform distributions tended to occur in the small gaps at distances of 2–4 m. Our findings indicated that larger forest gaps, ranging from 60 to 120 m2, were more conducive to spruce regeneration. The results can inform the development of targeted strategies for understory afforestation and the artificial promotion of natural regeneration in spruce forests.

Investigation of Taylor bubble dynamics in annular conduits with counter-current flow

This study numerically investigates counter-current slug flow by considering the motion of a Taylor bubble in annular conduits with downward-flowing liquids using the Volume-of-Fluid method implemented in the commercial computational fluid dynamics software ANSYS Fluent (Release 19.2). The translational velocity of a counter-current ascending or co-current descending Taylor bubble in vertical concentric annuli and the corresponding distribution parameter (C0) are analyzed. The latter is correlated in terms of Eötvös number (Eo) and inverse viscosity number (Nf) within the range of Eo between 40 and 400 and Nf between 40 and 320. The proposed correlation provides an accurate fit to the numerical data with an average error of 2.64%, and is successfully compared with published numerical findings. In general, the smooth and stable shape of the bubble is disrupted as the counter-current flow velocity (Frl) increases above a critical value, leading to the formation of surface waves and the displacement of the bubble tip away from the annular gap center and towards the outer pipe. C0 increases with Eo and Nf, plateauing at high values of Eo. The effects of annulus inclination (θ) and eccentricity (ε) on bubble rise velocity are examined within the common range of θ and ε encountered during the drilling of oil, gas, or geothermal wells, i.e. 0° ≤ θ ≤ 60° and 0 ≤ ε ≤ 0.7, and their impact on the C0. The increasing Frl and θ lead to a streamlined bubble with pointed nose and thus a reduction in the wrap angle (θwrap), ultimately leading to reduced drag compared to the vertical annulus case and a decrease in C0. As the ε increases, which is accompanied by an increase in the degree of bubble eccentricity, the corresponding C0 decreases. For a constant Eo = 100 and Nf = 160 with inclination angle of θ = 40°and eccentricity of ε = 0.5, the C0 < 1 is observed.

Streamer-induced kinetics of excited states in pure N2: I. Propagation velocity, and vibrational distributions of N2(C) and N(B) states

The emission spectra of a streamer discharge in pure nitrogen provide an important tool for investigating the fundamental kinetics of excited electronic states of N2 and benchmark data for validating advanced kinetic schemes for numerical models. In this work, we characterize a streamer monofilament developed in a dielectric barrier discharge configuration, including electrical characteristics, time-resolved images and N2/N emission spectra, all acquired with nanosecond temporal resolution. Time-resolved images and emission characteristics provide clear evidence of the formation of a cathode-directed streamer and allow determining the streamer propagation velocity and the typical values using the intensity ratio of nitrogen spectral bands in the center of the discharge gap. We also measure the vibrational distributions of the N2(C, 0–4) and N(B, 0–2) states. The population of N2(C, 0–4) state, initially formed by energetic electrons in the streamer head, changes later significantly due to the decrease in the mean energy and concentration of the streamer channel electrons. After a few tens of nanoseconds, the electron-impact excitation rate of N2(C) becomes negligible compared to its population by the N2() + N2() pooling. The experimental findings are supported and consistent with the 0D state-to-state kinetic model results and reveal the participation of high vibrational levels of N2() in the pooling reactions.