Cemented Paste Backfill Research Articles

Environmental disposal of sulphide-rich and desulfurized tailings: Thickening, rheological, mechanical, and leaching performance

The surface disposal of sulphide-rich tailings (compared to ordinary tailings, it contains many sulphides) will cause environmental and groundwater pollution, and it is an eco-friendly method to prepare cemented paste backfill (CPB) from sulphide-rich tailings and backfill it into underground goafs. However, the thickening performance of sulphide-rich and desulfurized tailings is unclear, the sulphide-rich CPB strength cannot meet the standard. Therefore, a comprehensive study was conducted on its thickening performance through settling columns and dynamic thickening experiments, mechanics, and leaching tests were also conducted. The optimal flocculant conditions with different sulphide contents were obtained through settling column experiments. Meanwhile, it was found that turbidity and initial settling rate (ISR) were linearly related to tailings feeding concentration. Due to the higher specific gravity of sulphide-rich tailings, under different flocculation conditions, the higher the sulphide content, the higher the concentration, and there is a linear correlation between sulphide content and concentration. The results of dynamic thickening show that rake-shearing can improve the concentration and the shear yield stress, both of which increase rapidly at first and then slowly with the extension of shearing time. A logarithmic model of concentration based on shear yield stress was established. The unconfined compressive stress of the CPB prepared from tailings desulfurized to 20.7 wt%-S (S20.7) is much higher than that of 30.7 wt%-S sulphide content tailings (S30.7), which can meet the backfilling requirements. The concentration of metal ions in the soaking solution of S20.7 CPB is higher, and the environmental impact is small. Finally, it is recommended to choose S20.7 for backfilling. The study is significant for revealing the thickening and mechanical performance evolution of sulphide-rich tailings and environmental protection disposal.

Alkali activation of blast furnace slag using Bayer red mud as an alternative activator to prepare cemented paste backfill

Alkali-activated materials (AAMs) are increasingly used in mine backfilling as substitutes for Ordinary Portland Cement (OPC) due to their superior performance and environmental advantages. However, the high cost of commercially available alkaline activators such as sodium hydroxide and sodium silicate limit the widespread use of AAMs. This study investigates the use of Bayer red mud (RM) as an alternative activator to sodium hydroxide (SH), with blast furnace slag (BFS) as the precursor. Cemented paste backfill (CPB) was prepared by replacing 75% of OPC with these AAMs, combined with tailings and water. The results showed that CPB made with AAMs exhibited significantly better mechanical properties, with a 57% to 94% increase in uniaxial compressive strength (UCS) at 28 days compared to CPB made with OPC. Even with an RM-to-SH ratio of 2:1, UCS improved by 3% over SH-only samples. Analysis of hydration products and microstructure revealed that RM provides more alkaline ions, enhancing the formation of calcium-alumino-silicate-hydrate (C-A-S-H) and effectively filling capillary pores. This study demonstrates a cost-effective, environmentally friendly approach for producing AAMs, highlighting RM's potential as a sustainable alternative to commercial activators for CPB applications.

The exploration of effect for nano-Al2O3 on solid waste based superfine tailings cemented paste backfill: Pyrolysis property, hydration mechanism and environmental risk

Resource utilization of superfine tailings has become a key research direction in filling mining. This study analyzes the mechanical properties, pyrolysis mechanism and hydration mechanism of nano-Al2O3(NA)-doped solid waste based superfine tailings cemented paste backfill (SWSCPB) by multiple microscopic characterization methods and pyrolysis kinetic theory. The results show that the main temperature interval for the pyrolysis of SWSCPB to happen is 280–900 °C, which is divided into two stages of dehydroxylation and decarbonization. The apparent activation energy(E) and pre-index factor(A) of pyrolysis are higher than those of NA0 and NA2 at 1 % NA dosage, indicating that NA increases the energy barrier of pyrolysis, the percentage of activated molecules, and the collision probability of hydration products in SWSCPB, but decreases due to agglomeration at exceeds 1 % NA dosage. NA can enhance macroscopic strength of SWSCPB, with the highest strength at 1 % NA dosage. Compared with NA0 and NA2, more hydration products such as AFt and C-(A)-S-H are present in NA1, and the distribution of Q2 and Q4 in C-(A)-S-H is more pronounced, with a higher degree of polymerization, a stronger tendency for the conversion of non-bridging to bridging oxygen bonds, and fewer pores in the microstructure of SWSCPB. The NA dosage can provide more nuclei for the formation of AFt, C-(A)-S-H in SWSCPB, and can also promote the replacement of Si by Al for the conversion of C-S-H to C-(A)-S-H with higher polymerization. In addition, the leaching risk and mechanism of heavy metal ions from SWSCPB are preliminarily explored in combination with leaching experiments. The results provide new insights and guidance for the application of SWSCPB in filling mining under cleaner production targets.

Geomechanical aspects of stabilizing arsenic trioxide roaster waste in cemented paste backfill at the Giant Mine, Canada

Giant Mine, an abandoned gold mine near Yellowknife in the Northwest Territories of Canada, generated significant arsenic trioxide roaster waste (ATRW) during its operations, posing a substantial environmental hazard. This study explored the feasibility of stabilizing ATRW by incorporating it into cemented paste backfill (CPB). Using response surface methodology (RSM), CPB samples with varying mixing ratios were analyzed to identify key parameters influencing strength. Unconfined compressive strength (UCS) tests assessed physical stability, while saturated hydraulic conductivity and computed tomography (CT) analyses examined the microstructure of the CPB. The results revealed that CPB samples prepared with general use (GU) cement exhibited significantly higher strength than those with a GU and lime kiln dust (LKD) mixture. Binder and solid contents were identified as the most critical factors influencing UCS, with binder content having a more pronounced influence. Curing time was found to be non-significant. Higher binder and solid contents correlated with higher UCS values in the CPB samples. The addition of 10% wt. ATRW reduced the UCS by over 30%, particularly in samples with lower binder and solid contents. Although microstructure differences were not evident in saturated hydraulic conductivity tests, CT scans showed increased formation of high-density arsenic-containing materials in samples with the highest UCS, especially those using GU binder. These findings suggest that optimizing binder and solid contents is crucial for enhancing CPB strength and effectively stabilizing ATRW.

Sulphate influence on strength development of cemented paste backfill with superplasticizer under field-like curing conditions

This study investigates the impact of sulphate on the strength development of cemented paste backfill (CPB) with polycarboxylate ether-based superplasticizers (PES) under curing conditions mimicking real field environments. These conditions include thermal (T, non-isothermal field temperature), hydraulic (H, drainage), mechanical (M, overburden stress), and chemical (C, PES, sulphate ions) factors. CPB samples with varying sulphate and PES contents were examined through mechanical and microstructural tests under these THMC conditions. The findings reveal that traditional methods for assessing sulphate influence on CPB strength, typically under standard lab conditions, do not adequately capture the mechanical response of CPB structures to sulphate in field scenarios. Real field curing conditions such as temperature, drainage, and stress significantly affect CPB’s mechanical response to sulphate. CPB samples incorporating PES and sulphate show notable improvements in early-age strength, emphasizing the beneficial role of elevated temperatures and the complex relationship between drainage, sulphate, and strength development. Elevated curing temperatures counterbalance sulphate's negative effects, boosting initial strength, while drainage conditions play a critical role in strength development by facilitating the removal of sulphate ions and reducing capillary water. Additionally, stress application at the start of curing aids solid particle rearrangement, promoting the release of free water and enhancing mechanical strength. The competitive adsorption between sulphate ions and PES on the cementitious matrix influences the dispersion of particles and strength development. This research offers crucial technical insights for designing durable CPB mixes suited to various on-site curing conditions, particularly enhancing initial strength across diverse field curing scenarios.

Study on the properties of alkali-activated ferrochrome slag paste filling materials prepared from multiple industrial solid wastes

ABSTRACT The enormous utilization potential of industrial solid waste in cemented paste backfill (CPB) materials has attracted considerable interest. To solve the treatment challenges of ferrochrome slag (FS), a green ferrochrome slag cemented paste backfill materials (FS-CPB) composed of FS, desulfurization gypsum (DG) and granulated blast furnace slag (GBFS) was proposed in the study. The setting time, slump, uniaxial compressive strength (UCS), microstructure and leaching behavior of FS-CPB were systematically investigated. The results indicated that FS and DG showed retarding properties, while the setting time first decreased and then increased with the increase of polycarboxylate superplasticizers (PCE) and sodium silicate dosage. The slump was positively correlated with FS and sodium silicate dosage. However, the addition of DG and PCE can improve the fluidity properties. The optimum UCS values (3 d: 0.92 MPa; 7 d: 2.43 MPa; 14 d: 3.19 MPa; 28 d: 4.58 MPa) was obtained with 6% sodium silicate. Moreover, the primary hydration products of FS-CPB were ettringite, C-S-H gels and N-A-S-H gels. The leaching concentrations of total Cr and Cr(VI) satisfied the Class Ι water quality standard limits (≤1.5 mg∙L−1) in GB 8978–1996 and Class III water quality standard limits (≤0.05 mg∙L−1) in GB 14,848-2017, respectively. The research results in this paper can provide new options for cement substitutes in mining companies and guide the large-scale application of FS.

Spatial evolution characteristics of the mechanical properties of gangue-cemented paste backfill with high-water-content materials: an experimental investigation

ABSTRACT The mechanical properties of cemented paste backfill (CPB) directly determine the effect of backfilling in coal mining. However, the current studies on the mechanical properties of CPB are all based on standard cylinder or cube specimens, which cannot accurately characterise the distribution of mechanical properties in different spatial positions of CPB in situ. In addition, high-water-content material (HWM) has developed rapidly as a new binder in recent years. Therefore, in this paper, the uniaxial compressive strength (UCS) and elastic modulus of CPB with gangue as the aggregate and HWM as the binder (GHW-CPB) were investigated under different gangue particle sizes. The following conclusions were drawn: (1) The spatial evolution and distribution characteristics of mechanical properties of GHW-CPB are analysed. (2) The spatial evolution regression models of mechanical properties of GHW-CPB are established. (3) We improved the GHW-CPB spatial evolution regression models for mechanical properties due to their limitations and confirmed its validity and rationality. Through the research results of this paper, the failure position of the CPB in the goaf can be accurately predicted, so that manual interventions can be carried out in the vulnerable areas in advance to reduce the risk of coal mining production.

Hydration process and fluoride solidification mechanism of multi-source solid waste-based phosphogypsum cemented paste backfill under CaO modification

The large-scale, environmentally friendly utilization of phosphogypsum (PG) remains a global challenge. PG cemented paste backfill (PCPB) is a promising method to manage PG, but using ordinary Portland cement as the binder has drawbacks such as high cost, low mechanical strength, and high fluoride leaching risk. This paper presents a multi-source solid waste-based PCPB (MPCPB) material that enhances mechanical properties and reduces fluoride leaching risks. In MPCPB, industrial waste residues like steel slag (SS) and ground granulated blast furnace slag (GBFS) are used as precursors (SS: GBFS = 1:2). Additionally, 4–8 wt% CaO (relative to the dry weight of PG) is used as a neutralizing modifier and alkaline activator. The results indicate that an optimal amount of CaO can neutralize the residual acidity of PG, provide sufficient Ca(OH)2 for MPCPB hydration, and react with PG to produce significant amounts of AFt. Furthermore, CaO promotes the geopolymerization reaction between SS and GBFS, generating more calcium silicate hydrate (C-S-H) and calcium aluminate silicate hydrate (C-A-S-H) gels. Fluoride stabilization in MPCPB results from synergistic effects involving hydration reactions, complexation, ionic mobility, rearrangement, and physical adsorption. Notably, CaO enhances the conversion of free fluoride ions into stable compounds like fluorapatite, fluorite (CaF2), [AlF6]3-, and [FeF6]3- complexes. This approach offers a cost-effective, environmentally friendly, and efficient solution to the PG stockpiling challenge.

Study of hydrophobic cemented paste backfill (H-CPB) to prevent sulphate attack

One of the challenges encountered in mining is acid mine drainage (AMD) in sulphurous ores in response to rainfall and groundwater. CPB one of the most prevalent waste management systems addresses this issue today. Nevertheless, in the long term, the concretion in CPB may become ineffective because of external factors, such as groundwater and rainfall. The relevant sources in the literature have no mention of AMD problems that may occur in the long term with CPB, particularly in metallic ores. Most studies indicate that the issue which can be prevented by using cement. However, due to the destructive effects of nature, cement alone would be insufficient. Consequently, the research's principal aim is to form CPB hydrophobic, thereby reducing the interaction between CPB and water. In the study, stearic acid was chosen as the hydrophobic agent and application method to the CPB and the changes in load-bearing capacity were studied. Specimens were tested by ion chromatography, X-ray diffraction (XRD), elemental analysis by combustion, water absorption, uniaxial compressive strength (UCS), and scanning electron microscopy (SEM). There was a decrease in the load-bearing capacity while gaining the hydrophobic properties of the material. The results confirm the validity of the selected agent and method and reveal that the effect of sulphate decreases with increasing hydrophobicity yet, there is no significant decrease in the 7, 14, and 28-day UCS tests. The optimal results were achieved when Stearic Acid (SA) was used at a concentration of 1.25 % for 7 % Portland cement and 0.75 % for 11 % Portland cement, with a UCS strength of 1.223 and 2.008 MPa, respectively. The expected benefit of stearic acid was realized as the water absorption value of the reference sample was 2.50 times higher in 7 % cement and 4.25 times higher in 11 % cement than the same value in Hydrophobic Cemented Paste Backfill (H-CPB). These results indicate that AMD formation can be prevented in the future with H-CPB. The results demonstrate that stearic acid, with the new methodology, forms the CPB hydrophobic, while only an acceptable strength loss was observed. Additionally, the outcomes point out that the methodology adopted does not consider a significantly adverse impact on hydration phase of concretation and can be utilized as an environmentally friendly backfilling method, thereby being evaluated as the cleaner backfilling for further CPB applications.

Effect of sodium dodecyl sulphate on the rheological and carbon sequestration properties of cemented paste backfill with CO2 injection

Cemented paste backfill (CPB) is a technology that has a positive impact on both the environment and mining safety. In recent years, it has been widely applied and developed. To improve the carbon sequestration efficiency of CPB, air-entraining agent addition to CO2-injected CPB (CO2-CPB) has been proposed. However, the influence of air-entraining agents on the rheological and carbon sequestration properties of CO2-CPB has not been investigated to date. Therefore, sodium dodecyl sulphate (SDS), an air-entraining agent, was selected in this study, and the rheological and carbon sequestration properties of CO2-CPB added with SDS were comprehensively investigated. CO2-CPB samples with 0.0‰, 0.5‰, 1.0‰, and 1.5‰ SDS were prepared, and the rheological parameters (yield stress and viscosity) were tested after curing for 0, 0.25, 1, and 2 h. Gas content testing, microscopic analysis, and zeta potential measurements were performed. The results show that SDS addition decreased the yield stress and viscosity of CO2-CPB at 0–1 h; however, the yield stress and viscosity increased at 2 h. SDS addition significantly improved the carbon sequestration performance of CO2-CPB. The findings of this study have important implications for carbon sequestration development in CPB and solid waste utilisation.

Hydration and Hardening Properties of High Fly-Ash Content Gel Material for Cemented Paste Backfill Utilization.

As more and more mines utilize the cemented paste backfill (CPB) mining method, the demand for reducing backfill cost and carbon footprint is increasing and becoming more critical. In this work, a new backfill gel binder made with 40 wt.% of low-quality Class F fly ash (FCM) is proposed to replace ordinary Portland cement (OPC). The binder hydration and gel hardening properties were experimentally investigated through X-ray diffraction, Mercury intrusion porosimetry, uniaxial compression, and thermogravimetric analysis. Three different mine tailings were used to verify the FCM's applicability. Results show that the strength performance of FCM-CPB is 72% of that of OPC-CPB, while FCM production cost is almost less than half of OPC. The hydration process of the FCM-CPB can be divided into five stages, and the main hydration products are ettringite and gel-like hydrates. The 31.2% porosity of FCM-CPB at 28-day curing is higher than that of 7-day curing, while the average pore size is lower, and the structure is denser. The FCM can meet the strength requirement of three different mine tailings regarding different subsequent filling and cut-and-fill mining methods. The proposed FCM provides a feasible alternative with economic and environmental benefits.

Study on the Rheological and Thixotropic Properties of Fiber-Reinforced Cemented Paste Backfill Containing Blast Furnace Slag

Study on the Rheological and Thixotropic Properties of Fiber-Reinforced Cemented Paste Backfill Containing Blast Furnace Slag

Experimental study on the macroscopic and microscopic properties of cement paste backfill after treatment with carbon dioxide carbonize filling slurries during the mixing process

Introducing CO2 during the mixing process of filling slurry for wet carbonation enables simultaneous carbonation and hydration reactions of the carbonated filling slurry (CSL). This study evaluates the microstructural evolution and strength development of carbonated cemented paste backfill (CCPB) under different carbonation times, and discusses the carbonation products and carbon sequestration of CCPB. The results reveal that introducing 99% pure CO2 at a flow rate of 1 L/min for 10 min into the filling slurry in a non-sealed container effectively optimizes the microscopic pore structure and mechanical properties of CCPB, achieving a carbon sequestration rate of 6.42%. Short-term carbonation leads to a continuous decrease in the T2 relaxation signal of CSL in the early hydration stage, enhancing pore structure by converting secondary pores to micropores. The main carbonation product is calcite crystalline CaCO3, which forms a dense carbonation layer on the surface of the tailings particles. However, prolonged carbonation results in the formation of microscopic pore encapsulation layer, hindering further CO2 diffusion, reducing carbonation efficiency, and deteriorating the mechanical properties of CCPB. With a carbonation time of 10 min, the UCS and EM of CCPB with different cement-to-tailings ratios show significant improvement, and the specimens exhibit lower fragmentation and fewer secondary cracks, maintaining better integrity after failure. In conclusion, the wet carbonation of filling slurry not only enhances the strength of the filling material but also achieves the reutilization of gaseous and solid wastes through carbon sequestration filling method, providing an efficient and eco-friendly solution for mine backfilling.

Multiphysical testing of strength development of cemented paste backfill containing superplasticizer

Current laboratory procedures for curing and testing the mechanical strength of cemented paste backfill (CPB) do not take into account the complex Multiphysics (thermal, T; hydraulic, H; mechanical, M; chemical, C) processes that CPB structures are subjected to in the field. This oversight can lead to unreliable measurements and unsafe designs. In this study, a multiphysical curing and testing procedures for CPB with superplasticizer (CPB-PES) has been developed to evaluate its strength development under THMC curing conditions close to those encountered in the field. The obtained results demonstrated that the strength development of CPB-PES is greatly affected by the THMC factors and their interactions. The contributions of each one of the investigated THMC factors on the strength are not equally similar and greatly depend on the interaction between these factors and curing time. CPB samples with 0.125 % PES that underwent drainage during THMC curing showed a strength increase of up to 809 % after 28 days of curing, compared to the control samples. The strength of CPB-PES samples cured under THMC can be up to 57 % higher than that of samples cured under THC conditions. The results indicate a significant interaction between thermal (T; elevated field curing temperature) and chemical (C; superplasticizer and cement hydration) factors, between chemical (C) and mechanical (M; field curing stress) factors, as well as between thermal and mechanical factors. The influence of the mechanical factor on strength development was observed to be less pronounced compared to the impact of chemical and thermal factor, and is reduced at elevated curing temperatures. The findings underscore the critical importance of accounting for field-relevant THMC factors and their interactions in the determination of the CPB-PES strength development, which is essential for the design of safer and more economical CPB structures, ultimately enhancing mine productivity and safety.

Improvement of Fluidity and Long-term Strength of Cemented Paste Backfill with Low Calcium Fly-ash

ABSTRACT Waste rocks and tailings are widely applied materials in underground metal mines to backfill mined-out areas. To test the effect of low calcium fly ash on slurry fluidity and long-term strength of cemented paste backfill, orthogonal experiments of backfill proportions with variable levels of waste, tailing, fly ash, water and their combinations were carried out. Results show that slurry slump is most sensitive to mass concentration, and slurry fluidity is optimal when fly ash-cement ration is 1:1. The longterm strength of cemented paste backfill after curing for 56 days is significantly affected by cement-(tailing + waste) ratio, and slightly evolves regardless of fly ash-cement ratio. Fly ash promotes the generation of active silicon oxide and aluminum oxide, which fills the pores within the backfill. The optimal proportion of cemented paste backfill is 77% mass concentration, 8:2 tailing–waste ratio, 1:30 cement-(tailing + waste) ratio and 1:1 fly ash–cement ratio. The correlative slurry slump and long-term backfill strength meet the requirement of pumping and backfill mining. Additionally, an industrial scale loop pumping test of backfill slurry shows the pipeline transportation resistance is 4 kPa/m, pipeline diameter is optimal at 150 mm, and flow rate is optimal at 90–100 m3/h. The experiment confirms that proper addition of low calcium fly ash is conducive to improve the slurry fluidity and long-term strength of cemented paste backfill.

Recycling arsenic-containing bio-leaching residue after thermal treatment in cemented paste backfill: Structure modification, binder properties and environmental assessment

Recycling arsenic-containing bio-leaching residue after thermal treatment in cemented paste backfill: Structure modification, binder properties and environmental assessment

Particle aggregation and breakage kinetics in cemented paste backfill

Particle aggregation and breakage kinetics in cemented paste backfill

Mechanical response, damage constitutive and failure localization characteristics of structural backfills composed of matrixes with different mechanical properties

To investigate the mechanical properties, damage progressivity characteristics, and failure modes of layered cemented paste backfills (LCPB), the unconfined compressive strength (UCS) tests were carried out on LCPB and supplemented with the digital image correlation (DIC) method. The damage characteristics were revealed from the energy perspective, and the damage constitutive equation was established. The results show that the ratio of yield stress to UCS increased with the increase of the c/t ratio and h/H ratio. The intersection point of the dissipation energy and the elastic energy curves could be conservatively considered as a sign that the LCPB is about to enter the accelerated damage stage. The appearance of the intersection point will be earlier with decreasing c/t ratio and increasing h/H ratio. The damage rate curves exhibited an evolutionary characteristic of increasing and then decreasing, and the maximum damage rate gradually decreased with decreasing c/t ratio and increasing h/H ratio; The failure mode showed a significant localization characteristic, and the damage of LCPB was mainly caused by tensile stress generated in the horizontal direction. The findings could provide guidance for the design of LCPB.

Study on the leaching of harmful elements and pore characteristics of phosphogypsum-based cemented paste backfill under multi-field coupling interaction

Study on the leaching of harmful elements and pore characteristics of phosphogypsum-based cemented paste backfill under multi-field coupling interaction

Effects of superabsorbent polymer on mechanical properties of cemented paste backfill and its mechanism evolution

Cemented paste backfill (CPB) technology offers advantages in safety, efficiency, environmental protection, and economy, and it has been increasingly applied in mines worldwide. The mechanical properties of CPB are critical indicators of the quality of the backfill. Traditionally, cement is used as the primary binding material; however, its high cost and the resulting inconsistent strength of CPB present challenges. Superabsorbent polymer (SAP) has been extensively used in cement-based materials due to its beneficial effects on mechanical properties, shrinkage, and durability. In this study, SAP is incorporated as an additive, with the unclassified tailings from an iron ore mine used as the research material to prepare SAP-enhanced CPB. The study focuses on SAP content, the cement-to-tailings ratio, and curing time as the main influencing factors. Uniaxial compressive strength (UCS) tests, thermogravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM) tests were conducted on CPB specimens to investigate the mechanical characteristics of SAP-enhanced CPB and to explore the influencing mechanisms of SAP on CPB. The results indicate that CPB strength initially increases and then decreases with rising SAP content, reaching a maximum UCS value at 0.2 % SAP content. XRD, TGA, and SEM results show that SAP affects the formation of hydration products and the pore structure of CPB. Specifically, when the SAP content is below 0.2 %, increasing SAP content leads to a denser pore structure and lower porosity, which correlates with higher UCS values. There is an exponential decrease in UCS with increasing porosity. Additionally, a quadratic relationship exists between UCS and the amount of calcium hydroxide, a key hydration product in CPB specimens. These findings provide valuable insights for improving the mechanical properties of CPB and serve as a reference for designing the strength of backfill in similar mining applications.