Cemented Paste Backfill Research Articles

Geomechanical aspects of stabilizing arsenic trioxide roaster waste in cemented paste backfill at the Giant Mine, Canada

Giant Mine, an abandoned gold mine near Yellowknife in the Northwest Territories of Canada, generated significant arsenic trioxide roaster waste (ATRW) during its operations, posing a substantial environmental hazard. This study explored the feasibility of stabilizing ATRW by incorporating it into cemented paste backfill (CPB). Using response surface methodology (RSM), CPB samples with varying mixing ratios were analyzed to identify key parameters influencing strength. Unconfined compressive strength (UCS) tests assessed physical stability, while saturated hydraulic conductivity and computed tomography (CT) analyses examined the microstructure of the CPB. The results revealed that CPB samples prepared with general use (GU) cement exhibited significantly higher strength than those with a GU and lime kiln dust (LKD) mixture. Binder and solid contents were identified as the most critical factors influencing UCS, with binder content having a more pronounced influence. Curing time was found to be non-significant. Higher binder and solid contents correlated with higher UCS values in the CPB samples. The addition of 10% wt. ATRW reduced the UCS by over 30%, particularly in samples with lower binder and solid contents. Although microstructure differences were not evident in saturated hydraulic conductivity tests, CT scans showed increased formation of high-density arsenic-containing materials in samples with the highest UCS, especially those using GU binder. These findings suggest that optimizing binder and solid contents is crucial for enhancing CPB strength and effectively stabilizing ATRW.

Sulphate influence on strength development of cemented paste backfill with superplasticizer under field-like curing conditions

This study investigates the impact of sulphate on the strength development of cemented paste backfill (CPB) with polycarboxylate ether-based superplasticizers (PES) under curing conditions mimicking real field environments. These conditions include thermal (T, non-isothermal field temperature), hydraulic (H, drainage), mechanical (M, overburden stress), and chemical (C, PES, sulphate ions) factors. CPB samples with varying sulphate and PES contents were examined through mechanical and microstructural tests under these THMC conditions. The findings reveal that traditional methods for assessing sulphate influence on CPB strength, typically under standard lab conditions, do not adequately capture the mechanical response of CPB structures to sulphate in field scenarios. Real field curing conditions such as temperature, drainage, and stress significantly affect CPB’s mechanical response to sulphate. CPB samples incorporating PES and sulphate show notable improvements in early-age strength, emphasizing the beneficial role of elevated temperatures and the complex relationship between drainage, sulphate, and strength development. Elevated curing temperatures counterbalance sulphate's negative effects, boosting initial strength, while drainage conditions play a critical role in strength development by facilitating the removal of sulphate ions and reducing capillary water. Additionally, stress application at the start of curing aids solid particle rearrangement, promoting the release of free water and enhancing mechanical strength. The competitive adsorption between sulphate ions and PES on the cementitious matrix influences the dispersion of particles and strength development. This research offers crucial technical insights for designing durable CPB mixes suited to various on-site curing conditions, particularly enhancing initial strength across diverse field curing scenarios.

Study on the properties of alkali-activated ferrochrome slag paste filling materials prepared from multiple industrial solid wastes

ABSTRACT The enormous utilization potential of industrial solid waste in cemented paste backfill (CPB) materials has attracted considerable interest. To solve the treatment challenges of ferrochrome slag (FS), a green ferrochrome slag cemented paste backfill materials (FS-CPB) composed of FS, desulfurization gypsum (DG) and granulated blast furnace slag (GBFS) was proposed in the study. The setting time, slump, uniaxial compressive strength (UCS), microstructure and leaching behavior of FS-CPB were systematically investigated. The results indicated that FS and DG showed retarding properties, while the setting time first decreased and then increased with the increase of polycarboxylate superplasticizers (PCE) and sodium silicate dosage. The slump was positively correlated with FS and sodium silicate dosage. However, the addition of DG and PCE can improve the fluidity properties. The optimum UCS values (3 d: 0.92 MPa; 7 d: 2.43 MPa; 14 d: 3.19 MPa; 28 d: 4.58 MPa) was obtained with 6% sodium silicate. Moreover, the primary hydration products of FS-CPB were ettringite, C-S-H gels and N-A-S-H gels. The leaching concentrations of total Cr and Cr(VI) satisfied the Class Ι water quality standard limits (≤1.5 mg∙L−1) in GB 8978–1996 and Class III water quality standard limits (≤0.05 mg∙L−1) in GB 14,848-2017, respectively. The research results in this paper can provide new options for cement substitutes in mining companies and guide the large-scale application of FS.

Spatial evolution characteristics of the mechanical properties of gangue-cemented paste backfill with high-water-content materials: an experimental investigation

ABSTRACT The mechanical properties of cemented paste backfill (CPB) directly determine the effect of backfilling in coal mining. However, the current studies on the mechanical properties of CPB are all based on standard cylinder or cube specimens, which cannot accurately characterise the distribution of mechanical properties in different spatial positions of CPB in situ. In addition, high-water-content material (HWM) has developed rapidly as a new binder in recent years. Therefore, in this paper, the uniaxial compressive strength (UCS) and elastic modulus of CPB with gangue as the aggregate and HWM as the binder (GHW-CPB) were investigated under different gangue particle sizes. The following conclusions were drawn: (1) The spatial evolution and distribution characteristics of mechanical properties of GHW-CPB are analysed. (2) The spatial evolution regression models of mechanical properties of GHW-CPB are established. (3) We improved the GHW-CPB spatial evolution regression models for mechanical properties due to their limitations and confirmed its validity and rationality. Through the research results of this paper, the failure position of the CPB in the goaf can be accurately predicted, so that manual interventions can be carried out in the vulnerable areas in advance to reduce the risk of coal mining production.

Hydration process and fluoride solidification mechanism of multi-source solid waste-based phosphogypsum cemented paste backfill under CaO modification

The large-scale, environmentally friendly utilization of phosphogypsum (PG) remains a global challenge. PG cemented paste backfill (PCPB) is a promising method to manage PG, but using ordinary Portland cement as the binder has drawbacks such as high cost, low mechanical strength, and high fluoride leaching risk. This paper presents a multi-source solid waste-based PCPB (MPCPB) material that enhances mechanical properties and reduces fluoride leaching risks. In MPCPB, industrial waste residues like steel slag (SS) and ground granulated blast furnace slag (GBFS) are used as precursors (SS: GBFS = 1:2). Additionally, 4–8 wt% CaO (relative to the dry weight of PG) is used as a neutralizing modifier and alkaline activator. The results indicate that an optimal amount of CaO can neutralize the residual acidity of PG, provide sufficient Ca(OH)2 for MPCPB hydration, and react with PG to produce significant amounts of AFt. Furthermore, CaO promotes the geopolymerization reaction between SS and GBFS, generating more calcium silicate hydrate (C-S-H) and calcium aluminate silicate hydrate (C-A-S-H) gels. Fluoride stabilization in MPCPB results from synergistic effects involving hydration reactions, complexation, ionic mobility, rearrangement, and physical adsorption. Notably, CaO enhances the conversion of free fluoride ions into stable compounds like fluorapatite, fluorite (CaF2), [AlF6]3-, and [FeF6]3- complexes. This approach offers a cost-effective, environmentally friendly, and efficient solution to the PG stockpiling challenge.

Effect of sodium dodecyl sulphate on the rheological and carbon sequestration properties of cemented paste backfill with CO2 injection

Cemented paste backfill (CPB) is a technology that has a positive impact on both the environment and mining safety. In recent years, it has been widely applied and developed. To improve the carbon sequestration efficiency of CPB, air-entraining agent addition to CO2-injected CPB (CO2-CPB) has been proposed. However, the influence of air-entraining agents on the rheological and carbon sequestration properties of CO2-CPB has not been investigated to date. Therefore, sodium dodecyl sulphate (SDS), an air-entraining agent, was selected in this study, and the rheological and carbon sequestration properties of CO2-CPB added with SDS were comprehensively investigated. CO2-CPB samples with 0.0‰, 0.5‰, 1.0‰, and 1.5‰ SDS were prepared, and the rheological parameters (yield stress and viscosity) were tested after curing for 0, 0.25, 1, and 2 h. Gas content testing, microscopic analysis, and zeta potential measurements were performed. The results show that SDS addition decreased the yield stress and viscosity of CO2-CPB at 0–1 h; however, the yield stress and viscosity increased at 2 h. SDS addition significantly improved the carbon sequestration performance of CO2-CPB. The findings of this study have important implications for carbon sequestration development in CPB and solid waste utilisation.

Hydration and Hardening Properties of High Fly-Ash Content Gel Material for Cemented Paste Backfill Utilization.

As more and more mines utilize the cemented paste backfill (CPB) mining method, the demand for reducing backfill cost and carbon footprint is increasing and becoming more critical. In this work, a new backfill gel binder made with 40 wt.% of low-quality Class F fly ash (FCM) is proposed to replace ordinary Portland cement (OPC). The binder hydration and gel hardening properties were experimentally investigated through X-ray diffraction, Mercury intrusion porosimetry, uniaxial compression, and thermogravimetric analysis. Three different mine tailings were used to verify the FCM's applicability. Results show that the strength performance of FCM-CPB is 72% of that of OPC-CPB, while FCM production cost is almost less than half of OPC. The hydration process of the FCM-CPB can be divided into five stages, and the main hydration products are ettringite and gel-like hydrates. The 31.2% porosity of FCM-CPB at 28-day curing is higher than that of 7-day curing, while the average pore size is lower, and the structure is denser. The FCM can meet the strength requirement of three different mine tailings regarding different subsequent filling and cut-and-fill mining methods. The proposed FCM provides a feasible alternative with economic and environmental benefits.

Study on the Rheological and Thixotropic Properties of Fiber-Reinforced Cemented Paste Backfill Containing Blast Furnace Slag

Study on the Rheological and Thixotropic Properties of Fiber-Reinforced Cemented Paste Backfill Containing Blast Furnace Slag

Experimental study on the macroscopic and microscopic properties of cement paste backfill after treatment with carbon dioxide carbonize filling slurries during the mixing process

Introducing CO2 during the mixing process of filling slurry for wet carbonation enables simultaneous carbonation and hydration reactions of the carbonated filling slurry (CSL). This study evaluates the microstructural evolution and strength development of carbonated cemented paste backfill (CCPB) under different carbonation times, and discusses the carbonation products and carbon sequestration of CCPB. The results reveal that introducing 99% pure CO2 at a flow rate of 1 L/min for 10 min into the filling slurry in a non-sealed container effectively optimizes the microscopic pore structure and mechanical properties of CCPB, achieving a carbon sequestration rate of 6.42%. Short-term carbonation leads to a continuous decrease in the T2 relaxation signal of CSL in the early hydration stage, enhancing pore structure by converting secondary pores to micropores. The main carbonation product is calcite crystalline CaCO3, which forms a dense carbonation layer on the surface of the tailings particles. However, prolonged carbonation results in the formation of microscopic pore encapsulation layer, hindering further CO2 diffusion, reducing carbonation efficiency, and deteriorating the mechanical properties of CCPB. With a carbonation time of 10 min, the UCS and EM of CCPB with different cement-to-tailings ratios show significant improvement, and the specimens exhibit lower fragmentation and fewer secondary cracks, maintaining better integrity after failure. In conclusion, the wet carbonation of filling slurry not only enhances the strength of the filling material but also achieves the reutilization of gaseous and solid wastes through carbon sequestration filling method, providing an efficient and eco-friendly solution for mine backfilling.

Multiphysical testing of strength development of cemented paste backfill containing superplasticizer

Current laboratory procedures for curing and testing the mechanical strength of cemented paste backfill (CPB) do not take into account the complex Multiphysics (thermal, T; hydraulic, H; mechanical, M; chemical, C) processes that CPB structures are subjected to in the field. This oversight can lead to unreliable measurements and unsafe designs. In this study, a multiphysical curing and testing procedures for CPB with superplasticizer (CPB-PES) has been developed to evaluate its strength development under THMC curing conditions close to those encountered in the field. The obtained results demonstrated that the strength development of CPB-PES is greatly affected by the THMC factors and their interactions. The contributions of each one of the investigated THMC factors on the strength are not equally similar and greatly depend on the interaction between these factors and curing time. CPB samples with 0.125 % PES that underwent drainage during THMC curing showed a strength increase of up to 809 % after 28 days of curing, compared to the control samples. The strength of CPB-PES samples cured under THMC can be up to 57 % higher than that of samples cured under THC conditions. The results indicate a significant interaction between thermal (T; elevated field curing temperature) and chemical (C; superplasticizer and cement hydration) factors, between chemical (C) and mechanical (M; field curing stress) factors, as well as between thermal and mechanical factors. The influence of the mechanical factor on strength development was observed to be less pronounced compared to the impact of chemical and thermal factor, and is reduced at elevated curing temperatures. The findings underscore the critical importance of accounting for field-relevant THMC factors and their interactions in the determination of the CPB-PES strength development, which is essential for the design of safer and more economical CPB structures, ultimately enhancing mine productivity and safety.

Improvement of Fluidity and Long-term Strength of Cemented Paste Backfill with Low Calcium Fly-ash

ABSTRACT Waste rocks and tailings are widely applied materials in underground metal mines to backfill mined-out areas. To test the effect of low calcium fly ash on slurry fluidity and long-term strength of cemented paste backfill, orthogonal experiments of backfill proportions with variable levels of waste, tailing, fly ash, water and their combinations were carried out. Results show that slurry slump is most sensitive to mass concentration, and slurry fluidity is optimal when fly ash-cement ration is 1:1. The longterm strength of cemented paste backfill after curing for 56 days is significantly affected by cement-(tailing + waste) ratio, and slightly evolves regardless of fly ash-cement ratio. Fly ash promotes the generation of active silicon oxide and aluminum oxide, which fills the pores within the backfill. The optimal proportion of cemented paste backfill is 77% mass concentration, 8:2 tailing–waste ratio, 1:30 cement-(tailing + waste) ratio and 1:1 fly ash–cement ratio. The correlative slurry slump and long-term backfill strength meet the requirement of pumping and backfill mining. Additionally, an industrial scale loop pumping test of backfill slurry shows the pipeline transportation resistance is 4 kPa/m, pipeline diameter is optimal at 150 mm, and flow rate is optimal at 90–100 m3/h. The experiment confirms that proper addition of low calcium fly ash is conducive to improve the slurry fluidity and long-term strength of cemented paste backfill.

Recycling arsenic-containing bio-leaching residue after thermal treatment in cemented paste backfill: Structure modification, binder properties and environmental assessment

Recycling arsenic-containing bio-leaching residue after thermal treatment in cemented paste backfill: Structure modification, binder properties and environmental assessment

Particle aggregation and breakage kinetics in cemented paste backfill

Particle aggregation and breakage kinetics in cemented paste backfill

Mechanical response, damage constitutive and failure localization characteristics of structural backfills composed of matrixes with different mechanical properties

To investigate the mechanical properties, damage progressivity characteristics, and failure modes of layered cemented paste backfills (LCPB), the unconfined compressive strength (UCS) tests were carried out on LCPB and supplemented with the digital image correlation (DIC) method. The damage characteristics were revealed from the energy perspective, and the damage constitutive equation was established. The results show that the ratio of yield stress to UCS increased with the increase of the c/t ratio and h/H ratio. The intersection point of the dissipation energy and the elastic energy curves could be conservatively considered as a sign that the LCPB is about to enter the accelerated damage stage. The appearance of the intersection point will be earlier with decreasing c/t ratio and increasing h/H ratio. The damage rate curves exhibited an evolutionary characteristic of increasing and then decreasing, and the maximum damage rate gradually decreased with decreasing c/t ratio and increasing h/H ratio; The failure mode showed a significant localization characteristic, and the damage of LCPB was mainly caused by tensile stress generated in the horizontal direction. The findings could provide guidance for the design of LCPB.

Study on the leaching of harmful elements and pore characteristics of phosphogypsum-based cemented paste backfill under multi-field coupling interaction

Study on the leaching of harmful elements and pore characteristics of phosphogypsum-based cemented paste backfill under multi-field coupling interaction

Effects of superabsorbent polymer on mechanical properties of cemented paste backfill and its mechanism evolution

Cemented paste backfill (CPB) technology offers advantages in safety, efficiency, environmental protection, and economy, and it has been increasingly applied in mines worldwide. The mechanical properties of CPB are critical indicators of the quality of the backfill. Traditionally, cement is used as the primary binding material; however, its high cost and the resulting inconsistent strength of CPB present challenges. Superabsorbent polymer (SAP) has been extensively used in cement-based materials due to its beneficial effects on mechanical properties, shrinkage, and durability. In this study, SAP is incorporated as an additive, with the unclassified tailings from an iron ore mine used as the research material to prepare SAP-enhanced CPB. The study focuses on SAP content, the cement-to-tailings ratio, and curing time as the main influencing factors. Uniaxial compressive strength (UCS) tests, thermogravimetric analysis (TGA), X-ray diffraction (XRD), and scanning electron microscopy (SEM) tests were conducted on CPB specimens to investigate the mechanical characteristics of SAP-enhanced CPB and to explore the influencing mechanisms of SAP on CPB. The results indicate that CPB strength initially increases and then decreases with rising SAP content, reaching a maximum UCS value at 0.2 % SAP content. XRD, TGA, and SEM results show that SAP affects the formation of hydration products and the pore structure of CPB. Specifically, when the SAP content is below 0.2 %, increasing SAP content leads to a denser pore structure and lower porosity, which correlates with higher UCS values. There is an exponential decrease in UCS with increasing porosity. Additionally, a quadratic relationship exists between UCS and the amount of calcium hydroxide, a key hydration product in CPB specimens. These findings provide valuable insights for improving the mechanical properties of CPB and serve as a reference for designing the strength of backfill in similar mining applications.

A novel alkali-slag cemented tailings backfill: Recycling of soda residue and calcium carbide slag

In order to address the safety and environmental concerns associated with high disposal cost and low disposal rate associated with mine tailings, low-cost cemented paste backfills (CPBs) were prepared from solid wastes such as calcium carbide slag (CS), soda residue (SR), ground granulated blast-furnace slag (GGBS) and iron tailings (TA) in this study. The effects of mass concentration of filling slurry, GGBS content, activator dosage, and SR proportion on the mechanical properties of CPBs were studied. The results showed that a flow of 235.8 mm and 28-d compressive strength of 2.3 MPa for the freshly mixed slurry could be attained with 75 % mass concentration, 14 % GGBS content, an activator-to-binder ratio of 0.4, and a CS-to-SR ratio of 3:7. The strength of CPBs first increased and then decreased with the increasing of activator dosage or SR proportion contents, and reached the optimal value for the activator-to-binder ratio of 0.4 and SR of 70 % – 75 %. Microstructural analyses by TG-DTG, FTIR, SEM-EDS, and XRD revealed that mainly C-(A)-S-H gel, hydrotalcite (HT), and Friedel's salt (FS) were formed as the hydration products in CS-SR synergistically-activated GGBS paste. The Ca2+ dissolved from CS facilitated GGBS hydration to generate the C-(A)-S-H gels and further reacted with Cl− in SR and [Al(OH)6]3− dissolved from GGBS to generate FS. The combined effect of C-(A)-S-H gel and FS enhances the strength of CPBs. When the percentage of SR is in the range of 70–75 %, the synergistic excitation of slag by alkali slag and calcium carbide slag is superior, and the matrix structure is denser.

The mesostructure evolution of cemented paste backfill during mixing

Mixing plays a crucial role in preparing Cemented Paste Backfill (CPB). Shearing, concentration, and particle size distribution are key factors that impact the flow of CPB slurry. This study employed focused beam reflectance measurement and a torque sensor to monitor the flow and structure evolution of CPB during the mixing process. The mixing process can be divided into three stages based on the torque curve: aggregation, destruction, and equilibrium. The structural evolution is the cause of the flow of fresh CPB. Each stage exhibits distinctive characteristics of the fresh CPB. During the aggregation stage, coarse tailings agglomerate via liquid bridges, binders agglomerate by hydration, and fine tailings interact mostly due to interparticle forces. Since the network is heterogeneous, the structure cannot resist shearing forces during the destruction and equilibrium stages. Finally, a rheological model was developed based on the mesostructure evolution mechanism of CPB.

Impact of virgin and recycled polymer fibers on the rheological properties of cemented paste backfill

The addition of polymer fibers to cemented paste backfill (CPB) has shown promise in enhancing mechanical properties, although it also introduces changes in rheological characteristics. This study aimed to investigate the influence of different types of polymer fibers, namely virgin commercial polypropylene fiber (CPPF), recycled tire polymer fiber (RTPF), and recycled tire rubber fiber (RF), on the rheological properties of CPB mixtures through an experimental program, and provide design references for CPB pipeline transport. The results revealed consistent reductions in bulk density upon the incorporation of polymer fibers into CPB, alongside varying impacts on slump. Specifically, the addition of CPPF had a mild effect, while RTPF caused a continuous decrease in slump, and RF exhibited minimal influence up to a 4% concentration, with substantial effects thereafter. Moreover, the inclusion of fibers led to increases in apparent viscosity parameters, with RTPF inducing the most significant changes, followed by varying responses from CPPF and RF. When using RTPF for CPB reinforcement, emphasis should be placed on enhancing technical indicators related to viscosity such as energy consumption and pipeline wear during pipeline transport. Furthermore, adjustments were necessary to account for flow curve instability resulting from interactions between fibers and the paddle, with the data aligning well with the Bingham model. The addition of fibers, particularly CPPF and RF, primarily influenced plastic viscosity rather than yield stress, underscoring the limitations of slump tests in assessing rheology.

Deformation field evolution characteristics of layered cemented paste backfill and strength prediction based on ultrasonic pulse velocity

ABSTRACT This study focused on investigating the damage development mode and strength prediction model of layered cemented paste backfill (LCPB) using digital image correlation (DIC) and ultrasonic pulse velocity (UPV). The results indicated that the damage mode was associated with the cement-to-tailings (c/t) ratio and the height (h/H) ratio of the middle layer of LCPB. The damage mode of LCPB was mainly tensile damage for a small h/H ratio while increasing the h/H ratio to 0.8 resulted in LCPB exhibiting macroscopic shear damage. With the reduction of the c/t ratio, the damage area of LCPB gradually shifted from the upper layer to the middle layer. The UPV tended to decrease exponentially with both the decrease of the c/t ratio and the increase of the h/H ratio. Comparing the predicted and experimental values, the maximum error of the predicted values was only 0.299, and the value of the a20-index was 0.9792, indicating that the predictive model was reliable. The findings could provide guidance for the design of LCPB.