Cement Mixtures Research Articles

Nonsurgical Endodontic Retreatment of a Cystic Apical Lesion Associated with Root Resorption: A Promising Approach

This case report highlights the successful management of a cystic apical lesion associated with root resorption through nonsurgical endodontic retreatment, utilizing calcium-enriched mixture (CEM) cement as an obturating biomaterial. A 35-year-old woman presented with mild discomfort in the mandibular right first molar (#46), with radiographic evidence of a well-defined radiolucent lesion at the apex of the mesial root. The tooth had a history of previous failed endodontic treatment with poor root canal obturation, indicating internal root resorption. Nonsurgical endodontic retreatment was performed, and the canals were filled/sealed with CEM cement. Follow-up radiographs showed a gradual reduction in the size of the cystic lesion. At 54 months, complete bone healing of the cystic apical lesion was evident. This case report provides clinical evidence supporting the potential efficacy of nonsurgical endodontic retreatment using CEM cement in managing certain cystic apical lesions, offering a promising alternative to traditional surgical enucleation, even in cases with inflammatory root resorption. Further research is needed to validate the long-term efficacy of this approach in larger patient populations.

Sustainable waste management options of waste plastic particles in cementitious mixtures for mass concrete applications

Sustainable waste management options of waste plastic particles in cementitious mixtures for mass concrete applications

Optimisation and Composition of the Recycled Cold Mix with a High Content of Waste Materials

This research focuses on a mineral–cement mixture containing bitumen emulsion, designed for cold recycling procedures, the formulation of which includes 80% (m/m) of waste material. Deep cold recycling technology from the MCE mixture guarantees the implementation of a sustainable development policy in the field of road construction. The utilised waste materials include 50% (m/m) reclaimed asphalt pavement (RAP) from damaged asphalt layers and 30% (m/m) recycled aggregate (RA) sourced from the substructure. In order to assess the possibility of using a significant amount of waste materials in the composition of the mineral–cement–emulsion (MCE) mixture, it is necessary to optimise the MCE mix. Optimisation was carried out with respect to the quantity and type of binding agents, such as Portland cement (CEM), bitumen emulsion (EMU), and redispersible polymer powder (RPP). The examination of the impact of the binding agents on the physico-mechanical characteristics of the MCE blend was performed using a Box–Behnken trivalent fractional design. This method has not been used before to optimise MCE mixture composition. This is a novelty in predicting MCE mixture properties. Examinations of the physical properties, mechanical properties, resistance to the effects of climatic factors, and stiffness modulus were conducted on Marshall samples prepared in laboratory settings. Mathematical models determining the variability of the attributes under analysis in correlation with the quantity of the binding agents were determined for the properties under investigation. The MCE mixture composition was optimised through the acquired mathematical models describing the physico-mechanical characteristics, resistance to climatic factors, and rigidity modulus. The optimisation was carried out through the generalised utility function UIII. The optimisation resulted in indicating the proportional percentages of the binders, enabling the assurance of the required properties of the cold recycled mix while utilising the maximum quantity of waste materials.

Applicability of 3D concrete printing technology in building construction with different architectural design decisions in housing

3D Printing (3DP) technology, one of the layered production methodologies where design and construction configurations can be made with increasing digitalization and Industry 4.0, is one of the leading techniques of the period. 3D Concrete Printing (3DCP) also comes to the fore in the construction industry. The study aims to observe the impact of architectural design decisions on the 3DCP process by developing controlled and consistent design alternatives. Architectural designs developed with different geometric forms in the housing function were subjected to digital planning, 3DCP preparation, and 3DCP prototype final product stages. In the integration of design and 3D concrete printing (3DCP), two key aspects were investigated: (i) the impact of different geometric forms (square, rectangle, hexagon, octagon, circle, and ellipse) on the buildability performance of 3D-printed structures, and (ii) how variations in design details influence printing time, material consumption, cost, and the feasibility of mass production in architectural applications. For the 3DCP process, 3D-printable cementitious mixture was developed, and a 3D printer with dimensions of 100 x 100 x 40 centimeters was used. The results obtained during the printing process were analyzed in comparison with the building evaluation parameters. As a result, the house with circular geometry showed the optimum behavior according to the parameters of buildability, cost, and mass producibility. The circle geometric form provides a 4.2% advantage over the octagon in terms of buildability, a 16.6% advantage over the ellipse in terms of cost, and a 20% advantage over the ellipse in terms of mass producibility.

Sustainable innovations and future prospects in construction material: a review on natural fiber-reinforced cement composites.

There is a growing trend in the construction industry to adopt environmentally friendly practices, and innovative materials are becoming increasingly popular. Within the scope of this paper, the potential of natural fiber-reinforced cement composites (NFRCs) as an environmentally friendly building material is examined. This work introduces plant fiber aspects such as micromorphology, primary components, physical and mechanical properties, chemical components, thermal properties, and degradation mechanisms in cement composites. It explores how plant fibers affect concrete's mechanical performance, durability, and thermal qualities. It is responsible for increasing permeability and decreasing durability in concrete material because plant fibers have porosity and a weak interface. The purpose of this in-depth investigation is to investigate the features, sustainability (social, environmental, and economical) performance, and applications of NFRCs, with a particular focus on environmentally responsible innovation and potential future applications. The exhaustive study also addresses the difficulties associated with attaining the highest possible level of compatibility between fibers and matrixes. The physical and chemical treatments of natural fibers in cement components give more resistance to aging by reducing water absorption and increasing roughness at the surface. It is also possible to reduce the effect of alkalinity of the cement mixture through optimization of the binder component and curing regimes, which retard the breakdown of natural fibers. The purpose of this study is to present a summary of existing research, with a particular emphasis on the benefits, drawbacks, and prospective ways in which NFRCs could potentially improve throughout the construction industry in the future.

Application of Phytoremediation to Hydraulic Binders Alkaline Inclusion in Forest Roads Pavement Construction

The use of hydraulic binder materials for the improvement of pavement subgrade has many implications for the surrounding ecosystem due to the possible leakage of alkaline compounds. The objective of this study is to evaluate the capacity of plants to remedy the subgrade affected by alkaline inclusion. To reduce the impact and return the subgrade to its original state, a phytoremediation process is studied. The impact of two materials commonly used for the subgrade improvement is analysed – fluid ash (slag) and lime+cement mixture. Three different mixes of plants – Mix A, Mix B and the native natural vegetation Mix N – are proposed. Totally 99 samples were collected and 990 specimens were chemically and geotechnically analysed and statistically evaluated. The success of phytoremediation process for both Mix A and Mix B can be observed. It is considerably higher for the undersurface alkaline inclusion than for the surface one. Mix B appears to be the best for fluid ash binder and Mix A for lime+cement mixture binder. It is worth noting that the native natural vegetation in Mix N also contributes to the phytoremediation process and that the appropriate plant selection – e.g. Mix A and Mix B – can accelerate this process.

Thermal activation of multi-recycled concrete powder as supplementary cementitious material for repeated and waste-free recycling

Utilizing powder generated during concrete recycling process is considered crucial for achieving complete recycling of concrete waste. However, integrating recycled concrete powder (RCP) often reduces cementitious mixture performance. This study aims to enhance RCP characteristics through thermal activation, facilitating its recycling as cement replacement over multiple recycling cycles. RCPs from three cycles of concrete recycling were heat-treated at 200 °C, 400 °C, 600 °C, and 800 °C for 2 h, and their chemical composition was analyzed before and after treatment. Subsequently, the RCPs replaced cement in mortar by 10 %, 20 %, and 30 %. Various properties of the mortars, such as flow, mechanical strength, water absorption, and drying shrinkage, were tested. The results showed a general decline in mortar properties with increasing RCP replacement ratios and recycling cycles. However, RCPs activated at 600 °C and 800 °C enhanced compressive and flexural strengths by up to 19 % and 16 %, respectively, and enhanced shrinkage resistance by 19 %. Particularly, the three-times RCP activated at 800 °C achieved mechanical performance comparable to standard mortar at 10 % replacement, meeting strength grading requirements per industry standards. This study demonstrates a viable pathway for the repeatable and waste-free recycling of concrete, contributing to more sustainable construction practices.

Study on the adhesive property of sludge-modified magnesium phosphate cement reinforcement coating for steel bars

The synergistic interaction inreinforced concrete systems originates from the strong bond between steel reinforcement and concrete, enabling them to collaborateunder load and optimize structural performance. This study applied various sludge-modified magnesium phosphate cement mixtures to the surfaces of plain round steel bars and ribbed steel bars to prepare steel-reinforced concrete specimens. The characterization of the bond performance of the sludge-modified magnesium phosphate cement reinforcement coating for steel bars and concrete was achieved through analyzing the failure modes, bond strength, and slip values of different groups. Microscopic analysis was performed using a scanning electron microscope. The results revealed that the primary failure mode of the steel-reinforced concrete specimens was steel bar pull-out, with some specimens exhibiting concrete splitting failure. Coating application on plain round steel bars increased bond strength, while on ribbed steel bars, it decreased bond strength. The application of the coating slightly reduced slip values to some extent.

Effects of seawater on properties of bentonite cut-off walls with/without cement addition

Bentonite-based cut-off walls have been widely used to protect coastal areas against seawater intrusion. However, salts contained in coastal soils affect the properties of bentonite cut-off walls, and the interactions between seawater and bentonite minerals with or without cement remain unclear. The aim of this study was therefore to evaluate the effects of seawater on the workability, strength and permeability of bentonite-based mixtures, prepared using three types of bentonite (sodium, calcium and seawater bentonite). The underlying mechanisms were further investigated through Atterberg limits, mineralogical and microstructural analyses. The results showed that cation exchange between seawater and bentonite leads to alterations in montmorillonite type and particle arrangement. This leads to a significantly reduced liquid limit and a slightly decreased plastic limit of bentonite, therefore narrowing the range of workable water content for bentonite–sand mixtures. Compared with sodium/calcium bentonite, seawater bentonite was less impacted by seawater, but showed a larger increment in workability after cement addition due to palygorskite dissolution. Under similar workability, the bentonite–sand–cement mixture with calcium bentonite yielded the highest strength and the lowest permeability. These findings illustrate correlations between bentonite mineral alterations and the properties of bentonite–sand mixtures with or without cement, and offer guidance for the construction of cut-off walls in coastal regions.

Hybrid extreme gradient boosting regressor models for the multi-objective mixture design optimization of cementitious mixtures incorporating mine tailings as fine aggregates

The design of cementitious mixtures incorporating mine tailings as fine aggregates is a multi-objective optimization (MOO) problem, in which both the uniaxial compressive strength (UCS) and cost of the mixtures need to be considered simultaneously. Given that data-driven methods have shown promising results when solving similar MOO problems, this study developed an extreme gradient boosting regressor (XGBR) model on a dataset extracted from the literature to predict the UCS. Among the efforts taken to improve the models, a genetic algorithm (GA)-based XGBR model demonstrated the optimal prediction performance, with an R2 of 0.959. Next, the GA-XGBR model and a cost equation were used as objective functions in the MOO problem. The non-dominated sorting genetic algorithm with elite strategy (NSGA-II) was selected to solve the optimization problem. A case study was conducted, generating mixture designs that offered improved trade-offs between cost and UCS compared to experimental designs. Finally, a graphical user interface was developed to provide access to the prediction model and optimization method. Overall, this work can be used as a guide for optimal mixture designs as it facilitates informed decision-making before the actual applications.

Early-age shrinkage behavior of cement mixtures regulated with metakaolin-based internal conditioning

Shrinkage occurs in concrete during its hardening and strength gain process leading to undesired deformation, cracking, and decreases in strength and durability. While metakaolin-based internal conditioning (MIC) has been validated as a promising technique for modifying cement and mitigating alkali-silica reactions in concrete, its impact on the early-age shrinkage behavior of cement remains unexplored. This study delves into the effects of MIC and its coupling with lithium on the chemical shrinkage, autogenous shrinkage, and drying shrinkage of portalnd cement incorporating 30 % metakaolin with varying degrees of saturation (50 %, 75 %, and 100 %). The results indicate that the hydration of cement can be substantially enhanced by MIC with 29.0 % more heat released and a 32.3 % decrease in calcium hydroxide content. As a result of the enhanced hydration, cement with MIC yielded increased chemical shrinkage. Compared with dry MK, the autogenous shrinkage and drying shrinkage of cement were decreased by 38.0 % and 11.0 %, respectively, in the presence of MIC. A synergistic effect between MIC and lithium was suggested by the higher efficacy in suppressing autogenous shrinkage.

Use of macromolecules lignosulfonate and graphene oxide to prepare non-autoclaved aerated concrete

The development of new structural materials with thermal insulation properties is urgently need in the construction of smart buildings. Besides, there is a need to develop environmentally friendly and sustainable concrete mix designs. Lignosulfonate (LS) macromolecule and graphene oxide (GO) were used to prepare non-autoclaved aerated concrete (NAC). The addition of a complex GO/LS additive of the composition (0.16/0.0002 wt%) increased the compressive strength by 54 %, and bending strength by 45 % at the age of 28 days' strength gain. The addition of an effective complex GO/LS additive to NAC made it possible to achieve a reduction in water absorption by up to 63 % and thermal conductivity by up to 29 % in comparison. The thermal conductivity coefficient of such NAC specimens was 0.092 W/m·K with water absorption of 9 %. The options for the interactions of the GO/LS modifier with calcium hydroaluminates using the type of ion exchange were proposed. Thus, the introduction of GO/LS nano modifier contributed to high-quality filling of free areas of the cement mixture with mineral formations, which helpd to increase the strength of the aerated concrete and its durability.

Aerobic bacteria induced biomineralization: effects of nutrient and calcium content on the nanostructure and chemical composition of simulated cement mixture

During the past two decades, aerobic bacteria induced biomineralization has gained popularity for autonomous sealing of cracks in concrete structures due to its environmentally friendly characteristics of carbon retention. However, the mechanism of the biomineralization induced by aerobic bacteria for concrete crack sealing is still unclear due to the complex chemistry of cement matrix. Also, as the main nutrient for bacterial growth, the effect of yeast extract (YE) on biomineralization should be properly evaluated. For the first time, this study investigates the effects of YE and calcium content on the development of nanostructure and chemical composition of cement matrix during the biomineralization process induced by aerobic bacteria Bacillus cohnii. The effects of calcium content were realized by constructing a simulated cement mixture consisting of calcium hydroxide and synthesised C-S-H with different C/S ratios. The effects of YE content were evaluated by the addition of different amounts of YE into simulated cement mixture with different C/S ratios. Results suggest that 10 g/l of YE can cause a high pH value of 10 and an unsuccessful growth of bacteria in simulated cement mixture with C/S ratios 0.6 and 0.8. Upon increasing the YE from 10 g/l to 20 g/l, the pH reduced from 10 to 9 and the bacteria was successfully grown. Higher amounts of bicarbonate ions can cause an enhanced decalcification of synthesised C-S-H rather than calcium hydroxide. The aerobic bacteria Bacillus cohnii showed superior performance on calcium absorption and calcite precipitation, being a promising way for practical concrete crack sealing.

Preparation of aragonite-rich whisker materials from magnesium slag and salt lake bischofite and its effects on cement properties

This study develops an innovative wet carbonation process utilizing Magnesium Slag(MS), Salt Lake Bischofite (SLB), and CO2 to prepare carbonized materials mainly composed of aragonite and active silica gel, all raw materials were solid wastes. Subsequently, it was employed as Supplementary Cementitious Materials (SCMs) additive in cement, with the goal of efficiently capturing carbon dioxide and transforming aragonite whiskers into high-value products. Investigated the parameters influencing the formation of aragonite, including temperature and the concentration of the SLB solution, while exploring the nucleation and growth mechanisms of aragonite. The findings reveal that under 80 °C, the suspension of MS with 0.83 % SLB solution swiftly produces needle-like aragonite whiskers with single crystal lengths ranging from 10-20 μm and diameters of 0.3–0.5 μm. With the increase in SLB concentration, the aspect ratio of aragonite whiskers decreases. Additionally, highly polymerized amorphous silica gel was also detected. Therefore, Carbonated Aragonite-type Magnesium Slag (CAMS) (34.0901 m2/g) exhibits a significantly larger specific surface area compared to MS (0.9877 m2/g), representing an enhancement factor of 34.5 times, which concurrently bolsters its capability to adsorb reactive ions. During the carbonation process, 1 g of MS can sequester and solidify 0.403 g of CO2. Furthermore, incorporating CAMS as SCMs into cement mixtures notably enhances both the compressive and flexural strengths of cement mortar. These findings offer a sustainable approach to the recycling of solid waste, CO2 sequestration, and the improvement of cement-based material properties.

Detailed Analytical EPMA Study of the OPC Pastes Prepared with the Addition of Raw and Milled Fly Ashes

Concrete and cement pastes belong to the most used building materials in human history and represent a solidified mixture of ordinary Portland cement (OPC), water, course and fine-grained aggregates. Fly ash is used as a pozzolanic additive to improve concrete properties. The fly ash property can also be modified by various treatments such as milling or size reduction with sieving. It was suggested that a beneficial pozzolanic reaction with fly ash gives high mechanical properties. Such pozzolanic reaction results in calcium silicate hydrate (C-S-H) phase formation. In this research comparative analytical EPMA study of the paste samples prepared with the addition of the milled and non-milled fly ashes has been performed to elucidate the pozzolanic reaction of the OPC with the milled and non-milled fly ashes. A higher pozzolanic reaction with CSH phase formation was observed in milled fly ash added paste.

AN EXPERIMENTAL INVESTIGATION ON EFFECT OF CONCRETE BY USING PARTIAL REPLACEMENT OF EGG SHELL POWDER IN CEMENT ALONG WITH E-WASTE AS COARSE AGGREGATE

The imagination of a world without concrete isimpossible. It is a soul of infrastructures. Concrete is necessary to gain strength in structures. Conventional concrete, which is the mixture of cement, fine aggregate, coarse aggregate and water, needs curing to achieve strength. Concrete is a counterfeit material in which the totals both fine and coarse are reinforced together by the bond when blended with water. The solid has turned out to be so prominent and essential in view of its natural, concrete acquired an upheaval uses of cement. Concrete has boundless open doors for creative applications, plan and development methods. Its extraordinary adaptability and relative economy in filling extensive variety of necessities has made it is exceptionally focused building material. This project focuses on concrete, keeping importance to this, an attempt has been made to develop strength in concrete incorporating recycling waste. As part of the project cement partially replaced with egg shall powder and e- waste as coarse aggregate Comparative studies were carried out for compressive strength, tensile strength and flexural test for conventional and material concrete mixture introducing new recycling materials

Dual admixtures for cement-based composites comprising steel slag powder and residual lignin-based liquor

Steel slag is a by-product of the steel industry that can be used as an aggregate and/or mineral admixture, conferring physical and mechanical benefits to cement-based composites. In parallel, sugarcane bagasse is a by-product of the sugar/alcohol industry used in biorefineries to produce bioethanol. The delignification processes, employed as a pretreatment in biorefineries, generate residual liquors that contain lignin. Lignin is a natural polymer with plasticizing properties when incorporated into cement mixtures. Given this scenario, this work sought to produce and evaluate dual admixtures containing a residual lignin-based liquor and a steel slag powder. The proposed dual admixtures were prepared from two strategies and incorporated in cement pastes and mortars at different dosages. Mixtures containing a commercial silica suspension and a reference mixture (without admixtures) were also evaluated. The flow test showed that the dual admixtures promoted higher spreading than the silica suspension in all the proposed dosages. Also, the mortars containing the dual admixtures had significantly higher compressive strengths and more refined pore structures than the reference mortar. The residual lignin-based liquor enhanced the workability of the composites and favored the dispersion of the steel slag powder into the matrix. The liquor's plasticizing and set-retarding capacities were attributed to its anionic functional groups and sugar content, respectively. Additionally, the high-efficiency grinding of the steel slag powder contributed to improving its specific surface area and fineness parameters, justifying its performance as a filler and a supplementary cementitious material. This study presents a new route for developing more eco-efficient cement-based composites. It also complies with the principles of circular economy by offering a feasible strategy for valorizing large-scale industrial wastes in civil construction.

The utilization of pulverized waste tire rubber in a soil–cement composite for sustainable compressed earth brick production

This study examined the suitability of blending waste tires with cement in indigenous soil for producing compressed earth bricks (CEB) to achieve a sustainable environment. CEB was produced with clay soil and a combination of cement at 5 and 10% levels with varying dosages of pulverized waste tire at 0, 2.5, 5, 7.5, and 10% mixture. Classification tests were conducted to determine engineering properties such as the particle size distribution, Atterberg limit, specific gravity, optimum moisture and unit weight of the soil. The physical properties of the pulverized tire were evaluated. Moreover, density, water absorption, and compressive strength were determined for hardened CEB samples produced from mixtures of soil and various proportions of blended cement and pulverized waste tire materials. The classification results showed that the soil was silty clay of low plasticity. The density of the CEB samples was observed to increase slightly with the addition of blended cement-tire residue. Furthermore, a considerable improvement in the compressive strength development of the CEB was observed; however, compared with those of the control, the peak compressive strength of the CEB samples was greater when the soil was stabilized with 7.5% pulverized waste tire material and 10% cement. A decrease in the water absorption capacity of CEB was observed with an increase in the amount of pulverized waste tire and cement in the soil mixture. The response models corroborate the experimental findings indicating that amount of waste tire rubber residue and cement had significant effects on the CEB performance. This study ensure the beneficial recycling of waste tires blended with cement in soil for making medium-strength CEB to achieve sustainable, resilient masonry construction applications.Graphical

Influence of magnesite/limestone addition on the hydration characteristics of ternary slag cement systems

To explore the potential of magnesite adopted as supplementary cementitious material (SCM) in cement industry, the authors of this paper investigated the hydration characteristics of ternary slag cement mixtures containing magnesite or limestone. All cement pastes were formulated with a water-to-binder ratio of 0.4, and a total of 50 % substitution level was applied across the blends, with varying slag and magnesite/limestone contents. Experimental results confirmed that adding limestone to slag cement can promote the hydration of cement clinker through the nucleation effect, while not for magnesite addition. As the substitution ratio of magnesite increased, there was a notable increase in both the critical pore diameter and cumulative pore volume, leading to a continuous decrease in the compressive strength of cement pastes. Compared to limestone-containing blends, the incorporation of magnesite was more beneficial to the compressive strength at 7 and 28 days. Additionally, limestone facilitated the precipitation of hemi- and mono-carboaluminate, whereas no hemicarbonate was observed in mixtures containing magnesite. The addition of magnesite promoted the formation of hydrotalcite-like phase, and the quantitative analysis revealed that the dissolution of magnesite primarily occurred in the first 7 days. The authors believed that the results obtained in this paper proposed new perspectives on utilizing magnesite as SCM in cement industry.

The effect of calcium stearate on the microbiological corrosion of cement stone concrete

To prevent biofouling of cement stone and its damage by fungal microorganisms, it is proposed to introduce 0,5 wt. % calcium stearate into the cement mixture. To ensure volumetric hydrophobization of cement stone, the additive is crushed to nanoparticles. The cement stone was cured in the air for 28 days. To study fungal corrosion, the surface of the cement stone was treated with a suspension of pores of Aspergillus niger fungi. The hydrophobic surface of the cement stone was not biofouled by fungal microorganisms Aspergillus niger during 6 months of the samples being in a humid environment, and black mold foci developed on the surface of ordinary cement stone during this period of time. The action of fungi and their waste products caused a decrease in the amount of calcium in the cement stone by 9 %, and had no effect on the hydrophobized cement stone. Due to the immunity of cement stone with a hydrophobizer to the action of microorganisms and water, free calcium hydroxide is not removed from the structure, but some amount is washed out of the surface layer and the pore liquid. A significant slowdown in mass transfer in cement stone under the action of liquids is provided by the hydrophobicity of the surface of cement stone and the walls of pores and capillaries, imparted by calcium stearate, as well as partial colmatation of the pore structure by means of the introduced additive.