Cellulose-reinforced Composites Research Articles

Prospecting cellulose fibre-reinforced composite membranes for sustainable remediation and mitigation of emerging contaminants

Many environmental pollutants caused by uncontrolled urbanization and rapid industrial growth have provoked serious concerns worldwide. These pollutants, including toxic metals, dyes, pharmaceuticals, pesticides, volatile organic compounds, and petroleum hydrocarbons, unenviably compromise the water quality and manifest a severe menace to aquatic entities and human beings. Therefore, it is of utmost importance to acquaint bio-nanocomposites with the capability to remove and decontaminate this extensive range of emerging pollutants. Recently, considerable emphasis has been devoted to developing low-cost novel materials obtained from natural resources accompanied by minimal toxicity to the environment. One such component is cellulose, naturally the most abundant organic polymer found in nature. Given bio-renewable sources, natural abundance, and impressive nanofibril arrangement, cellulose-reinforced composites are widely engineered and utilized for multiple applications, such as wastewater decontamination, energy storage devices, drug delivery systems, paper and pulp industries, construction industries, and adhesives, etc. Environmental remediation prospective is among the fascinating application of these cellulose-reinforced composites. This review discusses the structural attributes of cellulose, types of cellulose fibrils-based nano-biocomposites, preparatory techniques, and the potential of cellulose-based composites to remediate a diverse array of organic and inorganic pollutants in wastewater.

The effect of the dispersion of microfibrillated cellulose on the mechanical properties of melt-compounded polypropylene\u2013polyethylene copolymer

Microfibrillated cellulose (MFC) is a highly expanded, high surface area networked form of cellulose-based reinforcement. Due to the poor compatibility of cellulose with most common apolar thermoplastic matrices, the production of cellulose-reinforced composites in industry is currently limited to polar materials. In this study, a facile water-based chemistry, based on the reaction of MFC with tannic acid and subsequent functionalisation with an alkyl amine, is used to render the surface of the MFC fibrils hydrophobic and enhance the dispersion of the cellulose-based filler into an apolar thermoplastic matrix. The level of dispersion of the compatibilized MFC reinforced composites was evaluated using Time of Flight Secondary Ion Mass Spectrometry and multi-channel Spectral Confocal Laser Scanning Microscopy. The agglomeration of cellulosic filler within the composites was reduced by functionalising the surface of the MFC fibrils with tannic acid and octadecylamine. The resulting composites exhibited an increase in modulus at a high cellulose content. Despite the dispersion of a large portion of the functionalised filler, the presence of some remaining aggregates affected the impact properties of the composites produced.

Recyclable and Mendable Cellulose-Reinforced Composites Crosslinked with Diels⁻Alder Adducts.

Owing to their natural abundance and exceptional mechanical properties, cellulose fibers (CFs) have been used for reinforcing polymers. Despite these merits, dispersing hydrophilic CFs in a hydrophobic polymer matrix is challenging. To address this, an amphiphilic ammonium salt was employed as the dispersant for CFs in this study. The hydrophobic CFs were mixed with a healable polymer to produce CF-reinforced composites. As the thermosetting polymer was crosslinked with Diels–Alder (DA) adducts, it was mended and recycled via a retro DA reaction at 120 °C. Interestingly, the CF-reinforced polymer composites were mended and recycled as well. When 5 wt % of the hydrophobic CFs was added to the polymer, maximum tensile strength, elongation at break, Young’s modulus, and toughness increased by 70%, 183%, 75%, and 420%, respectively. After recycling, the CF-reinforced composites still featured better mechanical properties than recycled polymer.

Novel automated method for evaluating the morphological changes of cellulose fibres during extrusion-compounding of plastic–matrix composites

A novel method based on fluorescence optical microscopy has been developed for determining the fibre geometrical changes occurring during the melt processing of cellulose-reinforced composites, which are known to be closely related with composite properties. Determination of these changes is still a tedious and challenging task because existing methods are not well developed yet. The novel method proved its ability for explaining the screw configuration effects on the attrition bore by the fibres during extrusion-compounding of plastic–matrix composites. The percentage of fibres longer than the critical length parameter was revealed to highlight the mechanical degradation of fibres during compounding. The percentage of fines exhibited the clearest correlation with the differences in fibre content of composites. Relationships found between composite tensile properties and fibre characterization parameters revealed the ability of the novel method for explaining the effects of composition and processing on composite properties.

Char-forming behavior of nanofibrillated cellulose treated with glycidyl phenyl POSS

Cellulose-reinforced composites have received much attention due to their structural reinforcing, light weight, biodegradable, non-toxic, low cost and recyclable characteristics. However, the tendency for cellulose to aggregate and its poor dispersion in many polymers, such as polystyrene, continues to be one of the most challenging roadblocks to large scale production and use of cellulose-polymer composites. In this study, nanofibrillated cellulose (NFC) is modified using GlycidylPhenyl-POSS (a polyhedral oligomeric silsesquioxane). The product yield, morphology, and crystallinity are characterized using a variety of spectroscopy and microscopy techniques. Thermal analyses are performed using thermal gravimetric analysis and pyrolysis combustion flow calorimetry.

Recycling Ability of Biodegradable Matrices and Their Cellulose-Reinforced Composites in a Plastic Recycling Stream

The effect of multiple injection-moulding reprocessing of three biodegradable matrices on their mechanical properties, melt flow rate, molecular weight, phase transition temperatures and degradation temperature is presented. It has been found that, with successive reprocessing, tensile, flexural and impact strength decreased. Drop in mechanical properties has been assigned to degradation of the matrices, as corroborated by melt flow and molecular weight analysis. Although reprocessing did not significantly affect the glass transition, it diminished the melting point and degradation temperature of polymers. Results indicate that neat PLLA can be recycled for up to five times without suffering a drastic loss in mechanical and thermal properties. The aliphatic polyester Mater-Bi TF01U/095R can be recycled for up to 10 times, whilst starch-based Mater-Bi YI014U/C wastes should be destined to composting, since its recyclability is very poor. The effect of reprocessing on composites reinforced with chemithermomechanical pulp (CTMP) followed the tendencies observed for the neat matrices. Whilst CTMP-fibres behave mainly as filler in PLLA composites, reinforced thermoplastic starch-based composites presented enhanced mechanical properties and recyclability.

Nanoclay plating of cellulosic fiber surfaces

A basic problem in making cellulose-reinforced composites is achieving a dispersion of cellulosic fibers in an often olephinic polymer matrix. Drying cellulosic fibers results in the formation of fiber flocs/nodules because of their strong interfiber bonding, and this makes the hydrophilic cellulosic fibers difficult to disperse in a hydrophobic matrix material. One common approach to alleviate floc formation is to adsorb cationic surfactant onto anionically charged cellulose, which reduces the interfiber bonding, decreases floc formation and gives better compatibility with the matrix. In this report, a different approach is taken, namely to adsorb nanoclays onto the cellulosic fibers, and thereby reduce the natural hydrogen-bonding affinity between fibers. In a second report, the same technology will be shown to be advantageous to decrease floc formation in oleophinic composites reinforced with cellulosic fibers. This article summarizes experiments aimed at optimizing the chemistry of deposition of montmorillonite clay onto fiber surfaces. The aim was to optimize the chemical conditions for the heterodeposition of the anionic clay onto cationically charged fluff pulp. The experiments were designed to provide a theoretical framework for the deposition of the nanoclay onto the pulp fibers. High Mw p-DADMAC and an exfoliated clay (achieved by passing the clay through a homogenizer) were used. As expected, a certain degree of charge overcompensation by adding an electrolyte was necessary to bring about deposition. The adsorbed amount of clay could be calculated from the charge balance between the overcompensated charge and the net clay charge, constituting the theoretical framework for nanoclay heterodeposition. As expected, montmorillonite clay greatly destroyed the joint strength between fibers (determined by evaluating the strength of paper made from treated fibers). The surface coverage (determined by ESCA) was shown to be a linear function of the attached amount of clay, and ∼3% clay was required to fully cover the fiber surfaces. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008