Line Catalog Research Articles

JADES NIRSpec initial data release for the Hubble Ultra Deep Field. Redshifts and line fluxes of distant galaxies from the deepest JWST Cycle 1 NIRSpec multi-object spectroscopy

We describe the NIRSpec component of the JWST Deep Extragalactic Survey (JADES), and provide deep spectroscopy of 253 sources targeted with the NIRSpec micro-shutter assembly in the Hubble Ultra Deep Field and surrounding GOODS-South. The multi-object spectra presented here are the deepest so far obtained with JWST, amounting to up to 28 hours in the low-dispersion ($R 30-300$) prism, and up to 7 hours in each of the three medium-resolution $R 1000$ gratings and one high-dispersion grating, G395H ($R Our low-dispersion and medium-dispersion spectra cover the wavelength range $0.6-5.3\ We describe the selection of the spectroscopic targets, the strategy for the allocation of targets to micro-shutters, and the design of the observations. We present the public release of the reduced 2D and 1D spectra, and a description of the reduction and calibration process. We measure spectroscopic redshifts for 178 of the objects targeted extending up to $z=13.2$. We present a catalogue of all emission lines detected at $S/N>5$, and our redshift determinations for the targets. Combined with the first JADES NIRCam data release, these public JADES spectroscopic and imaging datasets provide a new foundation for discoveries of the infrared universe by the worldwide scientific community.

Emission-line galaxies at z ∼ 1 from near-IR HST Slitless Spectroscopy: Metallicities, star formation rates and redshift confirmations from VLT/FORS2 spectroscopy

Abstract We follow up emission line galaxies identified through the near-infrared slitless HST/WFC3 WISP survey with VLT/FORS2 optical spectroscopy. Over 4 WISP fields, we targetted 85 of 138 line emission objects at 0.4 < z < 2 identified in WFC3 spectroscopy. Half the galaxies are fainter than HAB = 24 mag, and would not have been included in many well-known surveys based on broad-band magnitude selection. We confirm 95% of the initial WFC3 grism redshifts in the 38 cases where we detect lines in FORS2 spectroscopy. However, for targets which exhibited a single emission line in WFC3, up to 65% at z < 1.28 did not have expected emission lines detected in FORS2 and hence may be spurious (although this false-detection rate improves to 33% using the latest public WISP emission line catalogue). From the Balmer decrement the extinction of the WISP galaxies is consistent with A(Hα) = 1 mag. From SED fits to multi-band photometry including Spitzer 3.6 μm, we find a median stellar mass of log10(M⋆/M⊙) = 8.94. Our emission-line-selected galaxies tend to lie above the star-forming main sequence (i.e. higher specific star formation rates). Using [O iii], [O ii] and Hβ lines to derive gas-phase metallicities, we find typically sub-solar metallicities, decreasing with redshift. Our WISP galaxies lie below the z = 0 mass-metallicity relation, and galaxies with higher star formation rates tend to have lower metallicity. Finally, we find a strong increase with redshift of the Hα rest-frame equivalent width in this emission-line selected sample, with higher EW0 galaxies having larger [O iii]/Hβ and O32 ratios on average, suggesting lower metallicity or higher ionisation parameter in these extreme emission line galaxies.

Tracing Prebiotic Molecules: Rotational Spectroscopy of Deuterated Glycolaldehyde and (Z)-1,2-Ethenediol.

Glycolaldehyde, an important prebiotic molecule, along with its monodeuterated species and its higher energy tautomer, (Z)-1,2-ethenediol, has been detected in the interstellar medium. Although the elemental D/H ratio in the universe is only ∼1.6 × 10-5, the deuterium relative abundance in interstellar molecules might be by far larger than this. As such, it provides a remarkable and almost unique diagnostic tool. In particular, it might help elucidate the reaction mechanisms that lead to the formation of the so-called complex organic molecules. It is therefore crucial to extend the census of the interstellar deuterated molecules. To this aim, in this work, we present for the first time a spectroscopic investigation of the rotational spectra of the CHDOD-CHO bideuterated variant of glycolaldehyde and of mono- and bideuterated species of (Z)-1,2-ethenediol (CHOD═CHOD, CHOD═CHOH, and CHOH═CHOD rotamers). For each species, more than a hundred transitions have been assigned. Their analysis led to the accurate determination of all rotational constants as well as quartic and sextic centrifugal distortion terms, thus providing spectroscopic line catalogs suitable for supporting astronomical searches. In addition, the rotational constants of the bideuterated glycolaldehyde isotopologue studied in this work allowed us to improve the semiexperimental equilibrium structure determination for this molecule.

CN and CCH azirine derivatives, possible precursors of prebiotic molecules: formation and spectroscopic parameters

ABSTRACT N-heterocycles are of special relevance in astrobiology but at present no nitrogen-containing heterocycles have been detected in the interstellar medium (ISM). Thus far, the simplest N-heterocyclic compound, 2H-Azirine (c-C2H3N), has not been conclusively identified, despite being searched for. Recently, several cyano and ethynyl derivatives of unsaturated hydrocarbons have been discovered in the cold prestellar core Taurus Molecular Cloud 1 (TMC-1). The purpose of this work is to assess the feasibility of the possible formation of cyano and ethynyl derivatives of azirine (c-C2H2N-CN, c-C2H2N-CCH) under interstellar conditions and provide high-level theoretical spectroscopic parameters of the most relevant cyano- and ethynyl-azirine isomers to facilitate their experimental identification. Six isomers are located for each, cyano- and ethynyl-azirine derivatives, and their interconversion processes are studied. The reactions of 2H-azirine with the CN or CCH radicals in the gas phase are explored as possible formation routes of cyano and ethynyl azirine. We found that the formation processes of the most stable isomers, namely 3-cyano-2H-azirine, 2-cyano-2H-azirine, 3-ethynyl-2H-azirine, and 2-ethynyl-2H-azirine, are exothermic and barrier free. Thus, these compounds stand out as potential targets to be searched for in space. Based on the newly determined rotational spectroscopic parameters, which also account for 14N hyperfine splittings, we compile a line catalogue for each system up to 50 GHz as a preliminary and required step to characterize these molecules experimentally, whether in the laboratory or directly in the ISM.

Machine learning uncovers the universe’s hidden gems: A comprehensive catalogue of C iv absorption lines in SDSS DR12

ABSTRACT We assemble the largest C iv absorption line catalogue to date, leveraging machine learning, specifically Gaussian processes, to remove the need for visual inspection for detecting C iv absorbers. The catalogue contains probabilities classifying the reliability of the absorption system within a quasar spectrum. Our training set was a sub-sample of DR7 spectra that had no detectable C iv absorption in a large visually inspected catalogue. We used Bayesian model selection to decide between our continuum model and our absorption-line models. Using a random hold-out sample of 1301 spectra from all of the 26 030 investigated spectra in DR7 C iv catalogue, we validated our pipeline and obtained an 87 per cent classification performance score. We found good purity and completeness values, both $\sim 80{{\ \rm per\ cent}}$, when a probability of $\sim 95{{\ \rm per\ cent}}$ is used as the threshold. Our pipeline obtained similar C iv redshifts and rest equivalent widths to our training set. Applying our algorithm to 185 425 selected quasar spectra from SDSS DR12, we produce a catalogue of 113 775 C iv doublets with at least 95 per cent confidence. Our catalogue provides maximum a posteriori values and credible intervals for C iv redshift, column density, and Doppler velocity dispersion. We detect C iv absorption systems with a redshift range of 1.37–5.1, including 33 systems with a redshift larger than 5 and 549 absorbers systems with a rest equivalent width greater than 2 Å at more than 95 per cent confidence. Our catalogue can be used to investigate the physical properties of the circumgalactic and intergalactic media.

From the laboratory to the interstellar medium: a strategy to search for exotic molecules in space

The chemistry of the interstellar medium occurs under extreme conditions and can lead to the formation of exotic molecules. These are species that on Earth are unstable and/or highly reactive. Their discovery in space is usually based on the astronomical observation of their rotational fingerprints, which requires an accurate laboratory investigation. This is based on a strategy that starts from the interplay of experiment and theory. State-of-the-art quantum-chemical calculations are used to predict the relevant spectroscopic information required to guide the spectral recording, analysis and assignment. Rotational spectra measurements are then performed in the centimeter-/millimeter-/submillimeter-wave region, thereby exploiting efficient on-the-fly production protocols for exotic molecules. Subsequently, the spectral analysis leads to accurate spectroscopic parameters, which are then used for setting up accurate line catalogs for astronomical searches and detections. This review is based on the strategy developed and the results obtained at the ROT&Comp Lab of the University of Bologna.

A complete catalogue of broad-line AGNs and double-peaked emission lines from MaNGA integral-field spectroscopy of 10K galaxies: stellar population of AGNs, supermassive black holes, and dual AGNs

ABSTRACT We analyse the integral field spectroscopy data for the ≈10 000 galaxies in final data release of the MaNGA survey. We identify 188 galaxies for which the emission lines cannot be described by single Gaussian components. These galaxies can be classified into (1) 38 galaxies with broad $\rm H\alpha$ and [O iii] $\rm \lambda$5007 lines, (2) 101 galaxies with broad $\rm H\alpha$ lines but no broad [O iii] $\rm \lambda$5007 lines, and (3) 49 galaxies with double-peaked narrow emission lines. Most of the broad-line galaxies are classified as active galactic nuclei (AGNs) from their line ratios. The catalogue helps us further understand the AGN-galaxy coevolution through the stellar population of broad-line region host galaxies and the relation between broad lines’ properties and the host galaxies’ dynamical properties. The stellar population properties (including mass, age, and metallicity) of broad-line host galaxies suggest there is no significant difference between narrow-line Seyfert-2 galaxies and Type-1 AGNs with broad $\rm H\alpha$ lines. We use the broad-$\rm H\alpha$ line width and luminosity to estimate masses of black hole in these galaxies, and test the MBH–σe relation in Type-1 AGN host galaxies. Furthermore, we find three dual AGN candidates supported by radio images from the VLA FIRST survey. This sample may be useful for further studies on AGN activities and feedback processes.

On gamma-ray spectrometry of rare earth elements on the moon: Reference data from proton accelerator experiment

The laboratory experiment was conducted at Joint Institute for Nuclear Research with a prototype of planetary gamma-ray spectrometer (GRS) based on a High Purity Germanium (HPGe) detector and a proton detector (PD) configured with the GRS in the coincidence mode. The instrument set-up allows to detect gamma rays produced in the target irradiated by protons using integrated gamma-ray spectra (all detected gamma rays) as well as tagged gamma-ray spectra that select only photons synchronized with the proton detection. The latter option improves signal-to-noise ratio by selecting prompt photons produced in the irradiated target. The main objective was to conduct experiment with an irradiation of 11 samples of Rare Earth Elements (REEs) with high energy protons (170 MeV) to find a set of uniquely characterized gamma-ray lines that confidently indicate the presence of the given REE. These measurements are acquired to understand the conditions of a hypothetical space experiment on the lunar surface aimed for the reconnaissance of lunar resources. In this experiment, ambient gamma radiation is produced by charged particles of Galactic Cosmic Rays (GCRs).45 significant gamma-ray lines were found for 11 tested samples of REEs in total. This list includes 7 gamma-ray lines which have already been identified in the existing catalog of characteristic gamma-ray lines produced in the inelastic scattering reactions. 18 gamma-ray lines are unique and they were detected for an individual REE only. Other 27 detected gamma-ray lines are associated with several REEs and therefore were combined into 10 joint groups. Some groups are rather large and consists of 4 REEs.The proposed method of spectrometry with the options of time-integrated and tagged spectra allowed to determine the fraction of the gamma-ray lines, which occurs promptly at moment of proton-nuclei interaction. For some gamma-ray lines such a fraction is rather large and approaching 50%, and for some other gamma-ray lines it could be as small as 10–15%.The obtained experimental results were used to predict the expected intensities of the REEs gamma-ray lines in a future gamma-ray spectrometric experiment on the lunar surface. In particular, for a hypothetical lunar ore field it is estimated that a gamma-ray spectrometer with 10 times larger total effective area, than one used for the experimental set-up, may detect Cerium gamma-ray line at 553 keV after 1.6 h of signal accumulations.

Hunting for interstellar molecules: rotational spectra of reactive species.

Interstellar molecules are often highly reactive species, which are unstable under terrestrial conditions, such as radicals, ions and unsaturated carbon chains. Their detection in space is usually based on the astronomical observation of their rotational fingerprints. However, laboratory investigations have to face the issue of efficiently producing these molecules and preserving them during rotational spectroscopy measurements. A general approach for producing and investigating unstable/reactive species is presented by means of selected case-study molecules. The overall strategy starts from quantum-chemical calculations that aim at obtaining accurate predictions of the missing spectroscopic information required to guide spectral analysis and assignment. Rotational spectra of these species are then recorded by exploiting the approach mentioned above, and their subsequent analysis leads to accurate spectroscopic parameters. These are then used for setting up accurate line catalogs for astronomical searches.

Rotational Spectra of Unsaturated Carbon Chains Produced by Pyrolysis: The Case of Propadienone, Cyanovinylacetylene, and Allenylacetylene.

Several interstellar molecules are highly reactive unsaturated carbon chains, which are unstable under terrestrial conditions. Laboratory studies in support of their detection in space thus face the issue of how to produce these species and how to correctly model their rotational energy levels. In this work, we introduce a general approach for producing and investigating unsaturated carbon chains by means of selected test cases. We report a comprehensive theoretical/experimental spectroscopic characterization of three species, namely, propadienone, cyanovinylacetylene, and allenylacetylene, all of them being produced by means of flash vacuum pyrolysis of a suitable precursor. For each species, quantum-chemical calculations have been carried out with the aim of obtaining accurate predictions of the missing spectroscopic information required to guide spectral analysis and assignment. Rotational spectra of the title molecules have been investigated up to 400 GHz by using a frequency-modulation millimeter-/submillimeter-wave spectrometer, thus significantly extending spectral predictions over a wide range of frequency and quantum numbers. A comparison between our results and those available in the literature points out the clear need of the reported laboratory measurements at higher frequencies for setting up accurate line catalogs for astronomical searches.

The Dwarf Galaxy Population at z ∼ 0.7: A Catalog of Emission Lines and Redshifts from Deep Keck Observations

We present a catalog of spectroscopically measured redshifts over 0 < z < 2 and emission-line fluxes for 1440 galaxies. The majority (∼65%) of the galaxies come from the HALO7D survey, with the remainder from the DEEPwinds program. This catalog includes redshifts for 646 dwarf galaxies with . Eight-hundred and ten catalog galaxies did not have previously published spectroscopic redshifts, including 454 dwarf galaxies. HALO7D used the DEIMOS spectrograph on the Keck II telescope to take very deep (up to 32 hr exposure, with a median of ∼7 hr) optical spectroscopy in the COSMOS, EGS, GOODS-North, and GOODS-South CANDELS fields, and in some areas outside CANDELS. We compare our redshift results to existing spectroscopic and photometric redshifts in these fields, finding only a 1% rate of discrepancy with other spectroscopic redshifts. We measure a small increase in median photometric redshift error (from 1.0% to 1.3%) and catastrophic outlier rate (from 3.5% to 8%) with decreasing stellar mass. We obtained successful redshift fits for 75% of massive galaxies, and demonstrate a similar 70%–75% successful redshift measurement rate in galaxies, suggesting similar survey sensitivity in this low-mass range. We describe the redshift, mass, and color–magnitude distributions of the catalog galaxies, finding HALO7D galaxies representative of CANDELS galaxies up to i-band magnitudes of 25. The catalogs presented will enable studies of star formation, the mass–metallicity relation, star formation–morphology relations, and other properties of the z ∼ 0.7 dwarf galaxy population.

Spectroscopic Characterization of 3-Aminoisoxazole, a Prebiotic Precursor of Ribonucleotides.

The processes and reactions that led to the formation of the first biomolecules on Earth play a key role in the highly debated theme of the origin of life. Whether the first chemical building blocks were generated on Earth (endogenous synthesis) or brought from space (exogenous delivery) is still unanswered. The detection of complex organic molecules in the interstellar medium provides valuable support to the latter hypothesis. To gather more insight, here we provide the astronomers with accurate rotational frequencies to guide the interstellar search of 3-aminoisoxazole, which has been recently envisaged as a key reactive species in the scenario of the so-called RNA-world hypothesis. Relying on an accurate computational characterization, we were able to register and analyze the rotational spectrum of 3-aminoisoxazole in the 6–24 GHz and 80–320 GHz frequency ranges for the first time, exploiting a Fourier-transform microwave spectrometer and a frequency-modulated millimeter/sub-millimeter spectrometer, respectively. Due to the inversion motion of the −NH2 group, two states arise, and both of them were characterized, with more than 1300 lines being assigned. Although the fit statistics were affected by an evident Coriolis interaction, we were able to produce accurate line catalogs for astronomical observations of 3-aminoisoxazole.

Museums’ accessibility for senior citizens: Some evidence from Italy

This paper uses the information on elderly visitors, drawn from a survey carried out by the Italian National Institute of Statistics (ISTAT) in 2018, to identify the factors that facilitate or hinder senior tourists’ visits to museums. The resulting evidence captures how the accessibility of museums impacts the share of elderly visitors who have access problems and higher need of assistance and, therefore, provides useful information to improve cultural supply. The econometric analysis shows some significant relationships between the dependent variable, namely, the share of senior visitors on the total visitors, and the dummy variables employed as regressors indicating the existence of free admission for a certain category of visitors who have a problem of access, free admission for accompanying person, the presence of communication/promotional campaigns aimed at seniors visitors, the presence of an on- line catalogue, and support for visitors with access difficulties. Monetary reasons are not a major hindrance to enjoy cultural sites. The study further outlines certain aspects that should be taken into account to increase senior citizens’ participation in museum activities.

Ultra-deep 31.0–50.3 GHz spectral survey of IRC+10216

Context. The carbon-rich envelope of the asymptotic giant branch star CW Leo, IRC+10216, is one of the richest molecular sources in the sky. Available spectral surveys below 51 GHz are more than 25 years old, and new work is needed. Aims. Characterizing the rich molecular content of this source, specially for heavy species, requires carrying out very sensitive spectral surveys at low frequencies. In particular, we have achieved an rms in the range 0.2−0.6 mK per MHz. Methods. Long Q band (31.0−50.3 GHz) single-dish integrations were carried out with the Yebes-40m telescope using specifically built receivers. The most recent line catalogs were used to identify the lines. Results. The data contain 652 spectral features, corresponding to 713 transitions from 81 species (we count the isomers, isotopologs, and ortho/para species separately). Only 57 unidentified lines remain with signal-to-noise ratios ≥3. Some new species and/or vibrational modes have been discovered for the first time with this survey. Conclusions. This IRC+10216 spectral survey is by far the most sensitive survey carried out to date in the Q band. It therefore provides the most complete view of IRC+10216 from 31.0 to 50.3 GHz, giving unique information about its molecular content, especially for heavy species. Rotational diagrams built from the data provide valuable information about the physical conditions and chemical content of this circumstellar envelope.

A high-spectral-resolution catalog of emission lines in the visible spectrum of comet C/2020 F3 (NEOWISE)

Aims. Comet C/2020 F3 (NEOWISE) is considered to be the brightest comet observed in the northern hemisphere since the passage of comet C/1995 O1 (Hale-Bopp) in 1997. Since the study of comets offers a unique opportunity to investigate the early stages of the formation and evolution of our Sun and the Solar System, we obtained high-resolution optical spectra (R = λ/Δλ = 11 5000) of comet NEOWISE. The unique passage and its brightness yielded spectra with a large number of emission lines, providing information on the coma composition and the physical and chemical processes occurring in the nucleus. The spectra have been used to generate a catalog of emission lines to be used for future studies of comets since there are no catalogs in the literature with such a high spectral resolution. Methods. Two high-resolution spectra of comet NEOWISE were obtained, on 26 July 2020 (geocentric distance of 0.7 AU) and 5 August 2020 (geocentric distance of 0.89 AU), with the High Accuracy Radial velocity Planet Searcher for the Northern hemisphere (HARPS-N) echelle spectrograph installed on the 360 cm Telescopio Nazionale Galileo. The spectra cover the range between 383 and 693 nm, and have been extracted using the HARPS-N Data Reduction Pipeline. To analyze the spectra and compile the high-resolution catalog, we collected several laboratory molecular line lists that cover the same wavelength range as that of our spectra. To validate the final identification, we compared our catalog with other atlases that resulted from the spectral analysis of other comets. Results. We generate a high-spectral-resolution catalog of emission lines observed in comet NEOWISE, providing the identification for 4488 lines. We found cometary lines due to CN, CH, C2, C3, and NH2 and atomic lines due to NaI and [OI].

Ionized emission and absorption in a large sample of ultraluminous X-ray sources

ABSTRACT Most ultraluminous X-ray sources (ULXs) are thought to be powered by super-Eddington accretion on to stellar-mass compact objects. Accretors in this extreme regime are naturally expected to ionize copious amounts of plasma in their vicinity and launch powerful radiation-driven outflows from their discs. High spectral resolution X-ray observations [with reflection grating spectrometer (RGS) gratings onboard XMM–Newton] of a few ULXs with the best data sets indeed found complex line spectra and confirmed such extreme (0.1–0.3c) winds. However, a search for plasma signatures in a large ULX sample with a rigorous technique has never been performed, thereby preventing us from understanding their statistical properties such as the rate of occurrence, to constrain the outflow geometry, and its duty cycle. We developed a fast method for automated line detection in X-ray spectra and applied it to the full RGS ULX archive, rigorously quantifying the statistical significance of any candidate lines. Collecting the 135 most significant features detected in 89 observations of 19 objects, we created the first catalogue of spectral lines detected in soft X-ray ULX spectra. We found that the detected emission lines are concentrated around known rest-frame elemental transitions and thus originate from low-velocity material. The absorption lines instead avoid these transitions, suggesting they were imprinted by blueshifted outflows. Such winds therefore appear common among the ULX population. Additionally, we found that spectrally hard ULXs show fewer line detections than soft ULXs, indicating some difference in their accretion geometry and orientation, possibly causing overionization of plasma by the harder spectral energy distributions of harder ULXs.

A MUSE spectro-imaging study of the Th 28 jet: Precession in the inner jet

Context. Th 28 is a Classical T Tauri star in the Lupus 3 cloud that drives an extended bipolar jet. Previous studies of the inner jet identified signatures of rotation around the outflow axis, a key result for theories of jet launching. Thus this is an important source in which to investigate the poorly understood jet launching mechanism. Aims. In this study we investigate the morphology and kinematics of the Th 28 micro-jets, with the aim of characterising their structure and outflow activity, using optical integral-field spectroscopy observations obtained with VLT/MUSE. Methods. We use spectro-imaging and position–velocity maps to investigate the kinematic and morphological features of the jet and to obtain a catalogue of emission lines in which the jet is visible. A Lucy-Richardson deconvolution procedure is used to differentiate the structure of the inner micro-jet region in selected emission lines. Spatial profiles extracted perpendicular to the jet axis are fitted to investigate the jet width, opening angle, and the evolution of the jet axis. Results. We confirm the previously identified knot HHW2 within the red-shifted jet and identify three additional knots in each lobe for the first time. We also find [O III]λ5007 emission from the blue-shifted micro-jet, including the knot closest to the star. Proper motions for the innermost knots on each side are estimated to be 0′′.35 yr−1 and 0′′.47 yr−1 for the red- and blue-shifted jets, respectively. Based on this we show that new knots are ejected on an approximate timescale of 10–15 yr. Gaussian fitting to the jet axis centroids shows a point-symmetric wiggle within the inner portion of both micro-jets, indicating precession of the jet. We use the jet shape to measure a precession period of 8 yr, with a half-opening angle β &lt; 0.6°. This precession may provide an alternative explanation for the rotation signatures previously reported. Conclusions. We find that these parameters are compatible with precession due to a brown dwarf companion orbiting at a separation of ≤0.3 au. Further observations with higher spatial resolution may help to clarify the source of this precession.

SISTEMA: A large and standardized collection of transcriptome data sets for human pluripotent stem cell research

SummaryHuman pluripotent stem cells have ushered in an exciting new era for disease modeling, drug discovery, and cell therapy development. Continued progress toward realizing the potential of human pluripotent stem cells will be facilitated by robust data sets and complementary resources that are easily accessed and interrogated by the stem cell community. In this context, we present SISTEMA, a quality-controlled curated gene expression database, built on a valuable catalog of human pluripotent stem cell lines, and their derivatives for which transcriptomic analyses have been generated using a single experimental pipeline. SISTEMA functions as a one-step resource that will assist the stem cell community to easily evaluate the expression level for genes of interest, while comparing them across different hPSC lines, cell types, pathological conditions, or after pharmacological treatments.

Improved centrifugal and hyperfine analysis of ND2H and NH2D and its application to the spectral line survey of L1544

Quantifying molecular abundances of astrochemical species is a key step towards the understanding of the chemistry occurring in the interstellar medium. This process requires a profound knowledge of the molecular energy levels, including their structure resulting from weak interactions between nuclear spins and the molecular rotation. With the aim of increasing the quality of spectral line catalogs for the singly- and doubly-deuterated ammonia (NH2D and ND2H), we have revised their rotational spectra by observing many hyperfine-resolved lines and more accurate high-frequency transitions. The measurements have been performed in the submillimeter-wave region (265–1565 GHz) using a frequency modulation submillimeter spectrometer and in the far-infrared domain (45–220 cm−1) with a synchrotron-based Fourier-transform interferometer. The analysis of the new data, with the interpretation of the hyperfine structure supported by state-of-the-art quantum-chemical calculations, led to an overall improvement of all spectroscopic parameters. Moreover, the effect of the inclusion of deuterium splittings in the analysis of astrophysical NH2D emissions at millimeter wavelengths has been tested using recent observations of the starless core L1544, an ideal astrophysical laboratory for the study of deuterated species. Our results show that accounting for hyperfine interactions leads to a small but significant change in the physical parameters used to model NH2D line emissions.

SISTEMA: A Large and Standardized Collection of Transcriptome Datasets for Human Pluripotent Stem Cell Research

Human pluripotent stem cells have ushered in an exciting new era for disease modelling, drug discovery and cell therapy development. Continued progress toward realizing the potential of human pluripotent stem cells will be facilitated by robust datasets and complementary resources that are easily accessed and interrogated by the stem cell community.In this context, we present SISTEMA, a quality-controlled curated gene expression database, built on a valuable catalogue of human pluripotent stem cell lines and their derivatives for which transcriptomic analyses have been generated using a single experimental pipeline. SISTEMA functions as a one-step resource that will assist the stem cell community to easily evaluate the expression level for genes of interest, while comparing them across different hPSC lines, cell types, pathological conditions or after pharmacological treatments.