Cassini Composite Infrared Spectrometer Research Articles

A pole-to-pole map of hydrocarbons in Saturn’s upper stratosphere and mesosphere

We analyze data from the final two years of the Cassini mission to retrieve the distributions of methane (CH4), ethane (C2H6), acetylene (C2H2), ethylene (C2H4), and benzene (C6H6) in Saturn’s upper stratosphere and mesosphere from stellar occultations observed by the Ultraviolet Imaging Spectrograph (UVIS), spanning latitudes from pole to pole. These observations represent the first two-dimensional snapshot of the photochemical production region with latitude and depth for these five light hydrocarbons around the northern summer solstice. To support this analysis, we combine temperature-pressure profiles retrieved from the UVIS occultations and limb scans observed by the Cassini Composite Infrared Spectrometer (CIRS) with the CH4 profiles to provide atmospheric structure models for each occultation location that span the middle and upper atmosphere. We detect a strong meridional trend in the homopause pressure level that implies much weaker mixing at the poles than near the subsolar point. This is shown by the homopause pressure level, which ranges from ∼0.05μbar around the subsolar point to ∼5μbar at the poles, with the corresponding values of the eddy diffusion coefficient Kzz ranging from ∼1000 m2 s−1 to 1-10 m2 s−1, respectively, at the 2 μbar level. This trend could be explained by upwelling at low latitudes and downwelling at high latitudes in both hemispheres and we estimate that vertical wind speeds of less than 2 cm s−1 would be required. The distributions of the photochemical products follow the homopause trend but they also show a clear seasonal trend at pressures between 0.01 and 10 μbar, with higher abundances in the summer hemisphere than in the winter hemisphere. We compare the observed distributions with results from one-dimensional seasonal photochemical models, with and without ion chemistry, to explore the impact of ion chemistry on the results. The best agreement between the models and the observations is obtained in the summer hemisphere, whereas disagreements in the winter hemisphere and auroral region may be due to the lack of transport by global circulation and auroral electron and ion precipitation in our photochemical models. Ion chemistry is particularly important for matching the observed C6H6 distribution, whereas differences between the neutral only and ion chemistry models are more modest for the other species. We also compare the C2H2 profiles retrieved from the UVIS occultations to those retrieved from the CIRS limb scans and find good agreement between the retrievals at pressures where they overlap.

Temporal Evolution of Titan’s Stratospheric Temperatures and Trace Gases from a Two-dimensional Retrieval of Cassini Composite Infrared Spectrometer Data

We use a two-dimensional (2D) radiative transfer model of Titan, which allows the atmospheric structure to vary in both altitude and latitude, to retrieve the spatial distribution of temperature, haze extinction, and C2H2, C2H6, C3H8, CH3C2H, C4H2, and HCN gases, from Cassini Composite Infrared Spectrometer (CIRS) limb-mapping observations over the duration of the Cassini mission. We compare our results with previous analyses of CIRS limb observations using radiative models that only allow the atmosphere to vary in altitude. The temperature, haze, and gas composition retrieved with the 2D model mostly show the same broad spatial and temporal trends as previously published results from 1D models. However, there are some significant differences in the retrieved structure at the fall and winter poles poleward of 60°. Most noticeably, the HCN abundance in the depleted region near 65°N at 350 km in northern winter is stronger in the 2D retrievals than in previous 1D retrievals, and the 2D retrievals show very different structure from earlier 1D retrievals in the north polar C2H2 structure during early northern spring, with a strong depletion around 70°N at 0.02 mbar.

Cassini composite infrared spectrometer: correcting an offset error and refining the pointing parameters for the midinfrared detectors.

Based on preflight laboratory testing, an unexpectedly large positional offset between the two midinfrared (mid-IR) detector arrays in the Cassini composite infrared spectrometer (CIRS) instrument has been noted in the literature. A much smaller offset was measured in-flight. We investigate this discrepancy by estimating several spatial relationships among the detectors and comparing these results with three independent data sets. This enables us to infer the probable cause of this offset and to derive a new reduced value. We comment on the effect that this change could have on previously published results involving CIRS data. We also present a graphical display of the arrays projected on the sky as CIRS would see it.

Spitzer IRS Observations of Titan as a Precursor to JWST MIRI Observations

In this work, we present for the first time infrared spectra of Titan from the Spitzer Space Telescope (2004–2009). The data are from both the short wavelength–low resolution (SL; 5.13–14.29 μm, R ∼ 60–127) and short wavelength–high resolution (SH; 9.89–19.51 μm, R ∼ 600) channels showing the emissions of CH4, C2H2, C2H4, C2H6, C3H4, C3H6, C3H8, C4H2, HCN, HC3N, and CO2. We compare the results obtained for Titan from Spitzer to those of the Cassini Composite Infrared Spectrometer (CIRS) for the same time period, focusing on the 16.35–19.35 μm wavelength range observed by the SH channel but impacted by higher noise levels in the CIRS observations. We use the SH data to provide estimated haze extinction cross sections for the 16.67–17.54 μm range that are missing in previous studies. We conclude by identifying spectral features in the 16.35–19.35 μm wavelength range that could be analyzed further through upcoming James Webb Space Telescope Cycle 1 observations with the Mid-Infrared Instrument (5.0–28.3 μm, R ∼ 1500–3500). We also highlight gaps in the current spectroscopic knowledge of molecular bands, including candidate trace species such as C60 and detected trace species such as C3H6, that could be addressed by theoretical and laboratory study.

Optical Properties of Cyanoacetylene Ices in the Far- to Near-infrared with Direct Relevance to Titan's Stratospheric Ice Clouds

Abstract Cyanoacetylene (HC3N) ice has been observed in Titan’s stratosphere by both Voyager 1's InfraRed Interferometer Spectrometer (IRIS) and Cassini's Composite InfraRed Spectrometer (CIRS), and it is likely prevalent in other objects in our solar system and exoplanetary systems as well. While previous experimental studies targeting Titan’s stratospheric clouds have determined the optical properties of HC3N ice in the infrared (IR) spectral range, those thin ice films were formed by annealing processes, which contradicts the formation mechanism of Titan’s stratospheric ice clouds. As a result, optical constants of HC3N ices, experimentally created in a similar manner to the way they are formed in Titan’s stratosphere, are crucial. Here we experimentally measured absorbance spectra of HC3N thin ice films from the near- to far-IR spectral region (50–8000 cm−1; 200–1.25 μm) formed via direct vapor deposition at 30, 50, 70, 90, 110, and 113 K. The corresponding optical constants at all temperatures were also computed, resulting in the largest continuous IR spectral range available for HC3N ice. New tentative peak assignments for spectral features in the near-IR are also reported, thereby further enhancing the inventory of optical constants available for HC3N ice spanning the near- to far-IR spectral range.

Infrared Spectra, Optical Constants, and Temperature Dependences of Amorphous and Crystalline Benzene Ices Relevant to Titan

Abstract Benzene ice contributes to an emission feature detected by the Cassini Composite InfraRed Spectrometer (CIRS) near 682 cm−1 in Titan’s late southern fall polar stratosphere. It is also one of the dominant components of the CIRS-observed High-Altitude South Polar ice cloud observed in Titan’s mid stratosphere during late southern fall. Titan’s stratosphere exhibits significant seasonal changes with temperatures that spatially vary with seasons. A quantitative analysis of the chemical composition of infrared emission spectra of Titan’s stratospheric ice clouds relies on consistent and detailed laboratory transmittance spectra obtained at numerous temperatures. However, there is a substantial lack of experimental data on the spectroscopic and optical properties of benzene ice and its temperature dependence, especially at Titan-relevant stratospheric conditions. We have therefore analyzed in laboratory the spectral characteristics and evolution of benzene ice’s vibrational modes at deposition temperatures ranging from 15 to 130 K, from the far- to mid-IR spectral region (50–8000 cm−1). We have determined the amorphous-to-crystalline phase transition of benzene ice and identified that a complete crystallization is achieved for deposition temperatures between 120 and 130 K. We have also measured the real and imaginary parts of the ice complex refractive index of benzene ice from 15 to 130 K. Our experimental results significantly extend the current state of knowledge on the deposition temperature dependence of benzene ice over a broad infrared spectral range, and provide useful new data for the analysis and interpretation of Titan-observed spectra.

Energy deposition in Saturn’s equatorial upper atmosphere

We construct Saturn equatorial neutral temperature and density profiles of H, H2, He, and CH4, between 10−12 and 1 bar using measurements from Cassini’s Ion Neutral Mass Spectrometer (INMS) taken during the spacecraft’s final plunge into Saturn’s atmosphere on 15 September 2017, combined with previous deeper atmospheric measurements from the Cassini Composite InfraRed Spectrometer (CIRS) and from the UltraViolet Imaging Spectrograph (UVIS). These neutral profiles are fed into an energy deposition model employing soft X-ray and Extreme UltraViolet (EUV) solar fluxes at a range of spectral resolutions (Δλ=4×10−3nm to 1 nm) assembled from TIMED/SEE, from SOHO/SUMER, and from the Whole Heliosphere Interval (WHI) quiet Sun campaign. Our energy deposition model calculates ion production rate profiles through photo-ionisation and electron-impact ionisation processes, as well as rates of photo-dissociation of CH4. The ion reaction rate profiles we determine are important to obtain accurate ion density profiles, meanwhile methane photo-dissociation is key to initiate complex organic chemical processes. We assess the importance of spectral resolution in the energy deposition model by using a high-resolution H2 photo-absorption cross section, which has the effect of producing additional ionisation peaks near 800 km altitude. We find that these peaks are still formed when using low-resolution (Δλ=1nm) or mid-resolution (Δλ=0.1nm) solar spectra, as long as high-resolution cross sections are included in the model.

Investigating the Condensation of Benzene (C6H6) in Titan’s South Polar Cloud System with a Combination of Laboratory, Observational, and Modeling Tools

Abstract We have combined laboratory, modeling, and observational efforts to investigate the chemical and microphysical processes leading to the formation of the cloud system that formed at an unusually high altitude (>250 km) over Titan’s south pole after the northern spring equinox. We present here a study focused on the formation of C6H6 ice clouds at 87°S. As the first step of our synergistic approach, we have measured, for the first time, the equilibrium vapor pressure of pure crystalline C6H6 at low temperatures (134–158 K) representative of Titan’s atmosphere. Our laboratory data indicate that the experimental vapor pressure values are larger than those predicted by extrapolations found in the literature calculated from higher-temperature laboratory measurements. We have used our experimental results along with temperature profiles and C6H6 mixing ratios derived from observational data acquired by the Cassini Composite Infrared Spectrometer (CIRS) as input parameters in the coupled microphysics radiative transfer Community Aerosol and Radiation Model for Atmospheres (CARMA). CARMA simulations constrained by these input parameters were conducted to derive C6H6 ice particle size distribution, gas volume mixing ratios, gas relative humidity, and cloud altitudes. The impact of the vapor pressure on the CIRS data analysis and in the CARMA simulations was investigated and resulted in both cases in benzene condensation occurring at lower altitude in the stratosphere than previously thought. In addition, the stratospheric C6H6 gas abundances predicted with the new saturation relationship are ∼1000× higher than previous calculations between 150–200 km, which results in larger particle sizes.

Ray-tracing thermal modelling of Saturn's main rings

The observations of the Cassini spacecraft gave new perspectives to our understanding of the rings of Saturn and their thermal studies due to their large variety of observation geometries. However, we still know little about the ring particles' physical and, particularly, thermal properties, which is the reason why a number of observations are not easy to explain. Nevertheless, the observed temperature profiles of the rings can be reproduced by considering the rings' general structural properties like local optical depth, τ, and, for the optically-thick rings, wake properties like the ratios H/W or wake thickness to wake width, and S/W or wake separation to wake width; as well as their main energy input sources (e. g., direct and reflected solar energy and Saturn's infrared energy).In this work, we assume that the main rings (C, B, Cassini Division and A rings) are monolayers and study the temperature variations with solar elevation angle, B′, of ten of their regions with a simple thermal balance equation that depends on the rings' shadowing behaviour due to the illumination geometry (B′) and the arrangement of particles across the rings (τ). The shadowing is a key feature, which we reproduce with a numerical function obtained via ray tracing from arrays of spherical particles (C(B′,τ)). Using the former model, we fit Cassini Composite Infrared Spectrometer (CIRS) temperature data with the Bond albedo, AV, and the so-called rotation parameter, f (which represents the rotation status of the ring particles) as only parameters. These parameters are two of the most important physical properties that define the rings' temperatures.With our method, we are able to reproduce the CIRS data temperature trends of the selected regions reasonably well. For evaluation purposes we compare the derived Bond albedo values with those obtained with the Cassini Imaging Science Subsystem (ISS) at wavelengths in the range 451 ≲ λ ≲ 650nm. The comparison suggests a dominance of slow rotators. Additionally, we evaluate the differences obtained when using either a numerical or an analytical shadowing function (in particular, that by (Altobelli et al., 2008)) in the thermal model. The differences between these two approaches reflect some details of the structure of the ring regions we study.

Seasonal changes in the middle atmosphere of Titan from Cassini/CIRS observations: Temperature and trace species abundance profiles from 2004 to 2017

The Cassini/Composite InfraRed Spectrometer (CIRS) instrument has been observing the middle atmosphere of Titan over almost half a Saturnian year. We used the CIRS dataset processed through the up-to-date calibration pipeline to characterize seasonal changes of temperature and abundance profiles in the middle atmosphere of Titan, from mid-northern winter to early northern summer all around the satellite. We used limb spectra from 590 to 1500 cm−1 at 0.5-cm−1 spectral resolution, which allows us to probe different altitudes. We averaged the limb spectra recorded during each flyby on a fixed altitude grid to increase the signal-to-noise ratio. These thermal infrared data were analyzed by means of a radiative transfer code coupled with an inversion algorithm, in order to retrieve vertical temperature and abundance profiles. These profiles cover an altitude range of approximately 100 to 600 km, at 10- or 40-km vertical resolution (depending on the observation). Strong changes in temperature and composition occur in both polar regions where a vortex is in place during the winter. At this season, we observe a global enrichment in photochemical compounds in the mesosphere and stratosphere and a hot stratopause located around 0.01 mbar, both linked to downwelling in a pole-to-pole circulation cell. After the northern spring equinox, between December 2009 and April 2010, a stronger enhancement of photochemical compounds occurred at the north pole above the 0.01-mbar region, likely due to combined photochemical and dynamical effects. During the southern autumn in 2015, above the South pole, we also observed a strong enrichment in photochemical compounds that contributed to the cooling of the stratosphere above 0.2 mbar (∼300 km). Close to the northern spring equinox, in December 2009, the thermal profile at 74°N exhibits an oscillation that we interpret in terms of an inertia-gravity wave.

Titan's neutral atmosphere seasonal variations up to the end of the Cassini mission

In this paper we report new results concerning the seasonal atmospheric evolution near Titan's poles and equator in terms of temperature and composition using nadir spectra acquired by the Cassini Composite Infrared Spectrometer (CIRS) at high spectral resolution during the last year of the Cassini mission in 2017 complementing previous investigations covering almost two Titan seasons. In recent previous papers (Coustenis et al., 2016, 2018), we have reported on monitoring of Titan's stratosphere near the poles after the mid-2009 northern spring equinox. In particular we have reported on the observed strong temperature decrease and compositional enhancement above Titan's southern polar latitudes since 2012 and until 2014 of several trace species, such as complex hydrocarbons and nitriles, which were previously observed only at high northern latitudes. This effect accompanied the transition of Titan's seasons from northern winter in 2002 to northern summer in 2017, while at that latter time, the southern hemisphere was entering winter. Our new data, acquired in 2017 and analyzed here, are important because they are the only ones recorded since 2014 close to the south pole in the mid-infrared nadir mode at high resolution. A large temperature increase in the southern polar stratosphere (by 10–50 K in the 0.1 mbar–0.01 mbar pressure range) is found associated with a change in the temperature profile's shape. The 2017 observations also show a related significant decrease in most of the southern abundances which must have started sometime between 2014 and 2017. For the north, the spectra indicate a continuation of the decrease of the abundances which we first reported to have started in 2015 and small temperature variations. We discuss comparisons with other results and with current photochemical and dynamical models which could be updated and improved by the new constraints set by the findings presented here.

Detailed infrared study of amorphous to crystalline propionitrile ices relevant to observed spectra of Titan's stratospheric ice clouds

We have conducted a comprehensive study of propionitrile (C2H5CN) ice from the amorphous to crystalline phase in order to provide detailed information on this specific cyanide, which may potentially contribute to the chemical composition of the Haystack ice cloud observed in Titan's stratosphere by the Cassini Composite InfraRed Spectrometer (CIRS). Infrared transmission spectra of thin films of pure propionitrile ices deposited at low temperature (30–160 K) were collected from 50 cm−1 to 11,700 cm−1 (200–0.85 μm). The far-infrared spectral region was specifically targeted to compare with CIRS far-infrared limb spectra. The temperature and time evolution of C2H5CN ice was thoroughly investigated to better understand discrepancies reported in previously published laboratory studies on the crystalline phase of C2H5CN. Specifically, we observe peculiar temperature and time-driven ice phase transitions, revealed by significant spectral variations in the ice, which stabilizes once a complete crystalline phase is achieved. From these results, the crystalline phase of propionitrile ice was identified at deposition temperatures greater than or equal to 135 K and <140 K. Our findings corroborate previous studies that ruled out pure propionitrile ice as the sole chemical identity of Titan's observed Haystack emission feature. In order to understand and identify the Haystack cloud, we have initiated co-deposition experiments that incorporate mixtures of Titan-relevant organics, many of which have corresponding vapors that are abundantly present in Titan's stratosphere. In this paper, we present the result of one example of a co-deposited ternary ice mixture containing 16% hydrogen cyanide (HCN), 23% C2H5CN, and 61% benzene (C6H6). Although this co-condensed ice mixture is the best fit thus far obtained to match the broad width of the Haystack, it is still not the appropriate chemical candidate. However, it reveals an intriguing result: the strong lattice mode of pure C2H5CN ice is drastically altered by the surrounding molecules as a result of mixing in a co-condensed phase. The laboratory results reported here on propionitrile ice may help to further constrain the chemical identification of Titan's stratospheric Haystack ice cloud, as well as improve on the current state of knowledge of Titan's stratospheric ice cloud chemistry.

Ethane in Titan’s Stratosphere from Cassini CIRS Far- and Mid-infrared Spectra

The Cassini Composite Infrared Spectrometer (CIRS) observed thermal emission in the far- and mid-infrared (from 10 cm$^{-1}$ to 1500 cm$^{-1}$), enabling spatiotemporal studies of ethane on Titan across the span of the Cassini mission from 2004 through 2017. Many previous measurements of ethane on Titan have relied on modeling the molecule's mid-infrared $\nu_{12}$ band, centered on 822 cm$^{-1}$. Other bands of ethane at shorter and longer wavelengths were seen, but have not been modeled to measure ethane abundance. Spectral line lists of the far-infrared $\nu_{4}$ torsional band at 289 cm$^{-1}$ and the mid-infrared $\nu_{8}$ band centered ay 1468 cm$^{-1}$ have recently been studied in the laboratory. We model CIRS observations of each of these bands (along with the $\nu_{12}$ band) separately and compare retrieved mixing ratios from each spectral region. Nadir observations of of the $\nu_{4}$ band probe the low stratosphere below 100 km. Our equatorial measurements at 289 cm$^{-1}$ show an abundance of (1.0$\pm$0.4) $\times$10$^{-5}$ at 88 km, from 2007 to 2017. This mixing ratio is consistent with measurements at higher altitudes, in contrast to the depletion that many photochemical models predict. Measurements from the $\nu_{12}$ and $\nu_{8}$ bands are comparable to each other, with the $\nu_{12}$ band probing an altitude range that extends deeper in the atmosphere. We suggest future studies of planetary atmospheres may observe the $\nu_{8}$ band, enabling shorter wavelength studies of ethane. There may also be an advantage to observing both the ethane $\nu_{8}$ band and nearby methane $\nu_{4}$ band in the same spectral window.

Seasonal evolution of Titan's stratosphere during the Cassini mission.

Titan's stratosphere exhibits significant seasonal changes, including break-up and formation of polar vortices. Here we present the first analysis of mid-infrared mapping observations from Cassini's Composite InfraRed Spectrometer (CIRS) to cover the entire mission (Ls=293-93°, 2004-2017) - mid-northern winter to northern summer solstice. The north-polar winter vortex persisted well after equinox, starting break-up around Ls∼60°, and fully dissipating by Ls∼90°. Absence of enriched polar air spreading to lower latitudes suggests large-scale circulation changes and photochemistry control chemical evolution during vortex break-up. South-polar vortex formation commenced soon after equinox and by Ls∼60° was more enriched in trace gases than the northern mid-winter vortex and had temperatures ∼20 K colder. This suggests early-winter and mid-winter vortices are dominated by different processes - radiative cooling and subsidence-induced adiabatic heating respectively. By the end of the mission (Ls=93°) south-polar conditions were approaching those observed in the north at Ls=293°, implying seasonal symmetry in Titan's vortices.

Cassini CIRS and ISS opposition effects of Saturn’s rings – I. C ring narrow or broad surge?

Abstract We focus on the thermal and optical opposition effects of Saturn’s C ring seen by Cassini CIRS (Composite InfraRed Spectrometer) at 15.7 ${\mu}$m and ISS (Imaging Science Subsystem) at 0.6 ${\mu}$m. The opposition surge is a brightness peak observed at low phase angle (α → 0°). Saturn rings’ opposition surge was recently observed in reflected light and thermal infrared emission by Cassini. There is debate on whether the C ring’s thermal opposition surge width is narrow (≲1°) or broad (≳30°). This surge is important because its width was used to define the scale of ring properties driving the thermal peak. We parametrize the CIRS and ISS phase curves with several morphological models to fit the surge shape. For five of the largest C ring’s plateaus, we find that their thermal surge is 10 times wider than the optical surge and that the thermal surge width (∼4°) is neither narrow, nor broad. We compare radial differences between CIRS and ISS surge morphologies with the optical depth τ (from UVIS, UltraViolet Imaging Spectrograph) and water ice band depth (from VIMS, Visual and Infrared Mapping Spectrometer) profiles. We find that: water ice band depths (microscopic ring signatures) and τ (macroscopic ring signatures) show respectively little and large contrasts between the background and the plateaus. The thermal surge amplitude and τ are correlated, and we found no band depth dependence, contrary to the optical surge amplitude, which shows no correlation with τ. These correlations suggest a macroscopic scale dominance in controlling the C ring’s thermal opposition effect.

Limits on Dione's Activity Using Cassini/CIRS Data

AbstractWe use nighttime Cassini Composite Infrared Spectrometer (CIRS) data to look for discrete regions of elevated nighttime temperatures indicative of endogenic activity on Dione's surface. This is achieved by producing low latitude and midlatitude (less than 60°) maps of Dione's nighttime surface temperature, derived from 10 to 1,100‐cm−1 CIRS data. The surface temperatures observed do not show evidence of any small discrete regions of elevated nighttime temperatures and are comparable to temperatures predicted by a passive thermophysical model of Dione's surface. Thus, we conclude that no evidence for activity exists on Dione at midlatitude to low latitude. Using the derived surface temperature maps, we set upper limits for the temperature at which a 50‐, 100‐, or 200‐km2 hot spot would remain undetected by this study. We find the mean temperature of such a hot spot would be 117.1 ± 47.2 K (−249 F), 104.8 ± 27.7 K (−272 F), and 95.4 ± 19.5 K (−288 F) for a 50‐, 100‐, and 200‐km2 hot spot, respectively, corresponding to endogenic emission of 1.07, 0.68, and 0.47 GW.

Equatorial Oscillation and Planetary Wave Activity in Saturn's Stratosphere Through the Cassini Epoch

AbstractThermal infrared spectra acquired by Cassini/Composite InfraRed Spectrometer (CIRS) in limb‐viewing geometry in 2015 are used to derive 2‐D latitude‐pressure temperature and thermal wind maps. These maps are used to study the vertical structure and evolution of Saturn's equatorial oscillation (SEO), a dynamical phenomenon presenting similarities with the Earth's quasi‐biennal oscillation (QBO) and semi‐annual oscillation (SAO). We report that a new local wind maximum has appeared in 2015 in the upper stratosphere and derive the descent rates of other wind extrema through time. The phase of the oscillation observed in 2015, as compared to 2005 and 2010, remains consistent with a ∼15 year period. The SEO does not propagate downward at a regular rate but exhibits faster descent rate in the upper stratosphere, combined with a greater vertical wind shear, compared to the lower stratosphere. Within the framework of a QBO‐type oscillation, we estimate the absorbed wave momentum flux in the stratosphere to be on the order of ∼7 × 10−6 N m−2. On Earth, interactions between vertically propagating waves (both planetary and mesoscale) and the mean zonal flow drive the QBO and SAO. To broaden our knowledge on waves potentially driving Saturn's equatorial oscillation, we searched for thermal signatures of planetary waves in the tropical stratosphere using CIRS nadir spectra. Temperature anomalies of amplitude 1–4 K and zonal wave numbers 1 to 9 are frequently observed, and an equatorial Rossby (n = 1) wave of zonal wave number 3 is tentatively identified in November 2009.

Study of Titan’s fall southern stratospheric polar cloud composition with Cassini/CIRS: Detection of benzene ice

We report the detection of a spectral signature observed at 682 cm−1 by the Cassini Composite Infrared Spectrometer (CIRS) in nadir and limb geometry observations of Titan’s southern stratospheric polar region in the middle of southern fall, while stratospheric temperatures are the coldest since the beginning of the Cassini mission. In the same period, many gases observed in CIRS spectra (C2H2, HCN, C4H2, C3H4, HC3N and C6H6) are highly enriched in the stratosphere at high southern latitude due to the air subsidence of the global atmospheric circulation and some of these molecules condense at much higher altitude than usually observed for other latitudes. The 682 cm−1 signature, which is only observed below an altitude of 300 km, is at least partly attributed to the benzene (C6H6) ice ν4 C–H bending mode. While we first observed it in CIRS nadir spectra of the southern polar region in early 2013, we focus here on the study of nadir data acquired in May 2013, which have a more favorable observation geometry. We derived the C6H6 ice mass mixing ratio in 5° latitude bins from the south pole to 65°S and infer the C6H6 cloud top altitude to be located deeper with increasing distance from the pole. We additionally analyzed limb data acquired in March 2015, which were the first limb dataset available after the May 2013 nadir observation, in order to infer a vertical profile of its mass mixing ratio in the 0.1–1 mbar region (250–170 km). We derive an upper limit of ∼1.5 µm for the equivalent radius of pure C6H6 ice particles from the shape of the observed emission band, which is consistent with our estimation of the ice particle size from condensation growth and sedimentation timescales. We compared the ice mass mixing ratio with the haze mass mixing ratio inferred in the same region from the continuum emission of CIRS spectra, and derived that the haze mass mixing ratios are ∼30 times larger than the C6H6 ice mass mixing ratios for all observations. Several other unidentified signatures are observed near 687 and 702 cm−1 and possibly 695 cm−1, which could also be due to ice spectral signatures as they are observed in the deep stratosphere at pressure levels similar to the C6H6 ice ones. We could not reproduce these signatures with pure nitrile ices (HCN, HC3N, CH3CN, C2H5CN and C2N2) spectra available in the literature except the 695 cm−1 feature that could possibly be due to C2H3CN ice. From this tentative detection, we derive the corresponding C2H3CN ice mass mixing ratio profile and also inferred an upper limit of its gas volume mixing ratio of 2 × 10−7 at 0.01 mbar at 79°S in March 2015.

Spatial variations in Titan’s atmospheric temperature: ALMA and Cassini comparisons from 2012 to 2015

Submillimeter emission lines of carbon monoxide (CO) in Titan’s atmosphere provide excellent probes of atmospheric temperature due to the molecule’s long chemical lifetime and stable, well constrained volume mixing ratio. Here we present the analysis of 4 datasets obtained with the Atacama Large Millimeter/Submillimeter Array (ALMA) in 2012, 2013, 2014, and 2015 that contain strong CO rotational transitions. Utilizing ALMA’s high spatial resolution in the 2012, 2014, and 2015 observations, we extract spectra from 3 separate regions on Titan’s disk using datasets with beam sizes ranging from 0.35 × 0.28″ to 0.39 × 0.34″. Temperature profiles retrieved by the NEMESIS radiative transfer code are compared to Cassini Composite Infrared Spectrometer (CIRS) and radio occultation science results from similar latitude regions. Disk-averaged temperature profiles stay relatively constant from year to year, while small seasonal variations in atmospheric temperature are present from 2012 to 2015 in the stratosphere and mesosphere ( ∼ 100–500 km) of spatially resolved regions. We measure the stratopause (320 km) to increase in temperature by 5 K in northern latitudes from 2012 to 2015, while temperatures rise throughout the stratosphere at lower latitudes. We observe generally cooler temperatures in the lower stratosphere ( ∼ 100 km) than those obtained through Cassini radio occultation measurements, with the notable exception of warming in the northern latitudes and the absence of previous instabilities; both of these results are indicators that Titan’s lower atmosphere responds to seasonal effects, particularly at higher latitudes. While retrieved temperature profiles cover a range of latitudes in these observations, deviations from CIRS nadir maps and radio occultation measurements convolved with the ALMA beam-footprint are not found to be statistically significant, and discrepancies are often found to be less than 5 K throughout the atmosphere. ALMA’s excellent sensitivity in the lower stratosphere (60–300 km) provides a highly complementary dataset to contemporary CIRS and radio science observations, including altitude regions where both of those measurement sets contain large uncertainties. The demonstrated utility of CO emission lines in the submillimeter as a tracer of Titan’s atmospheric temperature lays the groundwork for future studies of other molecular species – particularly those that exhibit strong polar abundance enhancements or are pressure-broadened in the lower atmosphere, as temperature profiles are found to consistently vary with latitude in all three years by up to 15 K.

Surface roughness of Saturn’s rings and ring particles inferred from thermal phase curves

We analyze thermal phase curves of all the main rings of Saturn (the A, B, C rings, and the Cassini division) measured by both the far-IR and mid-IR detectors of the Cassini Composite InfraRed Spectrometer (CIRS). All the rings show temperature increases toward zero phase angle, known as an opposition effect or thermal beaming. For the C ring and Cassini division, which have low optical depths, intra-particle shadowing is considered the dominant mechanism causing the effect. On the other hand, the phase curves of the optically thick B and A rings steepen significantly with decreasing absolute solar elevation angle from 21° to 14°, suggesting inter-particle shadowing plays an important role in these rings. We employ an analytic roughness model to estimate the degrees of surface roughness of the rings or ring particles. For optically thin rings, an isolated particle covered by spherical segment craters is employed while for the thick rings we approximate a packed particle layer as a slab covered by craters. The particles in the thin rings are found to have generally rough surfaces, except in the middle C ring. Across the C ring, the optical depth correlates with the degree of surface roughness. This may indicate that surface roughness comes mainly from particle clumping, while individual particles have rather smooth surfaces. For the optically thick rings, the surface roughness of the particle layer is found to be moderate. The modeled phase curves of optically thick rings are shallow if the phase angle change is primarily due to change of observer azimuthal angle. On the other hand, the phase curves are steep if the phase angle change is due to change of observer elevation angle, as inter-particle shadows become visible at higher observer elevation. In addition, the area of shadowed facets increases with decreasing solar elevation angle. These combined effects explain the large seasonal change of the phase curve steepness observed for the thick rings. The degrees of surface roughness inferred from the thermal phase curves are generally less than those from the phase curves in visible light. This is probably explained by different roughness scales seen in thermal and visible light or by dilution of thermal phase curve steepnesses due to particle motion.