Cashew Nut Shell Research Articles

Sulfonic Acid-Functionalized Solid Polymer Catalyst from Crude Cashew Nut Shell Liquid: Synthesis of Tetra(indolyl)methanes and Bis(indolyl)methanes from Xylochemicals

Sulfonic Acid-Functionalized Solid Polymer Catalyst from Crude Cashew Nut Shell Liquid: Synthesis of Tetra(indolyl)methanes and Bis(indolyl)methanes from Xylochemicals

Charcoal Residue from Cashew Nutshells as a Bioadsorbent in Fixed Bed Column for Produced Water

Charcoal Residue from Cashew Nutshells as a Bioadsorbent in Fixed Bed Column for Produced Water

Fabrication and characterization of polyvinyl alcohol/biowaste cashew nut shells powder-based hybrid biocomposite films

Fabrication and characterization of polyvinyl alcohol/biowaste cashew nut shells powder-based hybrid biocomposite films

Effect of Cashew Nutshell Extract, Saponins and Tannins Addition on Methane Emissions, Nutrient Digestibility and Feeding Behavior of Beef Steers Receiving a Backgrounding Diet.

The beef industry contributes to greenhouse gas emissions through enteric methane emissions, exacerbating climate change. Anacardic acid in cashew nutshell extract (CNSE), saponins and tannins (ST) are plant secondary metabolites that show promise in methane mitigation via antimicrobial effects, potentially exerting changes in ruminal fermentation patterns. This study examined the impact of CNSE, ST, and their combination on methane emissions, digestibility, intake, and performance of sixteen Angus crossbred steers (347 ± 30 kg) receiving a backgrounding diet (70:30 corn silage: cottonseed burrs). The study used a 4 × 4 Latin square design (4 steers, 4 treatments, 4 periods) with a 2 × 2 factorial arrangement, including the main effects of additive (CNSE or ST) fed individually or combined. Thus, steers received the following treatments: (1) no additive, (2) CNSE only, (3) ST only, or (4) both (CNSEST). Non-supplemented steers registered eight more feedbunk visits/d than ST-steers and spent an extra 10 min/d on the feedbunk. The addition of ST tended to increase dry matter, organic matter, and neutral detergent fiber intake. Additives fed individually reduced CP digestibility. Intake of the carrier containing CNSE only was lesser and coincided with a greater methane yield in that treatment. Digestibility and methane mitigation were improved after CNSEST compared with individual inclusion, suggesting synergistic reactions enhanced methane mitigation effects in fibrous diets without affecting the digestibility of nutrients nor animal growth performance.

An experimental investigation on enhancing diesel engine performance and emissions with cashew nut shell oil biodiesel and hydrogen fumigation

An experimental investigation on enhancing diesel engine performance and emissions with cashew nut shell oil biodiesel and hydrogen fumigation

The Effect of the Use of a Novel Urease Inhibitor Coated Urea on the Greenhouse Gas Emissions and Ammonia Volatilization Losses from a Maize Field

Nitrogen fertilizers are essential for enhancing agricultural productivity but are also major contributors to greenhouse gas (GHG) emissions and ammonia volatilization, which affect environmental sustainability. This study evaluated the effect of cashew nut shell liquid (CNSL)-coated urea on GHG emissions and ammonia losses from maize fields in the Indo-Gangetic Plains, known for excessive nitrogen fertilizer usage. A randomized block design was employed with four treatments: control (no nitrogen), prilled urea, neem-coated urea (NCU), and CNSL-coated urea (CCU). Gas samples were collected using the closed chamber method, and emissions of CO₂ and N₂O were analyzed via gas chromatography. Ammonia volatilization was measured using the forced air draft method. Results showed that the CCU treatment significantly reduced ammonia volatilization compared to prilled urea (15.84% reduction), with reductions of 9% to those observed with NCU. Moreover, CCU-treated plots exhibited reduced cumulative GHG and lower global warming potential (GWP) without compromising maize yields. Cumulative GHG emissions varied among the treatments in the order urea> CCU> NCU> Control. CCU treated plots exhibited a net GWP decrease of 8.59% compared to urea and an increase of 4.13% compared to NCU. These findings suggest that CNSL-coated urea can serve as an eco-friendly alternative to conventional urea, potentially mitigating environmental impacts associated with nitrogen fertilization. Further studies are recommended to assess the long-term efficacy of CNSL in various soil types and climatic conditions.

Extraction of fermentable sugars and phenolic compounds from Colombian cashew (Anacardium occidentale) nut shells using subcritical water technology: Response surface methodology and chemical profiling

Subcritical water extraction (SCWE) is a novel technology that uses water at high pressure and temperature to recover bioactive compounds. While promising, further studies are needed to fully understand the potential of SCWE when applied to cashew nut shells (CNS), which are rich in phenolic compounds, carbohydrates, and other natural substances. This study aimed to evaluate SCWE applied to CNS from Vichada, Colombia, using a surface response methodology and to perform a comprehensive chemical profiling of the recovered extracts and the remaining solids. A Box-Behnken experimental design was employed to study the extraction process, focusing on variables such as temperature, pressure, and solid-to-solvent ratio. The liquid extracts were analyzed using ultra-high-performance liquid chromatography and gas chromatography coupled with mass spectrometry, while the extracted solids were characterized using Fourier-transform infrared spectroscopy and scanning electron microscopy. The liquid extracts revealed a variety of compounds, including xylose, glucose, arabinose, long-chain phenols, organic acids, and furans. Extraction conditions significantly influenced the distribution of these compounds, with the optimal conditions for extracting fermentable sugars and organic acids identified as 180 °C, 15 bar, and a 20:1 mL/g solid-to-solvent ratio. The resulting hydrochar comprised lignin (58.82 ± 3.44 %) and structural carbohydrates (approximately 40 %), showing thermal stability up to 200 °C, OH functional groups on its surface, and a textured morphology under microscopy. These by-products have potential applications in various fields. This study demonstrates that SCWE effectively recovers valuable compounds from CNS for use in fermentation processes, suggesting that the resulting hydrochar could be utilized in soil amendment, adsorption, or energy applications. SCWE is highlighted as an innovative and environmentally friendly technology for managing cashew residual biomass, promoting sustainability and circularity in this production chain.

Modeling of adsorptive treatment of lead (II) ions contaminated effluents using cashew nut shell alkali activated carbon: Batch kinetic, isothermal and thermodynamic studies

The numerical study of the decontamination of lead(II) ions-rich effluent employing activated carbon derived from cashew nut shell was the central focus of this work. Chemical activation with zinc chloride (ZnCl2) was used to produce powdered activated carbon at optimized activation conditions of impregnation ratio (0.531), activation temperature (1083 K) and activation time (63min). The physiochemical properties of raw and activated cashew nut shell were determined using Fourier transform infrared spectroscopy, scanning, X-ray diffractor (XRD), scanning electron microscopy (SEM), and Brunauer-Emmet-Teller (BET) analyses. Batch adsorption experiments were performed at varied process conditions of temperature (303–323) K, contact time (5–80min), and initial lead(II) ion concentrations (100–400 mg.L−1). The adsorption behavior of the batch–type operation was mathematically described in the form of non-linear parabolic partial differential equations (PDE’S) incorporating film, pore and surface diffusion mechanisms. The batch mathematical model was solved by implementing a custom MATLAB program-OkiyNwabannebatch and calibrated to predict the desired response (percentage removal) using measured adsorption data. The equilibrium adsorption, kinetics and thermodynamics of lead(II) ions adsorption onto activated cashew nut shell were also assessed using nonlinear isotherm, kinetic and thermodynamic models. Sensitivity analysis unveiled that temperature with sensitivity value of 37.31 % had a predominant effect on the model performance. The simulated equilibrium data was well explicated by the Freundlich model for lead(II) ions adsorption onto activated cashew nut shell. The pseudo-second order kinetic model best reproduced the simulated adsorption data for lead(II) ions uptake by cashew nut shell adsorbent. Likewise, the kinetic data followed Boyd model, indicating that the adsorption process is controlled by external (film) diffusion for the uptake of lead(II) ions by alkali activated cashew nut shell. Thermodynamic analysis using the Gibbs and Van’t Hoff’s models indicated that lead(II) ions adsorption by modified cashew nut shell is spontaneous and exothermic. The physical nature of the adsorption process was elucidated from the low values of the isosteric heats of adsorption (ΔHX) evaluated (<80 kJ mol−1). This study showed that zinc chloride activated cashew nut shell has good potential to be used as a cost-effective and efficient adsorbent for the uptake of lead(II) ions from aqueous solution.

Effect of replacing Bis-GMA with a biobased trimethacrylate on the physicochemical and mechanical properties of experimental resin composites.

To analyze the incorporation of cardanol trimethacrylate monomer (CTMA), derived from the cashew nut shell liquid, as a substitute for Bis-GMA in acrylic resins formulations and its effect on experimental resin composites' physicochemical and mechanical properties. The intermediary cardanol epoxy was synthesized via cardanol epoxidation, followed by the synthesis of CTMA through methacrylic anhydride solvent-free esterification. Experimental resin composites were formulated with an organic matrix composed of Bis-GMA/TEGDMA (50/50 wt %) (control). CTMA was gradually added to replace different proportions of Bis-GMA: 10 wt % (CTMA-10), 20 wt % (CTMA-20), 40 wt % (CTMA-40), and 50 wt % (CTMA-50). The composites were characterized by degree of conversion, water sorption and solubility, viscosity, thermogravimetric analysis, dynamic mechanical analysis, flexural strength and elastic modulus. Data were analyzed with one-way ANOVA and Tukey's post-hoc test (α = 0.05), except for water sorption data, which were analyzed by Kruskall-Wallis and Dunn's method. CTMA-based and control composites did not show statistically significant differences regarding degree of conversion, flexural strength and elastic modulus. CTMA reduced the viscosity and solubility compared to the Bis-GMA-based composite. The CTMA-40 and CTMA-50 exhibited significantly lower water sorption compared to the control. Also, acceptable thermal stability and viscoelastic properties were obtained for safe use in the oral cavity. Incorporating CTMA into composites resulted in similar chemical and mechanical properties compared to Bis-GMA-based material while reducing viscosity, water sorption and solubility. CTMA could be used as a trimethacrylate monomer replacing Bis-GMA in resin composites, thereby minimizing BPA exposure.

One step beyond for CNSL‐based plasticizers for PVC: Use of cardol

AbstractPoly(vinyl chloride) (PVC) is a widely employed plastic across diverse industries and is often associated with plasticizers, additives that decrease the inherent rigidity and brittleness of the material. Conventional phthalate‐based plasticizers raise substantial toxicity concerns, encouraging the exploration of bio‐based alternatives. One such alternative is the inedible oil, cashew nutshell liquid (CNSL), mainly composed of cardanol and cardol. Recent efforts have focused on developing a cardanol‐based PVC plasticizers but the isolation of cardanol involves time‐consuming, energy‐intensive, and costly steps, limiting its market competitiveness. This study aims to assess for the first time, the efficiency of cardol esters, synthesized using acetic acid and different fatty acids (octanoic acid and myristic acid), in order to evaluate the influence of the alkyl chain on plasticizer properties. The chemical structures of these plasticizers were fully characterized by 1H NMR spectroscopy, and the mechanical properties and thermal behavior of PVC films plasticized with these additives were investigated. Finally, the endocrine activity was evaluated for cardol and cardanol acetates.

Mixed bio-based surfactant-templated mesoporous silica for supporting palladium catalyst

The study aimed on the synthesis of bio-based surfactant-templated mesoporous silica for supporting palladium catalyst using mixed bio-based templating agents namely cashew nut shell liquid (CNSL) and castor oil for pore direction purposes. The materials prepared through co-condensation of 3-aminopropyltriethoxysilane (APTS) and tetraethyl orthosilicate (TEOS) in a 1:4 M ratio using 1:1, 4:1 and 9:1 ratio of CNSL and castor oil. The resulting porous materials were utilized to support the palladium(II) chloride catalyst, resulting in a heterogeneous catalyst-a better and more environmentally friendly catalyst than a homogeneous one. Different instruments were used to characterize the prepared materials such as nitrogen porosimeter, Powder X-ray Diffraction, Diffuse Reflectance Infrared Fourier Transform Spectroscopy and Inductively coupled plasma optical emission spectroscopy. Physisorption studies of the prepared materials indicated that the largest pore diameter of 43.84 nm could be obtained by using a 1:1 M ratio of CNSL and castor oil. On the other hand, the largest surface area of 209 m2/g was obtained from a 9:1 whereas the largest pore volume was 1.55 cm3/g from a 4:1. Diffuse Reflectance Infrared Fourier Transform Spectroscopy analysis confirmed the presence of N-H group, the bending vibration bands at around 1640 and 1543 cm−1 indicating that the reaction of organoaminesilanes and tetraethyl orthosilicate had occurred. The palladium content of the supported catalyst was determined by ICP-OES which confirmed the attachment of palladium to the synthesized materials. The highest palladium loading was obtained from the adsorbent prepared by using 1:1 ratio of surfactants mixture which gave the adsorption value of 2.16 mmol/g. Powder X-ray Diffraction indicated that the synthesized organosilica materials are amorphous with improved crystallinity upon attachment of palladium catalyst. The incorporation of palladium in the synthesized materials using the mixed bio-based surfactant was successful.

Emission analysis of combustion of cashew nutshell biodiesel in a toroidal combustion chamber: an experimental study

Emission analysis of combustion of cashew nutshell biodiesel in a toroidal combustion chamber: an experimental study

Lactuca sativa Growth and Yield as Affected by Cashew Nut Shells Biochar, Cattle Manure and Urea in Northern and Central Benin

Aims: This study aims to identify good combinations of cashew nut shell biochar, cattle manure, and urea for enhancing lettuce (Lactuca sativa L.) growth and yield in the North and Central regions of Benin. Place and Duration of Study: Two agronomic trials were conducted: one in Tchaourou, Borgou department (2022), and another in Dassa, Colline department (2023). Methodology: A Fisher experimental design with three replications was used at each site, focusing on fertilization with seven treatments, including four reference treatments (local practices) and three treatments based on the reference treatments with biochar incorporation. Results: The results demonstrated significant improvements in plant growth parameters and yield, with the application of biochar combined with cattle manure and urea or with cattle manure only. The plants leaves number, height and yields obtained from the application of 10 t ha⁻¹ biochar + 20 t ha-1 cattle manure and 10 t ha-1 biochar + 0.025 t ha-1 urea +10 t ha-1 cattle manure were respectively at least 165 and 318%; 25 and 50%; 42 and 91% higher than those obtained under the producer's mineral fertilization practice at both sites. Conclusion: The findings showed that integrating cashew nut shell biochar with organic and inorganic fertilizers can significantly enhanced lettuce production, and thus overall vegetable crop yields while reducing the need for mineral fertilizers and dependence of cattle manure. Additionally, studying the best application methods and rates for different soil types and crop systems can help in maximizing the benefits of biochar.

Analytical evaluation of oil and water obtained from demulsification of crude oil using cashew (&lt;i&gt;Anacardium occidentale&lt;/i&gt;) nutshell liquid

The physiochemical characteristics of oil and water obtained from the demusifier treatment of crude oil using equal concentrations of Cashew nutshell liquid (CSNL) and a commercial grade demulsifier (DX077) were evaluated. Results obtained shows that basic sediment and water (BSW) of the crude after treatment with CSNL and DXO77 were 17.5 and 17.9 % respectively which was 0.4% apart. The total oil and grease (TOG) and total petroleum hydrocarbon (TPH) of the produced water after treatment with CSNL were 24.4 and 21.7 mg/l respectively while results after treatment with DXO77 were 23.7 and 20.5 mg/l respectively. The TOG and TPH of the produced water after demulsifier treatment with CSNL and DX077 were within acceptable limit of &lt; 30.0 mg/l as specified by Department of Petroleum Resources (DPR). Analyses of the same crude oil before demulsifier treatment gave a lower BSW of 9.50 % as well as an emulsion band of 16.2 % indicating improper oil/water separation. The TOG and TPH of the produced water before demulsifier treatment were 42.5 and 38.7 mg/l respectively which were above DPR specification. Disposal of produced water with high TOG and TPH into the environment can lead to the release of volatile organic compounds (VOCs) into the ecosystem resulting in environmental pollution as well as other health hazards. Results obtained also show that the water density, pH, electrical conductivity, salinity and chloride of the produced water after demulsifier treatment with CSNL and DX077 were within DPR specification. Reinjecting produced water with high salinity, chloride and conductivity into the reservoir can reduce oil recovery especially from sandstone and carbonate reservoirs. CSNL proved to be an effective demulsifier and is preferrable to the synthetic demulsifier (DX077) because it is more environmentally friendly owing to its green nature.

Synthesis and Tribological Investigation of Cashew Nutshell Liquid Cardanol Oil Dispersed with Modified Cu–Zn Nanoparticles

Synthesis and Tribological Investigation of Cashew Nutshell Liquid Cardanol Oil Dispersed with Modified Cu–Zn Nanoparticles

Changes in the Fatty Acid Composition of Vegetable Oils Affect the Feeding Behavior, Feed Preference, and Thermoregulatory Responses of Sheep

This research evaluated the effects of energy supplementation on sheep’s feeding behavior, feed preference, and thermoregulatory responses using technical cashew nutshell liquid (CNSL) and different vegetable oils with different unsaturated fatty acid (UFA) compositions. The experiment was completely randomized with five treatments: a mixture of CNSL (0.5%) + vegetable oils [canola (high in monounsaturated fatty acids—MUFA), and corn, soybean, sunflower, or cottonseed oil (high in polyunsaturated fatty acids-PUFA) at 1.5%] based on total diet dry matter, with eight replications. Forty uncastrated male sheep, with an average initial BW of 24.44 ± 1.5 kg, were evaluated for 70 days. The CNSL + vegetable oil blend did not affect DM and neutral detergent fiber (aNDF) intake (p &gt; 0.05). However, diets with canola oil resulted in higher SFA intake (p &lt; 0.05) than other oils. The canola oil + CNSL blend led to a higher intake of UFA and MUFA and lower PUFA intake than other oil blends (p &lt; 0.05). Sheep fed canola oil ruminated fewer boli per day than those fed soybean and sunflower oils. Using three sieves (pef1.18) reflected in higher sheep aNDF intake. Respiratory frequency and surface temperature of sheep were lower before feeding than 3 h after, without effects of the type of oil. Higher serum creatinine and cholesterol levels were observed in sheep fed CNSL with corn and canola oils compared to other oils. Serum calcium was lower in sheep fed CNSL with soybean and canola compared to sunflower and corn. Including CNSL with vegetable oils with different FA compositions did not affect physiological and thermographic variables. However, sheep showed better diet selectivity and lower bolus rumination with higher MUFA (canola oil) content. Including CNSL with canola oil in sheep diets is recommended, as it increases dietary energy content, enhances diet selectivity, reduces PUFA intake, and does not impact animal health.

Cashew Nut Shell Waste Derived Graphene Oxide.

The particular properties of graphene oxide (GO) make it a material with great technological potential, so it is of great interest to find renewable and eco-friendly sources to satisfy its future demand sustainably. Recently, agricultural waste has been identified as a potential raw material source for producing carbonaceous materials. This study explores the potential of cashew nut shell (CNS), a typically discarded by-product, as a renewable source for graphene oxide synthesis. Initially, deoiled cashew nut shells (DCNS) were submitted to pyrolysis to produce a carbonaceous material (Py-DCNS), with process optimization conducted through response surface methodology. Optimal conditions were identified as a pyrolysis temperature of 950 °C and a time of 1.8 h, yielding 29.09% Py-DCNS with an estimated purity of 82.55%, which increased to 91.9% post-washing. Using a modified Hummers method, the Py-DCNS was subsequently transformed into graphene oxide (GO-DCNS). Structural and functional analyses were carried out using FTIR spectroscopy, revealing the successful generation of GO-DCNS with characteristic oxygen-containing functional groups. Raman spectroscopy confirmed the formation of defects and layer separations in GO-DCNS compared to Py-DCNS, indicative of effective oxidation. The thermogravimetric analysis demonstrated distinct thermal decomposition stages for GO-DCNS, aligning with the expected behavior for graphene oxide. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX) further corroborated the morphological and compositional transformation from DCNS to GO-DCNS, showcasing reduced particle size, increased porosity, and significant oxygen functional groups. The results underscore the viability of cashew nut shells as a sustainable precursor for graphene oxide production, offering an environmentally friendly alternative to conventional methods. This innovative approach addresses the waste management issue associated with cashew nut shells and contributes to developing high-value carbon materials with broad technological applications.

Bioorganic activated carbon from cashew nut shells for H2 adsorption and H2/CO2, H2/CH4, CO2/CH4, H2/CO2/CH4 selectivity in industrial applications

This research explores the production of activated carbon (AC) from cashew nut shells using a potassium hydroxide (KOH) activation method, with a focus on its application in high-pressure gas adsorption. Among the synthesized samples, AC850 demonstrated the highest efficiency, displaying a specific surface area of 1972 m2/g and total and micropore volumes of 0.847 cm3/g and 0.724 cm3/g, respectively. The bioorganic activated carbon exhibited significant sorption capabilities for H2, with uptake values of 13.34 mmol/g (2.69 wt%) at 10 bar and 25 °C, and a H2/CH4 selectivity range between 43.4 and 2.6. Calculations were also conducted for selectivity in a mixture of three gases (H2, CO2, and CH4) in industrial settings. Advanced characterization methods such as N2/CO2 adsorption isotherms, FT-IR, Raman spectroscopy, SEM, and TGA were employed to analyze the structural and chemical properties of the produced AC, including its functional groups and molecular structure. The research underscores the potential of utilizing agricultural waste, particularly cashew nut shells, to develop efficient materials for H2 storage and purification. The high-pressure adsorption capability and eco-friendly nature of the manufactured activated carbon make it suitable for both environmental and industrial applications.

97 Influence of cashew nutshell extract (CNSE) on enteric methane emission, feeding behavior, and nutrients digestibility in beef steers receiving a finishing diet

97 Influence of cashew nutshell extract (CNSE) on enteric methane emission, feeding behavior, and nutrients digestibility in beef steers receiving a finishing diet

Characterization of banana and sisal fiber fabrics reinforced epoxy hybrid biocomposites with cashew nut shell filler for structural applications

Characterization of banana and sisal fiber fabrics reinforced epoxy hybrid biocomposites with cashew nut shell filler for structural applications