Carbon Sequestration Technologies Research Articles

Gigaton gear – policy insights for scaling up the global deployment of direct air carbon capture and sequestration technology (DACCS)

ABSTRACT Direct Air Carbon Capture and Sequestration (DACCS) is increasingly recognized as a pivotal technology for mitigating climate change by removing carbon dioxide (CO2) from the atmosphere and storing it securely. Despite significant technical potential, the current global capacity for DACCS is minimal, emphasizing the urgent need for accelerated deployment to meet climate targets. While there are technical intricacies, an accelerated deployment is substantially dependent on setting the right policy frameworks. This paper presents a comprehensive analysis of the global DACCS innovation system using the Technological Innovation Systems (TIS) framework, focusing on identifying systemic policy problems and suggesting policy leverage points. Through 34 semi-structured interviews with 37 key actors across Europe and North America, this study captures the current state and challenges within the DACCS innovation system. It offers insights on the status quo concerning entrepreneurial activities, knowledge creation and diffusion, supportive policy, market formation, resource mobilization, as well as public and local legitimacy issues. To advance the development of the DACCS innovation system towards achieving gigaton-scale carbon removal, the paper provides targeted insights for policymakers, such as creating clearer policy frameworks and incentives, securing demand, and investing more into research, as well as knowledge creation and knowledge diffusion. By pointing out these systemic issues and creating policy insights, the paper contributes valuable insights to scale DACCS technologies globally.

Advances in Carbon Dioxide Catalytic Conversion and Applications

To achieve the global climate goals set out in the Paris Agreement, reducing carbon dioxide (CO2) emissions and utilizing resources have become key areas of focus within international energy technology research and development. CO2 can be converted into high-value chemicals, including hydrocarbons, alcohols and hydrocarbons, through the catalytic technology. This process can potentially address environmental issues while generating economic benefits. This paper presents a review of the principal products resulting from the catalytic conversion of CO2, together with an examination of their practical applications. These include hydrogenation of olefins, light aromatics, methanol, polyols, and synthetic bioconversion technologies. The development of catalysts with high conversion and selectivity represents a key area of current research. In the future, it will be necessary to combine physical, chemical, and biological technologies to establish an engineered heterogeneous carbon sequestration technology system to achieve the efficient conversion and utilization of CO2.

Preparation of Chromium Carbide-Strengthened Ni-W Coatings by Electrodeposition and the Corresponding Anticorrosion Behavior in CO2-Saturated NaCl Solution

In this study, we have prepared Ni-W/Cr3C2 composite electrodeposits through the diffuse reinforcement mechanism of chromium carbide nanoparticles. These electrodeposits exhibit excellent corrosion resistance and are designed to effectively protect the structural materials of pipe columns under the harsh CO2 corrosion environments faced by carbon sequestration and utilization technologies. A systematic investigation was conducted into the micro-morphology, profile undulation, phase composition, and surface chemical state of the electrodeposits. Furthermore, the corrosion-resistant behavior of Ni-W/Cr3C2 composite electrodeposits was investigated in simulated corrosive environments (i.e., brine solution containing 3.5 wt% NaCl and CO2-saturated brine). We then evaluated their corrosion response under the aforementioned conditions using electrochemical methods. In addition, the EIS of electrodeposited coatings revealed that the dense oxide film layer formed on the surface of the deposits, which acted as a primary barrier against corrosion, playing a pivotal role in maintaining the overall corrosion resistance of the material.

A 4IR-Driven operational risk model for CO2 storage in deepwater abandoned hydrocarbon reservoirs

This study presents the development of an advanced operational risk model that leverages Fourth Industrial Revolution (4IR) technologies to optimize carbon dioxide (CO2) storage within deepwater abandoned hydrocarbon reservoirs. The model systematically combines Artificial Neural Networks (ANN) with the optimization capabilities of Genetic Algorithms (GA) and the probabilistic analysis strengths of a Bayesian Network (BN) to perform dynamic and comprehensive risk assessments. By applying the model to a dataset covering a 200-year timeframe, it effectively forecasts CO2 storage capacities while simultaneously evaluating associated risks across different operational scenarios. One of the key innovations of this model is the introduction of a novel loss function designed to precisely manage forecast deviations and enhance the efficiency of operational processes. This function is critical in ensuring that the model remains robust and accurate in real-time risk assessments, allowing for more reliable decision-making in CO2 storage operations. In addition, the study conducts an economic evaluation that underscores the crucial role of 45Q tax credits in bolstering the financial sustainability of carbon sequestration projects. The analysis highlights how these credits significantly reduce the economic barriers to adopting carbon utilization, storage, and sequestration (CUSS) technologies, making large-scale implementation more feasible. The model's performance is underscored by its ability to achieve a 49% CO2 retention rate over two centuries, with an impressively low average error margin of 0.249%. These results highlight the model's impressive efficiency and accuracy, while also demonstrating its capacity to markedly improve the predictability of CO2 storage outcomes. The findings suggest that this model could play a pivotal role in advancing global sustainability efforts by optimizing CO2 storage processes, thereby contributing to the reduction of atmospheric CO2 levels and supporting long-term climate goals.

The key role of sufficiency for low demand-based carbon neutrality and energy security across Europe

A detailed assessment of a low energy demand, 1.5 ∘C compatible pathway is provided for Europe from a bottom-up, country scale modelling perspective. The level of detail enables a clear representation of the potential of sufficiency measures. Results show that by 2050, 50% final energy demand reduction compared to 2019 is possible in Europe, with at least 40% of it attributable to various sufficiency measures across all sectors. This reduction enables a 77% renewable energy share in 2040 and 100% in 2050, with very limited need for imports from outside of Europe and no carbon sequestration technologies. Sufficiency enables increased fairness between countries through the convergence towards a more equitable share of energy service levels. Here we show, that without sufficiency measures, Europe misses the opportunity to transform energy demand leaving considerable pressure on supply side changes combined with unproven carbon removal technologies.

Optimizing CO2 Hydrate Sequestration in Subsea Sediments through Cold Seawater Pre-Injection

Carbon sequestration technology offers a solution to mitigate excessive carbon dioxide emissions and sustainable development in the future. This study proposes a method for subsea carbon sequestration through the injection of cold seawater to promote CO2 hydrate formation. Using a self-developed simulator, we modeled and calculated the long-term sequestration process. The study focuses on analyzing the thermal regulation of the seabed following cold seawater injection, the multiphysical field evolution during CO2 injection and long-term sequestration, and the impact of seawater injection volumes on sequestration outcomes. The feasibility and leakage risks of this method were evaluated on a 100,000-year timescale. Results indicate that the injection of cold seawater significantly improves the pressure–temperature conditions of subsea sediments, facilitating early hydrate formation and markedly increasing the initial CO2 hydrate formation rate. Consequently, the distribution pattern of hydrate saturation changes, forming a double-layer hydrate shell. Over the long term, while cold seawater injection does not significantly reduce CO2 leakage, it does increase the safety margin between the hydrate layer and the seabed, enhancing the safety coefficient for long-term CO2 hydrate sequestration. Through detailed analysis of the behavior of CO2 components during sequestration, this study provides new theoretical insights into subsea CO2 hydrate storage.

Current status and research prospects of terrestrial ecosystem carbon sink in Northeast China.

Increasing the carbon sink capacity of terrestrial ecosystems is a primary strategy to mitigate climate change and achieve the "carbon neutrality" goal. Clarifying the status and future dynamics of carbon sink of terrestrial ecosystems in Northeast China is crucial for achieving "carbon neutrality" as this region is a core contributor to carbon sink in China's terrestrial ecosystems. Here, we systematically summarized current research on carbon sink of terrestrial ecosystems across Northeast China, including the measurements and spatial-temporal patterns of carbon sinks, driving mechanisms of carbon sinks, the assessments of carbon sink potential, and technologies for increasing carbon sequestration. There are substantial uncertainties in quantifying terrestrial ecosystem carbon sink in Northeast China due to differences in data sources and methods, especially for forest carbon sink measurements, ranging from 0.020 to 0.157 Pg C·a-1. Carbon sink function depends on carbon exchange processes across plant-soil-atmosphere interfaces. The key pathways to enhance carbon sequestration in Northeast China under different temporal and spatial scales remains unclear. Improving terrestrial ecosystem quality is the key and core of carbon sequestration and sink enhancement. However, there is an urgent need to develop a multi-ecosystem collaborative carbon sequestration and sink enhancement technology system for the "dual carbon" goal. Future research needs to develop an accurate carbon sink measurement system that integrates multi-source data and multi-scale technologies to accurately assess the function and potential of carbon sink in Northeast China, focus on the multi-scale driving mechanism of carbon sink functions, develop new technical systems for coordinated enhancement of carbon sink for the Northeast terrestrial ecosystems, and carry out demonstrations of carbon sink enhancement technologies. These efforts will provide the scientific and technological supports for achieving the "carbon neutrality" goal.

Comprehensive life cycle assessment of garden organic waste valorisation: A case study in regional Australia

This study evaluates the environmental impacts associated with the conversion of garden organic waste into value-added products, namely compost or biochar, employing various processes. Three distinct scenarios are considered: composting garden organic waste followed by screening of oversized materials (CBP), pyrolysis of oversized screenings of compost into biochar AP(I), and in-situ conversion of garden organics into biochar AP(II). A comprehensive Life Cycle Assessment (LCA) was conducted using OpenLCA software and life cycle impact assessment was conducted using Recipe 2016 midpoint methodology. The environmental ramifications of each scenario were assessed, optimising transport distances in AP(II) to achieve a functional unit of one tonne of biochar produced within a cradle-to-gate system boundary. For the first time, this study offers a holistic exploration of the benefits of soil biochar application, extending its scope to climate change mitigation, incorporating the optimisation of transport distance and its influence when scaling up the technology. The results revealed that global warming was increased from 125 kgCO2 eq during composting of garden waste to 232 kgCO2 eq where oversized screenings of compost is converted to biochar at an off-site facility. However, direct conversion of the oversized organic waste to biochar, without composting, showed reduced global warming impact of 56 kgCO2 eq, and is thus the most favourable scenario to limit climate impacts of this fraction of organic garden waste. However, among 18 environmental impact indicators studied, eight indicators were either not influenced or did not significantly increase by transport distance to an off-site pyrolysis facility, while the magnitude of 10 impact indicators increased with transport distance. The insights and methodologies presented in this study hold global relevance, based on an actual case study in regional Australia, offering valuable recommendations for sustainable waste management practices and establishing biochar as a carbon-neutral or carbon-negative solution. The findings contribute to existing waste management knowledge and provide guidance for accessible carbon dioxide removal and soil carbon sequestration technologies.

Analysis of the Characteristics and Driving Mechanisms of Carbon Emission Decoupling in the Hu-Bao-O-Yu City Cluster under the “Double Carbon” Target

The Hu-Bao-O-Yu urban area is a major source of carbon emissions in China. It is also a major source of energy exports and high-end chemicals in China. Reaching peak carbon emissions early is especially important for meeting the national peak goal. For urban areas that rely on natural resources, we need to make it clearer how carbon emissions and economic growth affect each other and slowly break the strong link between the two. Therefore, in this paper, based on the data on carbon emissions, the decoupling state and the driving mechanism of carbon emissions in the Hu-Bao-O-Yu City group are researched by using the Tapio decoupling model and GDIM method. A new decoupling index model is constructed by combining GDIM and the traditional decoupling model. The main findings are as follows: (1) The Hu-Bao-O-Yu urban agglomeration, Ordos City, Baotou City and Yulin City have significant growth trends in annual carbon emissions, with Yulin City being the most important carbon source for the Hu-Bao-O-Yu urban agglomeration and its economic contribution to carbon emissions of the whole urban agglomeration is the most efficient. (2) The decoupling of Hu-Bao-O-Yu, Huhhot City, Baotou City, and Ordos City is dominated by expansionary negative decoupling, whereas Yulin City has strong negative decoupling. (3) The Hu-Bao-O-Yu urban cluster mainly affects the carbon intensity of fixed asset investments and output carbon intensity, which is a key part of the carbon separation process. The energy scale and structure also play a part in this process over time. (4) Changes in GDP per capita are a bigger part of changes in carbon emissions in the Hu-Bao-O-Yu urban agglomeration. These changes also determine the direction for changes in carbon emissions in the Hu-Bao-O-Yu urban agglomeration. In the future, the Hu-Bao-O-Yu urban agglomeration needs to coordinate its economic growth. Ordos and Yulin need to speed up the optimisation and transformation of their energy structures. Baotou needs to push for the low-carbon transformation of its industries. Huhhot needs to do more research on carbon sequestration technology and spend more on environmental protection. This will make the Hu-Bao-O-Yu urban agglomeration a resource-saving urban agglomeration and improve its ability to reduce emissions.

Recent Advances of Carbon Capture in Metal-Organic Frameworks: A Comprehensive Review.

The excessive emission of greenhouse gases, which leads to global warming and alarms the world, has triggered a global campaign for carbon neutrality. Carbon capture and sequestration (CCS) technology has aroused wide research interest as a versatile emission mitigation technology. Metal-organic frameworks (MOFs), as a new class of high-performance adsorbents, hold great potential for CO2 capture from large point sources and ambient air due to their ultra-high specific surface area as well as pore structure. In recent years, MOFs have made great progress in the field of CO2 capture and separation, and have published a number of important results, which have greatly promoted the development of MOF materials for practical carbon capture applications. This review summarizes the most recent advanced research on MOF materials for carbon capture in various application scenarios over the past six years. The strategies for enhancing CO2 selective adsorption and separation of MOFs are described in detail, along with the development of MOF-based composites. Moreover, this review also systematically summarizes the highly concerned issues of MOF materials in practical applications of carbon capture. Finally, future research on CO2 capture by MOF materials is prospected.

THE FINANCIAL IMPACT OF CARBON EMISSIONS ON POWER UTILITIES UNDER CLIMATE SCENARIOS

Power utilities, especially those that generate electricity by burning fossil fuels, produce significant amounts of carbon emissions. Mitigation of [Formula: see text]-equivalent ([Formula: see text]) emissions can be achieved by replacing power plants with renewable power installations and by adopting carbon-sequestration technologies. Physical upgrades are expensive, but carbon taxes, or the purchase of certificates and allowances on a voluntary carbon market, can be costly, too. Carbon costs may increasingly become a threatening liability for power utilities, eating into profits and undermining the financial viability of emission-intensive electricity generation. Thus, we consider an asset-and-liability, structural firm model to investigate the creditworthiness of a generic power utility. The utility’s assets dynamics are driven by the financial returns generated from the sold electricity for a set tariff which is modeled by a simple stochastic process. The liabilities not only depend on fuel, running, and depreciation costs, but also on the costs of [Formula: see text] emissions. As a case study, we consider Eskom, the South African power utility. We show the evolution of Eskom’s default probability under various fuel mix plans and technologies (as per SA’s Integrated Resources Plan (IRP) 2019), and under the Network for Greening the Financial System (NGFS) carbon price scenarios. The obtained results and insights present a trying path ahead, especially for carbon-intensive power utilities.

Comparing net zero pathways across the Atlantic A model inter-comparison exercise between the Energy Modeling Forum 37 and the European Climate and Energy Modeling Forum

Europe and North America account for 32 % of current carbon emissions. Due to distinct legacy systems, energy infrastructure, socioeconomic development, and energy resource endowment, both regions have different policy and technological pathways to reach net zero by the mid-century. Against this background, our paper examines the results from the net zero emission scenarios for Europe and North America that emerged from the collaboration of the European and American Energy Modeling Forums. In our analysis, we perform an inter-comparison of various integrated assessments and bottom-up energy system models. A clear qualitative consensus emerges on five main points. First, Europe and the United States reach net zero targets with electrification, demand-side reductions, and carbon capture and sequestration technologies. Second, the use of carbon capture and sequestration is more predominant in the United States due to a steeper decarbonization schedule. Third, the buildings sector is the easiest to electrify in both regions. Fourth, the industrial sector is the hardest to electrify in the United States and transportation in Europe.Fifth, in both regions, the transition in the energy mix is driven by the substitution of coal and natural gas with solar and wind, but to a different extent.

Enhancing fire resistance: Investigating mechanical properties of biochar-infused concrete under elevated temperatures

Biochar (BC) generated by pyrolysis at high temperature is a kind of porous material with great potential for carbon sequestration. The incorporation of BC into mortar as a substitute for cement can not only improve the mechanical properties of mortar, but enrich the means of carbon sequestration technology. However, the performance of concrete utilizing BC as a replacement for cement, particularly when exposed to elevated temperatures, has yet to be fully understood. Here, we provide an experimental investigation on the mechanical properties of biochar concrete (BCC) after exposure to elevated temperatures. 168 concrete specimens were poured with four different BC addition (0 %, 3 %, 5 % and 10 %) to test the mechanical strength at 7 and 28 days, and the mass loss, the residual strength, microstructures, and stress-strain curve of BCC after high temperature were obtained. The results showed that a small amount (3 %) of BC significantly improved the mechanical properties under conventional conditions. The apparent morphology of BCC after high temperature is similar to that of ordinary concrete, however, its mass loss, residual strength and peak stress have great changes. The addition of 3 % BC can increase the residual compressive strength of concrete at 300 °C, 500 °C and 700 °C by 4.8 %, 26.3 % and 25 %, respectively, compared to the BC-free one. Based on the findings, it is speculated that replacing a portion of cement with BC will be a feasible alternative to improve the performance of concrete at elevated temperature and curtail CO2 emissions that generate with the cement production.

Enhanced sequestration of carbon in ocean sediments as a means to reduce global emissions: A case study from a coastal wetland restoration project in the Liaohe Delta, Northeast China

Enhanced sequestration of carbon in ocean sediments is a promising approach to mitigate the adverse effects of climate warming. To assess the capacity of coastal regions to uptake and bury carbon, a wetland restoration project was carried out in the degraded coastal wetlands of the Liaohe Delta between 2011 and 2013. A 13.33-ha degraded salt marsh was selected to create two enhanced carbon sink experimental areas, one dominated by Phragmites australis and the other dominated by Suaeda salsa. Improvements to the wetland matrix, hydrological processes, and vegetation colonization were designed and constructed. Results revealed that after the three-year restoration effort, the biomass of vegetation in the demonstration area was 1.2–4.0 times that of a natural wetland, and the rate of organic carbon sequestration in the sediments was about 60–80% of the rate in a natural salt marsh. We show that restoring vegetation can significantly increase the rate of sedimentation and thus enhance the carbon sequestration capacity of a wetland dominated by S. salsa or P. australis. Carbon sequestration capacity can be restored more rapidly in salt marsh wetlands than in mangrove wetlands, and we argue that restoration of salt marsh wetlands is an urgent task suitable for the application of large-scale ocean carbon sequestration technologies.

The Future of Agriculture in A Carbon Constrained World

In a world grappling with the far-reaching consequences of climate change and a growing imperative to lower emissions of greenhouse gases, agriculture’s potential finds itself at a critical juncture. This paper explores the intricate dynamics of agriculture in a carbon-constrained world, presenting a nuanced analysis of the multifaceted challenges and opportunities that lie ahead. With a focus on sustainable practices, carbon sequestration, and innovative technologies, this study elucidates the pathways through which agriculture can transition towards a low-carbon and climate-resilient future. From precision farming and agroforestry to advanced breeding techniques and digital agriculture, a spectrum of strategies emerges to mitigate the carbon footprint of agriculture while concurrently enhancing productivity and food security. Moreover, the paper underscores the indispensable role of policy frameworks, international cooperation, and public-private partnerships in ushering in a transformative era for agriculture that aligns harmoniously with global climate goals. This review explores carbon foot printing methodologies in agriculture and their implications for sustainable practices. Additionally, it highlights role of carbon foot printing in informing decision-makers, examines emerging trends like precision agriculture, and addresses associated challenges. This review identifies these gaps and offers recommendations for future research. In elucidating these key themes, this paper advances to a thorough comprehensive understanding of the imperative to embrace innovation and sustainability as guiding principles for the future of farming in a carbon-constrained world.

Analysis of the impacts of carbon neutral policy portfolios on the economy, environment, and residents' welfare based on computable general equilibrium models

The efficacy of the synergistic interplay of various programs about energy efficiency and emission reduction in China's endeavor to achieve carbon peaking and carbon neutrality remains to be determined. This research constructed a computable general equilibrium (CGE) model to examine the economic, environmental, social, and energy consequences of various policy combinations. Using data from the 2018 input-output table of China, we create 21 industry sectors and examine the combined impacts of different carbon policies. Our findings indicate that the effects of carbon emission reduction are more favorable when multiple carbon-neutral policies are implemented together, compared to the impact of a single policy. Among the various combinations of policies examined, the combination of feed-in tariff subsidy policy (FIT), renewable energy quota policy (RPS), carbon trading, carbon tax, and carbon capture, utilization, and sequestration (CCUS) technology proves to be the most effective. The study predicts that by 2060, this combination of policies could lead to a reduction of 32.5% in carbon dioxide emissions. At the same time, it was discovered that a combination of lower-intensity renewable energy quotas, carbon trading, carbon taxes, and higher-intensity subsidies for carbon capture, utilization, and storage (CCUS) technologies, the synergy indicator θ exceeds 1, indicating a more stable economy; When the carbon tax policy is more robust, and the remaining three policies are more minor, carbon emissions fall the most and are the most ecologically beneficial. Imposing excessively high renewable energy quotas while maintaining the same level of technology and substitutability between fossil fuels and electric energy sources will result in economic instability afterward. Therefore, we suggest that to attain balanced growth of the environment, society, and economy, the government should increase the function of policy combinations and balance several objectives.

Addressing Health Equity in the Context of Carbon Capture, Utilization, and Sequestration Technologies.

To describe the role of health equity in the context of carbon capture, utilization, and sequestration (CCUS) technologies. CCUS technologies have the potential to both improve and worsen health equity. They could help reduce greenhouse gas emissions, a major contributor to climate change, but they could also have negative health impacts like air and noise pollution. More research is needed to fully understand the health equity implications of CCUS technologies. CCUS technologies have both health equity risks and benefits. Implementing misguided CCUS projects in vulnerable communities could exacerbate environmental injustice and health disparities and have the potential to increase carbon emissions. However, well-conceived projects could benefit communities through economic development. Governments, industry, and society should prioritize and expedite the reduction of CO2 emissions before considering carbon reductions via CCUS. Furthermore, CCUS projects must be thoroughly evaluated and should only proceed if they have demonstrated a net reduction in CO2 emissions and provide more benefits than risks to local communities. This underscores the importance of prioritizing health equity in the planning of CCUS projects.

Advanced Technologies for Carbon Sequestration and Capture

Advanced Technologies for Carbon Sequestration and Capture

The synergistic mechanism of hydration regulation and carbonation curing on the carbon sequestration and impermeability enhancement of cementitious materials

Carbonation curing, as a novel curing method, gradually plays an important role in the reduction of carbon emissions and the improvement of durability for cementitious materials. This study considers the intervention of carbonation at different ages of hydration and investigates the synergistic effect of nano-titanium dioxide (NT) regulating cement hydration and 20% CO2 carbonation curing on the enhancement of carbon sequestration and durability performance of cement mortar. The results show that early-age carbonation curing and the addition of NT increase the unit area carbon sequestration of cement mortar at the age of 28 days by 242.75% (0.41 kg/m2); meanwhile, some micro-nano-sized calcite crystals and NT jointly play a nucleation and filling role during hydration, optimizing the pore structure. As a result, the unit area capillary water absorption coefficient and gas permeability coefficient decrease by 70.55% and 91.89%, respectively, inhibiting the continuous diffusion of CO2 and achieving controlled surface carbonation. Based on the pore characteristics of the carbonated surface, this study also proposes a “Sieve filter” structure hypothesis model, which suggests a negative correlation between pore structure and surface depth under the synergistic mechanism. This can provide innovative ideas for the cement industry to enhance the durability performance of reinforced concrete prefabricated components using carbon sequestration technology.

Co-grafting of polyethyleneimine on facilely synthesized mesoporous P(DVB-D) for highly effective CO2 adsorption and enhanced oxidation resistance

Solid amine adsorbents are showing promise as effective adsorbents for the capture of CO2 from various gas mixtures, including biogas and flue exhaust gas. In this study, we introduced a co-grafting strategy using 1,4-butanediol diglycidyl ether (BDDE) on the surface of P(DVB-D). This approach aimed to exploit the reaction involving the opening of epoxy groups with amine groups, forming covalent bonds between polyethyleneimine (PEI) and mesoporous organic polymers, along with the introduction of hydroxy groups to enhance adsorbent long-term stability and antioxidation ability. After an extensive assessment, P(DVB-D)@B-41.2 %PEI exhibited a maximum CO2 capture capacity of 4.53 mmol/g at 50 °C and 50 % RH. Notably, its remarkable CO2 adsorption performance persisted across a diverse temperature spectrum (30–90 °C) and an extensive concentration span (5–30 % vol.). In contrast to conventional adsorbents prepared solely through impregnation methods, P(DVB-D)@B-41.2 %PEI exhibited impressive long-term stability throughout 50 successive cycles and excellent resistance to oxidative degradation. These findings underscore the considerable potential of P(DVB-D)@B-41.2 %PEI in the realm of carbon capture and sequestration (CCS) technology.