Mild Carbon Steel Research Articles

Synthesis and Electrochemical Properties of Oleylamine as a Sour Saline Corrosion Inhibitor Under Laminar Flow at 40 °C

In this study, the synthesis of a long-chain aliphatic amino compound and its sour corrosion inhibition properties were reported. Oleylamine was obtained through the reaction of 4-(Aminomethyl) pyridine with 1-chloro-octadecane. The identification and characterization of reaction products were carried out through Fourier transform infrared spectroscopy (FTIR) and gas chromatography/mass spectroscopy (GC-MS). Oleylamine was tested as a sour corrosion inhibitor for steels. Different concentrations of oleylamine (0, 5, 10, 25, and 100 ppm) in a sour saline electrolyte were analyzed. The dynamic anticorrosive behavior of oleylamine on carbon mild steel (AISI 1018) surfaces was evaluated using a laminar flow of 100 rpm and tested with potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) measurements. After electrochemical testing, the surface of the steel specimens that were used was characterized with Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The electrochemical results of the anticorrosive efficiency of oleylamine for steel showed an exponential behavior as a function of inhibitor concentration. At a concentration of 20 ppm of the inhibitor, the anticorrosive efficiency did not show any significant changes. However, at 100 ppm of the inhibitor, an efficiency of over 95% was achieved. After the electrochemical tests, the surface of the steel samples with the inhibitor revealed the formation of an inhibitor layer that prevented the corrosion of the steel.

Behaviour of Dissimilar Welded Connections of Mild Carbon (S235), Stainless (1.4404), and High-Strength (S690) Steels under Monotonic and Cyclic Loading

Behaviour of Dissimilar Welded Connections of Mild Carbon (S235), Stainless (1.4404), and High-Strength (S690) Steels under Monotonic and Cyclic Loading

Investigation into Morphology of Cavitation Erosion-Corrosion Pits on the Surface of Carbon Steel

Nano-sized films associated with the ring areasformed around micropits in cavitation erosion experimentswere investigated. The corrosion behavior and vibratory cavitation erosion tests of mild carbon steel in 3% NaCldistilled water were carried out. The results showed that thenano-sized films associated with the ring areas formedaround micropits in cavitation and free cavitation tests havea similar shape. The study proved that the nano-structure and the ring areas formed around micropits are the result ofcorrosion effects and not as a result of thermal effectsrelated to the collapse of the bubbles.

Corrosion Inhibition Performance of Whey Protein-Derived Inhibitors for Low Carbon and Dead Mild Steels in1M Hydrochloric Acid

This research investigates the corrosion inhibition capabilities of BCAA-derived inhibitors for low-carbon steels and dead mild carbon steels with distinct carbon contents when exposed to a 1M HCL solution. The effectiveness of the inhibitors was evaluated by measurements of weight loss and polarization. The study revealed that at a concentration of 10 grams, the weighing method showed that the BCAA inhibitor showed protection effectiveness (87 percent) at 313 K for low carbon steel and (89 percent) effectiveness at 303 K for dead carbon steel. Using a concentration of 15 g, the polarization method showed inhibitory activity of (96 percent) at 313 K for low-carbon steel and (96 percent) at 303 K for dead light carbon steel. These results indicate that the inhibition efficiency is affected by the carbon content. Samples were subjected to scanning electron microscopy (SEM) and optical microscope analysis before and after adding the inhibitor. When examined using FTIR spectroscopy, BCAA showed significant efficiency as a corrosion inhibitor for steel alloys immersed in acidic conditions.

Performance Assessment of A Developed Rolling Mill

Rolling of metals has found applications in automotive, construction, agriculture, railroads, housing, metal furniture making, home appliances, electronic cabinetry, pipes and tubing etc. These have as well contributed to human and environmental sustainability. Nevertheless, the applications of metal rolling processes and machines have not been adequately harnessed in our locality due to unavailability of the rolling machine in small scale industries, laboratories and workshops in institutions of learning in the region. Annealing heat treatment was carried out on a mild steel round bar of 50 mm diameter and length of 200 samples. The samples were charged into an SXL muffle furnace with an annealing temperature of 950oC. The mechanical properties and the microstructure of the rolled mild carbon steel were evaluated. The results of the performance evaluation of the machine through assessment of the metallurgical characteristics of the rolled products from the machine and assessment of mechanical properties such as tensile strength and hardness of the rolled products from the machine showed an increase in the tensile strength from 250.85 MPa to 258.85 MPa, an increase in the ultimate tensile strength from 535.88 MPa to 540.05 MPa, an increase in the hardness from 140 HV to 145 HV, and a decrease in the percentage ductility of the mild carbon steel from 56% to 51%. Also, the optical micrograph of the rolled samples shows a coarse microstructure of grain refinement from slipping and pilling of dislocations.

Effect of a Hybrid Pumice-Portland Cement Extract on Corrosion Activity of Stainless Steel SS304 and Carbon Mild Steel A36.

The change in the corrosion activities of SS304 and the carbon steel A36 were studied during their exposure for 30 days to hybrid pumice-Portland cement extract (CE), to simulate the concrete-pore environment. The ionic composition and the initial pH (12.99) of the CE were influenced by the reduction of Portland cement (PC) content, volcanic pumice oxides and alkaline activators. Because of the air CO2 dissolution, the pH decreased and maintained a constant value ≈ 9.10 (established dynamic ionic equilibrium). The CE promoted the passivation of both steels and their free corrosion potential (OCP) reached positive values. On the surfaces, Fe and Cr oxides were formed, according to the nature of the steel. Over the time of exposure, the presence of chloride ions in the pumice caused a localized pitting attack, and for carbon steel, this fact may indicate an intermediate risk of corrosion. The chloride effect was retarded by the accumulation of SO42- ions at the steel surfaces. Based on electrochemical impedance (EIS), the polarization resistance (Rp) and the thickness of the passive layers were calculated. Their values were compared with those previously reported for the steels exposed to CEs of Portland and supersulfated cements, and the hybrid cement was considered as a PC "green" alternative.

Enhanced oxygen evolution reaction of electrodeposited Functionally-Graded Ni-Cu-Fe coating

This study aimed to use a functionally graded (FG) Ni-Cu-Fe coating as an electrocatalyst for oxygen evolution reaction (OER) applications. The coating was applied on a mild carbon steel substrate by an electrodeposition technique, with the current density being progressively increased from 0.5 A/dm2 to 5 A/dm2 at a steady rate of 0.2 (A/dm2)/min during the coating operation. Using this specific method, the Ni content of the FG Ni-Cu-Fe coating changed along the cross-section when increasing the current density, 17 % more than the constant current coating. This technique also affected the surface morphology of the FG Ni-Cu-‌Fe coating and changed it from cauliflower to micro/nanocones when the current density was linearly increased, enhancing active sites significantly and thereby improving electrocatalytic activity. The coating's electrocatalytic behavior was studied by electrochemical impedance spectroscopy (EIS), linear sweep voltammetry (LSV), and cyclic voltammetry (CV). results showed that the FG Ni-Cu-Fe coating had the smallest overpotential (134 mV) at the current density of 10 mA.cm−2. Also, it had the smallest Tafel slope (24.3 mV.dec− 1) and smallest resistance (598 Ω.cm2) compared to all of the other coatings. The FG Ni-Cu-‌‌Fe coating had higher OER performance because of high Ni content, micro/nanocones morphology with many active sites, and FG nature. The FG Ni-Cu-Fe coating is finally concluded to be a promising and economical catalyst with high OER activity.

Assessing the Technical and Economic Viability of Galvanizing Snow Crab (Chionoecetes opilio) Traps

Commercial harvesting of snow crabs (Chionoecetes opilio) began in Newfoundland and Labrador, Canada, in 1967. Today, the fishery consists of 2188 active fishing licenses and has grown into the province’s most economically valuable fishery. Snow crabs are captured using conical traps consisting of a mild carbon steel frame, hard plastic entry funnel and a jacket of polyethylene netting. The frames of these traps corrode over time, which is expedited by being deployed in marine environments and stored on land near the ocean when not in use. As a result, there is interest within the community to increase the longevity of crab traps. One solution is to galvanize the steel frames prior to installing the funnel and netting. However, before harvesters transition to galvanized traps, two questions must be answered. Will the use of galvanized steel negatively impact catch rates? Will the life cycle of a crab trap be extended sufficiently to justify the additional cost of galvanizing? This study employed a generalized linear mixed model to evaluate the catch of legal-sized male crabs (CPUE) during the commercial fishery as a function of three trap frame treatments (old traditional, new traditional and new galvanized). We also assessed the economic viability of galvanizing trap frames by evaluating the life cycle cost (LCC) of traditional and galvanized traps to the harvester. The LCC was calculated over a range of inflation (0–6%) and discount (3–20%) rates. Our results found no significant difference in CPUE between new traps (traditional vs. galvanized) and concluded that except during instances of very high discount rates (12.9–19.9%), it is economically favourable to galvanize crab trap frames.

Inhibitor Efficiency of Cocogem Surfactants Based on C18 Carboxylic Acids on Corrosion of Carbon Mild Steel in CO2 Medium

Inhibitor Efficiency of Cocogem Surfactants Based on C18 Carboxylic Acids on Corrosion of Carbon Mild Steel in CO2 Medium

Performance Evaluation of Strengthened Scrapped Mating Rings of Face Seals Used as Single Point Turning Tool

The scrapped mating ring of face seals has been studied and recycled into single point turning tools (SPTTs) and performed comparably with standard turning tools. Three sets of tools, namely, standard tungsten tool, strengthened and unstrengthened scrapped ring, have been studied and performed satisfactorily as SPTTs. Standard tungsten tool, strengthened and unstrengthened scrapped mating ring of face seal respectively. The tools were configured with a nose radius 2mm, positive rake angles of 3o, 5o and 8o and used to perform turning operations on mild carbon steel (CS1030) with surface roughness measured. The results showed that the strengthened tools generated the best surface finish for mild carbon steel among all three tools under consideration. The statistical analysis showed that surface finish, the model, cutting speed and feed rate are significant with their P-values < 0.0001 but the depth of cut, rake angle and tool have no significant impact on surface finish at 95% confidence level. This research will provide the machine tools shop with more durable SPTT and enhance reliability, quality, minimize downtimes and accidents in machining processes.

Novel Lignin-Functionalized Waterborne Epoxy Composite Coatings with Excellent Anti-Aging, UV Resistance, and Interfacial Anti-Corrosion Performance.

Developing high-performance lignin anti-corrosive waterborne epoxy (WEP) coatings is conducive to the advancement of environmentally friendly coatings and the value-added utilization of lignin. In this work, a functionalized biomass waterborne epoxy composite coating is prepared using quaternized sodium lignosulfonate (QLS) as a functional nanofiller for mild carbon steel protection. The results showed that QLS has excellent dispersion and interface compatibility within WEP, and its abundant phenolic hydroxyl, sulfonate, quaternary ammonium groups, and nanoparticle structure endowed the coating with excellent corrosion inhibition and superior barrier properties. The corrosion inhibition efficiency of 100mgL-1 QLS in carbon steel immersed in a 3.5wt% NaCl solution reached 95.76%. Furthermore, the coating maintained an impedance modulus of 2.29×106Ωcm2 (|Z|0.01Hz) after being immersed for 51 days in the high-salt system. In addition, QLS imparted UV-blocking properties and thermal-oxygen aging resistance to the coating, as evidenced by a |Z|0.01Hz of 1.04×107Ωcm2 after seven days of UV aging while still maintaining a similar magnitude as before aging. The green lignin/WEP functional coatings effectively withstand the challenging outdoor environment characterized by high salt concentration and intense UV radiation, thereby demonstrating promising prospects for application in metal protection.

The inhibition efficiency of nitrated cottonseed oil on corrosion of mild carbon steel in CO2 medium

The inhibition efficiency of nitrated cottonseed oil on corrosion of mild carbon steel in CO2 medium

Carbon steel electrodes within chloride induced reinforcement corrosion in cracked concrete: Approximation to deterministic system response

AbstractResearch on chloride‐induced corrosion in cracked, reinforced concrete is of steady economic and scientific importance. The ever‐growing amount of reinforced concrete structures in need for maintenance and preservation calls for suitable and reliable methods to assess the current state. The present study demonstrates a specimen design that allows authentic corrosion monitoring, including solely carbon mild steel as working and counter electrodes, singularly cracked concrete as electrolytes and a conservative dismantling of the anodic steel‐concrete interface (SCI) at the end of 180 days of monitoring. The electrochemical features of the evolved specimen narrow down to the textbook behavior of the investigated electrodes according to the electro potential series of metals. The most prominent results are the chloride profiles at depth of rebar along the SCI, the build‐up of driving potential, and the decisive contribution arising from the anodic equilibrium potential. Accordingly, future repair methods should always include observation of the anodic equilibrium potential and their effectiveness is clearly addressed in the course of that value.

Experimental qualification of replaceable bolted links in dual eccentrically braced frames

AbstractThe performance of structures under severe seismic action is ensured by properly calibrated ductility, stiffness, and strength. The “plastic” members of ductile mild carbon steel (S235 to S355) dissipate the seismic energy, acting as “structural fuses”, while the “elastic” members must be provided with adequate overstrength, to have the capacity to carry the stresses corresponding to yielded and strain hardened plastic hinges. High strength steels, such as S460 to S690, might be used for these elastic members, providing them with the necessary overstrength, without enhancing the stiffness, as that could unbalance the structural system. Dual structural systems, as moment resisting frames (MRFs) combined with eccentrically braced frames (EBFs), can be equipped with replaceable mild carbon steel dissipative links acting as seismic fuses. The MRFs, possibly fabricated from high strength steel, remain elastic, being able to recover the initial position. The key problem in such systems is the design and calibration of the fuses, i.e. the replaceable bolted links, which should be carefully qualified by tests. The present paper reviews past research on bolted replaceable links and discusses the experimental qualification requirements.

Effect of copper content of AISI 1018 mild carbon steel on inhibition efficiency of imidazoline-based corrosion inhibitor in CO2-saturated brine

The effects of the copper content (varied from 0.054 to 0.158 wt%) of AISI 1018 mild carbon steel and pre-corrosion treatments on the inhibition efficiency (η) of an imidazoline-based corrosion inhibitor was investigated in CO2-saturated brine under dynamic flow conditions at 70 °C. An increase in the initial copper content of the steel results in a decrease in η and a decrease in the rate of inhibitor adsorption due to the formation of a porous cementite film enriched with iron carbide and zero-valent copper, leading to an increase in galvanic corrosion.

Experimental Investigation of Monotonic and Cyclic Behaviour of High-Performance Steels

As a new trend in modern structural design, the high-performance steels are increasingly used in steel structures, due to their superior mechanical properties, which could have decisive impact on the resistance and deformation capacity of structural components. High-performance steels include stainless and high-strength steels. The higher proof stress of the high-strength steels allows using thinner sections and material economy for those structural elements that do not experience stability problems. Austenitic stainless steel shows a series of advantages, including low maintenance costs and an excellent toughness at low temperatures. But the main characteristic which matters especially in seismic design, is the higher ductility, larger strain hardening and elongation at fracture in comparison with carbon steels. In this paper, the analysis of the behaviour of 1.4404 austenitic stainless steel and of S690 high-strength steel, in comparison with a reference S235 mild carbon steel is presented. This paper presents the assessment of the monotonic and cyclic performance of these steel grades, as well as the failure pattern, in order to assess the potential use in structural applications.

An assessment of new materials that are light weight for use in automobiles to improve fuel efficiency

Global energy demand is currently contributing to a severe problem of rising fuel prices for automobile users. One solution is to reduce the weight of the car body to improve fuel efficiency and reduce fuel costs. The choice of car body material can achieve this purpose. This paper will present the criteria such as stiffness, strength, and density to determine the suitability of substituting traditional materials, such as mild steel and carbon steel, with new materials High Strength Steel (HSS), aluminum alloys, and Long Fiber Thermoplastic (LFT). A literature review of the research is done to showcase the challenges traditional materials experience and how the development of these three new materials can overcome these challenges. Results from the case study show the feasibility of implementing these new materials in an automobile. More future research should be conducted to overcome the challenges and limitations posed by using these new materials, focusing on the low-cost replacement, manufacturing, and co-joining techniques of car body parts.

Ceratonia siliqua pulp extracts as a green corrosion inhibitor for mild carbon steel in 1 M HCl

Ceratonia siliqua pulp extracts as a green corrosion inhibitor for mild carbon steel in 1 M HCl

Wear Resistance Research and Its 2-factor Modeling of Nanoscaled Silicon Carbide Detonation Coatings

This research is related to the spheres of wearproof coating testing. The SiC coating has been deposited on the medium carbon steel using detonation deposition using the magnet coil flux of back direction. It has been established that only nanoscaled particles are deposited on the surface which had been accumulated in aggregates of different shape. The structure of the obtained coating has been thoroughly researched on the electronic microscope in previous publication. The obtained coating has been developed for testing on the friction bench modeling the friction process that is taking place in the couple of main and rod journals of internal combustion engines. The coating has also the corrosion protection properties. The nanoscaled coating on mild carbon steel had been tested under specified conditions and their friction surfaces had been researched on electronic microscope with the view of determination of wear mechanism. The two-factor modeling of the wear rate and friction factor has been done and three-dimensional diagrams have been plotted and analyzed.

Centrifugal Pump Shaft Coupling Durability Material S45C in the Water Treatment Plant Unit with the Destructive Test Method (impact)

The peg is a component that functions as a binder between the shaft and the hub in transmitting power and rotation. In general, the pegs are designed and made using metal materials such as mild carbon steel. In this research, the material of the coupling pin design on the centrifugal pump shaft is S45C. Where on the sample of the designed post, an impact test or the Charpy method of hitting the notch is carried out which aims to determine the amount of resistance to sudden loading and to determine the physical changes (failure modes) experienced by the post material. In this study, the sample of the post with dimensions of 6.10 mm x 6.10 mm x 55 mm obtained a large impact strength (impact strength) in the Charpy method impact test of 0.8445 Joule/mm2. And for the physical change (failure mode) experienced by the post material against the sudden loading, it is a brittle fracture that is characterized by physical characteristics in the form of granular (like sand) on the fracture surface, and the absence of plastic deformation that occurred first.