Carbon Isotope Studies Research Articles

Genesis of the Qingchayuan Flake Graphite Deposit in the Huangling Dome of Yangtze Block, South China

The Qingchayuan flake graphite deposit is located in the Huangling Dome, which represents a part of the Yangtze Block in South China. This deposit is a major and highly typical flake graphite deposit within this metallogenic region. The graphite ores are found within graphite-bearing mica schist and graphite-bearing biotite–plagioclase gneiss. The fixed carbon content varies from 3.52 to 13.78% with an average of 7.83%. The major element analysis shows that the main chemical components of the Qingchayuan flake graphite ore are SiO2, Al2O3, TFe2O3, and K2O. The carbon isotope study of the graphite ore indicates light carbon values ranging from −22.80 to −26.72‰, suggesting that it has a biogenic origin. In addition, the sulfur isotope values of the graphite samples range from −10.67 to −14.58‰, indicating the formation of the graphite deposit is related to biological processes. The presence of traces of migmatization around the graphite deposit indicates that the graphite has undergone ultra-high temperatures during the formation process. The origin of the Qingchayuan flake graphite deposit is explained by a two-stage genetic model, which involves material deposition and regional metamorphism (including migmatization). Firstly, after the deposition of carbonaceous material and its conversion into graphite by regional metamorphism, the graphite might have undergone recrystallization, resulting in the development of big flakes due to migmatization. This model is supported by previous studies and newly collected information.

A Comparative Study of Cave System Calcium Isotope Ratios: Implications for Quantitative Reconstruction of Paleorainfall From Speleothems

AbstractVariations in speleothem calcium isotope ratios (δ44Ca) are thought to be uniquely controlled by prior carbonate precipitation (PCP) above a drip site and, when calibrated with modern data, show promise as a semi‐quantitative proxy for paleorainfall. However, few monitoring studies have focused on δ44Ca in modern cave systems. We present a multi‐year comparative study of δ44Ca, carbon isotopes (δ13C), and trace elemental ratios from cave drip waters, modern calcite, and host rocks from two cave systems in California—White Moon Cave (WMC) and Lake Shasta Caverns (LSC). Drip water and calcite δ44Ca from both caves indicate PCP‐driven enrichment, and we used a simple Rayleigh fractionation model to quantify PCP variability over the monitoring period. Modern calcite trace element and δ44Ca data positively correlate at WMC, but not at LSC, indicating a shared PCP control on these proxies at WMC but not at LSC. At both WMC and LSC, we observe an inverse relationship between PCP and rainfall amounts, though this relationship is variable across individual drip sites. Our modeled data suggest that WMC experiences ∼20% more PCP than LSC, consistent with the fact that WMC receives less annual rainfall. This work supports speleothem δ44Ca as an independent constraint on PCP that can aid in the interpretation of other hydrologically sensitive proxies and provide quantitative estimates of paleorainfall. Additional, long‐term monitoring studies from a variety of climate settings will be key for understanding δ44Ca variability in cave systems more fully and better constraining the relationship between PCP and rainfall.

The subsistence strategy transformation of the Yangshao culture (6900-4800BP) in the Guanzhong Area and Western Henan based on new faunal materials from the Miaodigou site

While the significance of the Yangshao culture in early China is widely recognized, systematic and detailed analysis and discussion of its subsistence strategy are lacking, especially for faunal materials. This paper examines the new and crucial faunal remains that include 3,400 identified specimens from the Miaodigou site unearthed in 2002. At that site, pig husbandry was predominant and wild animals were occasionally hunted as supplemental resources. In combination with published research including zooarchaeology, paleoethnobotany, and carbon and nitrogen stable isotope studies of 29 other sites mainly from the Guanzhong area and western Henan, we argue that subsistence strategy underwent a comprehensive and profound transformation during the middle period of Yangshao culture, namely Miaodigou period, as crop production and pig husbandry flourished in a wide range of areas. Domestic pigs accounted for over 80% of mammals, reaching an unprecedented proportion in the Neolithic age and manifesting a high level of consistency in feeding and slaughtering, and foxtail millet replaced broomcorn to become the most important crop at all sites, both of which demonstrate the breadth and depth of this transformation. The tension between the deterioration of climate, the decrease of surrounding wildlife resources due to excessive development and the continuous growth of the population may have contributed to this transformation. This study enriches our understanding of human-environment interactions in the embryonic stage of Chinese civilization and triggers further thoughts on how culture, society, the environment and subsistence were entangled in the development of civilization.

The Role of Hydrocarbons in the Formation of Uranium Mineralization, Louzhuangzi District, Southern Junggar Basin (China)

In recent years, there have been important breakthroughs in the exploration for sandstone-hosted uranium (U) deposits in the Louzhuangzi district of the southern Junggar Basin. Between 2020 and 2023, a medium-sized sandstone-hosted uranium deposit production area was identified in the region. Only a few investigations have been conducted at the Louzhuangzi U deposit, including those analyzing its geological–tectonic evolution, basic geological features, hydrogeology, and ore-controlling factors. It is generally believed that uranium mineralization at the Louzhuangzi U deposit is controlled by a redox zone. Organic matter (referred to as OM hereafter) consisting of bitumen and carbonaceous debris is very common in the uranium ores (especially in high-grade ores) at the Louzhuangzi U deposit. However, the characteristics of the OM and its contribution to uranium’s mineralization have not been studied in detail. In this study, OM-rich U-ores, altered sandstone, and barren sandstone samples were collected for petrography, mineralogical, micro-spectroscopy, carbon, and sulfur isotope studies. The results of this study show that the distribution of U minerals and metal sulfides (pyrite, sphalerite, etc.) was strictly controlled by bitumen at the Louzhuangzi U deposit. The bitumen may have been formed by hydrocarbon-rich and U-rich ore-forming fluids, which were formed after hydrocarbon generation and expulsion in the underlying Jurassic coal-bearing source rocks. The fluids contained U, Zn, Fe, and other metal elements, which migrated together and then precipitated into the oxidized Toutunhe Formation sandstone through cracking and differentiation processes. Therefore, the results indicate that migrated hydrocarbons were involved in U mineralization, in addition to oxidation–reduction processes, in the Louzhuangzi district, south of the Junggar Basin (China).

Discussion on the studies of position-specific carbon isotopes of propane by Li et al. (2018), Zhang et al. (2022) and Shuai et al. (2023)

In a series of recent publications in Organic Geochemistry and elsewhere, investigators from State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry and their collaborators have reported position-specific δ13C of propane obtained from natural reservoirs and pyrolysis experiments. Based solely on the very negative ΔC-T values (δ13Ccenter – δ13Cterminal), ranging from −7 to −10 ‰, they advocated for abiogenic origins of the propanes from sedimentary settings (shale and coal deposits). However, they never demonstrated accuracy of the data and it is likely that correct ΔC-T values for these propanes are close to zero ‰. Therefore, their discussion and interpretation in terms of geochemical processes, including a putative abiogenic origin, are not substantiated.

Geochemical and Isotopic Investigation of Carbonate Deposits in the Central Kaladgi Basin, North Karnataka

Abstract Characteristic argillaceous-carbonate sediments covering parts of Belgaum, Bijapur and Bagalkot districts in north Karnataka have extensive deposits of high-grade limestone and have been commercially exploited since 1836. Despite their massive occurrence and commercial importance, the carbonate deposits in the Kaladgi basin have yet to receive enough attention. This study attempts to decipher the genetic aspects of the carbonate deposits occurring in the Neerubudihal region within the central part of the Kaladgi basin. The whole-rock carbon and oxygen isotopic compositions and the major and trace elemental compositions of the studied carbonates indicate that the rocks suffered a weak postdiagenetic alteration and retained the characteristics specific to the original diagenetic environment. The paleosalinity and palaeotemperature estimations reveal the carbonate precipitation in a stable marine environment in the study area with high salinity (av. 125) conditions at an average temperature of ~59 °C. The major and trace elemental studies classify the carbonates as dolomitic limestones and point to the dominance of the sedimentary process in their genesis. The carbon and oxygen isotopic studies suggest that the upper parts of the Bagalkot Group in the Kaladgi Basin had relatively lower organic content and diagenetic alteration than in the contemporary Bhima basin.

Paleoenvironmental Settings of the Soma Coal Basin (Turkey): Insights from Maceral Data, Biomarker, and Carbon Isotopic Composition.

Organic geochemical (TOC, pyrolysis, biomarker) and petrographic (maceral analysis) investigations together with organic carbon isotope studies were carried out to characterize in detail the depositional environment, determine the organic matter type, and assess the hydrocarbon production potential of three coal seams (KP1-upper, KM3-middle, and KM2-lower) in the Soma (Manisa, Western Anatolia) coal field in Turkey. The total organic carbon value of the upper coal seam ranged between 11.7 and 55.75%, the middle coal seam between 20.12 and 62.86%, and the lower coal seam between 50.03 and 65.71%. Coals in all three seams are characterized by low hydrogen index (HI) values (<151 mg HC/g TOC), low bitumen index (BI) (<19 g HC/g TOC), and quality index (QI) between 23 and 156 mg HC/g TOC. According to Rock-Eval pyrolysis data, the organic matter type of the coals is type III kerogen. Huminite reflectance, Tmax, and biomarker data (22S/22S+22R (C32) sterane, ββ/(αα + ββ) (C29) sterane, and MPI-1) indicate that the organic matter is not thermally mature and that the Soma-Manisa coal has reached the sub-bituminous rank. Rock-Eval data shows that coal is gas-prone and has not reached the maturity threshold required for initial gas production. The dominant maceral group is huminite while liptinite and inertinite macerals have been found in minor amounts. Groundwater index (GWI), vegetation index (VI), tissue preservation index (TPI), and gelification index (GI) parameters indicate a transition from limnic-limno-telmatic to limno-telmatic-telmatic environment from the upper seam to the lower seam. N-Alkane distributions show that paleoclimatic conditions have changed from KP1 to KM2. The higher abundance of pristane compared to phytane and low C35/C31-C35 homohopane index values demonstrate that the coals were deposited in a suboxic-oxic environment. The predominance of n-alkanes with generally high carbon number, relative variable abundances of C27-C28-C29 steranes, δ13C values, C/N ratios, and very low gammacerane index indicate a terrestrial ecosystem with nonmarine influence, although algae and microorganisms also contributed to the biomass.

δ13Corg perturbations preserved by the interglacial Datangpo Formation in South China with implications for stratigraphic correlation and carbon cycle

Palaeoclimatic and palaeoenvironmental reconstructions of the Cryogenian Period have attracted attention in relation to the debated “Snowball Earth” hypothesis and the early evolution of metazoan life. The carbon cycle and redox conditions of the Sturtian-Marinoan non-glacial interval have been subjected to much controversy in the past decades because of the difficulty of the lack of a high-resolution stratigraphic correlation scheme. As one of the typical Sturtian-Marinoan interglacial deposits, the Datangpo Formation was widely distributed in South China with shales continuously deposited. The previous zircon dating data of the Datangpo Formation provide important ages for global constrain of the Sturtian-Marinoan non-glacial interval. Here we present a high-resolution straitigraphic study of the organic carbon isotopes, of the Datangpo Formation from a drill core section in northern Guizhou Province. Based on measured episodic δ13Corg perturbations, three positive shifts and three negative excursions are identified. A δ13Corg-based chemostratigraphic correlation scheme is proposed herein that works well for the Datangpo Formation regionally. Meanwhile, the δ13Corg vertical gradients changed dynamically throughout the formation. This discovery implies that a significant ocean circulation overturn might have occurred in the upper Datangpo Formation, coinciding with the potential oxygenation.

Updating the dual C and O isotope-Gas-exchange model: A concept to understand plant responses to the environment and its implications for tree rings.

The combined study of carbon (C) and oxygen (O) isotopes in plant organic matter has emerged as a powerful tool for understanding plant functional responses to environmental change. The approach relies on established relationships between leaf gas exchange and isotopic fractionation to derive a series of model scenarios that can be used to infer changes in photosynthetic assimilation and stomatal conductance driven by changes in environmental parameters (CO2 , water availability, air humidity, temperature, nutrients). We review the mechanistic basis for a conceptual model, in light of recently published research, and discuss where isotopic observations do not match our current understanding of plant physiological response to the environment. We demonstrate that (1) the model was applied successfully in many, but not all studies; (2)although originally conceived for leaf isotopes, the model has been applied extensively to tree-ring isotopes in the context of tree physiology and dendrochronology. Where isotopic observations deviate from physiologically plausible conclusions, this mismatch between gas exchange and isotope response provides valuable insights into underlying physiological processes. Overall, we found that isotope responses can be grouped into situations of increasing resource limitation versus higher resource availability. The dual-isotope model helps to interpret plant responses to a multitude of environmental factors.

Environmental and trilobite diversity changes during the middle-late Cambrian SPICE event

The Steptoean Positive Carbon Isotope Excursion (SPICE) event at ca. 497−494 Ma was a major carbon-cycle perturbation of the late Cambrian that coincided with rapid diversity changes among trilobites. Several scenarios (e.g., climatic/oceanic cooling and seawater anoxia) have been proposed to account for an extinction of trilobites at the onset of SPICE, but the exact mechanism remains unclear. Here, we present a chemostratigraphic study of carbonate carbon and carbonate-associated sulfate sulfur isotopes (δ13Ccarb and δ34SCAS) and elemental redox proxies (UEF, MoEF, and Corg/P), augmented by secular trilobite diversity data, from both upper slope (Wangcun) and lower slope (Duibian) successions from the Jiangnan Slope, South China, spanning the Drumian to lower Jiangshanian. Redox data indicate locally/regionally well-oxygenated conditions throughout the SPICE event in both study sections except for low-oxygen (hypoxic) conditions within the rising limb of the SPICE (early-middle Paibian) at Duibian. As in coeval sections globally, the reported δ13Ccarb and δ34SCAS profiles exhibit first-order coupling throughout the SPICE event, reflecting co-burial of organic matter and pyrite controlled by globally integrated marine productivity, organic preservation rates, and shelf hypoxia. Increasing δ34SCAS in the “Early SPICE” interval (late Guzhangian) suggests that significant environmental change (e.g., global-oceanic hypoxia) was under way before the global carbon cycle was markedly affected. Assessment of trilobite range data within a high-resolution biostratigraphic framework for the middle-late Cambrian facilitated re-evaluation of the relationship of the SPICE to contemporaneous biodiversity changes. Trilobite diversity in South China declined during the Early SPICE (corresponding to the End-Marjuman Biomere Extinction, or EMBE, of Laurentia) and at the termination of the SPICE (corresponding to the End-Steptoean Biomere Extinction, or ESBE, of Laurentia), consistent with biotic patterns from other cratons. We infer that oxygen minimum zone and/or shelf hypoxia expanded as a result of locally enhanced productivity due to intensified upwelling following climatic cooling, and that expanded hypoxia played a major role in the EMBE at the onset of SPICE. During the SPICE event, global-ocean ventilation promoted marine biotic recovery, but termination of SPICE-related cooling in the late Paibian may have reduced global-ocean circulation, triggering further redox changes that precipitated the ESBE. Major changes in both marine environmental conditions and trilobite diversity during the late Guzhangian demonstrate that the SPICE event began earlier than the Guzhangian-Paibian boundary, as previously proposed.

Relative abundance of grazing and browsing herbivores is not a direct reflection of vegetation structure: Implications for hominin paleoenvironmental reconstruction.

The diet of fossil herbivores inferred from enamel stable carbon isotopes is often used to make paleoenvironmental reconstructions. While many studies have focused on using environmental indicator taxa to make paleoenvironmental reconstructions, community-based approaches are considered to provide a more complete picture of paleolandscapes. These studies assume that the diet and relative abundance of herbivores are related to the areal extent of different vegetation types on the landscape. Here, we quantitatively test this assumption in 16 modern ecosystems in eastern and southern Africa with a wide range of woody vegetation cover. We conducted a landscape-level spatial analysis of vegetation patterns using a published land cover data set and computed landscape metrics. We compiled data on relative abundance and diet of herbivores inferred from carbon isotope studies for all large herbivores in these ecosystems. We found that despite differences in the total areal extent of different vegetation types, numerous sizable patches of each vegetation type are available in most ecosystems. However, despite variation across the ecosystems examined, grazers are typically the most abundant herbivores even in sites that have a higher proportion of forest and shrub cover. This indicates that the diet and relative abundance of herbivores is not a simple reflection of the total areal extent of vegetation types available on the landscape. The higher proportion of grazers observed in these ecosystems is a result of multiple factors including habitat heterogeneity, differences in biomass turnover rate between grasses and woody vegetation, resource partitioning, and the advantages of group living in open environments. Comparison of diet and relative abundance of herbivores in modern ecosystems to fossil herbivore assemblages shows that very different vegetation regimes can support similar herbivore assemblages. This study has significant implications for paleolandscape reconstructions and cautions against a simplistic wooded vs. grassland paleoenvironmental interpretations based on fossil herbivore assemblages.

Paleomagnetism of the Ediacaran Avellaneda Formation (Argentina), Part II: Magnetic and chemical stratigraphy constraints on the onset of the Shuram carbon excursion

Magnetostratigraphy is a powerful technique for high-resolution stratigraphic correlation and accurate dating of the polarity history of the magnetic field. Up to now, magnetostratigraphic studies have been underutilized in Ediacaran successions. Here, we present a magnetostratigraphy coupled with a carbon isotope study in Ediacaran Avellaneda Formation (∼570 Ma), a sedimentary cover sequence in the Tandilia orogenic belt, of the Río de la Plata craton. Paleomagnetic results and δ13C profiles were obtained from three drill cores that cut across the sedimentary record of the Avellaneda Formation. Paleomagnetic results plotted stratigraphically allowed the identification of a prevalent reverse polarity separated by normal polarity interval. Our findings show a coincident correlative polarity transition at each drill core analyzed. δ13C values demonstrate that the magnetostratigraphic polarity pattern is laterally consistent. Furthermore, C-isotope curves show a transition from positive to negative values near the top of the Avellaneda Formation. This excursion is likely correlative with the onset of the Shuram excursion (ca. 570 Ma). Our findings suggest that the onset of Shuram excursion took place during a reverse polarity chron. Comparison with other coeval sequences validate this correlation. Geomagnetic polarity reversals pattern in the Avellaneda Formation and its correlative pattern, validates a magnetostratigraphy as a potential method to correlate Precambrian strata. Our new findings shed further light on the possible use of magnetic polarity reversals to correlate Ediacaran successions.

Ordovician of the conterminous United States

AbstractThe Ordovician rocks of the conterminous United States (US) have a complex history, spanning multiple ancient basins, shifting palaeoclimate and evolving tectonic regimes. The US portion of the palaeocontinent of Laurentia occupied a relatively stable and isolated position around the southern tropics during the Ordovician. In general, Lower Ordovician rocks form a vast autochthonous blanket of fine-grained (tropical) carbonates that covered much of Laurentia, named the ‘Great American Carbonate Bank’. Outboard, ribbon carbonates and graptolitic shales are found in allochthonous fragments of the ancient continental margin. Middle Ordovician strata are more lithologically diverse, including the addition of several regionally distributed sandstones of the inner detrital belt, mostly overlying the Sauk–Tippecanoe unconformity. Upper Ordovician strata show the greatest lithologic and faunal diversity, reflecting steepening topography resulting from regional compression along the south Laurentian (Appalachian) margin. Recent advances in the interpretation of the US Ordovician come primarily from studies of carbon and oxygen stable isotopes, sequence stratigraphy, palaeoecology, tephrochronology, redox geochemistry, strontium isotopes and geochronology.

RECONSTRUCTING KUNGURIAN (CISURALIAN, PERMIAN) TERRESTRIAL ENVIRONMENTS WITHIN A MEGACALDERA IN THE SOUTHERN ALPS (N-ITALY) USING LITHOFACIES ANALYSIS, PALYNOLOGY AND STABLE CARBON ISOTOPES

During the Permian, climate experienced a change from icehouse to greenhouse conditions. Few multidisciplinary studies have investigated Kungurian (late Cisuralian) tropical terrestrial ecosystem and climate changes. Here, we apply an interdisciplinary approach to two alluvial-lacustrine successions of the Athesian Volcanic Group (Southern Alps, northern Italy) deposited in a Kungurian megacaldera during periods of volcanic quiescence. Sedimentological analysis combined with palynofacies studies allowed the reconstruction of the depositional environments. The study of sporomorph assemblages and stable organic carbon isotopes provided information on plant communities and the climate context. Two different depositional environments were present in the megacaldera: one proximal and one more distal with respect to the source, distinguished by a slightly different composition of the sediments, palynofacies and organic carbon isotopes. The plant community in the area was dominated by xeromorphic-hygromorphic taxa. The δ13Corgvalues are comparable to those of other Cisuralian continental organic matter and plants. The stable carbon isotope values show a small variability, which correlates weakly, but significantly, with the abundance of xeromorphic elements. All observations support deposition during semiarid to arid climate conditions, typical of the mid-late Cisuralian in the area.

Carbon isotope study of conodont elements: Applications and limitations

Conodont elements composed of protein-apatite nanocomposites are considered a promising geochemical archive due to their high resistivity to weathering and diagenetic processes. This article introduces some possible applications and limitation of the carbon isotope investigations in conodont research. It is based on the author's collections of conodonts comprising stratigraphic interval from the Upper Devonian to the Mississippian. Total number of the studied conodont elements is 282. The data obtained suggest that isotopic compositions of carbon of conodont elements probably reflect isotopic composition of the conodont diet with some insignificant taphonomical and histological biases. The variations in δ13Ccon were probably controlled by changes in the C-isotope composition of the phytoplankton as the main part of conodont food, which, in turn, was affected by global and local changes in the pelagic ecosystem. Decrease in δ13Ccon may be provoked by shortening of the food chains, enhancing of C-isotope fractioning by phytoplankton, and a decrease in δ13C of atmospheric CO2. Significant changes in δ13Ccon mark probable perturbations in the pelagic ecosystems. Decoupling carbon isotope composition of carbonates and conodont elements is a proxy of the water temperature, CO2 concentration in atmosphere and hydrosphere, and phytoplankton growth rate. It is likely that the CO2 concentration was a leading factor affecting decoupling carbon isotope composition of carbonates and conodont elements in the late Famennian – Tournaisian interval. However, the CO2 signal can be obscured by variations in primary bioproductivity. Fluctuations in decoupling carbon isotope composition of carbonates and conodont elements reflect global and local changes in pelagic marine ecosystems, and prominent excursions can be used as stratigraphic markers.

A small‐scale neutral alumina column chromatography method for carbon isotope determination of hopanes in crude oils or rock extracts

This paper presents a small-scale column chromatography method for separating hopanes in crude oil or rock extracts using neutral alumina as a solid phase adsorbent and a Pasteur pipette as a separation device. Three oil samples were selected to study the effect of solid phase adsorbent type and column length on the separation of hopanes. The oil samples were eluted with mixed reagents (V hexane: V petroleum ether = 8:2) and collected at intervals of 0.5 ml. Ten Fractions were collected and tested for the compounds using GC–MS. A quantitative approach was used to reveal distribution characteristics of compounds in each eluted Fraction. Experimental results showed that 100–200 um neutral alumina exhibited significant differences in the adsorptive capacity of biomarkers from oil samples and rock extracts. The elution order of the biomarkers in the chromatographic column (the length is 180 mm) was n-alkanes, steranes and hopanes. The separation of hopanes could be realized by collecting the eluted Fractions 4 and 5. Compared with the urea complexation, the purity of hopanes separated by column chromatography was higher. The concentration of n-alkanes (nC16-nC34) could be reduced from 1.99 to 4.83 mg/ml to 0.79–0.94 mg/ml, and the content of steranes can be reduced from the original 12% to 0.45%. Residual n-alkanes and steranes were not visible in the GC–MS detection. The Total Ion Chromatography (TIC) of hopanes was consistent with the distribution characteristics of the m/z191 mass chromatogram. The isolated hopanes could meet the detection requirements of isotope ratio mass spectrometry. The C29Ts/C29αβ ratio of hopanes decreased gradually from 1.63 to 0.73 as the column length increased. It is speculated that the variation of the C29Ts/C29αβ ratio is not only affected by maturity but also by the oil and gas migration. This method is a new attempt in the field of compound purification and can be widely used in the study of stable carbon isotopes of hopanes monomeric hydrocarbons.

Middle to Late Miocene tectonic forcing of intensified humidity in the Xunhua Basin, NE Tibetan Plateau

The mechanisms and controls of the Middle-Late Miocene paleoenvironmental evolution of the northeastern Tibetan Plateau remain elusive. Here, we present an integrated multiproxy study of total organic carbon isotopes, lipid biomarkers, petrographic components and micropaleontological records in the well-dated Xigou section of the Xunhua Basin. Our data reveal a large decrease (−1.1 ‰) in bulk organic carbon isotopes (δ13Corg) at ∼12.7 Ma, a broad minimum at ∼12.7–8.0 Ma, and a large increase (+1.3 ‰) at ∼8.0 Ma. The decline in δ13Corg at 12.7 Ma was accompanied by pronounced changes in n-alkane indices, clay minerals, palynology, and ostracods, recording a major rise of lake level of paleo-Lake Xunhua due to increased precipitation in the regional catchment. Our inference of sustained elevated humidity in the Xunhua Basin at 12.7–8.0 Ma is contrary to previously reported cooling and drying trends on the NE Tibetan Plateau for the Middle-Late Miocene (∼14–8 Ma), thus precluding the role of global climate change as the dominant driver. Rather, we attribute the paleoenvironmental evolution of the Xunhua Basin to changes in regional rainfall patterns related to orogenic uplift. The Jishi Shan mountain range reached a critical threshold elevation at ∼12.7 Ma, becoming an orographic barrier to Westerlies-transported moisture and thus enhancing intensified precipitation within the Xunhua Basin. By ∼8 Ma, further uplift caused this orogen to become a barrier to the East Asian monsoon, resulting in aridification of the Xunhua Basin.

Are Madagascar's obligate grazing-lawns ancient and evolved with endemic herbivores, or recently selected by introduced cattle?

Are Madagascar's obligate grazing-lawns ancient and evolved with endemic herbivores, or recently selected by introduced cattle?

Detailed Carbon Isotope Study of PM2.5 Aerosols at Urban Background, Suburban Background and Regional Background Sites in Hungary

The aim of this study was to estimate and refine the potential sources of carbon in the atmospheric PM2.5 fraction aerosol at three sampling sites in Hungary. Quantification of total, organic and elemental carbon (TC, OC and EC, respectively), as well as radiocarbon (14C) and stable carbon isotope analyses were performed on exposed filters collected at an urban background site, a suburban background site of the capital of Hungary, Budapest from October 2017 to July 2018. Results were also collected from the rural regional background site of K-puszta. Compared to TC concentrations from other regions of Europe, the ratio of the lowest and highest values at all sites in Hungary are lower than these European locations, probably due to the specific meteorological conditions prevailing in the Carpathian Basin over the observation period. The concentration of OC was constantly higher than that of EC and a seasonal variation with higher values in the heating period (October–March) and lower values in the non-heating vegetation period (April–September) could be observed for both EC and OC fractions. Using 14C, the seasonal mean fraction of contemporary carbon (fC) within the TC varied between 0.50 and 0.78 at the sites, suggesting that modern sources were remarkable during the year, regardless of the heating or vegetation period. At the two urban sites, assuming constant industrial emission during the year, the fossil fuel combustion sources were responsible for the seasonal variation of EC, while modern carbon emissions from biomass-burning and biogenic sources influenced the OC concentration. The higher EC/TC ratios at these sites were associated with lower fC and δ13C values, which can be explained by soot emission from transportation. The notably high EC/TC ratios in the spring were likely caused by the reduced concentration of OC instead of increased EC concentrations. This could probably be caused by the ending of winter biomass burning, which emits a huge amount of OC into the atmosphere. On the contrary, the rural K-puszta site showed some differences relative to the sites in Budapest. No correlation could be revealed between the EC/TC ratio, fC and δ13C results, suggesting that the structure of sources was very stagnant and balanced in each season. In autumn, however, some less depleted values were observed, and agricultural corn-stalk burning after harvesting in the southern and eastern directions from Hungary can be suggested as the main source.

An integrated carbon isotope and bio-sequence stratigraphic study of the Early Cretaceous to Paleogene, Central North Sea

A stable carbon isotope (δ13C) profile of the Early Cretaceous to Paleogene (Berriasian – Danian) was generated from ditch-cuttings material recovered from well 30/2a-7, Central North Sea. The profile of δ13C values was integrated with calcareous nannofossil biostratigraphy and sequence stratigraphy from the Cromer Knoll Group to provide an integrated stratigraphic framework for the Early Cretaceous. Although, nannofossil data was not collected from most of the overlying Chalk Group, the associated δ13C profile was sufficiently resolved to correlate with other similar δ13C records from both the Boreal and Tethyan Realms. The δ13C profiles and nannofossil data from well 30/2a-7 were stacked with the nearby Shearwater A9 well data to create a composite section that provides a long-term near continuous record of the Early Cretaceous to Paleogene from the basinal deposits of the Central North Sea. Sequence stratigraphic analyses was conducted to provide an integrated bio-chemo-sequence stratigraphic framework for regional correlation. Several major globally recognized δ13C events that are recognized in the wells are seismically resolvable and can be correlated regionally across the Central North Sea, providing a chronostratigraphic framework for constraining hydrocarbon play elements for both exploration, production and carbon capture and storage projects.