Carbon Fiber-reinforced Thermoplastic Composites Research Articles

Research on damage repair and high-velocity impact characteristics of thermoplastic composites

Low-velocity impact (LVI) can result in imperceptible damage to carbon fiber reinforced thermoplastic composites (CFRTP) laminates during service, leading to a reduction in structural strength. The thermal repair of damaged CFRTP laminates is conducted using the repairability of thermoplastic resin at high temperatures. However, the high-velocity impact characteristics of CFRTP laminates following thermal repair remain uncertain. This study examines CFRTP laminates made of two different materials (CF/PEEK and CF/PPS) with varying levels of low-velocity impact damage, and investigates the thermal repair process. A comparative experimental analysis examined the high-speed impact characteristics of CFRTP laminates under varying conditions. The results indicate that CF/PEEK laminates consistently exhibit superior compressive properties and impact resistance compared to CF/PPS laminates under similar conditions. Following damage from low-velocity impact, the compressive properties and high-velocity impact resistance of CFRTP laminates decrease, with CF/PPS laminates typically showing a lower performance retention rate. However, the thermal repair process proposed in this study significantly enhances the performance of CF/PPS laminates. Moreover, the degree of performance healing in CF/PPS laminates is consistently higher than that in CF/PEEK laminates, which is closely related to the semi-crystalline nature of PEEK resin.

Linear viscoelasticity of anisotropic carbon fibers reinforced thermoplastics: From micromechanics to dynamic torsion experiments

The link between experimental characterization and the constitutive behavior of an anisotropic linear viscoelastic unidirectional carbon fiber-reinforced thermoplastic composite is explored using micromechanics modeling. Dynamic torsion tests were conducted at 1 Hz over a wide temperature range, from the glassy to the rubbery states of the polymeric matrix, on both the pure matrix and the composite, for various cutting angles relative to the fibers. A two-step modeling procedure in the frequency domain is presented to predict and validate the effective behavior of the composite. The first step involves FFT-based homogenization, which maps the microstructure and constituent behaviors to effective transversely isotropic viscoelastic properties. The second step consists of finite element simulations using the effective behavior calculated from homogenization as input to replicate the experiments. A comparison between experimental results and model predictions across the entire temperature range is performed. The modeling predictions show good accuracy at low temperatures, where the matrix is in the glassy state. At high temperatures, where the matrix is in the rubbery state, the predicted behavior becomes too soft. As the phase contrast increases and the ratio of matrix bulk modulus to shear modulus rises significantly, the impact of fiber arrangement on the effective properties becomes more pronounced.

Coupled heat transfer–crystallization analysis in continuous carbon fiber-reinforced thermoplastic composites 3D printing: simulation and experimental validation

AbstractThis study proposes an advanced progressive numerical modeling approach to investigate heat transfer phenomena occurring in the 3D printing of continuous carbon fiber-reinforced co-polyamide (Copa) composites. The material extrusion process is simulated using element activation techniques and active cooling methods, while thermal boundary conditions are updated during the printing process. Differential Scanning Calorimetry (DSC) tests are conducted on composite and neat polymer samples to include the crystallization behavior, where the Hoffman–Lauritzen model is employed for crystallization modeling based on the input data from DSC tests. It is demonstrated that the proposed modeling approach, coupled with the Hoffman–Lauritzen crystallization model, accurately predicts the thermal history of the composite extrudate post-deposition. In the case of a neat polymer, the results of the developed FEM model align well with existing literature. Experimental in-situ temperature measurements utilizing thermal vision agree very well with the predictions of the heat transfer model developed for 3D printing of continuous fiber-reinforced Copa composites, demonstrating the model's capability to predict temperature profiles during printing.

Influence of bionic texture on the mechanical properties of 6061Al/CFRTP laser joints

Joining carbon fiber reinforced thermoplastic composites (CFRTP) with metals is a significant challenge for lightweighting in the automotive sector. The lower strength of hybrid joints limits their applications in the relevant fields. In this study, three distinct surface textures were applied to 6061 aluminum alloy (6061Al), including a traditional groove texture and two novel bionic textures (shark skin and fish scale), to enhance the strength of the hybrid joint between the materials. The impact of these textures on the mechanical properties of 6061Al/CFRTP hybrid joints was investigated through experimental methods and finite element simulations. The results indicated that the stress distribution at the interface of the bionic textured samples was more uniform, reducing stress concentration at the interface. Furthermore, the hybrid joint strength was improved as the bionic texture hindered crack initiation and propagation and facilitated crack deflection. Compared to the untextured samples, the fish scale textured samples exhibited the highest strength, which increased by 431.3 % relative to the untextured samples.

Influence of laser texturing on the properties of fusion joints between aluminum alloys and carbon fiber reinforced thermoplastic composites

Laser texturing is an effective method to enhance the fusion joining of aluminum alloy (Al) to carbon fiber reinforced thermoplastics composite (CFRTP). The enhancement effect is related to the morphology and spacing of the microstructures on Al surface. However, because of the correlation between the morphology and the spacing of the microstructures, excessive dense microstructures change the morphology, leading to a reduction in the enhancement effect, while sparse microstructures are also difficult to significantly enhance the joint. To this end, this paper proposes an improved laser texturing process to enhance fusion joints, through the investigation of the recast layer formation process during laser texturing on the Al surface, which comprehensively reveals the synergistic effects of microstructural morphology and spacing on joint properties. The results indicated that the increase of the number of laser processes and the microstructure spacing increased the height of the recast layer, with the difference that the microstructure spacing had less effect after increasing to a certain value. With the increase of microstructure spacing, the morphology of the microstructure on the Al surface transformed from the serrated microstructure to the double-scale microstructure, and finally to the independent microstructure, affected by the recast layer on sides of the microstructure. Once the dual-scale microstructures were formed on the Al surface, the shear strength of the Al/CFRTP fusion joint was the highest with a value of 25.05 MPa. The findings could provide a basis for laser texturing pretreatment for fusion joining.

Online monitoring of pre-crack initiation in carbon fiber-reinforced thermoplastic composites by an ultrasonic cutting tool using high-speed optical imaging and infrared thermography

The ultrasonic-assisted manufacturing process is a promising machining approach for composite materials as it exerts less force, making it ideal for the aerospace and automotive sectors. This work reports about the pre-crack initiation in carbon fiber reinforced (CF)/ poly-ether-ether-ketone (PEEK) composite under ultrasonic frequency at room temperature. An iron-based cutting tool matching the system’s resonance frequency (20 kHz) was used to perform the ultrasonic pre-cracking. In this novel work, the pre-cracking of CF-PEEK is considered as the initial step for a complete fiber layer separation, which holds the key for circularity options in high-performance aerospace composites. State-of-the-art high-speed camera and infrared thermography were combined to monitor the crack initiation and propagation. By online monitoring, the different stages involved in the pre-cracking process, its temperature evolution, and consequently the dissipated energy during pre-cracking under ultrasonic frequency were evaluated. The results showed that oscillation amplitude had a significant influence on the determined pre-crack depth and measured global temperature and energy compared to cutting force. The measured global temperature data indicates that pre-cracking occurred in the solid state with a temperature well below the glass-transition temperature of PEEK. However, the local temperature at the contact between the sample and sonotrode could have been much higher during ultrasonic cutting which needed further investigation. The computed global dissipated energy and temperature were only reliable at the pre-crack initiation site due to the limitation in the infrared thermography system.

Electrochemical Jet Machining of Surface Texture: Improving the Strength of Hot-Pressure-Welded AA6061-CF/PA66 Joints

Diverse industries are witnessing an increase in demand for hybrid structures of metals and carbon-fiber-reinforced thermoplastic composites (CFRTPs). Welding is an essential technique in the manufacture of metal–CFRTP hybrid structures. However, achieving high-strength metal–CFRTP welded joints faces serious challenges due to the considerable disparities in material characteristics. As an effective method to strengthen metal–CFRTP joints, surface texturing on metal is gaining significant attention. This study introduces an emerging surface texturing approach, electrochemical jet machining (EJM) using a film electrolyte jet, for enhancing the performance of AA6061-CF/PA66 hot-pressure-welded (HPW) joints. Parametric effects on surface morphology and roughness in the EJM of AA6061 are investigated. The results show that a rough surface with multiscale pores can be generated on AA6061 by EJM, and that surface morphology can be modulated by adjusting the applied current density and jet translational speed. Subsequently, the effects of different EJM-textured surface morphologies on the performance of HPW joints are examined. Surface textures created by EJM are demonstrated to significantly enhance the mechanical interlocking effect at the bonding interface between AA6061 and CF/PA66, resulting in a substantial increase in joint strength. The maximum joint strength attained in the present work with EJM texturing is raised by 45.29% compared to the joints without surface texturing. Additionally, the joint strength slightly improves as the roughness of EJM-textured surfaces rises, with the exception of rough surfaces that are textured with a combination of low current density and rapid translational speed. Overall, these findings suggest that EJM texturing using a film jet prior to welding is a potential approach for the manufacture of high-performance metal–CFRTP hybrid structures.

Enhanced interlayer strength in 3D-printed PA12 composites via electromagnetic induction post-processing

Weak interlayer strength remains a critical limitation in the application of material extrusion 3D-printed parts. Herein, a non-contact method, electromagnetic induction post-processing, is proposed to address this issue. This method aims to enhance the weak interlayer strength of 3D-printed PA12 samples by introducing Fe3O4 particles for induced heat generation under alternating magnetic fields. The heat generation characteristics, surface morphology, crystallization behavior, and interlayer performance of 3D-printed samples subjected to induction post-processing are systematically investigated. The results indicate that a remarkable improvement in the interlayer strength of 3D-printed PA12 samples can be achieved through induction post-processing. Tensile strength along the Z-direction (perpendicular to the printing plane) exhibits a distinct increase of 218.3 %, while interlayer tear strength can rise by 328.1 %. Improvement in interlayer strength results from heat generation driving interfacial resin diffusion. Additionally, induction post-processing results in localized surface smoothing and a slight reduction in the crystallinity of the 3D-printed sample. Compared to traditional methods like in-oven heat treatment (annealing), induction post-processing offers higher efficiency by circumventing the initial constraints of heat transfer. Furthermore, the concept of selective induction heating (SIH) is proposed to achieve non-contact, localized heating by adjusting the composition of thermoplastics during printing. SIH holds good promise for applications in 3D-printed continuous carbon fiber-reinforced thermoplastic composites, including mold-free forming, complex surface welding, and repair (particularly in narrow and inaccessible areas).

An anchor-inspired interface for improving interfacial properties of carbon fiber-reinforced high-performance thermoplastic composites

Carbon fiber-reinforced thermoplastic composites are promising materials with many application prospects. However, surface inertness of CFs weakens the interfacial properties of these composites. Therefore, in this study, an anchor-inspired structure was designed and grafted onto CFs by using an anchor-inspired segmented copolymer, comprising of polyimide as the “chain” and polyhedral oligomeric silsesquioxane (POSS) as the “anchor”. In combination with atom transfer radical polymerization with the advantage of controllable molecular weight, degree of polymerization of the anchor-shaped structure with the best compatibility with poly (phthalazinone ether nitrile ketone) (PPENK) resin was pre-determined through molecular dynamics simulations, which reduced the experimental costs. The results of X-ray photoelectron spectroscopy indicated the successful connection of the numerous anchor-shaped structures to the CFs. Compared to composite made of origin fibers and PPENK, the interfacial shear strength at the microscopic level and interlaminar shear strength at the macroscopic level of grafted CF and PPENK composite increased by 184.9 % and 44.2 %, respectively. This is mainly attributed to the synergistic effect of mechanical interlocking and interfacial interaction between the anchor-shaped structure and the PPENK resin. This study serves as a feasible path to enhance the interfacial adhesion of composites by designing an anchor-shaped structure of organic macromolecules and inorganic nanoparticles on CFs.

Novel thermoplastic matrix resin with low processing temperature and good interfacial strength for carbon fiber-reinforced polyethersulfone

Owing to the increased demand for carbon fiber-reinforced thermoplastic composites with excellent recyclability, there is a need to improve the interfacial bonding between the fiber and matrix. Hydroxy-functionalized polyethersulfone (PES), i.e., PES-OH, and epoxy resin (ER) were included to impart functionality to PES. A mixture of PES, PES-OH, and ERs with a weight ratio of 8:1:1 reduced the Tg by −18% compared with 100% PES. The enhancement of the interfacial properties increased the interlaminar shear, tensile, compressive, and residual compressive strengths by 50%, 22%, 43%, and 25%, respectively. This study can contribute to the development of carbon fiber composites for future mobility.

Influence of interfacial micro-textures on CFRTP-TC4 hybrid joint formation with laser assistant joining technique

To investigate the influence of interfacial micro-textures on the carbon fiber reinforced thermoplastic composites (CFRTP)-TC4 alloy hybrid joint formation process, a finite element model with micro-textures was established. The joint formation mechanism and the impact of joining parameters on heat input were analyzed. The results show that the existence of interfacial micro-textures will lead to an uneven distribution of the temperature field on the surface of polyamide and reduce the heat transferred to the surface of CFRTP. And, mechanical interlocks and new chemical bonds are generated in the joining process because of these micro-textures, which enhances the joining strengthen significantly. The optimized joining parameter window was also obtained and the joining strength was predicted by numerical simulation. With the numerical assistant, the CFRTP-TC4 joint with highest shear strength was obtained as the laser power and the welding speed is 130 W and of 2 mm/s, respectively.

Testing and identification method for the interfacial heat transfer coefficient between CFRTP and tools under fast hot-stamping conditions

Carbon fiber reinforced thermoplastic composites (CFRTP) are increasingly applied in automobile structures. Hot-stamping is a fast forming process for complex components of CFRTP. During hot-stamping process, the variations of temperature field occur in entire forming process, which ultimately have an impact on the forming quality and dimensional precision of the part. The interfacial heat transfer behaviour between CFRTP and tools directly determines the temperature distribution in the part. However, the existing heat transfer testing and identification methods are designed for sheet metal, which may not be applicable for CFRTP due to the differences in material properties and forming processes. Therefore, in this work, a new test device was developed to reproduce the interfacial heat transfer behaviour of CFRTP under various hot-stamping conditions, and an inverse identification method of the interfacial heat transfer coefficient (IHTC) between CFRTP and tools was proposed. The influences of contact conditions on the IHTC were investigated, including the interfacial contact pressure, interfacial clearance, heating temperature of tools and sheets. The results showed that the IHTC demonstrated a positive correlation with the contact pressure. However, the IHTC would significantly decrease with the existence of a clearance at the interface. Within the entire heat transfer process, it was also found that an increase in tool temperature resulted in a decrease in the IHTC, while initial sheet temperature didn't exert a significant influence. Furthermore, the reliability of proposed testing and identification methods had been verified by the hot-stamping for U-shaped CFRTP parts. The temperature error between the simulation and experiment was less than 5 %.

Optical properties optimization of carbon fiber reinforced thermoplastic tapes by micro surface texturing for enhanced laser heating efficiency and in-situ consolidation quality during AFP process

The laser-assisted automated fiber placement (L-AFP) process of carbon fiber-reinforced thermoplastic composites suffers from insufficient heating efficiency and in-situ consolidation quality caused by significant reflection on the tape surface. Here, we propose a novel strategy to increase the heating efficiency by refocusing the reflected light, initially scattered to the environment and wasted, onto the tapes for multiple and full absorptions. The method for laser concentration is first validated through light-tracing simulation. Then, three kinds of tapes with different micro textures on the surface are prepared by the hot-embossing process. The transverse V-grooved texture tapes and flat surface tapes absorb 25% more laser energy than the longitudinal V-grooved and commercial tapes due to the reduction in transverse scattering angle from 180° to 2.72°. This leads to a temperature increase of 130 °C at the nip point during the L-AFP process at the lay-down rate of 500 mm/s with 1 kW laser power. Improved in-situ consolidation quality leads to a significant increase in the flexural and shear strength of L-AFP-prepared carbon fiber reinforced polyetheretherketone (CF/PEEK) laminates, with a reduction in porosity to around 2%.

Preparation and properties of hybrid specific length carbon fiber thermoplastic composites by suspension method

AbstractCarbon fiber reinforced thermoplastic composites have such advantages as low density, high strength, high temperature resistance, impact resistance, and good ductility, but due to the density difference between carbon fibers and resin fibers, it is difficult to mix them uniformly. Hence, it is difficult to prepare the composites with the uniform properties. In order to solve this problem, a preparation process based on solid phase mixing of carbon and resin fibers by suspension method is proposed in this paper. The carbon fiber reinforced thermoplastic composites (CFRTPs) can be prepared by dispersing carbon fibers of a certain length (~50 mm) and resin fibers in suspension through ultrasound‐assisted and churn‐combing methods. The effects of carbon fiber length, content and molding process on the mechanical properties of the CFRTPs were studied. The results show that the carbon fiber content and length are the main factors affecting the mechanical properties as well as void ratio of CFRTP. The performance of composites is significantly improved with the increase of carbon fiber length. While the length of carbon fiber is 50 mm and the content is 30 wt%, the prepared CFRTP has the best performance, with the tensile strength of 182.1 MPa, the bending strength of 354.3 MPa, the impact strength of 67.2 KJ·m−2, and the material void ratio of 0.65%. The study shows that the suspension method is feasible for the preparation of the CFRTPs. It is beneficial to improve production efficiency and decrease cost of production for the CFRTPs.Highlights Carbon fiber reinforced thermoplastic composites can be prepared by dispersing carbon fibers of a certain length (~50 mm) and resin fibers in suspension through ultrasound‐assisted and churn‐combing methods. Through the cooling‐high pressure molding process, the porosity of CFRTP is reduced and the mechanical properties of CFRTP are improved. The tensile strength, bending strength, and notch‐free impact strength properties of CFRTP are best when the carbon fiber content is 30% and the CF length is 50 mm. The method is characterized by simple process, low cost and high mechanical properties.

Toward a circular economy: zero-waste manufacturing of carbon fiber-reinforced thermoplastic composites

Fiber-reinforced composites are becoming ubiquitous as a way of lightweighting in the wind, aerospace, and automotive industries, but current recycling technologies fall short of a circular economy. In this work, fiber-reinforced composites made of recycled carbon fiber and polyphenylene sulfide were recycled and remanufactured using common processing technologies such as compression and injection molding. An industrially viable size-exclusive sieving technique was used to retain fiber length and reduce variability in the mechanical properties of the remanufactured composites. Fiber length reduction alone could not explain the strength reductions apparent in the composites, which we propose are due to microstructural inhomogeneity as defined by poor dispersion of the fibers. Future recycling efforts must focus on fiber length retention and good dispersion to make composite remanufacturing a viable path toward a circular economy.

High injection molding welding strength and cross-sectional analysis of carbon fiber composite materials

In this study, carbon fibers, commonly used as reinforcement materials, were added to polyamide (nylon) PA6 to fabricate carbon fiber-reinforced thermoplastic composites (CFRTP), which were then subjected to injection molding welding. The aim of this research was to investigate the positive influence of carbon fibers on injection molding welding strength and explore the optimal injection conditions. Three different joining combinations and various injection parameters were examined. The tensile fracture surfaces after welding were observed using polarized microscopy and scanning electron microscopy. The reinforcing mechanism of carbon fibers was analyzed. Ultimately, the optimal conditions were determined as a mold temperature of 120°C, an injection temperature of 380°C, and an injection velocity of 150 mm/s. The addition of carbon fibers exhibited significant strengthening effects on the injection molded joints, and it also provided the potential for injection molding welding between resins with poor compatibility.

The effect of groove texturing direction on laser joining of titanium alloy to CFRTP

Hybrid structure of titanium alloy and carbon fiber reinforced thermoplastic composite (CFRTP) provided a new direction for lightweight and laser had a great prospect for application in joining metal/plastic. In this work, before laser joining TC4 (Ti6Al4V) and CFRTP (PA66), three groove micro-structures in different texturing direction (0°, 45°, 90°) were prepared on the TC4 surface respectively by nanosecond laser. The effect of different groove texturing was studied. Research results showed that the existence of three groove texturing increased the affinity between TC4 and molten CFRTP to the same extent. The resin-carbon fiber mixture adhered to the surface of TC4 after laser texturing increased obviously. However, the groove micro-structure had different impact on the tensile performance of the joint. The maximum tensile shear strength could reach 10.9 MPa, which was increased by 111 % compared with the untreated when the groove micro-texturing direction was perpendicular to the tensile direction (0° texturing) while the 90° textured joint performance was only increased by 42.9 %. The FEA results revealed that micro-texturing provided mechanical resistance for the joint during the tensile process and 0° micro-texturing provided the largest mechanical resistance followed by 45° and 90° micro-texturing.

A Comparative Study on the Mechanical Properties of Open-Hole Carbon Fiber-Reinforced Thermoplastic and Thermosetting Composite Materials.

In this paper, the damage initiation/propagation mechanisms and failure modes of open-hole carbon fiber-reinforced thermoplastic composites and thermosetting composites with tension, compression, and bearing loads are investigated, respectively, by experiments and finite element simulations. The experimental evaluations are performed on the specimens using the Combined Loading Compression (CLC) test method, the tensile test method, and the single-shear test method. The differences in macroscopic damage initiation, evolution mode, and damage characteristics between thermoplastic composite materials and thermosetting composite material open-hole structures are obtained and analyzed under compressive load. Based on scanning electron microscope SEM images, a comparative analysis is conducted on the micro-failure modes of fibers, matrices, and fiber/matrix interfaces in the open-hole structures of thermoplastic and thermosetting composites under compressive load. The differences between thermoplastic and thermosetting composites were analyzed from the micro-failure mechanism. Finally, based on continuum damage mechanics (CDM), a damage model is also developed for predicting the initiation and propagation of damage in thermoplastic composites. The model, which can capture fiber breakage and matrix crack, as well as the nonlinear response, is used to conduct virtual compression tests, tensile test, and single-shear test, respectively. Numerical simulation results are compared with the extracted experimental results. The displacement-load curve and failure modes match the experimental result, which indicates that the finite element model has good reliability.

Enhancing the ultrasonic plastic welding strength of Al/CFRTP joint via coated metal surface and structured composite surface

Ultrasonic plastic welding (UPW) is a promising technology for joining metal to carbon fiber reinforced thermoplastic composite (CFRTP) but shows poor joint strength in the existing studies. This work conducts UPW of AA6061 aluminum alloy to carbon fiber reinforced PA66 (CF/PA66) by employing a polymer coating as an interlayer. Simple metal surface grinding and silane coupling agent (SCA) treatment are used to strengthen the bonding of the metal/coating interface. Structured CF/PA66 surface fabricated by ultrasonic embossing acts as energy directors to improve the bonding strength of the coating/plastic interface. The results show that relatively high tensile-shear strength (about 31.0 MPa) can be obtained. Micro-mechanical interlocking and chemical bonding (Al-O-C and Al-O-Si bonds) are considered as the bonding mechanism of the metal/coating interface.

Effect of Temperature Distribution on Interfacial Bonding Process between CFRTP Composite and Aluminum Alloy during Laser Direct Joining

Laser direct joining enables non-destructive and lightweight joining of carbon fiber reinforced thermoplastic (CFRTP) composites and aluminum alloys. The interfacial bonding process determines the joint performance and is influenced by the time-varying temperature distribution. However, the interfacial bonding process occurs inside the joint, making it difficult to study the effect of temperature distribution. To resolve this issue, a novel online observation device for the interfacial bonding process between CFRTP composites and aluminum alloys is design, and the polymer melting, flowing, and bonding with metal during laser direct joining are observed. Further, temperature field simulation models for laser direct joining are established, and temperature distribution and gradient are calculated. The results show that the temperature distribution determines the melting of CFRTP composites, and bubbles generated by the thermal decomposition of the polymer hinder the melting. The temperature gradient is related to the movement of the molten matrix and fibers, and the movement towards the aluminum alloy induces cracking and delamination. Once the interface is filled with polymer, the motion changes to along the laser scanning direction and the joining defects are reduced. The study can provide a foundation for promoting interfacial bonding and reducing the defects of laser direct joining.