Carbon Burning Research Articles

Preparation of phosphorus-nitrogen synergistic flame retardant cellulose composite aerogel from waste cotton/phytic acid/acrylamide

Cellulose aerogel is a green and biodegradable material, but the high flammability of cellulose aerogel hinders its development. In order to expand the application range of cellulose aerogel, it is necessary to improve the flame retardancy of cellulose aerogel. In this paper, cellulose hydrogels were prepared by decolorizing waste cotton fabrics (WCF) and dissolving them in 1-butyl-3-methylimidazole chloride salt ([Bmim]Cl)/DMSO. The cellulose hydrogels were impregnated in aqueous phytic acid (PA)/acrylamide (AM) solution for a period of time and then heated and treated. A cellulose composite aerogel with excellent flame retardant properties was successfully prepared by using in situ polymerization. The results show that the cellulose composite aerogel has a porous structure and good thermal stability, and the residual carbon content in the air at 800 °C is >2.86 %. At the same time, it has excellent flame retardancy, the ultimate oxygen index (LOL) is >40, and the vertical combustion carbon length is <3.5 cm. The thermal insulation performance has also been improved, and the composite aerogel with a height of 1 cm has a temperature difference of 40.2 °C between the upper and lower surfaces on the 80 °C heating table.

He-accreting Oxygen–Neon White Dwarfs and Accretion-induced Collapse Events

It has been widely accepted that mass-accreting white dwarfs (WDs) are the progenitors of Type Ia supernovae (SNe) or electron-capture supernovae. Previous work has shown that the accretion rate could affect the elemental abundance on the outer layers of CO WDs, and therefore affect the observational characteristics after they exploded as SNe Ia. However, it has not been well studied how elemental abundance changes on the outer layers of He-accreting ONe WDs as they approach the Chandrasekhar mass limit. In this paper, we investigated the evolution of He-accreting ONe WDs with MESA. We found that a CO-rich mantle will accumulate beneath the He layers resulting from the He burning, after which the ignition of the CO-rich mantle could transform carbon into silicon (Si). The amount of Si produced by carbon burning is strongly anticorrelated with the accretion rate. As the ONe WD nearly approaches the Chandrasekhar mass limit (M ch) through accretion, it is likely to undergo accretion-induced collapse, resulting in the formation of a neutron star.

Applications of Carbon Capture Technologies in Steel and Cement Industries

As problems such as the increase in extreme weather, rising sea levels, and social inequality continue to sharpen with the intensifying climate change, changes are demanded. The cement and iron and steel industries are among the major spheres responsible for the rising global temperature. Carbon reduction methods cannot fully solve the problem and help these industries reach carbon-neutral emissions. Therefore, carbon capture (CC) technology is urgently needed. This article introduces the application of pre-combustion carbon capture (PreCCC), post-combustion carbon capture (PostCCC), and oxyfuel combustion carbon capture in the cement industry and the iron and steel industry. Research has shown that oxyfuel combustion is one of the most assuring pathways to reach carbon neutrality in cement plants since problems of temperature management can be solved by recycling part of the fuel gases, and its cost is relatively lower than the other methods. However, PostCCC is a better solution in the iron and steel industries. Although technological innovations in physical absorption and chemical absorption are still needed, PostCCC can mitigate a large portion of steel plants carbon footprint. Carbon capture intensity can be increased with further technological development in combining PostCCC and oxygen-rich combustion. The combination of different pathways may be a novel hypothesis, but it has a great possibility of alleviating the carbon emission of the industrial sector.

Influence of moisture content and inlet temperature on the incineration characteristics of municipal solid waste (MSW)

Incineration is an effective method for the treatment of municipal solid waste, pre-treatment reduces the waste moisture content to increase the incineration performance. However, the inlet temperature variation influenced by the environment is often ignored at this stage, and the coupling of moisture content and inlet temperature directly affects the incineration performance. To investigate the optimal inlet conditions for the incineration, the numerical model of a 600 t/d incinerator was established according to a reference case. Detailed analyses of the combustion characteristics of the bed and furnace is conducted under various moisture contents and inlet temperatures. The incineration efficiency under multiple factors is analyzed using response surface methodology, with sensitivity to these factors derived from the surface derivative. The results indicate that at an inlet temperature of 30 °C, the rates of volatile release and fixed carbon combustion are negatively correlated with the moisture content, and maximum incineration efficiency of 39.02 % is reached at a moisture content of 28.12 %. At a moisture content of 33.26 %, The rates of moisture evaporation, volatile release, and fixed carbon combustion are positively correlated with inlet temperature, and the maximum incineration efficiency of 38.76 % is achieved at an inlet temperature of 40 °C. The incineration efficiency exhibits a negative sensitivity to moisture content, whereas its sensitivity to inlet temperature is contingent upon the specific temperature range. The combination of 26.53 % moisture content and 40.86 °C inlet temperature yields the highest incineration efficiency of 40.69 %. The findings of this study provide useful information for the pre-treatment of municipal solid waste, contributing to the enhancement of operational efficiency in waste-to-energy plants.

A Viability Study of Thermal Pre-Treatment for Recycling of Pharmaceutical Blisters

Pharmaceutical packaging is one of the most used packaging types which contains aluminum and plastics. Due to increasing amounts of waste and rising environmental concerns, recycling approaches are being investigated. Since blisters usually contain a balanced amount of plastics and metals, most of the approaches focus on recycling only one material. Therefore, more sustainable recycling approaches which recover both plastic and aluminum fractions are needed. This study investigates the thermal behavior and degradation mechanisms of plastic-rich and aluminum-rich pharmaceutical blisters using various analytical techniques. Structural characterization revealed that plastic-rich blisters have a thicker profile with plastic and aluminum layers, while aluminum-rich blisters consist of plastic layers between aluminum sheets. Thermal degradation analysis showed two main stages for both types: plastic-rich blisters (polyvinyl chloride) exhibited significant weight loss and long-chain hydrocarbon formation between 210 and 285 °C, and aluminum-rich blisters (polyamide/nylon) degraded from 240 to 270 °C. Differential Scanning Calorimetry and Fourier Transform Infrared Spectroscopy analyses confirmed the endothermic behavior of such a transformation. The gas emissions analysis indicated an increased formation of gasses from the thermal treatment of plastic-rich blisters, with the presence of oxygen leading to the formation of carbon dioxide, water, and carbon monoxide. Thermal treatment with 5%O2 in the carrier gas benefited plastic-rich blister treatment, reducing organic waste by up to 80% and minimizing burning risk, leveraging pyrolytic carbon for protection. This method is unsuitable for aluminum-rich blisters, requiring reduced oxygen or temperature to prevent pyrolytic carbon combustion and aluminum oxidation.

An in situ combustion carbon deposit diagnostic instrument based on Raman microscopy.

Carbon deposit of the aero-engine combustor, resulting from incomplete combustion and fuel pyrolysis, can cause nozzle blockage, fuel consumption increase, power decrease, and even flight unsafety. In this work, an in situ combustion carbon deposit diagnostic instrument is developed to reveal the crystalline structure and the changes under real combustion conditions. The instrument integrates the in situ microscopic Raman technique and the combustion system. The burner is characterized by a sloping tip, making it possible to observe the coke from the side view. The burner is installed to the optical positioning stage by a specially made adapter so that the relative location is fixed and it is possible to observe the carbon deposit from the ignition. The carbon deposit of acetylene/air diffusion jet flame was studied. A 50× objective lens was used to collect the Raman scattering signal of carbon deposits continuously 30s after ignition. A five-band model was used to fit the Raman spectra. The time-resolved information was calculated, including the normalized total area, area proportion, peak ratio, and crystalline size. The results show that the carbon deposit of acetylene flames with different velocities presents different tendencies of formation and degree of graphitization, which is attributed to the influence of temperature and flow. The performance of this system is evaluated quantitatively. The signal-to-noise ratio of Raman spectra of carbon deposits ranges from 6.4 to 28.9. This work provides an in situ method to analyze the dynamic change of carbon deposit on the burner, and further work is needed to reveal the mechanism.

High Resolution (30 m) Burned Area Product Improves the Ability for Carbon Emission Estimation in Africa

AbstractFire significantly contributes to greenhouse gas emissions. The current global burned area (BA) products mainly have coarse native spatial resolution, which leads to underestimation of global BA and carbon emissions from biomass burning. Performances of BA products in Africa from GABAM (30 m), MCD64A1 (500 m), GFED4s (0.25°), FireCCI51 (250 m), and GFED5 (0.25°) were compared. From 2014 to 2020, GFED5 detected the most BA, 1.58 times more than GABAM during the same period. GABAM detected 0.09 Mkm2 more burned area than FireCCI51 on average. From 2014 to 2016, GABAM detected an average of 2.99 Mkm2 of BA in Africa, which was 1.03 times more than GFED4s. From 2014 to 2021, the average African BA derived from GABAM was 2.89 Mkm2, 1.22 times more than MCD64A1. The increase in BA will inevitably lead to an increase in the estimation of carbon emissions from biomass burning. Based on GABAM products and GFED framework, we estimated the average vegetation burning carbon emissions in Africa from 2014 to 2021 to be 1113.25 Tg, which is higher than GFED4s' carbon emissions in the same time period. This shows that the use of high‐resolution (30 m) burned area products to estimate carbon emissions can effectively avoid the underestimation of overall fire carbon emissions.

Surface modification of carbon fibres via plasma-activated water for mitigating burnout risk from direct plasma treatment

This study presents a novel plasma jet discharge device designed to indirectly treat carbon fibre materials with plasma-activated water. This innovative method effectively mitigates issues related to carbon fibre conduction and combustion, which are common challenges encountered when directly modifying fibres using a plasma jet. Specifically, the atmospheric composition is adjusted to modulate the active particles in the liquid phase. The experimental results demonstrate that this technique significantly increases the surface wettability of carbon fibres without damaging their structure. Under the conditions of argon/oxygen cascade discharge, oxygen-containing substances generate ionomers that activate the water, which in turn introduces oxygen-containing groups (e.g., C−O, C=O, O−C=O) onto the carbon fibre surface. These groups catalyse monomer polymerisation on the material surface, which increases the wettability of the carbon fibres, as evidenced by a significant reduction in the water contact angle from 80.12° to 55.31°. This in turn improves the bonding strength with epoxy resin and slightly increases the monofilament strength. Furthermore, composites produced by this method exhibit 21% higher interlaminar shear strength than the untreated sample and an increased O/C ratio of up to 24.55%. In summary, these findings provide a valuable theoretical basis for enhancing the surface properties of carbon fibre composites through plasma–liquid interactions and open new possibilities for high-performance carbon fibre–resin matrix composites.

Formulating iron ore pellet induration process in an industrial straight grate system: Real-time experimentation and validation

Understanding the complex process of iron ore pellet induration is crucial in a straight grate system in the steelmaking industry. There is no attempt made so far to predict the behavior of this unit considering the physiochemical processes (drying, carbon combustion and limestone calcination) along with the heat transfer within the pellet, and between the hot gas and pellet. Moreover, the reported models are validated mainly with the pot test data. To address these research gaps, in this contribution, a rigorous model framework is proposed for an industrial induration unit considering all these above-mentioned issues together with some other practical aspects, including the heat transfer from hot gas to grate bar and heat loss due to air leakage into the system. To validate this rigorous formulation, attempt is further made to perform the real-time experimentation with induration system equipped with a thermocar. It is shown first time that the predicted temperature profiles of the pellets, grate bar and exit gas associated with the running bed are consistent with the plant data. The fuel consumption data is further obtained to investigate the performance of the proposed formulation at different operating regimes. It is observed that the mean absolute percentage error (MAPE) between the measured and predicted fuel rates is reasonably low (i.e., 4.2%). With this, it is recommended to use the proposed formulation for online property prediction, process design, optimization, troubleshooting, control and scale-up of the induration unit.

Hazardous waste alternative fuels to novel ecological energy: Combustion characteristics and effects on clinker's environmental safety

Due to their detrimental and persistent impacts on the environment, it is imperative to manage and dispose of hazardous wastes (HW) in a secure manner. This study investigates the combustion characteristics and environmental impacts of using HW as alternative fuels in clinker production. The HW categories analyzed include industrial hazardous waste (IHW), medical hazardous waste (MHW), and household hazardous waste (HHW). Specifically, IHW consists mainly of waste mineral oils, waste organic solvents, organic resin wastes, waste residues, and waste coatings. MHW primarily consists of medical plastic products. HHW mainly includes packaging from waste pharmaceuticals, waste pesticides, disinfectants, and waste paints. Compared to traditional pulverized coal, hazardous waste alternative fuel (HWAF) exhibits a lower fixed carbon content, with its heat generation primarily dependent on volatile substances, and a higher ash content, chemically similar to coal ash. The combustion process of HWAF involves three stages: moisture evaporation (0 °C–150 °C), volatile matter combustion (150°C–400 °C), and fixed carbon combustion (400 °C–550 °C). The primary emissions from this process include CO2, CO, trace amounts of SO2, NO2, H2O, and various complex organic compounds such as carboxylic acids, alcohols, ketones, and aldehydes. While HWAF ignites more readily than pulverized coal, it burns more slowly and less completely. The incorporation of combustion by-products into the cement clinker formulation does not interfere with the clinker's hydration processes or reactions. HWAF ensures a reduced heavy metal input rate in the firing system without significantly impacting the heavy metal content in the clinker. Mortar samples produced with this clinker meet the heavy metal leaching standards, affirming the environmental safety of the cement product. Increasing the proportion of HWAF results in a reduction in standard coal consumption and an increase in CO2 reduction, achieving a maximum coal saving of 3.67 kgce/t.cl and a CO2 emission reduction of 10.11 kg/t.cl. This study presents a clean production model for the co-processing of HWAF, effectively transforming waste into valuable resources by using hazardous waste materials as alternative fuels.

The impact of asteroseismically calibrated internal mixing on nucleosynthetic wind yields of massive stars

Context. Asteroseismology gives us the opportunity to look inside stars and determine their internal properties, such as the radius and mass of the convective core. Based on these observations, estimations can be made for the amount of the convective boundary mixing and envelope mixing of such stars and for the shape of the mixing profile in the envelope. However, these results are not typically included in stellar evolution models. Aims. We aim to investigate the impact of varying convective boundary mixing and envelope mixing in a range based on asteroseismic modelling in stellar models up to the core collapse, both for the stellar structure and for the nucleosynthetic yields. In this first study, we focus on the pre-explosive evolution and we evolved the models to the final phases of carbon burning. This set of models is the first to implement envelope mixing based on internal gravity waves for the entire evolution of the star. Methods. We used the MESA stellar evolution code to simulate stellar models with an initial mass of 20 M⊙ from zero-age main sequence up to a central core temperature of 109 K, which corresponds to the final phases of carbon burning. We varied the convective boundary mixing, implemented as ‘step-overshoot’, with the overshoot parameter (αov) in the range 0.05−0.4. We varied the amount of envelope mixing (log(Denv/cm2 s−1)) in the range 0−6 with a mixing profile based on internal gravity waves. To study the nucleosynthesis taking place in these stars in great detail, we used a large nuclear network of 212 isotopes from 1H to 66Zn. Results. Enhanced mixing according to the asteroseismology of main-sequence stars, both at the convective core boundary and in the envelope, has significant effects on the nucleosynthetic wind yields. This is especially the case for 36Cl and 41Ca, whose wind yields increase by ten orders of magnitude compared to those of the models without enhance envelope mixing. Our evolutionary models beyond the main sequence diverge in yields from models based on rotational mixing, having longer helium-burning lifetimes and lighter helium-depleted cores. Conclusions. We find that the asteroseismic ranges of internal mixing calibrated from core hydrogen-burning stars lead to similar wind yields as those resulting from the theory of rotational mixing. Adopting the seismic mixing levels beyond the main sequence, we find earlier transitions to radiative carbon burning compared to models based on rotational mixing because they have lower envelope mixing in that phase. This influences the compactness and the occurrence of shell mergers, which may affect the supernova properties and explosive nucleosynthesis.

Performance study of an electrified temperature vacuum swing adsorption cycle for post combustion carbon capture

The performance of a fully electrified temperature vacuum swing adsorption (E-TVSA) carbon capture process is investigated and compared with the performance of a VSA cycle as the reference case. A five-step process including (I) adsorption, (II) co-current heating, (III) counter-current evacuation, (IV) counter-current pressurizing, and (V) co-current closed loop cooling steps was devised and simulated. The adsorption time, electric heating power, and evacuation pressure were chosen as the independent variables for evaluating their impact on key performing indicators (KPI) of purity, recovery, productivity and energy consumption. In total 2717 cases were simulated to the cyclic steady state condition to provide 44 contours of the KPIs. From these contours it can be concluded that in E-TVSA carbon capture using 13X zeolite, a temperature rise of almost 50 degrees is necessary during the heating step, and the evacuation step should be continued to reach a pressure between 2.5 and 3 kPa. Under these conditions, a recovery and purity of more than 98 % were achieved with a production rate above 1.1 kg CO2/kg ads day and a specific energy consumption of 1.74 MJ/kg CO2 (0.61 MJ/kg CO2 for evacuation and 1.13 MJ/kg CO2 for heating). When comparing E-TVSA and VSA, it is noteworthy that the production rate and specific energy consumption of E-TVSA are in the same order as that of VSA. However, E-TVSA surpasses VSA in terms of purity and recovery rates. Further analysis of the transformation efficiency from electricity to heat revealed the transformation efficiency must be at least 50 % to keep the energy consumption below 3 MJ/kg CO2.

Kinetic analysis of solid fuel combustion in chemical looping for clean energy conversion

Chemical looping combustion (CLC) offers an advanced, eco-friendly method for converting solid fuels into energy with inherent CO2 capture, presenting a cost-efficient solution. The kinetics of solid fuel CLC, crucial for reactor design, are not well-understood, limiting its application and optimisation. Conducting a comprehensive kinetic analysis of solid fuel CLC is crucial, as it examines the combustion of both volatiles and fixed carbon, thereby addressing existing knowledge gaps and advancing clean conversion of solid fuels. In this study, a comprehensive kinetic analysis method for the first time has been applied to investigate the kinetics of CLC of low-volatile semi-anthracite coal with CuO at temperatures of 700–950 °C under varied oxygen excess ratios (0.5, 1.0, and 2.0). The results show that the combustion of coal in CLC can be divided into three distinct stages. The combustion of coal with CuO initiates with the combustion of volatiles interacting with solid CuO at 450–580 °C, where the combustion efficiency varies between 3–6 wt%. This is followed by a complex simultaneous mechanism involving gas-phase volatiles and solid-phase CuO, as well as gas-phase oxygen and solid-phase fixed carbon under non-isothermal conditions. The combustion efficiency is ranged 19–71 wt% at the temperature ranges from 580 °C to the isothermal temperatures of 750–950 °C. The activation energy for the combustion of volatiles was determined as Ea = 119 kJ/mol, whereas the initial combustion of fixed carbon in the non-isothermal stage ranged between Ea = 39–53 kJ/mol. The rate of combustion is initially limited by the oxygen diffusion rate from CuO, but with additional oxygen carriers and increased temperature, the reaction becomes constrained by first-order kinetics. Upon reaching the isothermal stage, the final combustion phase between fixed carbon and gas phase oxygen occurs, and the combustion efficiency increases to 77–96 wt% at 750–950 °C. The activation energy for fixed carbon combustion under the isotherm stage was approximately Ea = 234 kJ/mol, with a reaction rate constant (k0) of 7.84 × 109 min−1. This pioneering study not only clarifies the multi-stage kinetics of solid fuel CLC, bridging significant gaps in current knowledge but also sets the foundation for the enhanced design and efficiency of CLC systems for cleaner energy production.

Thermodynamic analysis of trigeneration system with controlled thermal-electric ratio by coupling liquefied natural gas cold energy and biomass partial gasification

Efficient utilization of biomass energy is crucial for addressing environmental challenges. However, the low calorific value of syngas from biomass gasification poses subsequent utilization issues. This study proposes a trigeneration system integrating biomass partial gasification and LNG cold energy to address surge problems using syngas combined cycle systems. The design includes air separation units, combined cycle, and biomass gasifier, achieving an adjustable thermal-electric ratio. An air separation unit and two-stage Organic Rankine Cycle fully utilize LNG cold energy. A thermodynamic model was established in Aspen Plus, and energy, exergy, and economic analyses were conducted to assess feasibility, followed by a sensitivity analysis. Results show that with a mix burning ratio and carbon conversion rate of 0.6 and 0.7, the system's exergy, energy, and electrical efficiencies are 36.94 %, 60.14 %, and 33.32 % in cooling mode. The unit exergy cost and CO2 emissions are 0.0748$ and 95.29 kg/s, respectively. Analysis reveals variations in efficiency and outputs with changes in mix burning ratio and carbon conversion rate. Adjusting operational parameters enhances the system's ability to regulate the thermal-electric ratio, demonstrating its potential for efficient biomass energy utilization and environmental sustainability.

Image-based quantitative probing of 3D heterogeneous pore structure in CBM reservoir and permeability estimation with pore network modeling

Coalbed methane (CBM) recovery is attracting global attention due to its huge reserve and low carbon burning benefits for the environment. Fully understanding the complex structure of coal and its transport properties is crucial for CBM development. This study describes the implementation of mercury intrusion and μ-CT techniques for quantitative analysis of 3D pore structure in two anthracite coals. It shows that the porosity is 7.04%–8.47% and 10.88%–12.11%, and the pore connectivity is 0.5422–0.6852 and 0.7948–0.9186 for coal samples 1 and 2, respectively. The fractal dimension and pore geometric tortuosity were calculated based on the data obtained from 3D pore structure. The results show that the pore structure of sample 2 is more complex and developed, with lower tortuosity, indicating the higher fluid deliverability of pore system in sample 2. The tortuosity in three-direction is significantly different, indicating that the pore structure of the studied coals has significant anisotropy. The equivalent pore network model (PNM) was extracted, and the anisotropic permeability was estimated by PNM gas flow simulation. The results show that the anisotropy of permeability is consistent with the slice surface porosity distribution in 3D pore structure. The permeability in the horizontal direction is much greater than that in the vertical direction, indicating that the dominant transportation channel is along the horizontal direction of the studied coals. The research results achieve the visualization of the 3D complex structure of coal and fully capture and quantify pore size, connectivity, curvature, permeability, and its anisotropic characteristics at micron-scale resolution. This provides a prerequisite for the study of mass transfer behaviors and associated transport mechanisms in real pore structures.

Low-carbon energy scheduling for integrated energy systems considering offshore wind power hydrogen production and dynamic hydrogen doping strategy

This paper proposes a low-carbon energy scheduling model for integrated energy systems (IES) considering offshore wind power hydrogen production and dynamic hydrogen doping strategy. The offshore wind electrolysis system, hydrogen mixed gas turbine (HMGT), carbon capture, utilization and storage, and laddered carbon trading are introduced to reflect the values of hydrogen blending in carbon emission reduction for IES. A carbon emission and combustion model for HMGT based on the system thermodynamics and chemical reaction kinetics is presented. The dynamic hydrogen doping strategy is leveraged to consider the impact of gas composition variations on HMGT operating and gas system. Then, an energy balance-based quasi-steady-state model is proposed to deal with the different calorific value of the gas mixture. In order to effectively solve the resulting highly nonlinear and nonconvex problem arising from the varying hydrogen blending ratio, the nonlinear hydrogen production efficiency, and the convex–concave energy balance-based quasi-steady-state model, a tractable solution formulation is proposed. Numerical results illustrate the effectiveness of the proposed model.

The Role of Lignin Molecular Weight on Activated Carbon Pore Structure.

Over the past decade, the production of biofuels from lignocellulosic biomass has steadily increased to offset the use of fuels from petroleum. To make biofuels cost-competitive, however, it is necessary to add value to the "ligno-" components (up to 30% by mass) of the biomass. The properties of lignin, in terms of molecular weight (MW), chemical functionality, and mineral impurities often vary from biomass source and biorefinery process, resulting in a challenging precursor for product development. Activated carbon (AC) is a feasible target for the lignin-rich byproduct streams because it can be made from nearly any biomass, and it has a market capacity large enough to use much of the lignin generated from the biorefineries. However, it is not known how the variability in the lignin affects the key properties of AC, because, until now, they could not be well controlled. In this work, various fractions of ultraclean (<0.6% ash) lignin are created with refined MW distributions using Aqueous Lignin Purification using Hot Agents (ALPHA) and used as precursors for AC. AC is synthesized via zinc chloride activation and characterized for pore structure and adsorption capacity. We show that AC surface area and the adsorption capacity increase when using lignin with increasing MW, and, furthermore, that reducing the mineral content of lignin can significantly enhance the AC properties. The surface area of the AC from the highest MW lignin can reach ~1830 m2/g (absorption capacity). Furthermore, single step activation carbonization using zinc chloride allows for minimal carbon burn off (<30%), capturing most of the lignin carbon compared to traditional burn off methods in biorefineries for heat generation.

High fat diet-induced obesity and gestational DMBA exposure alter folliculogenesis and the proteome of the maternal ovary†.

Obesity and ovotoxicant exposures impair female reproductive health with greater ovotoxicity reported in obese relative to lean females. The mother and developing fetus are vulnerable to both during gestation. 7,12-dimethylbenz[a]anthracene (DMBA) is released during carbon combustion including from cigarettes, coal, fossil fuels, and forest fires. This study investigated the hypothesis that diet-induced obesity would increase sensitivity of the ovaries to DMBA-induced ovotoxicity and determined impacts of both obesity and DMBA exposure during gestation on the maternal ovary. Female C57BL/6J mice were fed a control or a High Sugar High Fat (45% kcal from fat; 20% kcal from sucrose) diet until ~30% weight gain was attained before mating with unexposed males. From gestation Day 7, mice were exposed intraperitoneally to either vehicle control (corn oil) or DMBA (1mg/kg diluted in corn oil) for 7 d. Thus, there were four groups: lean control (LC); lean DMBA exposed; obese control; obese DMBA exposed. Gestational obesity and DMBA exposure decreased (P < 0.05) ovarian and increased liver weights relative to LC dams, but there was no treatment impact (P > 0.05) on spleen weight or progesterone. Also, obesity exacerbated the DMBA reduction (P < 0.05) in the number of primordial, secondary follicles, and corpora lutea. In lean mice, DMBA exposure altered abundance of 21 proteins; in obese dams, DMBA exposure affected 134 proteins while obesity alone altered 81 proteins in the maternal ovary. Thus, the maternal ovary is impacted by DMBA exposure and metabolic status influences the outcome.

Experimental and modeling study of CO2 capture by phase change blend of triethylenetetramine-ethanol solvent

Post combustion Carbon capture based on chemical absorption is the best-known technology to reduce CO2. Recently, attention has been paid to biphasic solvents due to their excellent potential in reducing energy consumption. This study investigated carbon dioxide absorption by biphasic non-aqueous triethylenetetramine (TETA)-ethanol solvent in a T-shaped microchannel. Effect of four parameters including: concentration of TETA (4–8 wt%), liquid flow (2–5 ml/min), inlet CO2 concentration (5–20 vol%) and gas flow (100–175 ml/min) have been examined. Mass transfer characteristics has been assessed by investigation of absorption percentage, molar flux and overall mass transfer coefficient. The results show that increasing the concentration of amine diminishes all three responses by increasing the solution viscosity. As a result, it decreases the penetration of CO2 in the solution and the rate of absorption.Furthermore, the TETA-ethanol phase change solvent has been compared with aqueous monoethanolamine (MEA). The results of this comparison indicated that the efficiency of CO2 absorption and mass transfer coefficient, for TETA-ethanol biphasic solvent are higher than MEA solvent, respectively. Finally, the dimensionless Damköhler number (Da) was utilized in the new correlation to predict KLa for CO2 absorption into TETA-Ethanol solution with acceptable accuracy.

Analysis of stored carbon reserves in trees in the green open spaces of Panatayuda Park, Bandung City, and surrounding areas

Climate change and global warming are partly caused by increasing air pollution. This air pollution results in incomplete carbon combustion, producing toxic gases. Carbon is a key component used by plants in the photosynthesis process. Therefore, trees play an important role in reducing pollution and lowering environmental temperatures that trigger climate change and global warming. The purpose of research on carbon reserves is to provide data for the future management of urban parks, utilizing them for climate change mitigation. The method used in this research is descriptive quantitative. Sampling in this study used the census method with purposive sampling, where all trees with a diameter of ≥ 20 cm were taken as samples. The highest biomass and carbon reserve values stored in trees in Panatayuda Park were found in Ficus elastica, with a biomass value of 51,752.77 kg and a carbon reserve value of 25,876.39 kg. Meanwhile, the lowest values were found in Pterocarpus indicus, with a biomass value of 807.39 kg and a carbon reserve value of 403.69 kg. The total carbon reserve in trees in Panatayuda Park is 79,122.21 kg, with a total biomass of 140,244.41 kg.