Carbon-bearing Species Research Articles

The Spectrum of C/2023 A3 Indicates a Depleted Composition

We report a spectroscopic observation of comet C/2023 A3 using an 80 mm apochromatic refractor equipped with a custom-built spectrometer with a resolution of R ∼ 2500 on the night of 2024 October 4. Sodium D lines were detected prominently, while no other emission lines, particularly carbon-bearing species, were observed, which suggests that comet C/2023 A3 may be carbon-depleted. The mobility and flexibility of our observational setup highlight the value of amateur telescopes in observing low-altitude targets like C/2023 A3 as a complement to professional facilities.

Techno-economic-environmental study of CO2 and aqueous formate solution injection for geologic carbon storage and enhanced oil recovery

As carbon capture, utilization, and storage (CCUS), carbon-dioxide enhanced oil recovery (CO2 EOR) has inherent shortcomings, such as inefficient oil recovery and carbon storage, and low storage security with mobile CO2. This paper presents a techno-economic-environmental analysis of using formate species, a product of CO2 electrochemical reduction, as an alternative carbon carrier for sequestration and EOR in a carbonate oil reservoir in the Gulf of Mexico Basin. CO2 injection, water-alternating-CO2 injection, and aqueous formate solution injection were compared using a compositional reservoir simulation model and an economic calculator. Formate solution injection yielded greater levels of oil recovery and net carbon storage, where the carbon-bearing species resided in the dense aqueous phase without having to rely on petrophysical trapping mechanisms (structural and capillary). The enhanced oil production, net carbon storage, and storage security can be promoted by providing formate-based CCUS with more incentives (e.g., greater tax credit) in comparison to CO2-based CCUS for EOR and the manufacture of chemicals and products. In establishing carbon storage incentive policies and regulations, policymakers should include alternative carbon carriers.

Methane throughout the atmosphere of the warm exoplanet WASP-80b.

The abundances of main carbon- and oxygen-bearing gases in the atmospheres of giant exoplanets provide insights into atmospheric chemistry and planet formation processes1,2. Thermochemistry suggests that methane (CH4) should be the dominant carbon-bearing species below about 1,000 K over a range of plausible atmospheric compositions3; this is the case for the solar system planets4 and has been confirmed in the atmospheres of brown dwarfs and self-luminous, directly imaged exoplanets5. However, CH4 has not yet been definitively detected with space-based spectroscopy in the atmosphere of a transiting exoplanet6-11, but a few detections have been made with ground-based, high-resolution transit spectroscopy12,13 including a tentative detection for WASP-80b (ref. 14). Here we report transmission and emission spectra spanning 2.4-4.0 μm of the 825 K warm Jupiter WASP-80b taken with the NIRCam instrument of the JWST, both of which show strong evidence of CH4 at greater than 6σ significance. The derived CH4 abundances from both viewing geometries are consistent with each other and with solar to sub-solar C/O and around five times solar metallicity, which is consistent with theoretical predictions15-17.

Retrieval of the dayside atmosphere of WASP-43b with CRIRES+

Accurately estimating the C/O ratio of hot Jupiter atmospheres is a promising pathway towards understanding planet formation and migration, as well as the formation of clouds and the overall atmospheric composition. The atmosphere of the hot Jupiter WASP-43b has been extensively analysed using low-resolution observations with HST and Spitzer, but these previous observations did not cover the K band, which hosts prominent spectral features of major carbon-bearing species such as CO and CH4. As a result, the ability to establish precise constraints on the C/O ratio was limited. Moreover, the planet has not been studied at high spectral resolution, which can provide insights into the atmospheric dynamics. In this study, we present the first high-resolution dayside spectra of WASP-43b with the new CRIRES+ spectrograph. By observing the planet in the K band, we successfully detected the presence of CO and provide evidence for the existence of H2O using the cross-correlation method. This discovery represents the first direct detection of CO in the atmosphere of WASP-43b. Furthermore, we retrieved the temperature-pressure profile, abundances of CO and H2O, and a super-solar C/O ratio of 0.78 by applying a Bayesian retrieval framework to the data. Our findings also shed light on the atmospheric characteristics of WASP-43b. We found no evidence for a cloud deck on the dayside, and recovered a line broadening indicative of an equatorial super-rotation corresponding to a jet with a wind speed of ~5kms−1, matching the results of previous forward models and low-resolution atmospheric retrievals for this planet.

Survived carbonates in orogenic dunites from recycling of subduction-related sediments

The carbon recycling between the Earth's surface and its interior is accomplished through plate subduction and magmatic processes. The orogenic mantle peridotites document multi-stage metasomatism in the subduction zone and play a significant role in revealing the material transportation and migration between the Earth's different spheres. However, how the migration process of carbon-bearing species influenced the subcontinental lithosphere mantle remains a mystery. To address these issues, we conducted detailed petrography, whole-rock and mineral geochemical compositions, and Sr–C–O isotope studies on two types of peridotites (silicate melt pocket-bearing and carbonate melt pocket-bearing dunites) of the Maowu ultramafic massif in the Dabie orogen. The silicate-melt pockets were captured earlier than the carbonate-melt pockets, and were derived from a large proportion of silicate melts during the formation of garnet pyroxenites. The subsequent carbonate metasomatism was mainly divided into two stages: the stage 1 reflects the reaction between dolomite melts and orthopyroxenes to generate clinopyroxenes with high CaO content and Mg# value (> 92); the stage 2 is the injection of Ca-rich fluids into dunites, forming dolomite veins and volatile-rich assemblages of tremolite, barite and monazite. The clinopyroxenes display high 87Sr/86Sr (0.7079–0.7097) and (La/Yb)N ratios, low Ti/Eu ratios, and different enrichment in Th, U, Sr and light rare earth elements (LREEs), indicating a carbonate metasomatic origin. The equilibrium melts of them are similar to sedimentary limestones with positive Sr anomaly and depleted high field strength elements (HFSEs). The Sr-O isotope mixing simulation shows a mixing of 80–90% carbonate sediments with the upper mantle peridotite. The C-O isotopes of the carbonate minerals have similar variation ranges (δ13CV-PDB: 19.7–15.6 ‰, δ18OV-SMOW: 18.1–28.1 ‰) within the range of sedimentary organic carbon. The 87Sr/86Sr ratios of limestone reservoir (0.708–0.709) suggest the addition of sedimentary carbonates into the mantle wedge at ∼370–500 Ma. Therefore, we propose that the sedimentary carbonates and organic carbon migrated into the deep mantle-wedge through the subducted Tethyan-Ocean slab in the Early Paleozoic, which experienced complex metasomatism and formed as carbonate minerals in the Maowu dunites to achieve the carbon recycling between the sedimentary carbon reservoir and the mantle wedge beneath the North China Craton.

Awesome SOSS: atmospheric characterization of WASP-96 b using the JWST early release observations

ABSTRACT The newly operational JWST offers the potential to study the atmospheres of distant worlds with precision that has not been achieved before. One of the first exoplanets observed by JWST in the summer of 2022 was WASP-96 b, a hot Saturn orbiting a G8 star. As a part of the Early Release Observations programme, one transit of WASP-96 b was observed with NIRISS/SOSS to capture its transmission spectrum from 0.6 to 2.85 μm. In this work, we utilize four retrieval frameworks to report precise and robust measurements of WASP-96 b’s atmospheric composition. We constrain the logarithmic volume mixing ratios of multiple chemical species in its atmosphere, including: H2O = $-3.59 ^{+ 0.35 }_{- 0.35 }$, CO2 = $-4.38 ^{+ 0.47 }_{- 0.57 }$, and K = $-8.04 ^{+ 1.22 }_{- 1.71 }$, thus generally consistent with 1× solar (with the exception of CO2). Notably, our results offer a first abundance constraint on potassium in WASP-96 b’s atmosphere and important inferences on carbon-bearing species such as CO2 and CO. Our short wavelength NIRISS/SOSS data are best explained by the presence of an enhanced Rayleigh scattering slope, despite previous inferences of a clear atmosphere – although we find no evidence for a grey cloud deck. Finally, we explore the data resolution required to appropriately interpret observations using NIRISS/SOSS. We find that our inferences are robust against different binning schemes. That is, from low R = 125 to the native resolution of the instrument, the bulk atmospheric properties of the planet are consistent. Our systematic analysis of these exquisite observations demonstrates the power of NIRISS/SOSS to detect and constrain multiple molecular and atomic species in the atmospheres of hot giant planets.

Strong Depletion of 13C in CO Induced by Photolysis of CO2 in the Martian Atmosphere, Calculated by a Photochemical Model

The isotopic signature of atmospheric carbon offers a unique tracer for the history of the Martian atmosphere and the origin of organic matter on Mars. The photolysis of CO2 is known to induce strong isotopic fractionation of the carbon between CO2 and CO. However, its effects on the carbon isotopic compositions in the Martian atmosphere remain uncertain. Here, we develop a 1D photochemical model to consider the isotopic fractionation via photolysis of CO2, to estimate the vertical profiles of the carbon isotopic compositions of CO and CO2 in the Martian atmosphere. We find that CO is depleted in 13C compared with CO2 at each altitude, due to the fractionation via CO2 photolysis: the minimum value of the δ 13C in CO is about −170‰ under the standard eddy diffusion setting. This result supports the hypothesis that fractionated atmospheric CO is responsible for the production of the 13C-depleted organic carbon in the Martian sediments detected by the Curiosity Rover, through the conversion of CO into organic materials and their deposition on the surface. The photolysis and transport-induced fractionation of CO that we report here leads to a ∼15% decrease in the amount of inferred atmospheric loss when combined with the present-day fractionation of the atmosphere and previous studies of carbon escape to space. The fractionated isotopic composition of CO in the Martian atmosphere may be observed by ExoMars Trace Gas Orbiter and ground-based telescopes, and the escaping ion species produced by the fractionated carbon-bearing species may be detected by the Martian Moons eXploration mission in the future.

Oxidation and Scale Adhesion of a Type 430 Stainless Steel in Ar–CO2 Gas Mixtures at 800 °C

Biogas is an alternative source of fuel potentially used to run solid oxide fuel cells (SOFCs). It mainly consists of CH4 and CO2 which can degrade the SOFC interconnect, which is typically made of stainless steel. To investigate the effect of each gas constituent, we focussed here on the effect of CO2 on high-temperature oxidation behavior of and scale adhesion on the stainless steel interconnect, Type 430 stainless steel. The samples studied were oxidised in CO2 at contents of 5–100% at 800 °C. The oxidation kinetics were found to be parabolic with the rate constant increasing when the CO2 content increased. The scale adhesion was assessed using a tensile-test method. The scale formed in the atmosphere containing higher CO2 content exhibited poorer scale adhesion, as indicated by a lower strain initiating the first spallation and a larger spallation percentage after the first spallation took place. The worsened scale adhesion relates to pores formed at the scale/steel interface. The adhesion energies were further quantified giving the values of about 40–100 J m–2. Oxidation mechanisms were suggested based on the dependence of the parabolic rate constant on the oxygen partial pressure and the inward diffusion of carbon-bearing species.

Early Release Science of the exoplanet WASP-39b with JWST NIRCam

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy (for example, refs. 1,2) provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution and high precision, which, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST’s Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0–4.0 micrometres, exhibit minimal systematics and reveal well defined molecular absorption features in the planet’s spectrum. Specifically, we detect gaseous water in the atmosphere and place an upper limit on the abundance of methane. The otherwise prominent carbon dioxide feature at 2.8 micrometres is largely masked by water. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1–100-times solar (that is, an enrichment of elements heavier than helium relative to the Sun) and a substellar C/O ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation (for example, refs. 3,4,) or disequilibrium processes in the upper atmosphere (for example, refs. 5,6).

Survey of Ices toward Massive Young Stellar Objects. I. OCS, CO, OCN−, and CH3OH

An important tracer of the origin and evolution of cometary ices is the comparison with ices found in dense clouds and toward young stellar objects (YSOs). We present a survey of ices in the 2–5 μm spectra of 23 massive YSOs, taken with the NASA InfraRed Telescope Facility SpeX spectrometer. The 4.90 μm absorption band of OCS ice is detected in 20 sight lines, more than 5 times the previously known detections. The absorption profile shows little variation and is consistent with OCS embedded in CH3OH-rich ices, and proton-irradiated H2S or SO2-containing ices. The OCS column densities correlate well with those of CH3OH and OCN−, but not with H2O and apolar CO ice. This association of OCS with CH3OH and OCN− firmly establishes their formation location deep inside dense clouds or protostellar envelopes. The median composition of this ice phase toward massive YSOs, as a percentage of H2O, is CO:CH3OH:OCN−:OCS = 24:20:1.53:0.15. CS, due to its low abundance, is likely not the main precursor to OCS. Sulfurization of CO is likely needed, although the source of this sulfur is not well constrained. Compared to massive YSOs, low-mass YSOs and dense clouds have similar or somewhat lower CO and CH3OH ice abundances, but less OCN− and more apolar CO, while OCS awaits detection. Comets tend to be underabundant in carbon-bearing species, but this does not appear to be the case for OCS, perhaps signalling OCS production in protoplanetary disks.

Comet 21P/Giacobini–Zinner: Narrowband Photometry of the Prototype of Carbon-chain Depleted Comets at Multiple Apparitions

We obtained extensive narrowband photoelectric photometry of Comet 21P/Giacobini–Zinner with observations spanning 33 yr. The original data from 1985 were re-reduced and are presented along with data from three additional apparitions, including 2018/19. The original conclusion regarding Giacobini–Zinner’s chemical composition remains unchanged, with it having a 4–6× depletion in the carbon-chain molecules C2 and C3 and in NH, as compared with both OH and CN. The comet continues to exhibit a large asymmetry in production rates as a function of time and heliocentric distance, with production reaching a peak 3–5 weeks prior to perihelion. All species, including dust, follow the same general production rate curve each apparition, and the carbon-bearing species are always very similar to one another. However, OH and NH each differ in detail from the carbon-bearing species, implying somewhat varied composition between source regions. Longer term, there are only small secular changes among the apparitions before and near perihelion, but larger changes are evident as the comet recedes from the Sun, suggestive of a progressive precession of the rotation axis.

A Model Earth-sized Planet in the Habitable Zone of α Centauri A/B

Abstract The bulk chemical composition and interior structure of rocky exoplanets are fundamentally important to understand their long-term evolution and potential habitability. Observations of the chemical compositions of solar system rocky bodies and of other planetary systems have increasingly shown a concordant picture that the chemical composition of rocky planets reflects that of their host stars for refractory elements, whereas this expression breaks down for volatiles. This behavior is explained by devolatilization during planetary formation and early evolution. Here we apply a devolatilization model calibrated with solar system bodies to the chemical composition of our nearest Sun-like stars—α Centauri A and B—to estimate the bulk composition of any habitable-zone rocky planet in this binary system (“α-Cen-Earth”). Through further modeling of likely planetary interiors and early atmospheres, we find that, compared to Earth, such a planet is expected to have (i) a reduced (primitive) mantle that is similarly dominated by silicates, albeit enriched in carbon-bearing species (graphite/diamond); (ii) a slightly larger iron core, with a core mass fraction of 38.4 − 5.1 + 4.7 wt% (see Earth’s 32.5 ± 0.3 wt%); (iii) an equivalent water-storage capacity; and (iv) a CO2–CH4–H2O-dominated early atmosphere that resembles that of Archean Earth. Further taking into account its ∼25% lower intrinsic radiogenic heating from long-lived radionuclides, an ancient α-Cen-Earth (∼1.5–2.5 Gyr older than Earth) is expected to have less efficient mantle convection and planetary resurfacing, with a potentially prolonged history of stagnant-lid regimes.

On Spectroscopic Phase-curve Retrievals: H2 Dissociation and Thermal Inversion in the Atmosphere of the Ultrahot Jupiter WASP-103 b

Abstract This work presents a reanalysis of the spectroscopic phase-curve observations of the ultrahot Jupiter WASP-103 b obtained by the Hubble Space Telescope (HST) and the Spitzer Telescope. Traditional 1D and unified 1.5D spectral retrieval techniques are employed, allowing to map the thermal structure and the abundances of trace gases in this planet as a function of longitude. On the dayside, the atmosphere is found to have a strong thermal inversion, with indications of thermal dissociation traced by continuum H− opacity. Water vapor is found across the entire atmosphere but with depleted abundances of around 10−5, consistent with the thermal dissociation of this molecule. Regarding metal oxide and hydrides, FeH is detected on the hot spot and the dayside of WASP-103 b, but TiO and VO are not present in detectable quantities. Carbon-bearing species such as CO and CH4 are also found, but since their detection is reliant on the combination of HST and Spizer, the retrieved abundances should be interpreted with caution. Free and Equilibrium chemistry retrievals are overall consistent, allowing to recover robust constraints on the metallicity and C/O ratio for this planet. The analyzed phase-curve data indicates that the atmosphere of WASP-103 b is consistent with solar elemental ratios.

The First Retrieval of a Substellar Subdwarf: A Cloud-free SDSS J125637.13–022452.4

Abstract We present the first retrieval analysis of a substellar subdwarf, SDSS J125637.13−022452.4 (SDSS J1256−0224), using the Brewster retrieval code base. We find SDSS J1256−0224 is best fit by a cloud-free model with an ion (neutral H, H−, and electron) abundance corresponding to Fe / H ion = − 1.5 . However, this model is indistinguishable from a cloud-free model with Fe / H ion = − 2.0 and a cloud-free model with Fe / H ion = − 1.5 assuming a subsolar carbon-to-oxygen ratio. We are able to constrain abundances for H2O, FeH, and CrH, with an inability to constrain any carbon-bearing species likely due to the low metallicity of SDSS J1256−0224. We also present an updated spectral energy distribution (SED) and semiempirical fundamental parameters. Our retrieval- and SED-based fundamental parameters agree with the Baraffe low-metallicity evolutionary models. From examining our “rejected” models (those with ΔBIC > 45), we find that we are able to retrieve gas abundances consistent with those of our best fitting model. We find the cloud in these poorer fitting “cloudy” models is either pushed to the bottom of the atmosphere or made optically thin.

Molecules and Outflows in NML Cygni: New Insights from a 1 mm Spectral Line Survey

Abstract A sensitive (1σ rms ≤ 3 mK) 1 mm spectral survey (214.5–285.5 GHz) of the oxygen-rich circumstellar envelope of the red hypergiant NML Cygni (NML Cyg) has been conducted using the Sub-millimeter Telescope (SMT) of the Arizona Radio Observatory (ARO). Over 100 spectral lines were detected, arising from 17 different molecules, including the carbon-bearing species CO, HCN, HCO+, CN, and HNC; sulfur- and silicon-containing compounds H2S, SO, SO2, SiO, and SiS; and more exotic NaCl and AlO. The 1 mm spectrum of NML Cyg closely resembles that of VY Canis Majoris (VY CMa) suggesting that the chemistries of hypergiant stars are similar. The line profiles in NML Cyg consist of multiple velocity features, particularly evident in SO2 and SO. In addition to a spherical wind at the star’s systemic velocity, the spectra suggest an asymmetric, blueshifted component near V LSR = −21 ± 3 km s−1 and a collimated, redshifted component near 15 ± 3 km s−1, positioned ∼34° and ∼12°, respectively, from the line of sight. The red- and blueshifted flows appear to be randomly oriented, and likely trace sporadic mass loss events. Their LSR velocities align closely with those of 22 GHz water masers, suggesting an NE–SE orientation. The winds may also be associated with the asymmetric nebula in F555W HST images but extending to 5″ (∼600R *). NML Cyg appears to be another example of rare, massive stars with collimated, episodic ejections, analogous to Betelgeuse and VY CMa, lending support for an important new mass loss mechanism—surface activity.

High Spatial Resolution Observations of Molecular Lines toward the Protoplanetary Disk around TW Hya with ALMA

Abstract We present molecular line observations of 13CO and C18O J = 3 − 2, CN N = 3 − 2, and CS J = 7 − 6 lines in the protoplanetary disk around TW Hya at a high spatial resolution of ∼9 au (angular resolution of 0.″15), using the Atacama Large Millimeter/Submillimeter Array. A possible gas gap is found in the deprojected radial intensity profile of the integrated C18O line around a disk radius of ∼58 au, slightly beyond the location of the au-scale dust clump at ∼52 au, which resembles predictions from hydrodynamic simulations of planet–disk interaction. In addition, we construct models for the physical and chemical structure of the TW Hya disk, taking account of the dust surface density profile obtained from high spatial resolution dust continuum observations. As a result, the observed flat radial profile of the CN line intensities is reproduced due to a high dust-to-gas surface density ratio inside ∼20 au. Meanwhile, the CO isotopologue line intensities trace high temperature gas and increase rapidly inside a disk radius of ∼30 au. A model with either CO gas depletion or depletion of gas-phase oxygen elemental abundance is required to reproduce the relatively weak CO isotopologue line intensities observed in the outer disk, consistent with previous atomic and molecular line observations toward the TW Hya disk. Further observations of line emission of carbon-bearing species, such as atomic carbon and HCN, with high spatial resolution would help to better constrain the distribution of elemental carbon abundance in the disk gas.

Narrowband Observations of Comet 46P/Wirtanen during Its Exceptional Apparition of 2018/19. II. Photometry, Jet Morphology, and Modeling Results

Abstract We report on our extensive photometry and imaging of comet 46P/Wirtanen during its 2018/19 apparition and use these data to constrain the modeling of Wirtanen’s activity. Narrowband photometry was obtained in 9 epochs from 2018 October through 2019 March as well as 10 epochs during the 1991, 1997, and 2008 apparitions. The ensemble photometry reveals a typical composition and a secular decrease in activity since 1991. Production rates were roughly symmetric around perihelion for the carbon-bearing species (CN, C3, and C2), but steeper for OH and NH outbound. Our imaging program emphasized CN, whose coma morphology and lightcurve yielded rotation periods reported in a companion paper (Farnham et al. 2021). Here, we compare the gas and dust morphology on the 18 nights for which observations of additional species were obtained. The carbon-bearing species exhibited similar morphology that varied with rotation. OH and NH had broad, hemispheric brightness enhancements in the tailward direction that did not change significantly with rotation, which we attribute to their originating from a substantial icy grain component. We constructed a Monte Carlo model that replicates the shape, motion, and brightness distribution of the CN coma throughout the apparition with a single, self-consistent solution in principal axis rotation. Our model yields a pole having (R.A., decl.) = 319°, −5° (pole obliquity of 70°) and two large sources (radii of 50° and 40°) centered at near-equatorial latitudes and separated in longitude by ∼160°. Applications of the model to explain observed behaviors are discussed.

Deserpentinization in Subduction Zones as a Source of Oxidation in Arcs: a Reality Check

AbstractPrevious studies have concluded that dehydration of serpentinites in subduction zones produces oxidizing fluids that are the cause of oxidized arc magmas. Here, observations of natural samples and settings are combined with thermodynamic models to explore some of the factors that complicate interpretation of the observations that form the basis of this conclusion. These factors include the variability of serpentinite protoliths, the roles of carbon and sulfur in serpentinite evolution, variability in serpentinization in different tectonic settings, changes in the bulk compositions of ultramafic rocks during serpentinization, fundamental differences between serpentinization and deserpentinization, and the absence of precise geothermobarometers for ultramafic rocks. The capacity of serpentinite-derived fluids to oxidize sub-arc magma is also examined. These fluids can transport redox budget as carbon-, sulfur-, and iron-bearing species. Iron- and carbon-bearing species might be present in sufficient concentrations to transport redox budget deep within subduction zones, but are not viable transporters of redox budget at the temperatures of antigorite breakdown, which produces the largest proportion of fluid released by serpentinite dehydration. Sulfur-bearing species can carry significant redox budget, and calculations using the Deep Earth Water (DEW) model show that these species might be stable during antigorite breakdown. However, oxygen fugacities of ∼ΔFMQ + 3 (where FMQ refers to the fayalite–magnetite–quartz buffer, and ΔFMQ is log fO2 – log fO2, FMQ), which is close to, or above, the hematite–magnetite buffer at the conditions of interest, are required to stabilize oxidized sulfur-bearing species. Pseudosection calculations indicate that these conditions might be attained at the conditions of antigorite breakdown if the starting serpentinites are sufficiently oxidized, but further work is required to assess the variability of serpentinite protoliths, metamorphic pressures and temperatures, and to confirm the relative positions of the mineral buffers with relation to changes in fluid speciation.

KELT-11 b: Abundances of Water and Constraints on Carbon-bearing Molecules from the Hubble Transmission Spectrum

Abstract In the past decade, the analysis of exoplanet atmospheric spectra has revealed the presence of water vapor in almost all the planets observed, with the exception of a fraction of overcast planets. Indeed, water vapor presents a large absorption signature in the wavelength coverage of the Hubble Space Telescope’s (HST) Wide Field Camera 3 (WFC3), which is the main space-based observatory for atmospheric studies of exoplanets, making its detection very robust. However, while carbon-bearing species such as methane, carbon monoxide, and carbon dioxide are also predicted from current chemical models, their direct detection and abundance characterization has remained a challenge. Here we analyze the transmission spectrum of the puffy, clear hot-Jupiter KELT-11 b from the HST WFC3 camera. We find that the spectrum is consistent with the presence of water vapor and an additional absorption at longer wavelengths than 1.5 μm, which could well be explained by a mix of carbon bearing molecules. CO2, when included is systematically detected. One of the main difficulties to constrain the abundance of those molecules is their weak signatures across the HST WFC3 wavelength coverage, particularly when compared to those of water. Through a comprehensive retrieval analysis, we attempt to explain the main degeneracies present in this data set and explore some of the recurrent challenges that are occurring in retrieval studies (e.g., the impact of model selection, the use of free versus self-consistent chemistry, and the combination of instrument observations). Our results make this planet an exceptional example of a chemical laboratory to test current physical and chemical models of the atmospheres of hot Jupiters.

Abundance measurements of H2O and carbon-bearing species in the atmosphere of WASP-127b confirm its supersolar metallicity

ABSTRACT The chemical abundances of exoplanet atmospheres may provide valuable information about the bulk compositions, formation pathways, and evolutionary histories of planets. Exoplanets with large, relatively cloud-free atmospheres, and which orbit bright stars provide the best opportunities for accurate abundance measurements. For this reason, we measured the transmission spectrum of the bright (V ∼ 10.2), large (1.37 RJ), sub-Saturn mass (0.19 MJ) exoplanet WASP-127b across the near-UV to near-infrared wavelength range (0.3–5 μm), using the Hubble and Spitzer Space Telescopes. Our results show a feature-rich transmission spectrum, with absorption from Na, H2O, and CO2, and wavelength-dependent scattering from small-particle condensates. We ran two types of atmospheric retrieval models: one enforcing chemical equilibrium, and the other which fit the abundances freely. Our retrieved abundances at chemical equilibrium for Na, O, and C are all supersolar, with abundances relative to solar values of 9$^{+15}_{-6}$, 16$^{+7}_{-5}$, and 26$^{+12}_{-9}$, respectively. Despite giving conflicting C/O ratios, both retrievals gave supersolar CO2 volume mixing ratios, which adds to the likelihood that WASP-127b’s bulk metallicity is supersolar, since CO2 abundance is highly sensitive to atmospheric metallicity. We detect water at a significance of 13.7σ. Our detection of Na is in agreement with previous ground-based detections, though we find a much lower abundance, and we also do not find evidence for Li or K despite increased sensitivity. In the future, spectroscopy with James Webb Space Telescope will be able to constrain WASP-127b’s C/O ratio, and may reveal the formation history of this metal-enriched, highly observable exoplanet.