The inverse processes of photoionization and electron-ion recombination of (Ca XV + hν↔ Ca XVI + e), are studied using the unified method of Nahar and Pradhan for a large number of bound states, 582 in total with n≤10 and l≤9, for their characteristic features particularly in the high energy region that can impact plasmas at high temperature. The unified method which implements close-coupling (CC) approximation and the R-matrix method includes both the radiative recombination (RR) and dielectronic recombination (DR) for the total recombination and yields self-consistent sets of results for both the inverse processes. The present study, carried out in large scale computations, employs a large CC wavefunction expansion of 29 LS states belonging to n=2,3 complexes of the core ion Ca XVI, and appeared to be the first detailed study for the electron-ion recombination of the ion. The present results include (i) state-specific photoionization cross sections (σPI(nLS)) leaving the core ion in the ground state, (ii) state-specific recombination rate coefficients (αRC(nLS,T)) that include both the RR and DR, (iii) total recombination rate coefficients (αRC) with temperature that include contributions of infinite number of recombined states, and (iv) a spectrum of total electron-ion recombination cross sections and rates with respect to photoelectron energy. The study finds that the core ion excitations from the ground to high n=3 states have introduced Rydberg resonances which are stronger and Seaton resonances which are more enhanced in the high energy region of σPI compared to those introduced by excitations to the n=2 states. Such features have contributed to the shape of the temperature dependent state-specific αRC(nLS,T), and have resulted in three DR bumps/ shoulders in the high temperature region of the total αRC(T) where the third DR bump at temperature of ∼ 4 MK has raised αRC(T) at high T above all previous rates. The results are expected to be accurate within 10%–15% and provide more complete and precise spectral modelings for the high temperature plasmas where the highly charged Ca XV is more abundant.