C-130 Research Aircraft Research Articles

Tropospheric HONO distribution and chemistry in the southeastern US

Abstract. Here we report the measurement results of nitrous acid (HONO) and a suite of relevant parameters on the NCAR C-130 research aircraft in the southeastern US during the NOMADSS 2013 summer field study. The daytime HONO concentration ranged from low parts per trillion by volume (pptv) in the free troposphere (FT) to mostly within 5–15 pptv in the background planetary boundary layer (PBL). There was no discernible vertical HONO gradient above the lower flight altitude of 300 m in the PBL, and the transport of ground surface HONO was not found to be a significant contributor to the tropospheric HONO budget. The total in situ HONO source mean (±1 SD) was calculated as 53 (±21) pptv h−1 during the day. The upper-limit contribution from NOx-related reactions was 10 (±5) pptv h−1, and the contribution from photolysis of particulate nitrate (pNO3) was 38 (±23) pptv h−1, based on the measured pNO3 concentrations and the median pNO3 photolysis rate constant of 2.0 × 10−4 s−1 determined in the laboratory using ambient aerosol samples. The photolysis of HONO contributed to less than 10 % of the primary OH source. However, a recycling NOx source via pNO3 photolysis was equivalent to ∼ 2.3 × 10−6 mol m−2 h−1 in the air column within the PBL, a considerable supplementary NOx source in the low-NOx background area. Up to several tens of parts per trillion by volume of HONO were observed in power plant and urban plumes during the day, mostly produced in situ from precursors including NOx and pNO3. Finally, there was no observable accumulation of HONO in the nocturnal residual layer and the nocturnal FT in the background southeastern US, with an increase in the HONO ∕ NOx ratio of ≤ 3 × 10−4 h−1 after sunset.

Liquid–Ice Mass Partition in Tropical Maritime Convective Clouds

Abstract The liquid–ice mass partitioning in tropical maritime convective clouds is studied using data collected by the National Center for Atmospheric Research C-130 research aircraft during the Ice in Clouds Experiment–Tropical project. The clouds investigated by the C-130 in this study generally contained weak to moderate updrafts. The liquid water content (LWC) is calculated using a combination of hot-wire and imaging probes. The total condensed water content (CWC) is measured by a counterflow virtual impactor. The ice water content (IWC) is calculated as CWC minus LWC. Taking into account potential significant measurement uncertainties, the liquid fraction [i.e., LWC/(LWC + IWC)] between 0° and −15°C appears to decrease by a factor of about 3 in updrafts near (<500 m) cloud top and a factor of 2 in updrafts far below (>500 m) cloud top. The decrease in liquid fraction as a function of temperature is also correlated with cloud life cycle. In dissipating clouds, ice dominates in all temperature ranges. A comparison between this study and two parameterizations shows that at different geographic locations the liquid fraction in convective clouds differs. Because of the sampling bias and the limitations of instruments, more measurements, especially with more advanced instruments, are needed in the future.

Mercury Emission Ratios from Coal-Fired Power Plants in the Southeastern United States during NOMADSS.

We use measurements made onboard the National Science Foundation's C-130 research aircraft during the 2013 Nitrogen, Oxidants, Mercury, and Aerosol Distributions, Sources, and Sinks (NOMADSS) experiment to examine total Hg (THg) emission ratios (EmRs) for six coal-fired power plants (CFPPs) in the southeastern U.S. We compare observed enhancement ratios (ERs) with EmRs calculated using Hg emissions data from two inventories: the National Emissions Inventory (NEI) and the Toxics Release Inventory (TRI). For four CFPPs, our measured ERs are strongly correlated with EmRs based on the 2011 NEI (r(2) = 0.97), although the inventory data exhibit a -39% low bias. Our measurements agree best (to within ±32%) with the NEI Hg data when the latter were derived from on-site emissions measurements. Conversely, the NEI underestimates by approximately 1 order of magnitude the ERs we measured for one previously untested CFPP. Measured ERs are uncorrelated with values based on the 2013 TRI, which also tends to be biased low. Our results suggest that the Hg inventories can be improved by targeting CFPPs for which the NEI- and TRI-based EmRs have significant disagreements. We recommend that future versions of the Hg inventories should provide greater traceability and uncertainty estimates.

Entrainment, Mixing, and Microphysics in Trade-Wind Cumulus

The vertical evolution of microphysics in trade-wind cumuli (Cu) observed from the NCAR C-130 research aircraft during one flight of the RICO (Rain in Cumulus Over the Ocean) study is analyzed. Conditional sampling of > 200 Cu traversed on this flight is used to chose Cu for which the aircraft penetrated single and growing Cu turrets about 250-m below cloud top where maximum LWC is often found and where radar has often observed initial stages of precipitation. The vertical evolution of the sampled set of Cu was assumed to follow Lagrangian behavior. The entrainment rate, entrained parcel scales, mixing mechanisms, and effects on the droplet size distribution are measured and evaluated. A parcel model is applied over the 1100-m maximum Cu height of the traverses to determine the relationship between the observed large number of small droplets and the fewer ultra-giant sea-salt nuclei (UGN) in order to assess the role of these nuclei in evolving the size spectrum and in causing a growing “drizzle tail”. New insight on these topics is obtained by using the PVM (Particle Volume Monitor) probe to measure incloud microphysics with 10-cm resolution.The results include the following: Entrainment causes primarily dilution of the drops without significant size changes, thus either extreme inhomogeneous mixing or more likely homogeneous mixing resulting from mixing with cool and humid entrained air take place. The entrained parcels are surprisingly small following lognormal behavior and decaying rapidly upon entering the Cu, as a result super-adiabatic drops are not evident. The entrained parcels are consistent with the Bragg-scattering “mantle echo” often observed by radar in small Cu. The FSSP (Forward Scattering Spectrometer Probe) droplet spectra are nearly constant with height. These “self-preserving” spectra are a result of an approximate balance between dilution by entrainment of droplets originating at cloud base, droplet activation on entrained CCN (cloud condensation nuclei), and detrainment and coalescence losses. Sea-salt nuclei follow Woodcock’s wind dependence, and are shown with the parcel model to play an important role in forming the observed drizzle that increases with cloud height. Accretion is the dominant coalescence mechanism near cloud top in these Cu.

Aircraft investigations of an As-Cs cloud system in the arctic

Results of aircraft investigations of the microphysical structure and properties of an As-Cs cloud system in the Arctic are presented. Data were collected over the Beaufort Sea using the US National Center for Atmospheric Research (NCAR) C-130 research aircraft. One of the modern sets of instruments was used to study the microphysical cloud structure. It was found that the clouds consisted of several layers of limited horizontal length. Spherical crystals were the prevailing habit. A decrease in their concentration with height decrease was discovered. Measurements of particle size spectra indicate their significant inhomogeneity. Spectra parametrization was carried out with the help of a gamma distribution for particles less smaller than 50 μm and exponential distribution for particles larger than 50 μm.

EPIC 95°W Observations of the Eastern Pacific Atmospheric Boundary Layer from the Cold Tongue to the ITCZ

Abstract The atmospheric boundary layer (ABL) along 95°W in the eastern equatorial Pacific during boreal autumn is described using data from the East Pacific Investigation of Climate (EPIC) 2001, with an emphasis on the evolution of the thermodynamic ABL properties from the cold tongue to the cold-advection region north of the sea surface temperature (SST) front. Surface sensible and latent heat fluxes and wind stresses between 1°S and 12°N are calculated from data from eight NCAR C-130 research aircraft flights and from Tropical Atmosphere Ocean (TAO) buoys. Reduced surface wind speed and a 10 m s−1 jet at a height of 500 m are found over the equatorial cold tongue, demonstrating the dependence of the surface wind speed on surface stability. The ABL exhibits a maximum in cloud cover on the north (downwind) side of the warm SST front, at 1°–3°N. Turbulent mixing driven by both surface buoyancy flux and radiative cooling at the cloud tops plays a significant role in maintaining the depth and structure of the ABL. The ABL heat budget between the equator and 3°N is balanced by comparable contributions from advective cooling, radiative cooling, surface warming, and entrainment warming. Entrainment drying is a weak contributor to the moisture budget, relative to dry advection and surface evaporation. Both the heat and moisture budgets are consistent with a rapid entrainment rate, 12 ± 2 mm s−1, deduced from the observed rise of the inversion with latitude between 0° and 4°N.

Airborne digital holographic system for cloud particle measurements

An in-line holographic system for in situ detection of atmospheric cloud particles [Holographic Detector for Clouds (HOLODEC)] has been developed and flown on the National Center for Atmospheric Research C-130 research aircraft. Clear holograms are obtained in daylight conditions at typical aircraft speeds of 100 m s(-1). The instrument is fully digital and is interfaced to a control and data-acquisition system in the aircraft via optical fiber. It is operable at temperatures of less than -30 degrees C and at typical cloud humidities. Preliminary data from the experiment show its utility for studies of the three-dimensional spatial distribution of cloud particles and ice crystal shapes.

Measurements of the sum of HO<sub>2</sub>NO<sub>2</sub> and CH<sub>3</sub>O<sub>2</sub>NO<sub>2</sub> in the remote troposphere

Abstract. The chemistry of peroxynitric acid (HO2NO2) and methyl peroxynitrate (CH3O2NO2)is predicted to be particularly important in the upper troposphere where temperatures are frequently low enough that these compounds do not rapidly decompose. At temperatures below 240K, we calculate that about 20% of NOy in the mid- and high-latitude upper troposphere is HO2NO2. Under these conditions, the reaction of OH with HO2NO2 is estimated to account for as much as one third of the permanent loss of hydrogen radicals. During the Tropospheric Ozone Production about the Spring Equinox (TOPSE) campaign, we used thermal dissociation laser-induced fluorescence (TD-LIF) to measure the sum of peroxynitrates (PNs HO2NO2+CH3O2NO2+PAN+PPN+...) aboard the NCAR C-130 research aircraft. We infer the sum of HO2NO2 and CH3O2NO2 as the difference between PN measurements and gas chromatographic measurements of the two major peroxy acyl nitrates, peroxy acetyl nitrate (PAN) and peroxy propionyl nitrate (PPN). Comparison with NOy and other nitrogen oxide measurements confirms the importance of HO2NO2 and CH3O2NO2 to the reactive nitrogen budget and shows that current thinking about the chemistry of these species is approximately correct. During the spring high latitude conditions sampled during the TOPSE experiment, the model predictions of the contribution of (HO2NO2+CH3O2NO2) to NOy are highly temperature dependent: on average 30% of NOy at 230K, 15% of NOy at 240K, and 5% of NOy above 250K. The temperature dependence of the inferred concentrations corroborates the contribution of overtone photolysis to the photochemistry of peroxynitric acid. A model that includes IR photolysis (J=1x10-5s-1) agreed with the observed sum of HO2NO2+CH3O2NO2 to better than 35% below 240K where the concentration of these species is largest.

Lagrangian air mass tracking with smart balloons during ACE-2

A 3rd-generation smart balloon designed at National Oceanic and Atmospheric Administration, Air Resources Laboratory Field Research Division, in collaboration with the University of Hawaii, was released from ship-board during the recent Second Aerosol Characterization Experiment (ACE-2) to provide Lagrangian air-mass tracking data. ACE-2 is the 3rd in a series of field experiments designed to study the chemical, physical, and radiative properties and processes of atmospheric aerosols and their role in climate and is organized by the international global atmospheric chemistry (IGAC) program. The adjective smart in the title of this paper refers to the fact that the buoyancy of the balloon automatically adjusts through the act of pumping air into or releasing air from the ballast portion of the balloon when it travels vertically outside a barometric pressure range set prior to release. The smart balloon design provides GPS location, barometric pressure, temperature, relative humidity, and other data via a transponder to a C130 research aircraft flying in the vicinity of the balloon. The addition of 2-way communication allows interactive control of the balloon operating parameters by an observer. A total of 3 cloudy Lagrangian experiments were conducted during the ACE-2 field program which lasted from 16 June through 26 July 1997. This paper reviews the design and capability of the smart balloons and their performance during the ACE-2 Lagrangian experiments. Future development and applications of the technology are discussed.

Mesoscale dynamics of cold fronts: Structures described by dropsoundings in FRONTS 87

The FRonts 87 project was a European experiment to make mesoscale observations to deduce the dynamics of active cold fronts approaching north-west Europe, with a minimum of orographic influences. In this paper data from dropsoundings made by the Meteorological Office's C-130 research aircraft are analysed. The aircraft flew a pattern with 4 or 5 runs oriented approximately at right angles to the front, but with each run displaced in the along-front direction by about 100 km. The dropsondes gave soundings to a height of approximately 7 km with a cross-frontal spacing of 20 km at best and 60 km on average. Between 30 and 50 soundings were made in each event, over an area of 500 × 500 km2. These data are unique in their mesoscale resolution over a synoptic-scale region; this was made possible by the ability to track up to 5 sondes in the air at any time. Several new aspects of cold-front dynamics have been identified from these data; the approach here is to treat each run as an instantaneous cross-frontal section. The discussion is centred on the hypotheses postulated before the experiment; these were intended to allow verification or refutation of aspects of models of frontal dynamics such as those embodied in semi-geostrophic theory. A minimal and purely objective analysis has been performed on the data presented here, but the high resolution of the dropsonde observations permits evaluation of differentiated quantities, such as potential vorticity (PV), with some confidence. Issues raised here include the degree of thermal-wind balance, the structure of conserved variables such as equivalent potential temperature and absolute momentum, the cross-frontal circulation and the role of diabatic processes such as the evaporation, of snow, and the potential vorticity structure on the mesoscale and its interpretation. The intention is to present an integrated view of the dynamical structure of fronts in the light of theoretical rather than conceptual or airflow models.

Nitric acid column densities over Antarctica

Nitric acid column densities derived from atmospheric infrared spectral emission data measured from the NSF USARP C130 research aircraft in the Spring of 1978 are presented, summarized by latitude. An increase of the column density with latitude is noted, along with a longitudinal asymmetry in the latitudinal dependence. Column densities range in values from 1.2±0.2×1020 molecules m−2 at 53°S latitude to 3.4±0.7×1020 molecules m−2 at 89°S latitude. Also, the liquid helium cooled spectral radiometer used to obtain the data and the associated calibration procedures are described.