Coal Combustion Research Articles

Mechanism of Inhibiting Spontaneous Coal Combustion by Dopa Hydrosol

ABSTRACT A new type of biomass environmentally friendly hydrosol (DEP) was proposed to inhibit coal spontaneous combustion (CSC). The DEP consists of two parts, the PDopa side chain solution formed by the redox reaction of Dopa and EGCG and the main chain sol solution formed by the free radical polymerization of AA under the action of APS initiator. The −COOH, −NH2, and −OH in Dopa can be grafted onto the skeleton of the main chain via double strong hydrogen bonding interactions with the −COOH group in PAA to form a stable three-dimensional cross-linked network structure. DEP can inhibit CSC through three aspects: oxygen isolation, increasing the activation energy of coal oxidation, scavenging active groups and free radicals. The calculation simulation results show that EGCG in DEP can remove various active free radicals with lower activation energy at room temperature, breaking the chain cycle reaction of coal spontaneous combustion, which proves its high efficiency. This study provides a new way to apply mussel-inspired adhesion mechanisms to the prevention of CSC.

A centrifuge modelling setup for dewatering, rewetting, and characterizing soil deposits

Dewatering in soils serves various purposes in the field of geotechnical engineering as well as other disciplines. In geotechnical engineering, dewatering is effective for improving stability, reducing settlements, and limiting seepage of contaminated pore fluid. This study details the development of an experimental setup that enables dewatering and rewetting soil deposits in-flight in a geotechnical centrifuge while the pore pressures/suctions and moisture contents are measured. Cone penetration tests and shear wave velocity measurements are also used to characterize the material in-flight. Detailed discussion is provided regarding the construction of the tensiometers and calibration of the moisture content probes. Tests are performed on two coal combustion products (CCPs) to exemplify the capabilities of the equipment. Illustrative test results provide time histories and profiles of soil suction and water content at different depths, agreeing well with measurements from laboratory soil-water retention curves. The results also show that dewatering of the CCP deposits leads to significant increases in strength and stiffness, and that after subsequent rewetting, the material maintains a permanent increase in stiffness. The developed system enables an economical and reliable study of the impacts related to dewatering and rewetting cycles to fulfill research purposes in a broad range of engineering disciplines.

Characteristic of PM2.5 concentration and source apportionment during winter in Seosan, Korea

Seosan is a concentrated industrial complex in the midwestern region of Korea. A study was conducted from December 2020 to January 2021, measuring PM2.5 and chemical components in Seosan using online instruments every hour. The concentration of PM2.5 during the winter season was 31.4±17.8 μg/m3, exceeding the national ambient air quality standard of Korea. The mass fraction of organic matter, elemental carbon, three major ions, five minor ions, crustal elements, and trace elements in PM2.5 accounted for 24.5%, 4.36%, 32.0%, 2.82%, 4.11%, and 5.17% of the total PM2.5 mass concentration, respectively. Source identification was conducted using positive matrix factorization modeling, revealing eight sources of PM2.5: Secondary inorganic aerosol (SIA), vehicle exhaust, industry, coal combustion, biomass burning/incinerator, oil combustion, soil, and aged sea salt. Source contributions varied during high pollution episodes (HPE), with SIA dominating in HPE1 and soil and aged sea salt in HPE2. The potential source contribution function and conditional probability function were utilized to estimate the potential local and regional emission areas for the identified sources. In Seosan, vehicle exhaust and biomass burning/incinerator were primarily influenced by local sources. SIA, industry, and oil combustion sources were significantly affected by short-range transport from eastern China. Soil and aged sea salt, which exhibited high contributions during HPE2, were associated with long-range transport from Inner Mongolia. Coal combustion was attributed to both local sources, particularly large industrial complexes near Seosan, and long-range transport from Northeast China and Inner Mongolia.Graphical

Fire prevention and extinguishing technologies in coal spontaneous combustion: a bibliometric and systematic review

Fire prevention and extinguishing technologies in coal spontaneous combustion: a bibliometric and systematic review

From Waste to Strength: A Comprehensive Review on Using Fly Ash in Composites with Enhanced Mechanical Properties

This article explores the diverse applications of fly ash (FA), a by-product generated during the combustion of coal. The introductory segment thoroughly comprehends the origins, composition, and widespread occurrence of FA. FA, which comprises an estimated 38% of worldwide power generation, frequently encounters disposal and storage obstacles on account of its classification as non-hazardous waste in the majority of countries. The environmental issues linked to the dispersal of FA are underscored in the problem statement, which further emphasizes the urgency for sustainable alternatives. Due to the fugitive emissions and potential health hazards associated with metal melting in FA, it is critical to investigate novel applications and disposal techniques immediately. Environmental sustainability is a primary focus of research, with the development of synthetic FA composites being one such alternative. The analysis presents significant findings that underscore the wide-ranging applications of FA. These applications include its utilization as a filler in composites, as well as its incorporation into cement and geo-polymerization processes. Notably, (10-20) wt. % Nano-FA enhances epoxy-based composites, showcasing remarkable improvements in tensile strength, flexural strength, and impact resistance. In thermoplastic composites, substantial enhancements occur within the (5–10) wt. % FA range, but exceeding optimal ranges weakens matrix-fiber interaction, leading to diminishing returns. The article emphasizes the criticality of FA in improving the mechanical and thermodynamic characteristics of substances, specifically within the domain of composites. The investigation into FA nanoparticles, including their processing techniques and surface treatments, unveils encouraging prospects for enhancing material characteristics.

Generation characteristics and molecular reaction dynamics mechanism of PAHs during oxygen-lean combustion of jet coal

Severe coalfield fires occur in China, mainly in the northwest provinces of Xinjiang, Inner Mongolia, and Ningxia. Among the organic pollutants produced by oxygen-lean combustion, PAHs are considered one of the most dangerous pollutants due to their environmental contamination and “carcinogenic, teratogenic, and mutagenic” effects on human beings. In this paper, to address the problems of PAHs generation and reaction mechanism in coalfield fire, the jet coal from Xinjiang Zhundong Coalfield was selected to conduct the experiments, and the combustion products were detected using GC–MS and FTIR. The molecular dynamics method based on the reaction force field was also used to calculate the reaction process of 17 single molecules (5083 atoms) of jet coal combusted from 300 K to 4000 K at 0.5 oxygen equivalent ratio. The experimental results show that the generation of PAHs increased roughly from 573 K to 773 K at the three oxygen concentrations, and an increase in oxygen content can enhance PAHs generation to some degree. The structural evolutions and product changes in the system have been traced, and it is also clarified that the reaction history of oxygen-lean combustion mainly experiences two stages: thermal decomposition of coal structure and transformation of aromatic structure. The generation mechanism of PAHs is proposed from the perspective of molecular reaction dynamics. On the one hand, it is due to the breakage of active sites such as C-S, C-O, and O-H during the decomposition of coal structure. On the other hand, it originates from the polycondensation reaction triggered by the dehydrogenation of aromatic structure that enlarges the aromatic dimension The research results reveal the generation characteristics and reaction pathways of PAHs in the oxygen-lean combustion of low-rank coal in the fire zone and provide certain references for coal fire management and pollutant control.

Dissolved PAHs in the Beibu Gulf and adjacent waters of the South China Sea: Physical and biochemical processes-driven distributional variations

Polycyclic aromatic hydrocarbons (PAHs) in semi-enclosed gulfs are influenced by physical and biochemical processes, which haven’t been well understood. This study aims to investigate the spatial distribution and vertical profiles of dissolved PAHs in the Beibu Gulf and adjacent waters of the South China Sea, along with hydrological, meteorological, and biochemical variables. Particularly relevant are the effects of atmospheric pressure, salinity, ammonium, chlorophyll-a, as well as riverine inputs (RI), sea currents, and upwelling. In surface seawater, the total concentrations of eight dissolved PAHs (∑8PAHs) were 7.76 ± 2.16ng/L, with a distribution pattern of western Guangdong waters (WGWs) > BG > Qiongzhou Strait (QS). ∑8PAHs in the northern BG (9.10 ± 2.00ng/L) was significantly higher than that in the southern BG (6.65 ± 1.54ng/L) (p < 0.01), suggesting that local anthropogenic activities and unique environmental characteristics significantly influenced PAHs distribution. In water column, PAHs in BG displayed enrichment in surface and bottom but decreased in medium water, while those in WGWs and QS decreased with increasing depth. Source apportionment concluded that PAHs in QS and WGWs were primarily from petroleum sources, and PAHs in BG were mainly from coal combustion. RI, combined with circulation, coastal current, and intrusion of SCS water influenced the surface PAHs distribution in BG, with eddy impacts observed. Specifically, regarding the surface PAHs distribution, differences in atmospheric pressure may influence the air-sea exchange of PAHs, especially positively affecting 4-ring PAHs. Salinity factors further corroborated the contribution of RI to 3-ring PAHs, followed by the regulation of PAHs through biological pumps (ammonia and chlorophyll-a). Moreover, upwelling-induced biodegradation and resuspension affected the vertical distribution of PAHs. While most PAHs posed a negligible risk, coking-generated fluorene posed a moderate risk to ecosystems due to changes in the energy structure, warranting further investigation into its toxicological impacts.

Exploring effects of supplementary cementitious materials on setting time, strength, and microscale properties of mortar

The concept of sustainability has become a crucial concern for safeguarding the planet. The current research has focused on developing affordable and eco-friendly mortar by using industrial wastes. This study explores the use of fly ash (FA) and ground granulated blast furnace slag (GGBFS), byproducts of steelmaking and coal burning, in mortar production. It examines their impacts on the compressive strength and setting times, when utilizing varying proportions of the materials. The study also evaluates water requirements for the workability, thus demonstrating the sustainability of these waste products in construction. The cementitious materials were employed in finely ground form and were replaced with further tertiary mixes including both supplements at 10%, 30%, and 50% of each. The mixtures were allowed to cure for 7, 14, and 28 days by immersion in water. The results showed improvements in the compressive strength of mortar samples incorporating FA and GGBFS at various curing ages. However, the water requirement and workability of mortar samples were altered as a result of utilizing these supplementary cementitious materials (SCMs). These findings will serve as a standard for environmentally responsible mortar using GGBFS and/or FA as SCMs.

Tourism activities significantly contributed toatmospheric pollutants in a remote town of Tianshan revealed by the continuous observation of two years

The large reduction in tourism activities in 2020 provided a unique opportunity to investigate their contribution on atmospheric pollutants in Bayanbulak, a remote town in Tianshan, China. In this scenic and sensitive region, we measured total suspended particulates (TSP) along with concentrations of polycyclic aromatic hydrocarbons (PAHs), organic carbon (OC), elemental carbon (EC) and water-soluble inorganic ions (WSIIs) during the lockdown in 2020 and compared these to levels in the pre-pandemic period of 2019. The study revealed significant reductions in PAHs, OC, EC, and some WSIIs concentrations during the tourist season (May–October) of 2020 compared with 2019, whereas variations between non-tourist seasons were less pronounced. Furthermore, by comparing pollutant characteristics in tourist seasons of these two years, we found that 5- and 6-ring groups were main PAH constituents in 2019, while 5- and 3-ring groups contributed more to total PAHs in 2020. OC/EC ratio increased from 2019 to 2020, indicating an increase of biomass burning contribution after the lockdown. Using positive matrix factorization, we determined that emissions from tourism-related transportation and combustion of natural gas and coal (mainly for cooking) contributed 21.9% and 46.6%, respectively, to certain atmospheric pollutants in 2019, whereas they decreased significantly to 3% and 19.4% in 2020 with dust and biomass contributions increased substantially. The levels of PAHs, OC, and EC from tourism-related sources were as high as 9.31 ng m−3, 1.28 μg m−3 and 0.11 μg m−3 and decreased by 54.37%, 25.16%, and 9.54%, respectively, compared to 2019. Hence, the impact of tourism must be considered during the assessment of local air pollutant emissions, particularly in remote areas.

An Experimental Study on Monitoring and Early Warning of Spontaneous Coal Combustion Fires Using CPM

An Experimental Study on Monitoring and Early Warning of Spontaneous Coal Combustion Fires Using CPM

Simulation of Pulverized Coal Combustion in Blast Furnace Tuyere

Coal injection is an important way to reduce the coke ratio in the blast furnace. The combustion of pulverized coal in tuyere and raceway directly affects the production efficiency of smelting. Based on the design and production data of a 2000 m3 blast furnace, a three‐dimensional mathematical model of pulverized coal combustion in tuyere and raceway is established. The lower part of the blast furnace consisting of blowpipe‐coal lance‐tuyere‐raceway and coke bed is numerically simulated to study the influence of blast rate and oxygen on pulverized coal combustion under a certain coal injection ratio and a certain coal particle size distribution. The simulation results show that the pulverized coal burnout decreases from 69.2% to 67.4% when the blast velocity is increased by 20 m s−1, and the oxygen content increases from 23% to 27%, which can improve the pulverized coal burnout and increase the temperature in the raceway. A new direction is proposed to increase the pulverized coal burnout by optimizing the particle size selection and increasing the injection ratio of small particle size below 50 μm. The research provides theoretical and data support for increasing pulverized coal burnout.

Unveiling the role of oxygen in ammonia coal combustion: A DFT study on NOx emission mechanism

Ammonia-coal combustion mitigates CO2 emissions, yet nitrogen oxide emissions and char nitrogen oxidation mechanisms require further study. Our research employs density functional theory to explore coal char interactions with NO, NH3, and the impact of hydroxyls (–OH) and oxygen on reduction–oxidation processes. Findings indicate oxygen aids in forming hydroxyls on coal char, facilitating NO to NO2 conversion, lowering the activation energy for ammonia-coal oxidation to NO2. Oxygen also promotes char nitrogen oxidation to NO, reducing its activation energy. In NH3/coal/O2 systems, NH3 oxidation initiates NO formation. With the increase of the temperature, the reduction rate of NO by ammonia is always higher than the production rate of NO.

Study on the Parameters of Collaborative Fire Prevention by Plugging Air Leakage with Isolation Wall and Injecting Nitrogen in the Goaf of Re-Mining Working Face

ABSTRACT This study focuses on preventing coal spontaneous combustion in re-mining working face, using Yunhe Coal Mine as a case study. The investigation of spontaneous combustion characteristics in both new and re-mined coal samples revealed that the re-mined coal exhibits a higher oxygen consumption rate and greater heat release intensity compared to new mining coal. Through field observations and numerical simulations, the distribution range of oxidation zones in goaf within different zones of the re-mining working face was determined. Based on these findings, a collaborative fire prevention measure is proposed, involving plugging air leakage with isolation wall and injecting nitrogen into the goaf. The implementation of these fire prevention measures results in a reduction in the size of the oxidation zone, an increase in the size of the asphyxiation zone, and a decrease in the maximum temperature. To further enhance fire prevention efforts, it is recommended that distinct cooperative fire prevention parameters be established for both new mining zones and re-mining zones. These research findings provide a theoretical foundation for more efficient fire prevention measures in re-mining working face.

Study on the influence of aerosol atomization by ultrasonic atomization on coal spontaneous combustion

ABSTRACT Influenced by the complex environment and the nature of process materials in goaf, the prevention and control of spontaneous combustion of coal (CSC) in the deep part of goaf were facing many difficulties. To investigate the performance of ultrasonic atomized aerosols, a series of atomization experiments were conducted using a self-developed ultrasonic atomization device. The main conclusions are as follows: under the same atomization conditions, the atomized particle sizes of several inhibitors (except PAS-W) are concentrated in the <8 μm range, with a content of more than 88%, indicating that the aerosol particles produced by ultrasonic atomization are small in size and uniform in distribution. Compared with water and MgCl2 inhibitors, aerosol particles produced by PAS-W are less likely to pass through the voids of the coal body, and have poorer permeability and diffusivity. As the temperature increases, the viscosity and surface tension of the inhibitor decrease, and the percentage of aerosol particles with particle size <8 μm produced by ultrasonic atomization is more than 88%, indicating that the atomization effect is improved. After increasing the temperature, the contact angle between PAS-W inhibitor and coal reduces from 54.7° to 40.8°, and the wettability is better. Compared with raw coal, the final temperature of the PAS-W aerosol treated coal sample is delayed 21.86°C, and has significant retarding property. When the wind speed is 3 m/s, the effect of PAS-W aerosol particle generation, permeability, and particle size distribution is the best. The results of the study are of great significance in improving the ultrasonic atomized aerosol fire prevention technology and realizing large-scale CSC prevention in goaf.

Mathematical model for heat transfer during underground coal gasification process

Purpose. To develop a mathematical model of the “coal-gas” medium heat transfer during underground coal gasification to predict the combustion face advance velocity and the duration of gasification column mining. Methodology. To detect the temperature fields in the coal seam and gas, depending on the displacement length of the phase transition boundary, a boundary-value problem of mathematical physics has been developed. To solve this boundary-value problem, Boltzmann transformations, as well as methods for solving ordinary differential equations, are used. Newton-Raphson method, which has quadratic convergence, is used to find the roots of the transcendental equation. Findings. Tendencies in the formation of mathematical models when studying temperature fields around an underground gasifier have been analyzed, with highlighting their disadvantages. A mathematical model of heat transfer during underground gasification has been developed, taking into account the phase transition boundaries of the “coal-gas” medium. A computational experiment was conducted to determine the temperature of the phase transition boundary based on the length of the gasification column and the duration of the process. Originality. A mathematical model for heat transfer during coal gasification in the form of a boundary-value problem of mathematical physics, which consists of parabolic heat-transfer equations, the Stefan condition at the phase transition boundary, and the Dirichlet boundary conditions, has been constructed. As a result of solving the boundary-value problem, a self-similar solution has been obtained for the distribution of the coal seam and gas temperature fields, as well as the position of the phase transition boundary depending on the gasification duration and on the medium density, thermal conductivity coefficients, specific heat capacity of gas and coal, specific calorific value and temperature of coal combustion, initial coal temperature and constant temperature of the gasification process. The conducted analysis of numerical calculations provides a deeper understanding of the dynamics of underground coal gasification process and makes necessary corrections to achieve the maximum process efficiency. Practical value. A methodology for determining the displacement length of the phase transition boundary of the “coal-gas” medium has been developed, taking into account the change in the combustion face temperature along the gasification zone length depending on the duration of this process. Application of the methodology makes it possible to predict the time of mining the gasified coal column for drawing up a calendar plan for mining operations.

Experimental and molecular dynamics study on combustion characteristics of non-stick coal

To investigate the combustion characteristics of non-stick coal and the formation patterns of main combustion products and radicals, this study initially conducted a TG-DSC experiment of non-stick coal. Subsequently, non-stick coal was characterized and analyzed using XPS and 13C NMR experiments, and a molecular model with the formula C208H199O23N3S was constructed. Subsequently, the ReaxFF MD method was employed to simulate the combustion molecular dynamics of the non-stick coal periodic mixing model under varying oxygen content and temperature conditions. The analysis focused on elucidating the formation patterns of free and primary products during combustion. Experimental findings indicate that the combustion of non-stick coal progresses through stages, including water evaporation and desorption (30–145.65 °C), dynamic equilibrium (145.65–181.76 °C), oxygen weight gain (181.76–263.56 °C), thermal decomposition (263.56–379.14 °C), combustion (379.14–562.04 °C) and burnout (562.04–800 °C). The ignition temperature of non-stick coal was determined to be 379.14 °C. The simulation results indicate that an increase in temperature and oxygen content further enhances the relatively stable peak production of CO2. The peak increase of CO production is weaker than that of CO2. The rise in temperature also promotes the formation of H2O, while the increase in oxygen content initially enhances and subsequently inhibits the peak production of H2O. H radicals, O radicals, and OH radicals are primarily generated through the decomposition reactions of small molecular compounds or other free radicals. Free radical polymerization and the decomposition of small molecular compounds represent the primary pathways for the formation of CO, CO2, and H2O.

Characteristics of Combustion and NOx Emission in a 600 MWe Wall-Fired Boiler Under Varying Coal Mill and Burner Damper Configurations

ABSTRACT To accelerate China’s transition toward providing capacity support and prioritizing electricity generation, detailed research is necessary regarding the continuous peak output of coal-fired boilers during peak periods. However, high-load operation of coal-fired boilers may lead to issues such as NOx emission and increased flue gas temperature. This study conducted industrial experiments on a 600 MWe wall-fired boiler operating under peak conditions (500 MWe), using different pulverized coal mill operating modes. The boiler was optimized by adjusting the damper openings of the burners. Experimental results showed coal powder ignited within 0.2 m of burner outlets, indicating good performance. With the reduction in the damper openings of the burners, the concentration of NOx decreased, and the flue gas temperature gradually dropped, with the maximum temperature differential being 179°C. The ABCEF pulverized coal mill case had high water consumption and flue gas loss, unfavorably affecting economic operation. The ABDEF case delayed temperatures by 100°C, with the lowest NOx concentration at 277 ppm, enhancing environmental friendliness. In addition, the ABCDE case exhibited optimal coal burnout, with 0.838% fly ash carbon content, and the lowest flue gas temperature at 111.49°C, reducing flue gas loss by 5.9% compared to the ABDEF case, showing good economic performance.

High-Temperature-Resistant Dual-Scale Ceramic Nanofiber Films toward Improved Air Filtration.

Currently, air pollution primarily arises from industrial emissions, coal combustion, and automobile exhaust, posing significant challenges for mitigation. This highlights the urgent need for advanced and efficient filtration materials with low pressure drop and high-temperature resistance. Traditionally, improving filtration property has involved increasing the thickness of the filtration materials, which consequently leads to higher costs. Here, dual-scale mullite nanofiber (MNF) films containing interwoven thick nanofibers (606 nm) and thin nanofibers (186 nm) are prepared using solution blow spinning. The dual-scale structure design enables the films to maintain a low pressure drop while achieving high filtration efficiency. At an airflow velocity of 5.3 cm s-1, the films with an areal density of 3.8 mg cm-2, achieve a filtration efficiency of 98.23% and a pressure drop of 141 Pa for PM0.3. In addition, the MNF films exhibit excellent flexibility and high-temperature resistance, making them have great potential for use in high-temperature flue gas filtration.

Synergistic inhibition effect and mechanism of an inhibitor for entire process inhibition of coal spontaneous combustion

Traditional coal spontaneous combustion (CSC) inhibitors, while effective, have limitations such as frequent application or short-term efficacy. To this end, we developed a slow-release and water-soluble synergistic inhibitor (SWSI) to achieve long-term CSC inhibition. The SWSI was formulated by integrating synergistic antioxidants (SA) composed of ascorbic acid (AsA) and Fe-superoxide dismutase (Fe-SOD) dissolved in a super absorbent polymer (SAP) encapsulated within hydrogel microcapsules. The effectiveness of SWSI was evaluated through simultaneous thermal analysis and in-situ free radical tests. The formulation optimization demonstrated that AsA and Fe-SOD had the maximum synergistic inhibition effect at a 1:1 molar ratio. The optimal SA: SAP ratio of 3:1 achieved the lowest oxygen consumption rate and highest inhibition rate. The encapsulation formulation, consisting of 3% SA, 6% PAM, 1% CaCl2, and 0.5% citric acid, generated the highest swelling ratio. Simultaneous thermal analysis and in-situ free radical tests indicated that SWSI greatly increased feature temperatures and the apparent activation energy, lowered reaction heat, and substantially reduced free radical concentration in the full oxidation process. The newly developed SWSI offers a significant advancement in long-term CSC prevention by integrating physical and chemical inhibition, which provides sustained and effective inhibition throughout the entire oxidation process.

Comprehensive Review of Fly Ash: Environmental Impact and Applications

ABSTRACTFly ash (FyA), a byproduct from coal combustion in power plants, has become increasingly valuable due to its pozzolanic properties. Primarily, FyA finds applications in the construction industry, including road and brick construction, forest road building, and the cement industry. When added to concrete, it enhances splitting tensile strength, compressive strength, and workability, while also reducing the environmental impact of cement production. Beyond construction, FyA is utilized for air pollutant removal and serves as an adsorbent for various contaminants. It also plays a role in creating geopolymers and nanocomposites, promoting the development of eco‐friendly construction materials. This review article presents current data on thermal power plants (ThPPs) in India, the challenges in FyA management, and its environmental impact. It also discusses relevant Indian policies and highlights ongoing research aimed at improving the efficiency and expanding the applications of FyA in various industrial sectors, such as battery manufacturing, zeolite synthesis, and cenosphere extraction. These efforts underscore FyA's potential in supporting sustainable practices. The findings of this review address critical issues related to FyA. By reducing the environmental footprint of cement manufacturing, removing air pollutants, and acting as an adsorbent for various contaminants, FyA demonstrates significant potential in pollution mitigation. It also contributes to the development of eco‐friendly construction materials and promotes sustainability in the construction sector. Effective management practices are essential to minimize FyA's negative impact on human health and the environment. The article emphasizes the need for greater awareness and implementation of policies to address these issues comprehensively. By providing a detailed understanding of the benefits and challenges associated with FyA, it aims to pave the way for more effective and sustainable utilization of this industrial byproduct.