Bulk Resonance Research Articles

Observation of multiple bulk bound states in the continuum modes in a photonic crystal cavity.

Obtaining bound states in the continuum (BICs) in photonic crystals gives rise to the realization of resonances with high quality factors for lasing and nonlinear applications. For BIC cavities in finite-size photonic crystals, the bulk resonance band turns into discrete modes with different mode profiles and radiation patterns. Here, photonic-crystal BIC cavities encircled by the photonic bandgap of lateral heterostructures are designed. The mirror-like photonic bandgap exhibits strong side leakage suppression to confine the mode profile in the designed cavity. Multiple bulk quantized modes are observed both in simulation and experiment. After exciting the BIC cavity at different positions, different resonance peaks are observed. The physical origin of the dependence between the resonance peak and the illuminating position is explained by analyzing the mode profile distribution and further verified by numerical simulations. Our findings have potential applications regarding the mode selectivity in BIC devices to manipulate the lasing mode in photonic-crystal surface-emitting lasers or the radiation pattern in nonlinear optics.

Terahertz band range adjustable hyperbolic metamaterial refractive index sensor

Terahertz sensing has an important position in biochemical detection due to its unique advantages. In this work, we design a sensor with tunable analytes refractive index interval using graphene/dielectric multilayer structured hyperbolic metamaterials (GMHMM). We use the attenuated total reflection method to match the bulk high k waves mode in the GMHMM and derive dispersion relation of the bulk resonance mode in combination with waveguide mode analysis. By tuning the graphene Fermi energy level and incidence angle, the sensor can detect analytes with different refractive indices with a maximum sensitivity of 20.5 THz/RIU and an average sensitivity of 11.05 THz/RIU in the band of 2.4 THz. We believe that the proposed structure can be applied to biochemical molecule detection in the terahertz band and contribute to the development of hyperbolic metamaterial sensors from laboratory research to practical applications.

Impact of Polypropylene Fibers on the Mechanical and Durability Characteristics of Rubber Tire Fine Aggregate Concrete.

In this research, the consequence of using rubber tire aggregates (RTA) on the durability and mechanical characteristics of polypropylene fibers (PF) reinforced concrete is evaluated. Fifteen concrete mixtures were produced and tested in the laboratory. RTA was utilized instead of fine natural aggregates (FNA) to the concrete at concentrations of 0%, 5%, 10%, 15%, and 20% by a volumetric fraction; also, the contents of PF in the concrete mixtures were 0%, 1%, and 2% by weight fraction. Finally, the following parameters were tested for all the mixtures: compressive and tensile resistances, fracture, changes in drying shrinkage, bulk electrical resistivity, elastic moduli, and resonance occurrences. The control sample was the one without RTA and PF. According to the results, by adding RTA to the mixtures, the shrinkage deformation amplified, but the PF addition caused a decrease in the shrinkage deformation. Furthermore, adding 0%, 5%, 10%, and 15% RTA, with 2% PF leads to an upsurge in the flexural resistance by 34%, 24%, 16%, and 6%, respectively, relative to the control sample without PF and RTA. Moreover, the fracture energy of mixtures increased by utilizing PF and RTA simultaneously.

Predictability of concrete damage level by non-destructive test methods

Non-destructive methods have many advantages over traditional test methods, especially since it does not damage the specimen, it can be used multiple times on the same specimen. These advantages also provide a great benefit in terms of following the property development in concrete as the same specimens are used which eliminates the variations related to the specimens. In this study, it is aimed to determine the damaged amount of concrete produced with different binders by electrical bulk resistivity, resonance frequency, and ultrasonic pulse velocity methods. Firstly, concretes containing different binders were produced, and along with the mechanical properties, ultrasonic wave velocity, resonance frequency, and electrical resistivity values of the produced concrete were determined at the 7, 28, and 90 days. Besides, the specimens were subjected to gradually increase compressive loads and non-destructive methods were used to estimate the extent of damage on specimens. It was attempted to establish a relationship between the damage on concrete specimens and the results obtained by non-destructive methods. Consequently, the compressive strength, electrical resistivity, ultrasonic pulse velocity and resonance frequency values of all specimens increased with the advancing age. It was concluded that the resonant frequency method is more successful than other methods in estimating the amount of damage in concrete.

Magnetoelastic Coupling and Delta-E Effect in Magnetoelectric Torsion Mode Resonators.

Magnetoelectric resonators have been studied for the detection of small amplitude and low frequency magnetic fields via the delta-E effect, mainly in fundamental bending or bulk resonance modes. Here, we present an experimental and theoretical investigation of magnetoelectric thin-film cantilevers that can be operated in bending modes (BMs) and torsion modes (TMs) as a magnetic field sensor. A magnetoelastic macrospin model is combined with an electromechanical finite element model and a general description of the delta-E effect of all stiffness tensor components Cij is derived. Simulations confirm quantitatively that the delta-E effect of the C66 component has the promising potential of significantly increasing the magnetic sensitivity and the maximum normalized frequency change . However, the electrical excitation of TMs remains challenging and is found to significantly diminish the gain in sensitivity. Experiments reveal the dependency of the sensitivity and of TMs on the mode number, which differs fundamentally from BMs and is well explained by our model. Because the contribution of C11 to the TMs increases with the mode number, the first-order TM yields the highest magnetic sensitivity. Overall, general insights are gained for the design of high-sensitivity delta-E effect sensors, as well as for frequency tunable devices based on the delta-E effect.

Ultrafast evolution of bulk, surface and surface resonance states in photoexcited hbox {Bi}_{2}hbox {Te}_{3}

We use circular dichroism (CD) in time- and angle-resolved photoemission spectroscopy (trARPES) to measure the femtosecond charge dynamics in the topological insulator (TI) hbox {Bi}_{2}hbox {Te}_{3}. We detect clear CD signatures from topological surface states (TSS) and surface resonance (SR) states. In time-resolved measurements, independently from the pump polarization or intensity, the CD shows a dynamics which provides access to the unexplored electronic evolution in unoccupied states of hbox {Bi}_{2}hbox {Te}_{3}. In particular, we are able to disentangle the unpolarized electron dynamics in the bulk states from the spin-textured TSS and SR states on the femtosecond timescale. Our study demonstrates that photoexcitation mainly involves the bulk states and is followed by sub-picosecond transport to the surface. This provides essential details on intra- and interband scattering in the relaxation process of TSS and SR states. Our results reveal the significant role of SRs in the subtle ultrafast interaction between bulk and surface states of TIs.

Kinetics of the conformational cycle of Hsp70 reveals the importance of the dynamic and heterogeneous nature of Hsp70 for its function

Hsp70 is a conserved molecular chaperone that plays an indispensable role in regulating protein folding, translocation, and degradation. The conformational dynamics of Hsp70 and its regulation by cochaperones are vital to its function. Using bulk and single-molecule fluorescence resonance energy transfer (smFRET) techniques, we studied the interdomain conformational distribution of human stress-inducible Hsp70A1 and the kinetics of conformational changes induced by nucleotide and the Hsp40 cochaperone Hdj1. We found that the conformations between and within the nucleotide- and substrate-binding domains show heterogeneity. The conformational distribution in the ATP-bound state can be induced by Hdj1 to form an "ADP-like" undocked conformation, which is an ATPase-stimulated state. Kinetic measurements indicate that Hdj1 binds to monomeric Hsp70 as the first step, then induces undocking of the two domains and closing of the substrate-binding cleft. Dimeric Hdj1 then facilitates dimerization of Hsp70 and formation of a heterotetrameric Hsp70-Hsp40 complex. Our results provide a kinetic view of the conformational cycle of Hsp70 and reveal the importance of the dynamic nature of Hsp70 for its function.

2N+4-rule and an atlas of bulk optical resonances of zigzag graphene nanoribbons

Development of on-chip integrated carbon-based optoelectronic nanocircuits requires fast and non-invasive structural characterization of their building blocks. Recent advances in synthesis of single wall carbon nanotubes and graphene nanoribbons allow for their use as atomically precise building blocks. However, while cataloged experimental data are available for the structural characterization of carbon nanotubes, such an atlas is absent for graphene nanoribbons. Here we theoretically investigate the optical absorption resonances of armchair carbon nanotubes and zigzag graphene nanoribbons continuously spanning the tube (ribbon) transverse sizes from 0.5(0.4) nm to 8.1(12.8) nm. We show that the linear mapping is guaranteed between the tube and ribbon bulk resonance when the number of atoms in the tube unit cell is 2N+4, where N is the number of atoms in the ribbon unit cell. Thus, an atlas of carbon nanotubes optical transitions can be mapped to an atlas of zigzag graphene nanoribbons.

Surface plasmon induced enhancement in selective laser melting processes

PurposeSelective laser melting (SLM) is an advanced rapid prototyping or additive manufacturing technology that uses high power density laser to fabricate metal/alloy components with minimal geometric constraints. The SLM process is multi-physics in nature and its study requires development of complex simulation tools. The purpose of this paper is to study – for the first time, to the best of the authors’ knowledge – the electromagnetic wave interactions and thermal processes in SLM based dense powder beds under the full-wave formalism and identify prospective metal powder bed particle distributions that can substantially improve the absorption rate, SLM volumetric deposition rate and thereby the overall build time.Design/methodology/approachWe present a self-consistent thermo-optical model of the laser-matter interactions pertaining to SLM. The complex electromagnetic interactions and thermal effects in the dense metal powder beds are investigated by means of full-wave finite difference simulations. The model allows for accurate simulations of the excitation of gap, bulk and surface electromagnetic resonance modes, the energy transport across the particles, time dependent local permittivity variations under the incident laser intensity, and the thermal effects (joule heating) due to electromagnetic energy dissipation.FindingsLocalized gap and surface plasmon polariton resonance effects are identified as possible mechanisms toward improved absorption in small and medium size titanium powder beds. Furthermore, the observed near homogeneous temperature distributions across the metal powders indicates fast thermalization processes and allows for development of simple analytical models to describe the dynamics of the SLM process.Originality/valueTo the best of the authors’ knowledge, for the first time the electromagnetic interactions and thermal processes with dense powder beds pertaining to SLM processes are investigated under full-wave formalism. Explicit description is provided for important SLM process parameters such as critical laser power density, saturation temperature and time to melt. Specific guidelines are presented for improved energy efficiency and optimization of the SLM process deposition rates.

Investigation of valence electron excitation and plasmonic enhancement in sputter grown NMZO thin films: For energy harvesting applications

We report a novel approach of sputter-stimulated plasmonic generation in Na-doped MgZnO (NMZO) thin films. Sputtering of material during film growth by utilizing secondary direct-coupled ion-source present in dual-ion beam sputtering system leads to the generation of nanoclusters of its constituent elements due to different sputtering-out rates of various elements present in the films. The authentication of plasmonic generation in NMZO is conducted as follows a) identification of plasmonic signature in electron energy loss spectra obtained by ultraviolet photoelectron spectroscopy measurement, b) valence bulk, valence surface, and particle plasmon resonance energy calculations are performed, and each plasmon peak is indexed with corresponding plasmon energy peak of different nanoclusters, and c) spectroscopic ellipsometric measurement is deployed to verify plasmonic behavior by investigating different optical properties. Additionally, incorporation of the plasmonic feature along with alkali metals plays a crucial role in the improvement of the performance of solar cells. Therefore, plasmon enhanced NMZO as a backscattering layer in between CIGSe/back contact is probed to ascertain the additional benefits of 1) Na incorporation into the absorber layer as a result of the Na diffusion from the NMZO layer, and 2) improvement in the morphology of the CIGSe thin film with the incorporation of NMZO layer in between the back-contact and CIGSe. The diffusion of Na into the absorber layer is probed by deploying secondary ion mass spectroscopy measurements, and improvement in the morphology of CIGSe with the incorporation of NMZO layer between the back-contact/absorber is investigated using field-emission scanning electron microscope analysis.

Probing dynamic response to temperature changes in Berea Sandstone using acoustic time-of-flight and resonant ultrasound spectroscopy

In this study, through-transmission acoustic time-of-flight experiments and bulk resonance tracking were used to study the anomalous elastic behavior in Berea Sandstone with temperature cycling. Previously published results (Davis et al., 2016) using Resonant Ultrasound Spectroscopy (RUS) indicated that Berea Sandstone softens by as much as 10% when cooled from 205°C to 110°C. This result is in contrast to the behavior of most materials, which stiffen when cooled. The time-of-flight experiments confirmed the RUS results and revealed the need for additional analysis of this phenomenon. By tracking the location of resonant frequencies at each temperature step, the qualitative behavior of the sample was obtained without the need for a rigorous RUS analysis. The results from this analysis showed that Berea Sandstone has significant hysteretic behavior under temperature cycling. It was also revealed that the qualitative elastic behavior of Berea Sandstone is unchanged with increasing relaxation time from the thermal shock induced by rapid cooling of the sample.

Investigation of Dual-Ion Beam Sputter-Instigated Plasmon Generation in TCOs: A Case Study of GZO.

The use of the high free-electron concentration in heavily doped semiconductor enables the realization of plasmons. We report a novel approach to generate plasmons in Ga:ZnO (GZO) thin films in the wide spectral range of ∼1.87-10.04 eV. In the grown GZO thin films, dual-ion beam sputtering (DIBS) instigated plasmon is observed because of the formation of different metallic nanoclusters are reported. Moreover, formation of the nanoclusters and generation of plasmons are verified by field emission scanning electron microscope, electron energy loss spectra obtained by ultraviolet photoelectron spectroscopy, and spectroscopic ellipsometry analysis. Moreover, the calculation of valence bulk, valence surface, and particle plasmon resonance energies are performed, and indexing of each plasmon peaks with corresponding plasmon energy peak of the different nanoclusters is carried out. Further, the use of DIBS-instigated plasmon-enhanced GZO can be a novel mean to improve the performance of photovoltaic, photodetector, and sensing devices.

Pseudoknot Formation Seeds the Twister Ribozyme Cleavage Reaction Coordinate.

The twister RNA is a recently discovered nucleolytic ribozyme that is present in both bacteria and eukarya. While its biological role remains unclear, crystal structure analyses and biochemical approaches have revealed critical features of its catalytic mechanism. Here, we set out to explore dynamic aspects of twister RNA folding along the cleavage reaction coordinate. To do so, we have employed both bulk and single-molecule fluorescence resonance energy transfer (FRET) methods to investigate a set of twister RNAs with labels strategically positioned at communicating segments. The data reveal that folding of the central pseudoknot (T1), the most crucial structural determinant to promote cleavage, exhibits reversible opening and closing dynamics at physiological Mg2+ concentration. Uncoupled folding, in which T1 formation precedes structuring for closing of stem P1, was confirmed using pre-steady-state three-color smFRET experiments initiated by Mg2+ injection. This finding suggests that the folding path of twister RNA requires proper orientation of the substrate prior to T1 closure such that the U5-A6 cleavage site becomes embraced to achieve its cleavage competent conformation. We also find that the cleaved 3'-fragment retains its compacted pseudoknot fold, despite the absence of the phylogenetically conserved stem P1, rationalizing the poor turnover efficiency of the twister ribozyme.

Microwave permeability of stripe patterned FeCoN thin film

Magnetic stripe patterns are of great importance for microwave applications owing to their highly tunable microwave permeability by adjusting the geometrical dimensions. In this work, stripe patterned FeCoN films with 160nm thickness are fabricated by using standard UV photolithography. Their microwave permeability are investigated systematically via both experiment and micromagnetic simulation. The good agreement between experimental and simulation results suggests that stripe width is crucial for the microwave magnetic properties of the stripe pattern. It is demonstrated by simulation that with increasing stripe width from 1 to 80µm the initial permeability shows a continuous growth from about 8–322, whiles the resonance frequency drops dramatically from 18.7 to 3.1GHz at 4µm gap size. Smaller gap size would result in slightly increased initial permeability due to larger magnetic volume ratio, accompanied by decreased resonance frequency because of stronger magnetostatic interaction. Moreover, the experimental investigation on stripe length effect indicates that the stripe length should be kept as long as possible to achieve uniform bulk resonance mode and high permeability value. Insufficient stripe length would result in low frequency edge mode and decayed bulk mode. This study could provide valuable guidelines on the selection of proper geometry dimensions of FeCoN stripe patterns for high frequency applications.

Interband interaction between bulk and surface resonance bands of a Pb-adsorbed Ge(001) surface

We investigated the valence band structure of a Pb-adsorbed Ge(001) surface by angle-resolved photoelectron spectroscopy. Three Ge bands, G1, G2, and G3, were observed in a Ge(001) 2 × 1 clean surface. In addition to these three bands, a fourth band (R band) is found on the surface with 2 ML of Pb. The R band continuously appeared even when the surface superstructure was changed. The position of the R band does not depend on Pb coverage. These results indicate that the R band derives from Ge subsurface states, known as surface resonance states. Furthermore, the effective mass of G3 is significantly reduced when the R band exists. We found that this reduction of G3 effective mass was explained by the interaction of the G3 and R bands. Consequently, the surface resonance band is considered to penetrate into the Ge subsurface region affecting the Ge bulk states. We determine the hybridization energy to be 0.068 eV by fitting the observed bands.

Multiscale approach to (micro)porosity quantification in continental spring carbonate facies: Case study from the Cakmak quarry (Denizli, Turkey)

AbstractCarbonate spring deposits gained renewed interest as potential contributors to subsurface reservoirs and as continental archives of environmental changes. In contrast to their fabrics, petrophysical characteristics – and especially the importance of microporosity (< 1µm) – are less understood. This study presents the combination of advanced petrophysical and imaging techniques to investigate the pore network characteristics of three, common and widespread spring carbonate facies, as exposed in the Pleistocene Cakmak quarry (Denizli, Turkey): the extended Pond, the dipping crystalline Proximal Slope Facies and the draping Apron and Channel Facies deposits formed by encrustation of biological substrate. Integrating mercury injection capillary pressure, bulk and diffusion Nuclear Magnetic Resonance (NMR), NMR profiling and Brunauer–Emmett–Teller (BET) measurements with microscopy and micro‐computer tomography (µ‐CT), shows that NMR T2 distributions systematically display a single group of micro‐sized pore bodies, making up between 6 and 33% of the pore space (average NMR T2 cut‐off value: 62 ms). Micropore bodies are systematically located within cloudy crystal cores of granular and dendritic crystal textures in all facies. The investigated properties therefore do not reveal differences in micropore size or shape with respect to more or less biology‐associated facies. The pore network of the travertine facies is distinctive in terms of (i) the percentage of microporosity, (ii) the connectivity of micropores with meso‐ to macropores, and (ii) the degree of heterogeneity at micro‐ and macroscale. Results show that an approach involving different NMR experiments provided the most complete view on the 3‐D pore network especially when microporosity and connectivity are of interest.

Damping constant estimation in magnetoresistive readers

The damping constant is a key design parameter in magnetic reader design. Its value can be derived from bulk or sheet film ferromagnetic resonance (FMR) line width. However, dynamics of nanodevices is usually defined by presence of non-uniform modes. It triggers new damping mechanisms and produces stronger damping than expected from traditional FMR. This work proposes a device-level technique for damping evaluation, based on time-domain analysis of thermally excited stochastic oscillations. The signal is collected using a high bandwidth oscilloscope, by direct probing of a biased reader. Recorded waveforms may contain different noise signals, but free layer FMR is usually a dominating one. The autocorrelation function is a reflection of the damped oscillation curve, averaging out stochastic contributions. The damped oscillator formula is fitted to autocorrelation data, producing resonance frequency and damping constant values. Restricting lag range allows for mitigation of the impact of other phenomena (e.g., reader instability) on the damping constant. For a micromagnetically modeled reader, the technique proves to be much more accurate than the stochastic FMR line width approach. Application to actual reader waveforms yields a damping constant of ∼0.03.

An intermode-coupled thin-film micro-acoustic resonator

A novel concept for the development of thin-film micro-acoustic resonators based on the coupling between different plate acoustic modes is demonstrated. The basic principles for the design and fabrication of intermode-coupled plate acoustic wave resonators on c-textured thin aluminum nitride films are presented. More specifically, the lowest order symmetric S0 Lamb wave is excited and then coupled to the fundamental thickness shear bulk resonance by means of a metal strip grating with specific periodicity. The experimental results demonstrate that the grating-assisted intermode coupling can be employed in high-frequency resonators inheriting the low dispersive nature of the S0 mode in combination with the energy localization in the plate bulk typical for the fundamental thickness shear resonance.

Design and technology of micro-machined coplanar grounded wave-guides

Coplanar wave-guide grounded lines (CPWGs) with micro-machined via-holes have been designed, realised on high-resistivity silicon wafers, and tested up to 40 GHz. Several configurations, designed by changing the dimensions of the micro-machined via-holes used for the ground connection, as well as their number and separation, have been compared to get the best electrical matching conditions. Wide-band matching and suppression of bulk resonance peaks have been obtained within the 40 GHz range.

Modeling Fluorescence Observables, Particularly for FRET Experiments, using Markov Chain Analysis of Molecular Dynamics and Quantum Mechanics Simulations

We present a new method for simulating fluorescence observables, particularly those related to bulk and single-molecule fluorescence-detected resonance energy transfer (FRET) experiments. In this method, a molecular dynamics (MD) simulation is used to sample configuration space and quantum mechanics (QM) calculations are used to estimate the electronic coupling between the donor and acceptor probes for snapshots along the MD trajectory. A Markov chain method is used to sample the resulting electronic coupling trajectory allowing accurate simulation of any desired fluorescence observables, such as FRET efficiency histograms or time-resolved donor fluorescence decays. The Markov chain results will be compared with the results of simple histogram and averaging schemes showing that the Markov chain is the only one that yields realistic results in well known examples such as the rapid diffusion limit. This combination of computational methods also avoids some pitfalls of traditional FRET analysis such as the kappa-squared and the ideal dipole approximations. Because the simulation results can be compared directly with experimental observables, this method may allow more detail to be derived from experiment than is traditionally possible.