By minimizing free energy density, we show that the stellar core of a hydrogen burning star is not in a global thermodynamical equilibrium unless density, temperature, mass and composition assume given values. The core (as the solar interior) can more appropriately be viewed as a metastable state with very long lifetime. Slightly non-extensive distribution function could be the natural distribution for a weakly non-ideal plasma like a stellar core and represents a more appropriate approximation to this system than a Maxwellian distribution, without affecting bulk properties of stars.