Bulk Part Research Articles

Zr-Based Thin Film Metallic Glasses As High-Efficiency Materials for Electrocatalysis of the Hydrogen Evolution Reaction

The production of hydrogen through water electrolysis is a major limiting step in the implementation of hydrogen-based energy storage. Currently used materials for catalyzing the hydrogen evolution reaction require large overpotentials, reducing the efficiency of hydrogen production. Metallic glasses are of interest for use in electrocatalysis due to their high activity and diversity of catalytic sites. However, only a small selection of metallic glass compositions can be manufactured into bulk parts, necessitating the use of metallic glass coatings. In this research, a Zr-based metallic glass was produced as a thin film using sputtering deposition. Combinatorial co-sputtering was used to produce a library of quaternary Zr-based metallic glasses to enable high-throughput characterization of the anode material and electrochemical testing. Metallic glass surfaces were characterized prior to and after electrochemical testing using a range of techniques to explore the physiochemical properties of the catalytic surface. Nano-structured metallic glass coatings are a promising material for catalysis of the hydrogen evolution reaction. This work is funded by ARPA-e under DE-AR0001697. JRH is funded as a fellow under the NSF GRFP.

BRST covariant phase space and holographic Ward identities

This paper develops an enlarged BRST framework to treat the large gauge transformations of a given quantum field theory. It determines the associated infinitely many Noether charges stemming from a gauge fixed and BRST invariant Lagrangian, a result that cannot be obtained from Noether’s second theorem. The geometrical significance of this result is highlighted by the construction of a trigraded BRST covariant phase space, allowing a BRST invariant gauge fixing procedure. This provides an appropriate framework for determining the conserved BRST Noether current of the global BRST symmetry and the associated global Noether charges. The latter are found to be equivalent with the usual classical corner charges of large gauge transformations. It allows one to prove the gauge independence of their physical effects at the perturbative quantum level. In particular, the underlying BRST fundamental canonical relation provides the same graded symplectic brackets as in the classical covariant phase space. A unified Lagrangian Ward identity for small and large gauge transformations is built. It consistently decouples into a bulk part for small gauge transformations, which is the standard BRST-BV quantum master equation, and a boundary part for large gauge transformations. The boundary part provides a perturbation theory origin for the invariance of the Hamiltonian physical -matrix under asymptotic symmetries. Holographic anomalies for the boundary Ward identity are studied and found to be solutions of a codimension one Wess-Zumino consistency condition. Such solutions are studied in the context of extended BMS symmetry. Their existence clarifies the status of the 1-loop correction to the subleading soft graviton theorem.

Magnetization dynamics in single and trilayer nanowires

We have studied the magnetization dynamics of single Py(t) (t= 20 nm, 50 nm) and trilayer [Py(50)/Pd(tPd)/Py(20)] nanowire arrays fabricated over large areas using deep ultraviolet lithography technique. The dynamic properties are sensitive to the field orientation and magnetic film thicknesses. A single resonant mode corresponding to the excitations at the bulk part of the wire is detected in all the single-layer nanowire arrays. Furthermore, the spacer layer thickness influenced the dynamic properties in trilayer samples due to the different coupling mechanisms. A single resonant mode is observed intPd= 2 nm trilayer nanowires with a sharp frequency jump from 13 GHz to 15 GHz across the reversal regime. This indicates the exchange coupling and the coherence in magnetization precession in the ferromagnetic layers. On the other hand, wires with 10 nm-spacer display two well-resolved modes separated by ∼3 GHz with a gradual change in frequency across the reversal regime from-26mT to-46mT, indicating the presence of long-range dipolar interactions instead of exchange coupling. The spacer layer of the proposed spin-valve-type structure can be tailored for desired microwave splitters or combiners.

Sulfated Alginate for Biomedical Applications.

Alginate (Alg) polymers have received much attention due to the mild conditions required for gel formation and their good bio-acceptability. However, due to limited interactions with cells, many drugs, and biomolecules, chemically modified alginates are of great interest. Sulfated alginate (S-Alg) is a promising heparin-mimetic that continues to be investigated both as a drug molecule and as a component of biomaterials. Herein, the S-Alg literature of the past five years (2017-2023) is reviewed. Several methods used to synthesize S-Alg are described, with a focus on new advances in characterization and stereoselectivity. Material fabrication is another focus and spans bulk materials, particles, scaffolds, coatings, and part of multicomponent biomaterials. The new application of S-Alg as an antitumor agent is highlighted together with studies evaluating safety and biodistribution. The high binding affinity of S-Alg for various drugs and heparin-binding proteins is exploited extensively in biomaterial design to tune the encapsulation and release of these agents and this aspect is covered in detail. Recommondations include publishing key material properties to allow reproducibility, careful selection of appropriate sulfation strategies, the use of cross-linking strategies other than ionic cross-linking for material fabrication, and more detailed toxicity and biodistribution studies to inform future work.

Ultraviolet–Visible-Near InfraRed spectroscopy for assessing metal powder cross-contamination: A multivariate approach for a quantitative analysis

The last few years have seen an increasing use of spherical metals powders to produce bulk parts through metal forming technologies like Additive Manufacturing and Metal Injection Molding. This, coupled with the wide availability of metal powders, leads to a critical issue: contamination across different systems in different process steps. Consequently, it is necessary to find a new, fast, and reliable analysis sensible to tiny traces of contamination. This work evaluates the applicability of Ultraviolet–Visible-Near InfraRed (UV–Vis-NIR) spectroscopy, a technique providing information on powders’ reflectance, for studying contaminated powders. This work focuses on assessing 3 binary systems obtained from the cross-contamination of 3 components (A92618, C10200 and S31603) in a low contamination range (from 0.5 vol% to vol. 6%) and in a high contamination range (25 vol% and vol.50%). After the UV–Vis-NIR analysis, multivariate analysis has been used to obtain quantitative results. Results show that, as the contamination level increases in the binary system, the shape of spectra changes and becomes progressively more similar to the contaminant one. The chemometric analysis allows the detection of the contaminant type and its concentration percentage in the contaminated powder.

A review on mechanical alloying and spark plasma sintering of refractory high-entropy alloys: Challenges, microstructures, and mechanical behavior

Refractory high-entropy alloys (RHEAs) are promising candidates for those applications requiring of strong materials at high temperatures with elevated thermal stability and excellent oxidation, irradiation, and corrosion resistance. Particularly, RHEAs synthesized using mechanical alloying (MA) followed by spark plasma sintering (SPS) has proven to be a successful path to produce stronger alloys than those produced by casting techniques. This superior behavior, at both room and high temperature, can be attributed to the microstructural features resultant from this powder metallurgy route, that include the presence of homogeneously distributed non-metallic particles, fine- and ultrafine-grained microstructures, and higher content of interstitial solutes. Nevertheless, the powder metallurgy fabrication relies over a complex balance of several operational variables, and the process is no exempt of certain challenges, such as contamination or the presence of pores in the bulk parts. This review aims to cover all the peculiarities of the MA + SPS route, the resultant microstructures, their mechanical properties, and the strengthening and deformation mechanisms behind their superior performance, as well as a brief description of their oxidation resistance.

Interface Effect on the Out‐of‐Plane Spin‐Orbit Torque in the Ferromagnetic CoPt Single Layers

AbstractField‐free switching of a perpendicularly magnetized heavy metal/ferromagnetic metal bilayer or single alloy layer through spin‐orbit torque (SOT) provides a potential way for next‐generation spintronic devices with fast speed and high efficiency. Here, a sizable symmetry dependence of field‐free magnetization switching via an out‐of‐plane torque in CoxPt100−x single layers is reported. It is found that the sign of in‐plane SOT in CoxPt100−x when x ≤ 25 is positive. However, it changes to negative when x > 25, while the out‐of‐plane SOT changes its sign when x > 30. The polarized neutron reflectometry measurement further suggests an interface layer with rich Pt content near the substrate, which could have a strong interface effect on the out‐of‐plane SOT. The sign of the out‐of‐plane SOT, and then the polarity of the field‐free magnetization switching, is determined by the competition between the out‐of‐plane torques arising from the bulk and interface parts in the CoxPt100−x single layers. It is expected that such interface effect of the out‐of‐plane torque is desirable to the applications in spin logic devices using symmetry dependence of field‐free magnetization switching in the ferromagnetic CoPt single layers.

Additively manufactured β-Ti5553 with laser powder bed fusion: Microstructures and mechanical properties of bulk and lattice parts

Ti5553 (Ti-5Al-5Mo-5V-3Cr wt%) is a titanium alloy widely used for its high strength-to-weight ratio and good formability at elevated temperatures. Unlike Ti-6Al-4V, Ti5553 does not undergo martensitic transformation, preventing cracking of brittle martensite upon rapid cooling. This makes it a strong candidate for additive manufacturing (AM), particularly laser powder bed fusion (L-PBF). L-PBF offers the unique opportunity to make fine lattice structures to reduce component weight. Despite the growing field of AM, there have been limited studies on L-PBF Ti5553 lattices and how their properties differ from the bulk. The present work addresses this knowledge gap by investigating microstructures and properties of L-PBF bulk and lattice parts and the effect of post L-PBF heat treatments. Electron microscopy and mechanical testing show that the high dislocation density formed during L-PBF increases bulk part’s yield strength by approximately 100 MPa compared to the conventional alloy. Digital image correlation during compression testing of octet truss lattices reveals a layer-by-layer failure mode. Compared to the bulk, the lattice contains copious ω nanoprecipitation, weaker <001> texture, smaller average grain sizes, and larger content of high-angle grain boundaries. These features elicit differences in Taylor factor distributions for the lattice depending on load direction, underlining challenges in predicting lattice mechanical response based on bulk properties. By examining the processing-structure-property relationships in the bulk and lattice, the present results delineate their microstructural and mechanical differences and establish a benchmark for the future design applications of L-PBF Ti5553.

Dual material fused filament fabrication of composite core‐shell structures with improved impact resistance and interfacial adhesion

AbstractThe mechanical performance of parts produced by fused filament fabrication (FFF) has been limited due to the presence of voids and poor interlayer welding. Recent advancements in FFF have enabled the fabrication of void‐free objects with strong interlayer welding through the use of semicrystalline polymer shells such as high‐density polyethylene (HDPE) along with a high viscosity core polymer like acrylonitrile‐butadiene‐styrene (ABS). The zero‐shear viscosity (η0) of ABS is three orders of magnitude higher than HDPE making the ABS‐HDPE core‐shell configuration preferable. ABS holds the shape by preventing bulk flow and part bending while HDPE promotes full surface contact across the layers. Most polymers, however, are immiscible which causes a weak weld line along the core‐shell interface. Herein, maleic anhydride (MAH) is grafted to the butadiene segment of the ABS core thereby compatibilizing the interface with HDPE, improving the interfacial adhesion. Attenuated total reflectance‐Fourier transform infrared spectroscopy was employed to confirm successful grafting. Using a custom‐made die affording the core‐shell structure, the ABS‐g‐MAH is shown to improve the impact resistance by 253% and 16% compared to neat HDPE and ABS specimens, respectively. Additionally, a 10% increase compared to the unmodified ABS‐HDPE core‐shell configuration is observed.

Carrollian structure of the null boundary solution space

We study pure D dimensional Einstein gravity in spacetimes with a generic null boundary. We focus on the symplectic form of the solution phase space which comprises a 2D dimensional boundary part and a 2(D(D − 3)/2 + 1) dimensional bulk part. The symplectic form is the sum of the bulk and boundary parts, obtained through integration over a codimension 1 surface (null boundary) and a codimension 2 spatial section of it, respectively. Notably, while the total symplectic form is a closed 2-form over the solution phase space, neither the boundary nor the bulk symplectic forms are closed due to the symplectic flux of the bulk modes passing through the boundary. Furthermore, we demonstrate that the D(D − 3)/2 + 1 dimensional Lagrangian submanifold of the bulk part of the solution phase space has a Carrollian structure, with the metric on the D(D − 3)/2 dimensional part being the Wheeler-DeWitt metric, and the Carrollian kernel vector corresponding to the outgoing Robinson-Trautman gravitational wave solution.

The surface counter-terms of the ϕ44 theory on the half space R+×R3

In a previous work, we established perturbative renormalizability to all orders of the massive ϕ44-theory on a half-space also called the semi-infinite massive ϕ44-theory. Five counter-terms which are functions depending on the position in the space, were needed to make the theory finite. The aim of the present paper is to establish that for a particular choice of the renormalization conditions the effective action consists of a part which is independent of the boundary conditions (Dirichlet, Neumann and Robin) plus a boundary term in the case of the Robin and Neumann boundary conditions. The key idea of our method is the decomposition of the correlators into a bulk part, which is defined as the scalar field model on the full space R4 with a quartic interaction restricted to the half-space, plus a remainder which we call “the surface part.” We analyse this surface part and establish perturbatively that the ϕ44 theory in R+×R3 is made finite by adding the bulk counter-terms and two additional counter-terms to the bare interaction in the case of Robin and Neumann boundary conditions. These surface counter-terms are position independent and are proportional to ∫Sϕ2 and ∫Sϕ∂nϕ. For Dirichlet boundary conditions, we prove that no surface counter-terms are needed and the bulk counter-terms are sufficient to renormalize the connected amputated (Dirichlet) Schwinger functions. A key technical novelty as compared to our previous work is a proof that the power counting of the surface part of the correlators is better by one scaling dimension than their bulk counterparts.

Influence of ab initio derived site-dependent hopping parameters on electronic transport in graphene nanoribbons.

Graphene Nano Ribbons (GNRs) have been studied extensively due to their potential applications in electrical transport, optical devices, etc. The Tight Binding (TB) model is a common method used to theoretically study the properties of GNRs. However, the hopping parameters of two-dimensional graphene (2DG) are often used as the hopping parameters of the TB model of GNRs, which may lead to inaccuracies in the prediction of GNRs. In this work, we calculated the site-dependent hopping parameters from density functional theory and construction of Wannier orbitals for use in a realistic TB model. It has been found that due to the edge effect, the hopping parameters of edge C atoms are markedly different from the bulk part, which is prominently observed in narrow GNRs. Compared to graphene, the change of hopping parameter of edge C atoms of zigzag GNRs (ZGNRs) and armchair GNRs (AGNRs) is as high as 0.11 and 0.08 eV, respectively. Moreover, we investigated the impact of the calculated site-dependent (SD) hopping parameters on the electronic transport properties of GNRs in the absence and presence of the perpendicular electric field and dilute charged impurities using the Green function approach, Landauer-Büttiker formalism and self-consistent Born approximation. We find an electron-hole asymmetry in the electronic structure and transport properties of ZGNRs with SD hopping parameters. Furthermore, AGNRs with SD hopping energies show a band gap regardless of their width, while AGNRs with 2DG hopping parameters exhibit metallic or semiconductor phases depending on their width. In addition, electric field-induced 4-ZGNR with SD hopping parameters undergoes a metallic to n-doped semiconducting phase transition whereas for 4-ZGNR with 2DG hopping parameters and 8-AGNRs with 2DG or SD hopping parameters, the application of an electric field opens the band gap in both conduction and valence bands simultaneously. Our findings provide evidence for the electron-hole symmetry breaking in ZGNR with SD hopping parameters and make ZGNRs a suitable candidate in valleytronic devices.

Manufacture of zircon bulk parts and scaffolds by digital light processing

Zircon (ZrSiO4) is a low cost and widely available ceramic raw material used in thermal applications due to its low thermal conductivity and high thermal shock resistance. The aim of the present work was to obtain solid and reticular zircon pieces by digital light processing (DLP), scarcely reported in the literature. For this aim, the dispersion of zircon powders in two different solvents (benzyl alcohol and cyclohexanol) was studied using different UV-curable polymeric systems. The effect of different dispersant concentrations as well as different dispersion/homogenisation methods were evaluated by rheological characterisation. Bulk bodies and scaffolds were obtained by DLP, studying the effect of different printing parameters on the quality and resolution of the produced parts. Debinding and sintering steps were optimised using different thermal cycles. Dense zircon scaffolds (>96%TD) were obtained from the cyclohexanol based slurries. Finally, the obtained materials were characterised in terms of crystallographic composition and microstructure.

Effect of Plasma Treatment on the Luminescent and Scintillation Properties of Thick ZnO Films Fabricated by Sputtering of a Hot Ceramic Target

The paper presents the results of a comprehensive study of the structural-phase composition, morphology, optical, luminescent, and scintillation characteristics of thick ZnO films fabricated by magnetron sputtering. By using a hot ceramic target, extremely rapid growth (~50 µm/h) of ZnO microfilms more than 100 µm thick was performed, which is an advantage for the industrial production of scintillation detectors. The effects of post-growth treatment of the fabricated films in low-temperature plasma were studied and a significant improvement in their crystalline and optical quality was shown. As a result, the films exhibit intense near-band-edge luminescence in the near-UV region with a decay time of &lt;1 ns. Plasma treatment also allowed to significantly weaken the visible defect luminescence excited in the near-surface regions of the films. A study of the luminescence mechanisms in the synthesized films revealed that their near-band-edge emission at room temperature is formed by phonon replicas of free exciton recombination emission. Particularly, the first phonon replica plays the main role in the case of optical excitation, while upon X-ray excitation, the second phonon replica dominates. It was also shown that the green band peaking at ~510 nm (2.43 eV) is due to surface emission centers, while longer wavelength (&gt;550 nm) green-yellow emission originates mainly from bulk parts of the films.

Improvement of mechanical, biological, and electrochemical properties of Ti6Al4V alloy modified with Nb and Ag for biomedical applications

This study aims to evaluate the mechanical and biological properties of a spark plasma-sintered (SPS) Ti6Al4V alloy modified with 5 and 10 wt% niobium (Nb) together with 2 wt% Ag. Five batches of Ti6Al4V, Ti6Al4V-5 Nb, Ti6Al4V-10 Nb, Ti6Al4V-5 Nb-2Ag, and Ti6Al4V-10 Nb-2Ag were sintered using SPS at 1400 °C for 5 min. X-ray diffraction (XRD) analysis was used to identify the phases of the specimens. Scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and X-ray mapping analyses were also utilized to study the powder morphology, microstructure, and fractured surfaces of the samples. Three-point flexural strength and Vickers microhardness tests were performed and the fracture toughness (K1 C) was calculated subsequently. The bulk parts showed a very high building density, which means that the plasma sintering parameters were optimal. X-ray diffraction (XRD) analysis confirmed the existence of alpha and beta phases by adding niobium and silver. Potentiodynamic, electrochemical impedance spectroscopy, MTT assay, and antibacterial tests were also conducted to evaluate the biological properties of the sintered samples. The maximum values of flexural strength and K1 C were obtained for Ti6Al4V-5 Nb samples up to 1943 ± 12 MPa and 63 ± 1.1 MPa.m0.5, respectively. The hardness values of samples showed no significant difference by adding Nb and Ag. The samples containing Nb exhibit a lower passive current density compared to the pure Ti6Al4V alloy, suggesting that the addition of Nb positively influences corrosion resistance. According to the results of the antibacterial test, Nb slightly deteriorated the antibacterial properties, while after adding Ag, this property improved. The results of the MTT assay revealed that adding niobium and silver had no toxic effect on the samples.

In situ observation of melt pool evolution in ultrasonic vibration-assisted directed energy deposition

The presence of defects, such as pores, in materials processed using additive manufacturing represents a challenge during the manufacturing of many engineering components. Recently, ultrasonic vibration-assisted (UV-A) directed energy deposition (DED) has been shown to reduce porosity, promote grain refinement, and enhance mechanical performance in metal components. Whereas it is evident that the formation of such microstructural features is affected by the melt pool behavior, the specific mechanisms by which ultrasonic vibration (UV) influences the melt pool remain elusive. In the present investigation, UV was applied in situ to DED of 316L stainless steel single tracks and bulk parts. For the first time, high-speed video imaging and thermal imaging were implemented in situ to quantitatively correlate the application of UV to melt pool evolution in DED. Extensive imaging data were coupled with in-depth microstructural characterization to develop a statistically robust dataset describing the observed phenomena. Our findings show that UV increases the melt pool peak temperature and dimensions, while improving the wettability of injected particles with the melt pool surface and reducing particle residence time. Near the substrate, we observe that UV results in a 92% decrease in porosity, and a 54% decrease in dendritic arm spacing. The effect of UV on the melt pool is caused by the combined mechanisms of acoustic cavitation, ultrasound absorption, and acoustic streaming. Through in situ imaging we demonstrate quantitatively that these phenomena, acting simultaneously, effectively diminish with increasing build height and size due to acoustic attenuation, consequently decreasing the positive effect of implementing UV-A DED. Thus, this research provides valuable insight into the value of in situ imaging, as well as the effects of UV on DED melt pool dynamics, the stochastic interactions between the melt pool and incoming powder particles, and the limitations of build geometry on the UV-A DED technique.

Storage requirements to mitigate intermittent renewable energy sources: analysis for the US Northeast

Moving away from fossil fuels is essential for a sustainable future. Carrying out this transition without reversing the improvements in the quality of life is the ultimate challenge. While minimizing the anticipated impacts of climate change is the primary driver of decarbonization, the inevitable exhaustion of fossil energy sources should provide just as strong or perhaps even stronger incentives. The vast majority of publications outlining the pathways to “net-zero carbon emission” fall short from leading to a truly “fossil fuel-free” future without falling back to some level of dependence on fossil fuels with carbon capture and sequestration. While carbon capture and sequestration might be a necessary step toward decarbonization, such intermediate goals might turn into a dead end without defining the end point. The main obstacle to wider adoption of renewable energy resources is their inherent intermittency. Solar and wind are, by far, the most abundant renewable energy sources that are expected to take the lion share in transitioning to a sustainable future. Intermittency arises at multiple levels. The most recognized are the short-term (minute-by-minute, hourly, or diurnal) variations that should be the easiest to address. Less frequently realized are the seasonal and inter-annual variabilities. Seasonality poses far greater challenges than minute-by-minute or hourly variations because they lead to the absence of energy resources for prolonged periods of time. Our interest is the feasibility of a future where all energy (100%) comes from renewable sources leaving no room for fossil fuels. We carry out rudimentary statistical analyses of solar radiation and wind speed time series records to quantify the degree of their intermittencies seasonally and inter-annually. We employ a simple but robust accounting of the shortfalls when the supplies do not meet demand via a modified cumulative supply/deficit analysis that incorporates energy losses arising from transporting excess energy to storage and retrieving it as needed. The presented analysis provides guidance for choosing between the installation of excess capacity or the deployment of energy storage to guarantee reliable energy services under the assumption that the energy system is powered exclusively by renewable energy sources. This paper examines the seasonal and inter-annual variability of hydropower and biofuel resources to estimate their potential to mitigate the intermittencies of solar and wind resources. The presented analyses are meant to provide crude, bulk part estimates and are not intended for planning or operational purposes of the actual energy infrastructures. The primary focus of this paper is the Northeast region of the United States using the conterminous United States as a reference to assess the viability of reducing the energy storage need in the study region via improved connectivity to the national grid. This paper builds on the modeling exercises carried out as part of the climate-induced extremes on food, energy, water systems studies.

Enhancing Mechanical and Biocorrosion Response of a MgZnCa Bulk Metallic Glass through Variation in Spark Plasma Sintering Time

Development of metallic glasses is hindered by the difficulties in manufacturing bulk parts large enough for practical applications. Spark plasma sintering (SPS) has emerged as an effective consolidation technique in the formation of bulk metallic glasses (BMGs) from melt-spun ribbons. In this study, Mg65Zn30Ca5 melt-spun ribbons were sintered at prolonged sintering times (15 min to 180 min) via SPS under a pressure of 90 MPa and at a temperature of 150 °C (which is below the crystallization temperature), to provide an insight into the influence of sintering time on the consolidation, structural, and biodegradation behavior of Mg-BMGs. Scanning Electron Microscopy was used to characterize the microstructure of the surface, while the presence of the amorphous phase was characterized using X-ray diffraction and Electron Backscatter Diffraction. Pellets 10 mm in diameter and height with near-net amorphous structure were synthesized at 150 °C with a sintering time of 90 min, resulting in densification as high as 98.2% with minimal crystallization. Sintering at extended durations above 90 min achieved higher densification and resulted in a significant amount of local and partial devitrification. Mechanical properties were characterized via compression and microhardness testing. Compression results show that increased sintering time led to better structural integrity and mechanical properties. Notably, SPS150_90 displayed ultimate compressive strength (220 MPa) that matches that of the cortical bone (205 MPa). Corrosion properties were characterized via potentiodynamic polarization with Phosphate Buffered Solution (PBS). The results suggest that the sintered samples have significantly better corrosion resistance compared to the crystalline form. Overall, SPS150_90 was observed to have a good balance between corrosion properties (10× better corrosion resistance to as-cast alloy) and mechanical properties.

Black hole horizon edge partition functions

We extend a formula for 1-loop black hole determinants by Denef, Hartnoll, and Sachdev (DHS) to spinning fields on any (d + 1)-dimensional static spherically symmetric black hole. By carefully analyzing the regularity condition imposed on the Euclidean eigenfunctions, we reveal an unambiguous bulk-edge split in the 1-loop Euclidean partition function for tensor fields of arbitrary integer spin: the bulk part captures the “renormalized” thermal canonical partition function recently discussed in [1]; the edge part is related to quasinormal modes (QNMs) that fail to analytically continue to a subset of Euclidean modes with enhanced fall-offs near the origin. Since the edge part takes the form of a path integral on Sd−1, this suggests that these are associated with degrees of freedom living on the bifurcation surface in the Lorentzian two-sided black hole geometry. For massive higher spin on static BTZ and massive vector on Nariai black holes, we find that the edge partition function is related to the QNMs with lowest overtone numbers.

Nanoparticle Assembly at the Water-Oil Interface Induced by Spontaneous Emulsification for Microdroplet Immunoassay.

Micron-sized water-in-oil droplets (microdroplets) have been used for various biochemical analyses. Many studies have been reported on immunoassays using microdroplets because of their high versatility. A selective enrichment method using spontaneous emulsification was developed as a pretreatment method for analytical systems of microdroplets. In this study, a one-step immunoassay for microdroplets using nanoparticle assembly at the interface by spontaneous emulsification is proposed. At the interface of the microdroplet, with aqueous nanoparticle dispersion, it was found that nanoparticles with diameters less than 50 nm were uniformly adsorbed to the microdroplet interface as a Pickering emulsion, whereas larger nanoparticles tended to aggregate in the bulk part of the microdroplet. Based on this phenomenon, a proof of concept of the one-step immunoassay was demonstrated using rabbit IgG as the analyte. This method is expected to be a powerful tool for trace biochemical analyses.