Bulk Nanostructures Research Articles

Nanochannels in Fused Silica through NaOH Etching Assisted by Femtosecond Laser Irradiation

Sodium hydroxide (NaOH) is increasingly drawing attention as a highly selective etchant for femtosecond laser-modified fused silica. Unprecedented etching contrasts between the irradiated and pristine areas have enabled the fabrication of hollow, high-aspect-ratio structures in the bulk of the material, overcoming the micrometer threshold as the minimum feature size. In this work, we systematically study the effect of NaOH solutions under different etching conditions (etchant concentration, temperature, and etching time) on the tracks created by tightly focused femtosecond laser pulses to assess the best practices for the fabrication of hollow nanostructures in bulk fused silica.

Green synthesized extracts/Au complex of Phyllospongia lamellosa: Unrevealing the anti-cancer and anti-bacterial potentialities, supported by metabolomics and molecular modeling

The anti-cancer and anti-bacterial potential of the Red Sea sponge Phyllospongia lamellosa in its bulk (crude extracts) and gold nanostructure (loaded on gold nanaoparticles) were investigated. Metabolomics analysis was conducted, and subsequently, molecular modeling studies were conducted to explore and anticipate the P. lamellosa secondary metabolites and their potential target for their various bioactivities. The chloroformic extract (CE) and ethyl acetate extract (EE) of the P. lamellosa predicted to include bioactive lipophilic and moderately polar metabolites, respectively, were used to synthesize gold nanoparticles (AuNPs). The prepared AuNPs were characterized through transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), and UV–vis spectrophotometric analyses. The cytotoxic activities were tested against MCF-7, MDB-231, and MCF-10A. Moreover, the anti-bacterial, antifungal, and anti-biofilm activity were assessed. Definite classes of metabolites were identified in CE (terpenoids) and EE (brominated phenyl ethers and sulfated fatty amides). Molecular modeling involving docking and molecular dynamics identified Protein-tyrosine phosphatase 1B (PTP1B) as a potential target for the anti-cancer activities of terpenoids. Moreover, CE exhibited the most powerful activity against breast cancer cell lines, matching our molecular modeling study. On the other hand, only EE was demonstrated to possess powerful anti-bacterial and anti-biofilm activity against Escherichia coli. In conclusion, depending on their bioactive metabolites, P. lamellosa-derived extracts, after being loaded on AuNPs, could be considered anti-cancer, anti-bacterial, and anti-biofilm bioactive products. Future work should be completed to produce drug leads.

Bulk Nanostructure of Mixtures of Choline Arginate, Choline Lysinate, and Water.

Neutron diffraction with empirical potential structure refinement was used to investigate the bulk liquid nanostructure of mixtures of choline arginate (Ch[Arg]), choline lysinate (Ch[Lys]), and water at mole ratios of 1Ch[Arg]:1Ch[Lys]:6H2O (balanced), 1Ch[Arg]:1Ch[Lys]:20H2O (balanced dilute), 3Ch[Arg]:1Ch[Lys]:12H2O (Arg- rich), and 1Ch[Arg]:3Ch[Lys]:12H2O (Lys- rich). The Arg- and Lys- anions tend not to associate due to electrostatic repulsion between charge groups and weak anion-anion attractions. This means that the local ion structures around the anions in these mixtures resemble the parent single-component systems. The bulk liquid nanostructure varies with the Arg-:Lys- ratio. In the Lys--rich mixture (1Ch[Arg]:3Ch[Lys]:12H2O), Lys- side chains cluster into a continuous apolar domain separated from a charged domain of polar groups. In the balanced mixture (1Ch[Arg]:1Ch[Lys]:6H2O), Lys- side chains form discrete apolar aggregates within a continuous polar domain of Arg-, Ch+, and water, and in the Arg--rich mixture (3Ch[Arg]:1Ch[Lys]:12H2O), the distribution of Lys- and Arg- is nearly homogeneous. Finally, in the balance dilute system (1Ch[Arg]:1Ch[Lys]:20H2O), a percolating water domain forms.

Small-Angle X-ray Scattering Study of the Amphiphilic Bulk Nanostructure of Tetraalkylammonium Deep Eutectic Solvents.

Deep eutectic solvents (DESs) are low-melting mixtures, often prepared from a salt and a molecular hydrogen bond donor. Like ionic liquids, DESs that contain at least one sufficiently amphiphilic component can form bicontinuous nanostructures consisting of polar and nonpolar domains, although this has not been widely explored for many DES combinations. Here, the bulk nanostructures of DESs comprising tetraalkylammonium bromide salts (tetrabutylammonium bromide, tetraoctylammonium bromide, and methyltrioctylammonium bromide) with alkanols and alkanoic acids of systematically varied chain lengths (C2, C6, C8, and C10) as hydrogen bond donors have been studied. Small-angle X-ray scattering techniques were used to identify the relationship between the alkyl chain length and functionality of the hydrogen bond donor on the nature of the amphiphilic nanostructures formed. These findings demonstrated that the amphiphilic nanostructures of the DESs were not affected by the functional group on the hydrogen bond donor, with these nanostructures influenced primarily by both the absolute and relative alkyl chain lengths of the salt and hydrogen bond donor.

Enhanced Light-Matter Interaction in Metallic Nanoparticles: A Generic Strategy of Smart Void Filling.

The intrinsic properties of materials play a substantial role in light-matter interactions, impacting both bulk metals and nanostructures. While plasmonic nanostructures exhibit strong interactions with photons via plasmon resonances, achieving efficient light absorption/scattering in other transition metals remains a challenge, impeding various applications related to optoelectronics, chemistry, and energy harvesting. Here, we propose a universal strategy to enhance light-matter interaction, through introducing voids onto the surface of metallic nanoparticles. This strategy spans nine metals including those traditionally considered optically inactive. The absorption cross section of void-filled nanoparticles surpasses the value of plasmonic (Ag/Au) counterparts with tunable resonance peaks across a broad spectral range. Notably, this enhancement is achieved under arbitrary polarizations and varied particle sizes and in the presence of geometric disorder, highlighting the universal adaptability. Our strategy holds promise for inspiring emerging devices in photocatalysis, bioimaging, optical sensing, and beyond, particularly when metals other than gold or silver are preferred.

Modulating Polarization in Second Harmonic Generation through Symmetry Evolution in Plasmonic Lattices.

We report a strategy for preparing cost-effective plasmonic square lattices with tunable unit structures of circles, crosses, and circle-cross pairs on a centimeter scale. The asymmetrical electromagnetic (EM) field distribution of the lattice enhances second harmonic generation (SHG) under oblique incidence. The SHG signals are progressively strengthened as the unit symmetry decreases from C∞v (circle) to C4v (cross) to C2v (circle-cross pair). The peak SHG signal is observed from the plasmonic lattice with a circle-cross pair, showcasing a conversion efficiency of 1.0 × 10-2, which is a 7.3-fold enhancement relative to the dielectric lattice comprised of circle units. This notably high conversion efficiency of SHG is on par with that of phase-matched bulk nanostructures under normal incidence, benefiting from the Bloch-surface plasmon polariton (Bloch-SPP) modes associated with the distribution of the photonic local density of states (LDOS). Furthermore, the SHG emission exhibits distinctive directional and polarization characteristics as the unit symmetry is reduced. This work offers valuable insights into a structural symmetry-dependent SHG in plasmonic lattices and the way forward for the design of functional nonlinear plasmonic devices.

Shock-induced plastic deformation of nanopowder Ti during consolidation and spallation.

Consolidating nanopowder metals via impact loading is a potentially significant method for synthesizing and processing bulk nanocrystalline materials. However, until now, the microstructural features, plastic deformation during consolidation, and corresponding mechanisms have been seldom revealed. Using molecular dynamics (MD) simulations, we have studied the plastic deformation, densification, spallation, and micro-jetting in nanopowder titanium (np-Ti) during shock. Upon impact, np-Ti undergoes a transition from heterogeneous plasticity, including basal stacking faults (SFs) and {101̄2} twinning, to homogeneous disordering, as the impact velocity increases. Then the nanopowder structure evolves into a bulk nanostructure after the final densification, contributed by pore collapse. The subsequent detwinning arises during the release and tension stage, conducing to a partial structural recovery. When the impact velocity up ≥ 1.0 km s-1, the spallation is following, prompted via GB-sliding and disordering. Upon shock impact, it also facilitates micro-jetting owing to the presence of nanopores, contributing to the pressure gradient and transverse velocity gradient.

Self-Assembly of Discrete Oligomers of Naphthalenediimides in Bulk and on Surfaces.

Here, we report on the synthesis of discrete oligomers of alkyl-bridged naphthalenediimides (NDIs) and study their molecular nanostructures both in bulk, in solution, and at the liquid-solid interface. Via an iterative synthesis method, multiple NDI cores were bridged with short and saturated alkyl-diamines (C3 and C12 ) or long and unsaturated alkyl-diamines (u2 C33 to u8 C100 ) at their imide termini. The strong intermolecular interaction between the NDI cores was observed by probing their photophysical properties in solution. In bulk, the discrete NDI oligomers preferentially ordered in lamellar morphologies, irrespective of whether a saturated or unsaturated spacer was employed. Moreover, both the molecular architecture as well as the crystallization conditions play a significant role in the nanoscale ordering. The long unsaturated alkyl chains lead preferably to folded-chain conformations while their saturated analogues form stretched arrangements. At the solution-solid interface, well-defined lamellar regions were observed. These results show that precision in chemical structure alone is not sufficient to reach well-defined structures of discrete oligomers, but that it must be combined with precision in processing conditions.

Multi‐Dimensional Shingled Optical Recording by Nanostructuring in Glass

AbstractIn the digital era, the need for high‐density data storage techniques has become increasingly imperative. To address this, the study has demonstrated a multi‐dimensional shingled optical recording technique, utilizing femtosecond laser‐induced nanostructures in silica glass. The evolution of the bulk nanostructures is investigated on a pulse‐by‐pulse basis using multiple microscopic analysis techniques. The formation of the nanostructures is attributed to a self‐adaptive near‐field anisotropic nanostructuring process. Furthermore, it is shown that writing in a 3D shingled configuration significantly reduces the volume per data voxel to a size of 500 nm × 500 nm × 1.0 µm, surpassing the diffraction limit. This reduction is achieved even when employing an infrared laser and a relatively low numerical aperture objective lens. As a result, the approach increases the data storage capacity by at least two orders of magnitude compared to conventional techniques. The work paves the way for advanced shingled optical recording techniques offering ultra‐dense capacity, ultra‐long lifetime, and low energy consumption.

Phase behaviour and aggregate structures of the surface-active ionic liquid [BMIm][AOT] in water

HypothesisThe surface-active ionic liquid, 1-butyl-3-methylimidazolium 1,4-bis-2-ethylhexylsulfosuccinate ([BMIm][AOT]), has a sponge-like bulk nanostructure consisting of percolating polar and apolar domains formed by the ion charge groups and alkyl chains, respectively. We hypothesise that added water will swell the polar domains and change the liquid nanostructure. ExperimentsSmall angle X-ray scattering (SAXS), small angle neutron scattering (SANS) and polarizing optical microscopy (POM) were used to investigate the nanostructure of [BMIm][AOT] as a function of water content. Differential scanning calorimetry (DSC) was employed to probe the thermal transitions of [BMIm][AOT]-water mixtures and the mobility of water molecules. FindingsSAXS, SANS and POM show that at lower water contents, [BMIm][AOT]-water mixtures have a sponge-like nanostructure similar to the pure SAIL, at medium water contents a lamellar phase forms, and at high water contents vesicles form. DSC results reveal that water molecules are supercooled in the lamellar phase. For the first time, results reveal a series of transitions from inverse sponge, to lamellar then to vesicles, for [BMIm][AOT] upon dilution with water.

Impedance spectroscopy and conduction mechanism analysis of bulk nanostructure Prussian blue pellets

The structure and morphology of the fabricated Prussian Blue (PB) pellets are examined using FTIR, XPS, XRD and FESEM techniques. The morphology of the crystalline Prussian blue (PB) revealed a nanostructure with an average crystallite size of 91 nm. The frequency (42 Hz–1 MHz) and temperature (303–393K) of the Prussian Blue (PB) in Bulk form are dependent. In the medium region (1 kHz–100 kHz), the electric dipoles relax and start to lag the applied ac electric field signal and the estimated activation energy of 0.247 eV. The investigated Nyquist plots (Z″ versus Z′) of the Prussian Blue (PB) samples at different temperatures (303–393 K) are interpreted by an equivalent parallel RgCg circuit. The bulk resistance of Prussian Blue samples was estimated at various temperatures, and its behaviour exhibited temperature dependence; generally, it follows the Nearest Neighbor Hopping (NNH) model. According to Meyer–Neldel rule, the calculated activation energy is 0.565 ± 0.001 eV. The evidence of localized states is investigated, and its density, N(EF) ∼ 5.47 × 1018 eV−1 cm−3. The ac conductivity, σac, merges into a plateau of two parts: the first is a frequency-independent dc conductivity, σdc, which is strongly temperature-dependent. The rest of the plateau at higher frequencies showed the temperature-insensitive ac conductivity obeying Jonscher's power law. The values of the exponent s were investigated to figure out the intimate conduction mechanism in Prussian Blue (PB) samples; it follows the correlated barrier hopping (CBH) theoretical model. The hopping distance and energy have values ∼ unity and ≥ kBT, respectively. The experimental results revealed a linear relationship between hopping distance and energy against temperature, with the first decreasing and the second increasing linearly.

Hofmeister effects influence bulk nanostructure in a protic ionic liquid

HypothesisThe origins and behaviour of specific ion effects have been studied in water for more than a century, and more recently in nonaqueous molecular solvents. However, the impacts of specific ion effects on more complex solvents such as nanostructured ionic liquids remains unclear. Here, we hypothesise that the influence of dissolved ions on the hydrogen bonding in the nanostructured ionic liquid propylammonium nitrate (PAN) constitutes a specific ion effect. ExperimentsWe performed molecular dynamics simulations of bulk PAN and 1–50 mol% PAN-PAX (X = halide anions F−, Cl−, Br−, I−) and PAN-YNO3 (Y = alkali metal cations, Li+, Na+, K+ and Rb+) solutions to investigate how monovalent salts influence the bulk nanostructure in PAN. FindingsThe key structural characteristic in PAN is a well-defined hydrogen bond network formed within the polar and non-polar domains in its nanostructure. We show that dissolved alkali metal cations and halide anions have significant and unique influences on the strength of this network. Cations (Li+, Na+, K+ and Rb+) consistently promote hydrogen bonding in the PAN polar domain. Conversely, the influence of halide anions (F−, Cl−, Br−, I−) is ion specific; while F− disrupts PAN hydrogen bonding, I− promotes it. The manipulation of PAN hydrogen bonding therefore constitutes a specific ion effect – i.e. a physicochemical phenomena caused by the presence of dissolved ions, which are dependent on these ions’ identity. We analyse these results using a recently proposed predictor of specific ion effects developed for molecular solvents, and show that it is also capable of rationalising specific ion effects in the more complex solvent environment of an ionic liquid.

Effect of ion structure on the nanostructure and electrochemistry of surface active ionic liquids.

The ion structure of surface active ionic liquids (SAILs), i.e. ion charge group and alkyl chain structure, controls their bulk and interfacial nanostructure and the electrochemical properties near an electrode. The structures in the bulk and at the interface were investigated by small and wide-angle X-ray scattering (SAXS) and atomic force microscopy (AFM), respectively. An investigation was performed using cyclic voltammetry. All SAILs show pronounced sponge-like bulk nanostructure. For the first time, the bulk nanostructures of SAILs are found to change from anion bilayer structures to cation-anion interdigitated structures as the ion structures change from short alkyl chain cations and linear alkyl chain anions to long alkyl chain cations and branched alkyl chain anions. The bulk nanostructure packs more compactly at a higher temperature, likely due to the conformational change and enhanced interdigitations of alkyl chains. The thicknesses of SAIL interfacial layers align with the repeat distances of the bulk nanostructure, similar to conventional ILs with long cation alkyl chains. All SAILs have wide electrochemical windows >4V, which are not affected by the alkyl chain structure and cation charge groups.

Bulk nanostructure of a deep eutectic solvent with an amphiphilic hydrogen bond donor.

Neutron diffraction with empirical potential structure refinement (EPSR) show the deep eutectic solvent (DES) 1 : 4 choline chloride : butyric acid is amphiphilically nanostructured. Nanostructure results from solvophobic interactions between the alkyl chains of the butyric acid hydrogen bond donor (HBD) and is retained with addition of 10 wt% water. EPSR fits to the diffraction data is used to produce a three-dimensional model of the liquid which is interrogated to reveal the interactions leading to the solvophobic effect, and therefore nanostructure, in this DES at atomic resolution. The model shows electrostatic and hydrogen bond interactions cause the cation, anion and HBD acid group to cluster into a polar domain, from which the acid alkyl chains are solvophobically excluded into theapolar domain. The polar and apolar domains percolate through the liquid in a bicontinuous sponge-like structure. The effect of adding 10 wt% water is probed, revealing that water molecules are sequestered around the cation and anion within the polar domain, while the neat bulk structure is retained. Alkyl chain packing in the apolar domain becomes slightly better-defined indicating water marginally strengthens solvophobic segregation. These findings reveal bulk self-assembled nanostructure can be produced in DESs via an amphiphilic HBD.

Geometry-Modulated Self-Assembly Structures of Covalent Polyoxometalate–Polymer Hybrid in Bulk and Thin-Film States

This work reports the synthesis, characterization, and self-assembled structures of three series of Keggin-type polyoxometalate (POM)-based hybrid molecules KPOM-mPSn (m = 1, 2 and 3), in which one, two, or three polystyrene (PS) chains are covalently attached to a POM head, respectively. The classical “click” reaction was applied to prepare samples with predesigned molecular geometry, which were further purified by C18 reversed-phase high-performance liquid chromatography (RP-HPLC). Strong chemical incompatibility between inorganic POMs and organic PS chains drives the hybrid molecules to microphase separate into versatile nanostructures in both bulk and thin-film states. In thermally annealed bulk samples, four phase morphologies were found depending on both the overall molecular geometry and the volume fractions of PS tails, including lamellae (LAM), hexagonal packed cylinders (HEX), disordered micelles (DM), and body-centered cubic (BCC) packed spheres, as revealed by small-angle X-ray scattering (SAXS). In the thin-film state, LAM, HEX, and BCC structures were observed and proved by transmission electron microscopy (TEM) images and grazing incidence SAXS (GISAXS). This work expands the scope of self-assembled nanostructures of POM-based hybrid materials to spherical phases and provides a platform for the study of the basic physical principles of their self-assembly behavior.

Tailored Solid-State Carbohydrate Nanostructures Based on Star-Shaped Discrete Block Co-Oligomers.

Carbohydrates are key building blocks for advanced functional materials owing to their biological functions and unique material properties. Here, we propose a star-shaped discrete block co-oligomer (BCO) platform to access carbohydrate nanostructures in bulk and thin-film states via the microphase separation of immiscible carbohydrate and hydrophobic blocks (maltooligosaccharides with 1-4 glucose units and solanesol, respectively). BCOs with various star-shaped architectures and saccharide volume fractions were synthesized using a modular approach. In the bulk, the BCOs self-assembled into common lamellar, cylindrical, and spherical carbohydrate microdomains as well as double gyroid, hexagonally perforated lamellar, and Fddd network morphologies with domain spacings of ∼7 nm. In thin films, long-range-ordered periodic carbohydrate microdomains were fabricated via spin coating. Such controlled spatial arrangements of functional carbohydrate moieties on the nanoscale have great application potential in biomedical and nanofabrication fields.

Sustainable Hydrogen Production Using Group‐10 Metal Chalcogenides as Low‐Cost Effective Electrocatalysts

AbstractClean hydrogen production is crucial to the prospects of the energy transition. Electrochemical water splitting is one of the most promising tools for the sustainable and efficient production of hydrogen. One of the main open challenges is the replacement of precious Pt for electrodes with new materials combining cheapness, robustness to CO poisoning, and fast reaction kinetics. Group‐10 metal chalcogenides represent suitable candidates to address all main open challenges in the quest for alternative materials to pure Pt as electrocatalysts, with the further advantage of the ease of their synthesis as both bulk crystals and nanostructures. All compounds of this class of materials show surface stability, chemical inertness toward CO adsorption, and electrode durability in acidic and alkaline environments. Here, the physicochemical mechanisms ruling hydrogen production with group‐10 metal chalcogenides are focused on by combining surface‐science experiments and theory. Especially, the Tafel slope in Pt3Te4 nanocrystals and NiTe2 nanotubes is as low as 32 and 59 mV dec−1, respectively, making them competitive with state‐of‐the‐art reference materials Pt and Pt/C already in the first implementation. Moreover, the presence of massless Dirac‐cone electrons in many group‐10 metal chalcogenides, with an intrinsically large electron mobility, is naturally beneficial for fast electron transfer, and correspondingly, for fast reaction kinetics. These results pave the way for the advent of this new class of materials in electrocatalysis, and for sustainable hydrogen production through water splitting.

Bulk and interfacial nanostructure and properties in deep eutectic solvents: Current perspectives and future directions

Deep eutectic solvents (DESs) are a tailorable class of solvents that are rapidly gaining scientific and industrial interest. This is because they are distinct from conventional molecular solvents, inherently tuneable via careful selection of constituents, and possess many attractive properties for applications, including catalysis, chemical extraction, reaction media, novel lubricants, materials chemistry, and electrochemistry. DESs are a class of solvents composed solely of hydrogen bond donors and acceptors with a melting point lower than the individual components and are often fluidic at room temperature. A unique feature of DESs is that they possess distinct bulk liquid and interfacial nanostructure, which results from intra- and inter-molecular interactions, including coulomb forces, hydrogen bonding, van der Waals interactions, electrostatics, dispersion forces, and apolar-polar segregation. This nanostructure manifests as preferential spatial arrangements of the different species, and exists over several length scales, from molecular- to nano- and meso-scales. The physicochemical properties of DESs are dictated by structure–property relationships; however, there is a significant gap in our understanding of the underlying factors which govern their solvent properties. This is a major limitation of DES-based technologies, as nanostructure can significantly influence physical properties and thus potential applications. This perspective provides an overview of the current state of knowledge of DES nanostructure, both in the bulk liquid and at solid interfaces. We provide definitions which clearly distinguish DESs as a unique solvent class, rather than a subset of ILs. An appraisal of recent work provides hints towards trends in structure–property relationships, while also highlighting inconsistencies within the literature suggesting new research directions for the field. It is hoped that this review will provide insight into DES nanostructure, their potential applications, and development of a robust framework for systematic investigation moving forward.

Nanostructure, electrochemistry and potential-dependent lubricity of the catanionic surface-active ionic liquid [P6,6,6,14] [AOT

HypothesisA catanionic surface-active ionic liquid (SAIL) trihexyltetradecylphosphonium 1,4-bis(2-ethylhexoxy)-1,4-dioxobutane-2-sulfonate ([P6,6,6,14] [AOT]) is nanostructured in the bulk and at the interface. The interfacial nanostructure and lubricity may be changed by applying a potential. ExperimentsThe bulk structure and viscosity have been investigated using small angle X-ray scattering (SAXS) and rheometry. The interfacial structure and lubricity as a function of potential have been investigated using atomic force microscopy (AFM). The electrochemistry has been investigated using cyclic voltammetry. Findings[P6,6,6,14] [AOT] shows sponge-like bulk nanostructure with distinct interdigitation of cation–anion alkyl chains. Shear-thinning occurs at 293 K and below, but becomes less obvious on heating up to 313 K. Voltammetric analysis reveals that the electrochemical window of [P6,6,6,14] [AOT] on a gold micro disk electrode exceeds the potential range of the AFM experiments and that negligible redox activity occurs in this range. The interfacial layered structure of [P6,6,6,14] [AOT] is weaker than conventional ILs and SAILs, whereas lubricity is better, confirming the inverse correlation between the near-surface structure and lubricity. The adhesive forces of [P6,6,6,14] [AOT] are lower at −1.0 V than at open circuit potential and +1.0 V, likely due to reduced electrostatic interactions caused by shielding of charge centres via long alkyl chains.

3D Printing of Superhydrophobic Objects with Bulk Nanostructure.

The rapid development of 3D printing (or additive manufacturing) technologies demands new materials with novel properties and functionalities. Superhydrophobic materials, owing to their ultralow water adhesion, self-cleaning, anti-biofouling, or superoleophilic properties are useful for myriad applications involving liquids. However, the majority of the methods for making superhydrophobic surfaces have been based on surface functionalization and coatings, which are challenging to apply to 3D objects. Additionally, these coatings are vulnerable to abrasion due to low mechanical stability and limited thickness. Here, a new materials concept and methodology for 3D printing of superhydrophobic macroscopic objects with bulk nanostructure and almost unlimited geometrical freedom is presented. The method is based on a specific ink composed of hydrophobic (meth)acrylate monomers and porogen solvents, which undergoes phase separation upon photopolymerization to generate inherently nanoporous and superhydrophobic structures. Using a desktop Digital Light Processing printer, superhydrophobic 3D objects with complex shapes are demonstrated, with ultralow and uniform water adhesion measured with scanning droplet adhesion microscopy. It is shown that the 3D-printed objects, owing to their nanoporous structure throughout the entire volume, preserve their superhydrophobicity upon wear damage. Finally, a superhydrophobic 3D-printed gas-permeable and water-repellent microfluidic device and a hierarchically structured 3D-printed super-oil-absorbent are demonstrated.