Bubble Surface Research Articles

Numerical simulation on dehydrogenation behavior during argon blowing enhanced vacuum refining process of high-quality steel

Argon bubble blowing enhanced vacuum refining is a crucial process to remove hydrogen element in molten steel for high-quality steel manufacturing. However, the whole refining process is a black-box operation and the field information inside the reactor is not clear yet. In this work, an integrated mathematical model that coupling computational fluid dynamics and degassing chemical reaction is established to investigate dehydrogenation behavior under vacuum condition. The model accounts for three potential reaction sites to clarify the dehydrogenation mechanism of molten steel in detail. The simulation results indicate that the hydrogen removal by argon bubble surface contributes the most, followed by steel free surface, and little by bulk steel near the bath surface where the dehydrogenation occurs mainly at the initial treating stage. The total hydrogen removal ratio increases with reducing vacuum pressure and increasing the argon gas flow rate, but is independent of the initial hydrogen content.

A simulation study on the influence of marginal pinching upon liquid film dynamics

In fluid dynamics, the generation and bursting of surface bubble liquid films in surfactant-laden environments involve complex phenomena, one of which is marginal pinching at the film's foot—a crucial yet inadequately understood aspect due to experimental limitations. Considering its profound impact on liquid film drainage and lifetime, we utilize high-resolution numerical simulations incorporating a weakly compressible scheme and adaptive mesh refinement to dissect the marginal pinching dynamics with unprecedented detail. Our approach elucidates the pinching dynamics and tracks the evolution of film thickness during the critical late-stage drainage process. By leveraging detailed geometric data from pinched regions, we significantly refine existing drainage models, enhancing their predictive accuracy regarding rupture thickness and film lifetime across various viscosities, surfactant concentrations, and bubble sizes. This refined model demonstrates robust alignment with our simulation results. Furthermore, we establish a quantifiable relationship between the prefactor governing reverse flow induced by the Marangoni effect and surfactant concentration. The methodologies and findings of this study provide foundational knowledge that paves the way for optimized industrial processes and an enhanced understanding of natural phenomena.

Near-field underwater explosion and its interaction with a sandwich composite plate

Polymeric composite sandwich materials are critical for marine structures, but their behavior under near-field underwater explosions is not well understood. This study investigates the dynamic response of carbon-fiber-reinforced sandwich composites with varying core densities subjected to near-field underwater explosions. Lab-scale experiments were conducted at two explosive stand-off distances using high-speed imaging and Digital Image Correlation (DIC) to capture the evolution of gas bubble dynamics, surface cavitation, and structural deformation. Results showed that reducing the stand-off distance led to a 0.7 ms increase in gas bubble period, along with an 80 mm increase in horizontal migration of the bubble, while vertical migration remained unaffected. The interaction between the gas bubble and surface cavitation, driven by fluid-structure interaction (FSI), significantly influenced the structural response. In particular, the simultaneous collapse of the gas bubble and surface cavitation resulted in higher localized impulsive loading, causing catastrophic failure in low-density core panels. Meanwhile, panels with higher core densities exhibited a 40 % reduction in out-of-plane deflection, demonstrating enhanced resistance to blast loading. This study provides new insights into the fluid-structure interaction mechanisms that occur during near-field underwater explosions and offers a basis for improving the design of marine structures by optimizing material selection and geometric configurations. These findings contribute to a deeper understanding of shock mitigation strategies in composite materials and inform future research in marine structural design under extreme loading conditions.

Impact of sea surface waves and bubbles on water-leaving reflectance using Monte Carlo simulations

Impact of sea surface waves and bubbles on water-leaving reflectance using Monte Carlo simulations

IRROTATIONAL FLOW DUE TO FORCED OSCILLATIONS OF A BUBBLE

Abstract The behaviour of an axisymmetric bubble in a pure liquid forced by an acoustic pressure field is analysed. The bubble is assumed to have a sharp deformable interface, which is subject both to surface tension and to Rayleigh viscosity damping. Two modelling regimes are considered. The first is a linearized solution, based on the assumption of small axisymmetric deformations to an otherwise spherical bubble. The second involves a semi-numerical solution of the fully nonlinear problem, using a novel spectral method of high accuracy. For large-amplitude nonspherical bubble oscillations, the fully nonlinear solutions show that a complicated resonance structure is possible and that curvature singularities may occur at the interface, even in the presence of surface tension. Rayleigh viscosity at the interface prevents singularity formation, but eventually causes the bubble to become purely spherical unless shape-mode resonances occur. An extended analysis is also presented for purely spherical bubbles, which allows for a more detailed study of the effects of resonance and the Rayleigh viscosity at the bubble surface.

Bio-inspired powder bed fusion 3D printed surfaces for enhanced critical heat flux and boiling heat transfer

The thermal performance and sizing of two-phase heat exchangers employed in various industries can be significantly improved by modifying the surface topology of tubes. The advancement in metal 3D printing technology enables the modification of surfaces to generate distinct patterns that enhance the heat transfer coefficient. This study aligns with these advances by investigating the boiling heat transfer performance of 3D printed surfaces using methanol as the working fluid. The enhanced surfaces studied include four bio-inspired 3D printed surfaces (Mushroom, Cactus, Petal, and Torus), each strategically designed to improve the heat transfer coefficient (HTC) and delay the onset of critical heat flux (CHF). The primary objective of this research is to discuss and analyze the heat transfer mechanism in terms of bubble dynamics, particularly focusing on the interaction between surface morphology and bubble behavior. Experimental results reveal significant enhancements in CHF and HTC for 3D printed surfaces compared to plain surfaces. Among the 3D printed surfaces, the Mushroom surface exhibits the highest enhancement in CHF of 88 % compared to the plain surface. Similarly, the maximum HTC enhancements are 138 %, 86 %, 65 %, and 46 % for the Mushroom, Cactus, Petal, and Torus surfaces, respectively, compared to the plain surface. The methodologies and findings of this study are poised to have a lasting impact on the field, potentially opening new avenues for improving the efficiency and effectiveness of various two-phase heat exchangers.

Effective and environment-friendly oil removal with microbubble jet

Effective removal of oil contaminants from solid surfaces is crucial for various applications. However, traditional cleaning methods often involve the use of hazardous chemicals. Because of their stability and ability to adsorb pollutants, microbubbles are considered as a promising alternative for environmentally friendly cleaning. This study explores the enhancement of oil cleaning efficiency using a microbubble water jet. The properties of the microbubbles generated via ultrasonic agitation are examined under varying water temperatures, ultrasonic amplitudes, and surfactant concentrations. The microbubble jet demonstrates approximately 29 % enhanced cleaning efficiency compared with a single-phase water jet. Visualization techniques, including particle image velocimetry, reveal that this enhancement is driven by the behavior of microbubbles consistently adsorbing oil through hydrophobic interactions as well as the instability and increased turbulence intensity of the microbubble jet. Additionally, the higher (by 7 %) spreading velocity of the microbubble jet indicates the free surface of bubbles results in a drag reduction. Consequently, this enables the jet to cover wider regions to be cleaned effectively. The present findings demonstrate the potential of microbubble jets as an effective and eco-friendly alternative for oil removal and offer insights for their practical implementation in diverse fields utilizing microbubbles.

Study on the Oil-Water Separation Performance of Axial-Flow Hydrocyclone Enhanced by Condensate Bubbles

Abstract Produced water is the main by-product of the oilfield extraction process. Due to its high emulsification degree and density close to water, micron oil droplets are inefficiently separated by ordinary cyclone, and it is difficult to meet the standards of external discharge and reinjection after treatment. In this study, micron bubbles were prepared by mixing hydrocarbon components as gas and passed into the cyclone separator to enhance the oil-water separation effect. After the bubbles entered the cyclone, due to the pressure environment inside, the heavier components in the bubbles were found to condense and precipitate from the bubble surface, while the lighter components did not undergo phase change. The heavy hydrocarbons condense and spread out in the bubble and form a condensate film, because the condensate and oil droplets belong to the hydrocarbon homologue is easier to capture the oil droplets. This technology realizes the modification of lipophilic and hydrophobic surface of the bubbles. After the oil removal experiments found that the traditional axial cyclone separator separation of 65%, through the ordinary bubble assisted separation efficiency of 74%, and through the preparation of condensate bubbles to enhance flotation can be raised to 89% of the oil removal efficiency. Therefore, the condensate bubble-enhanced cyclone separator oil-water separation has a good application prospect.

Wettability-dependent dissolution dynamics of oxygen bubbles on Ti64 substrates

In this study, the dissolution of a single oxygen bubble on a solid surface, here Titanium alloy Ti64, in ultrapure water with different oxygen undersaturation levels is investigated. For that purpose, a combination of shadowgraph technique and planar laser-induced fluorescence is used to measure simultaneously the changes in bubble geometry and in the dissolved oxygen concentration around the bubble. Two different wettabilities of the Ti64 surface are adjusted by using plasma-enhanced chemical vapor deposition. The dissolution process on the solid surface involves two distinct phases, namely bouncing of the oxygen bubble at the Ti64 surface and the subsequent dissolution of the bubble, primarily by diffusion. By investigating the features of oxygen bubbles bouncing, it was found that the boundary layer of dissolved oxygen surrounding the bubble surface is redistributed by the vortices emerging during bouncing. This establishes the initial conditions for the subsequent second dissolution phase of the oxygen bubbles on the Ti64 surfaces. In this phase, the mass transfer of O2 proceeds non-homogeneously across the bubble surface, leading to an oxygen accumulation close to the Ti64 surface. We further show that the main factor influencing the differences in the dynamics of O2 bubble dissolution is the variation in the surface area of the bubbles available for mass transfer, which is determined by the substrate wettability. As a result, dissolution proceeds faster at the hydrophilic Ti64 surface due to the smaller contact angle, which provokes a larger surface area.

3D Numerical Investigation of Bubble Upflow Condensation Behaviors During Subcooled Flow Boiling in Mini-Channel with VOSET

In the subcooled flow boiling process, bubble condensation is an inevitable basic phenomenon. This paper studies the condensation phenomenon of the single, double vertical/horizontal saturated bubbles rising in a three-dimensional mini-rectangular channel based on the interface capture method VOSET (coupled volume-of-fluid and level set method) and the phase transition model. Bubble condensation behaviors are investigated at different initial diameters, inlet velocity distributions, subcooling temperatures, bubble gaps, and arrangement for the two-bubble condensing system especially. The effects of these parametric on bubble motion trajectory, shape evolution, volume variation, and condensation rate are presented. The numerical results indicated that the initial bubble size and liquid subcooling play an important role in influencing the shape and volume variation of condensing bubble behaviors significantly, while the inlet velocity distribution only affects bubble motion trajectory. Furthermore, the interaction and coalescence between the bubbles will affect the bubble behaviors and the condensation rate. Finally, the condensation heat transfer coefficients at the bubble surfaces for different cases simulated in this paper are presented, seemingly first in the literature.

Ultracompact all-fiber self-transceiving ultrasonic probe with an enhanced working distance.

All-optical ultrasonic probes exhibit notable benefits in ultrasonic detection and imaging. Typically, two separate optical fibers are used for excitation and detection, yet limited research has explored the integration of both functionalities within a single fiber. In this Letter, to our knowledge, a new method for fabricating an all-fiber self-transceiving ultrasonic probe is proposed with a lateral dimension of less than 500 µm. Double cladding fiber (DCF) is spliced with a short segment of thin-diameter single-mode fiber (TDSMF), which is then embedded into a fiber bubble to form a Fabry-Perot cavity, and the bubble surface is coated with a composite material layer. The pulsed laser propagates through the inner cladding of DCF and leaks from the splicing point of DCF-TDSMF, inducing the material excitation for efficient ultrasound generation. The core-guided detection laser is directed to the TDSMF end, entering the bubble microcavity and inducing an optical interference for weak echo detection. The emitting functionality produces an ultrasound with a -6 dB bandwidth of 17.5 MHz and a peak frequency of 6.29 MHz, which is well-matched with the fiber microcavity's response frequency of 3.29 MHz. Through self-transceiving experiments, low-noise pulse-echo signals are captured at varying working distances of up to 3.78 cm. The proposed probe exhibits great potential in biomedical and industrial fields due to its all-fiber miniaturization and enhanced-distance detection capability.

Flotation separation of lithium–ion battery electrodes predicted by a long short-term memory network using data from physicochemical kinetic simulations and experiments

Anode and cathode active materials from spent lithium–ion batteries may be recovered and potentially used in new batteries to promote recycling and resource circulation. Froth flotation was applied to pristine active materials and the black mass obtained from pretreated spent batteries. Flotation kinetics was simulated with the use of computational fluid dynamics and surface chemistry. Bubble surface coverage and entrainment in the flotation kinetics model were selected and optimized by systematic fitting to experimental data. Entrainment influences the recovery and grade of the active materials. The optimized flotation kinetics model was used for generating additional data that, along with the fitted data, were used to train a deep learning neural network. The trained network was validated using anode–cathode and black mass flotation experiments, and its predictions showed a maximum residual error of 0.18 ± 0.11 recovery. The simulation framework was developed into a desktop application that predicts the flotation behavior of active materials. It provides information for estimating results following operational and physicochemical changes and for optimizing flotation processes. Finally, recovered anode active materials from black mass were selected for coin cell tests. The coulombic efficiency of these coin cells was initially lower (86.8 %) than that of cells made with pristine graphite particles (98.4 %).

The Local Bubble Is a Local Chimney: A New Model from 3D Dust Mapping

Leveraging a high-resolution 3D dust map of the solar neighborhood from Edenhofer et al., we derive a new 3D model for the dust-traced surface of the Local Bubble, the supernova-driven cavity surrounding the Sun. We find that the surface of the Local Bubble is highly irregular in shape, with its peak extinction surface falling at an average distance of 170 pc from the Sun (spanning 70–600+ pc) with a typical thickness of 35 pc and a total dust-traced mass of (6.0 ± 0.7) × 105 M ⊙. The Local Bubble displays an extension in the Galactic northern hemisphere that is morphologically consistent with representing a “local chimney.” We argue this chimney was likely created by the “bursting” of this supernova-driven superbubble, leading to the funneling of interstellar medium (ISM) ejecta into the lower Galactic halo. We find that many well-known dust features and molecular clouds fall on the surface of the Local Bubble and that several tunnels to other adjacent cavities in the ISM may be present. Our new, parsec-resolution view of the Local Bubble may be used to inform future analysis of the evolution of nearby gas and young stars, the investigation of direct links between the solar neighborhood and the Milky Way’s lower halo, and numerous other applications.

Enhancing sludge thickening in continuous treatment using polymeric bubbles with cationic polymer P2900 and cocamidopropyl betaine.

Sludge thickening is a fundamental stage of treatment. This study investigated the application, in continuous treatment, of polymeric bubbles produced with cationic polymer P2900 and cocamidopropyl betaine (CAPB), a zwitterionic surfactant. The proposed reagent combination aims to form aerated flakes, solid waste structures, and rapidly rising air bubbles, ideal for treatments in compact units. Using this combination, it was possible to achieve a total solids concentration of 45% with the modified bubbles and 25% with the conventional water treatment. This level of thickening occurred under the following operating conditions: initial total solids (TS) concentration of 10g L-1, a flow rate of 5 L min-1, saturation pressure (psat) of 3atm, and polymer dosage of 10mg (gTS)-1. The suggested mechanism of action involves the adhesion of P2900 molecules to CAPB at the air/water interface, forming a lining on the bubble surface. Additionally, polymerized species form due to the residual aluminum (Al) in the sludge, which would occur during flocculation in the helical tubular flocculator (HTF), adsorbing the micelles and bubbles of CAPB. The critical micellar concentration (CMC) of CAPB was 0.26mmol L-1. Polymeric bubble technology can provide an efficient and cost-effective approach to sludge thickening in continuous treatment.

Evaluation of foaming performance for polymer modified and virgin asphalt binders

The pavement suffers rapid deterioration as a result of the weak bonding strength exhibited by the foamed virgin asphalt in the mixture. Consequently, it is crucial to develop a modified asphalt suitable for foaming. The expansion height and bubble size of foamed asphalt can be continuously and simultaneously monitored by binocular ranging equipment. By analyzing these dynamic responses, the evolution of the spatial domain expansion characteristics and the geometric features of the surface bubbles of foamed thermoplastic resin modified asphalt (TRA) was analyzed. Meanwhile, multi-stress creep recovery (MSCR) and bending beam rheometer (BBR) tests were conducted to analyze its rheological properties. Subsequently, the dispersibility of foamed TRA in the mixture was explored. The results showed that thermoplastic resin significantly improved the physical performance stability of foamed asphalt, as evidenced by an increase in its half-life by 2–3 times compared to the virgin asphalt when the dosage of thermoplastic resin reached 8 %. Foamed modified asphalt has fewer bubbles, but it has larger bubble sizes and more uniform distribution of bubbles. Meanwhile, the TRA exhibited excellent high-temperature deformation resistance and elastic recovery ability. The dispersion uniformity of foamed TRA in the mixture was superior to that of virgin asphalt. This study serves as a valuable reference for the exploration of foaming behavior in modified asphalt and the utilization of foamed modified asphalt in the mixture.

Pickering Foam Stabilized by Diacylglycerol-Based Solid Lipid Nanoparticles: Effect of Protein Modification.

Pickering foams have great potential for applications in aerated foods, but their foaming ability and physical stability are still far from satisfactory. Herein, solid lipid particles (SLNs) were fabricated by using diacylglycerol of varying acyl chain lengths with modification by a protein. The SLNs showed different crystal polymorphisms and air-water interfacial activity. C14-DAG SLN with a contact angle ∼ 79° formed aqueous foam with supreme stability and high plasticity. Whey protein isolate and sodium caseinate (0.1 wt %) considerably enhanced the foamability and interfacial activity of SLNs and promoted the packing of particles at the bubble surface. However, high protein concentration caused foam destruction due to the competitive adsorption effect. β-sheet increased in protein after adsorption and changed the polymorphism and thermodynamic properties of SLN. The foam collapsing behaviors varied in the presence of protein. The results gave insights into fabricating ultrastable aqueous foams by using high-melting DAG particles. The obtained foams demonstrated good temperature sensitivity and plasticity, which showed promising application prospects in the food and cosmetic fields.

The velocity fields around aspherical bubbles

Abstract This paper studies the simplest system, which can possess the left-right symmetrical and asymmetrical surroundings, three bubbles in a line. Assuming that the deformations are small, the surfaces of bubbles are described by a combination of the first three Legendre polynomials, that is, spherical symmetrical mode P0, antisymmetrical mode P1 and symmetrical mode P2. Based on the dynamics of three-bubble system, this paper further studies the velocity fields distribution around them. It can be seen from the contour distribution of the velocity field that the velocity component always decreases with the increase of the distance r. When three identical bubbles are separated uniformly, the velocity field around the central bubble is always in a symmetric, while there are asymmetric velocity fields around two side bubbles.

The Passage of the Solar System through the Edge of the Local Bubble

The Sun moves through the interstellar medium (ISM) at a velocity of ∼19 pc Myr−1, making the conditions outside the solar system vary with time over millions of years. Today’s solar system is protected from interstellar particles by the heliosphere, the bubble formed by the solar wind as the Sun moves through the ISM, which engulfs the planets. There is geological evidence from 60Fe that Earth was in direct contact with the ISM 2–3 and 5–7 million years ago (MYA). Recent work argues that the Sun encountered a massive cold cloud 2 MYA as part of the Local Ribbon of Cold Clouds that shrunk the heliosphere and exposed Earth to the ISM. Here, we consider the effects of the passage of the Sun through the edge of the Local Bubble occurring at 6.8−0.4+0.5 MYA assuming that the Sun encountered a cloud with a density of 900 cm−3. If we consider additional turbulent motion within the cloud due to shocks, the density encountered can be as low as 283 cm−3. Clouds of this density cover a small but nonzero (≲4.6%) fraction of the surface of the Local Bubble, making an encounter plausible. Using a state-of-the art magnetohydrodynamic model, we show that the heliosphere shrank to a scale smaller than Earth’s orbit, thereby exposing Earth to cold dense ISM, consistent with 60Fe evidence. The timing of the event matches perturbations observed in the paleoclimate record recovered from deep-sea sediments. The passage through the Local Bubble’s surface and contraction of the heliosphere therefore may have impacted the climate and biosphere significantly, suggesting a new driver of major events in Earth’s history.

Flotation separation mechanism of rutile and chlorite using CMC as depressant

In ores containing rutile, chlorite is the most common silicate gangue mineral. However, the flotation separation of rutile and chlorite has yet to be thoroughly studied. In this study, carboxymethyl cellulose (CMC) was used to depress chlorite when sodium oleate (NaOL) was used as the collector of rutile. The selective depression and its mechanism were investigated through micro-flotation experiments, zeta potential analyses, Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and particle video microscopy (PVM). Single mineral flotation showed selective depression of chlorite by CMC appeared at pH 7, NaOL concentration of 20 mg/L, and CMC concentration of 10 mg/L, when 88.39 % recovery difference between rutile and chlorite was obtained. The most effective concentration of CMC for the artificially mixed ore test was 15 mg/L, resulting in rutile recoveries and grades of 87.78 % and 75.28 % respectively. The results of Zeta, FTIR, and XPS tests indicate that the adsorption of CMC on chlorite surface is attributed to chemical and hydrogen bonding interactions, wherein the OH– and COOH– groups in CMC interact with hydroxyl groups of Fe2+ and Al3+ complexes, thereby diminishing chlorite floatability and impeding subsequent NaOL adsorption. PVM image further elucidates that hydration-repulsion interaction potentials between CMC-absorbed chlorite particles and gas bubbles deter particle adhesion. This markedly reduces chlorite ore carryover on bubble surfaces while minimally impacting rutile. This study can provide a theoretical basis for separating rutile and other vein minerals under the NaOL system.

Water-Templated Growth of Interfacial Superglue Polymers for Tunable Thin Films and In Situ Fluid Encapsulation.

Thin polymer films (TPFs) are indispensable elements in numerous technologies ranging from liquid encapsulation to biotechnology to electronics. However, their production typically relies on wet chemistry involving organic solvents or chemical vapor deposition, necessitating elaborate equipment and often harsh conditions. Here, an eco-friendly, fast, and facile synthesis of water-templated interfacial polymers based on cyanoacrylates (superglues, CAs) that yield thin films with tailored properties is demonstrated. Specifically, by exposing a cationic surfactant-laden water surface to cyanoacrylate vapors, surfactant-modulated anionic polymerization produces a manipulable thin polymer film with a thickness growth rate of 8nmmin-1. Furthermore, the shape and color of the film are precisely controlled by the polymerization kinetics, wetting conditions, and/or exposure to patterned light. Using various interfaces as templates for film growth, including the free surface of drops and soap bubbles, the developed method advantageously enables in situ packaging of chemical and biological cargos in liquid phase as well as the encapsulation of gases within solidified bubbles. Simple, versatile, and biocompatible, this technology constitutes a potent platform for programmable coating and soft/smart encapsulation of fluids.