Single-layered brazed diamond wheels, composed of uni-layered diamond grits, metal binder, and metal core, have potentially good thermal conductivity to dissipate heat from the grinding zone. Considering this characteristic feature, the current study aims to explore the performance and suitability of various indigenously developed single-layered brazed diamond tools in plunge-grinding of fine-grained cemented carbide in a challenging dry atmospheric condition. Single crystalline synthetic diamond particles with different strengths and friability were utilized to develop indigenous diamond wheels with random and patterned grit distribution. The current study explores the role of diamond-grit friability and grit distribution patterns to identify the most suitable wheel for dry grinding of WC-6Co composite. Detailed analysis of the wheel morphology, signifying the fracture behavior of the diamond grit used, justified the variation in the grinding forces, tool life, and ground surface roughness. Irrespective of the grit and distribution type, all wheels showed saturation of dynamic changes in work-surface topography with the number of passes and more sensitively to the degree of increase of uncut chip thickness. Grinding wheels containing friable diamond grits with irregular granular structures performed better than the high-strength, cubo-octahedral grains during the dry grinding experiments.