Boundary Layer Ozone Research Articles

Impact of the Indian Ocean Dipole Mode on Planetary Boundary Layer Ozone in China

AbstractThe Indian Ocean Dipole (IOD) mode exerts distinct impacts on the climate in China and can further affect tropospheric ozone. Using long‐term GEOS‐Chem simulations, we found distinct changes in planetary boundary layer ozone throughout China during positive and negative phases of IOD. In summer, ozone shows synchronized increases except in southern China during positive IOD; the ozone increases are dominated by chemical production and transport in northern and western China, respectively. The increased precursor from biogenic emissions contributed to ozone chemical formation in the northern region, and the increased precipitation and decreased solar radiation hindered ozone production in southern China. Ozone changes show good symmetry over most regions during negative IOD. In autumn, the ozone reduction in southern China shares the same reason as summer, while the chemical increase over northern China is affected more by changes in solar radiation and relative humidity than in the precursor emission.

Elucidating key factors in regulating budgets of ozone and its precursors in atmospheric boundary layer

The vertical variations and key drivers of ozone and its precursors, namely NOx and VOCs, in the atmospheric boundary layer, have vital impacts on surface ozone budgets but are poorly understood so far. Using online gradient measurements from a 356 m tower, we obtained continuous vertical profiles of ozone and its precursors, which exhibited strong gradients throughout the day. In the daytime, the vertical gradients of ozone precursors are significantly regulated by reactions with OH radicals. At night, our observations confirmed more intense VOC reactions with NO3 radicals in the residual layer than in the boundary layer. Additionally, we found that residual layer entrainment could contribute to over half of the boundary-layer ozone enhancements in the morning periods. Our results underscore the importance of considering vertical changes of ozone and its precursors in the atmospheric boundary layer when developing future ozone mitigation strategies.

Ground-based MAX-DOAS observations of tropospheric formaldehyde and nitrogen dioxide: Insights into ozone formation sensitivity

Tropospheric profiles of HCHO, NO2, and O3 are important for analyzing ozone formation mechanism. In this study, ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS), light detection and ranging (LIDAR), and in-situ measurements were simultaneously performed to diagnose ozone formation sensitivity at the Heshan Observatory in the Pearl River Delta (PRD) region from September to end October 2019. The profiles of tropospheric HCHO and NO2 were retrieved from MAX-DOAS measurements using an optimal estimation method. The retrieved surface HCHO and NO2 results were validated with 2,4-dinitrophenylhydrazine (DNPH) and Thermo 42i measurements, and the correlation coefficients (R) were 0.78 and 0.81, respectively. The retrieved tropospheric vertical column densities (VCDs) of HCHO and NO2 were compared with TROPOMI measurements, and the correlation coefficients (R) were 0.68 and 0.87, respectively. In addition, MAX-DOAS and LIDAR measurements were combined to diagnose a typical planetary boundary layer (PBL) ozone pollution episode from September 28 to October 10, 2019; this episode was analyzed using HCHO/NO2 ratio as an indicator and was found to be dominated by the VOC-sensitive regime. Moreover, the regime transition of ozone formation sensitivity was calculated using the surface HCHO/NO2 ratio and increased O3 from the MAX-DOAS and Thermo 49i measurements, with transition thresholds of 1.43 and 1.78, respectively. Based on this definition, the ozone formation sensitivity at Heshan Observatory varied from VOC-sensitive (< 0.2 km and > 0.8 km) to NOx-sensitive (0.3–0.7 km) to VOC-NOx-sensitive (0.2–0.3 km and 0.7–0.8 km). The results improve our understanding of ozone formation sensitivity in the PRD region.

Observing low-altitude features in ozone concentrations in a shoreline environment via uncrewed aerial systems

Abstract. Ozone is a pollutant formed in the atmosphere by photochemical processes involving nitrogen oxides (NOx) and volatile organic compounds (VOCs) when exposed to sunlight. Tropospheric boundary layer ozone is regularly measured at ground stations and sampled infrequently through balloon, lidar, and crewed aircraft platforms, which have demonstrated characteristic patterns with altitude. Here, to better resolve vertical profiles of ozone within the atmospheric boundary layer, we developed and evaluated an uncrewed aircraft system (UAS) platform for measuring ozone and meteorological parameters of temperature, pressure, and humidity. To evaluate this approach, a UAS was flown with a portable ozone monitor and a meteorological temperature and humidity sensor to compare to tall tower measurements in northern Wisconsin. In June 2020, as a part of the WiscoDISCO20 campaign, a DJI M600 hexacopter UAS was flown with the same sensors to measure Lake Michigan shoreline ozone concentrations. This latter UAS experiment revealed a low-altitude structure in ozone concentrations in a shoreline environment showing the highest ozone at altitudes from 20–100 m a.g.l. These first such measurements of low-altitude ozone via a UAS in the Great Lakes region revealed a very shallow layer of ozone-rich air lying above the surface.

Evaluating WRF-GC v2.0 predictions of boundary layer height and vertical ozone profile during the 2021 TRACER-AQ campaign in Houston, Texas

Abstract. The TRacking Aerosol Convection ExpeRiment – Air Quality (TRACER-AQ) campaign probed Houston air quality with a comprehensive suite of ground-based and airborne remote sensing measurements during the intensive operating period in September 2021. Two post-frontal high-ozone episodes (6–11 and 23–26 September) were recorded during the aforementioned period. In this study, we evaluated the simulation of the planetary boundary layer (PBL) height and the vertical ozone profile by a high-resolution (1.33 km) 3-D photochemical model, the Weather Research and Forecasting (WRF)-driven GEOS-Chem (WRF-GC). We evaluated the PBL heights with a ceilometer at the coastal site La Porte and the airborne High Spectral Resolution Lidar 2 (HSRL-2) flying over urban Houston and adjacent waters. Compared with the ceilometer at La Porte, the model captures the diurnal variations in the PBL heights with a very strong temporal correlation (R&gt;0.7) and ±20 % biases. Compared with the airborne HSRL-2, the model exhibits a moderate to strong spatial correlation (R=0.26–0.68), with ±20 % biases during the noon and afternoon hours during ozone episodes. For land–water differences in PBL heights, the water has shallower PBL heights compared to land. The model predicts larger land–water differences than the observations because the model consistently underestimates the PBL heights over land compared to water. We evaluated vertical ozone distributions by comparing the model against vertical measurements from the TROPospheric OZone lidar (TROPOZ), the HSRL-2, and ozonesondes, as well as surface measurements at La Porte from a model 49i ozone analyzer and one Continuous Ambient Monitoring Station (CAMS). The model underestimates free-tropospheric ozone (2–3 km aloft) by 9 %–22 % but overestimates near-ground ozone (&lt;50 m aloft) by 6 %-39 % during the two ozone episodes. Boundary layer ozone (0.5–1 km aloft) is underestimated by 1 %–11 % during 8–11 September but overestimated by 0 %–7 % during 23–26 September. Based on these evaluations, we identified two model limitations, namely the single-layer PBL representation and the free-tropospheric ozone underestimation. These limitations have implications for the predictivity of ozone's vertical mixing and distribution in other models.

Impact of Annular Solar Eclipse on the Trace Gases and Dynamics of the Lower and Middle Atmosphere: Results Inferred From an Integrated Campaign “Suryagrahan‐2019”

AbstractAn integrated campaign “Suryagrahan‐2019” with multi‐institutional support was conducted by launching a series of radiosondes/ozonesondes over 6‐different locations in India along with the operation of ST/MST radars and launching of RH‐200 rockets during the annular solar eclipse of 26 December 2019. We present the eclipse‐induced changes in the thermal structure, dynamics and trace gases in the lower and middle atmosphere. One of the novel findings is the formation of three step‐like isothermal structures in the lower stratosphere with a layer height of 1.4, 2.5, and 4 km, which is attributed to the adiabatic compression and expansion of the air parcel. These structures have both warming and cooling effect of the order of ±6 K. A significant increase of ozone by 20% in post‐eclipse scenario between 29 and 32 km is observed over Cochin. Strong downdrafts of ∼−0.25 m s−1 are observed between 12 and 16 km during the eclipse event, which is attributed to the atmospheric compression due to the sudden cooling during the eclipse event. Due to the changes in thermal structure, the atmospheric circulation changes are observed in the meridional wind. During the maximum obscuration, there is a sudden decrease in near‐surface and boundary layer ozone by 12–15 ppbv. The present study reiterates that the eclipse‐induced perturbations depend on the local time of the eclipse event and place of observations. It is envisaged that the results discussed in the study will improve our understanding of the eclipse induced perturbations in the Earth's atmosphere.

An extensive database of airborne trace gas and meteorological observations from the Alpha Jet Atmospheric eXperiment (AJAX)

Abstract. The Alpha Jet Atmospheric eXperiment (AJAX) flew scientific flights between 2011 and 2018 providing measurements of trace gas species and meteorological parameters over California and Nevada, USA. This paper describes the observations made by the AJAX program over 229 flights and approximately 450 h of flying. AJAX was a multi-year, multi-objective, multi-instrument program with a variety of sampling strategies resulting in an extensive dataset of interest to a wide variety of users. Some of the more common flight objectives include satellite calibration/validation (GOSAT, OCO-2, TROPOMI) at Railroad Valley and other locations and long-term observations of free-tropospheric and boundary layer ozone allowing for studies of stratosphere-to-troposphere transport and long-range transport to the western United States. AJAX also performed topical studies such as sampling wildfire emissions, urban outflow and atmospheric rivers. Airborne measurements of carbon dioxide, methane, ozone, formaldehyde, water vapor, temperature, pressure and 3-D winds made by the AJAX program have been published at NASA's Airborne Science Data Center (https://asdc.larc.nasa.gov/project/AJAXTS9 (last access: 1 November 2022), https://doi.org/10.5067/ASDC/SUBORBITAL/AJAX/DATA001, Iraci et al., 2021a).

Low ozone dry deposition rates to sea ice during the MOSAiC field campaign: Implications for the Arctic boundary layer ozone budget

Dry deposition to the surface is one of the main removal pathways of tropospheric ozone (O3). We quantified for the first time the impact of O3 deposition to the Arctic sea ice on the planetary boundary layer (PBL) O3 concentration and budget using year-round flux and concentration observations from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) campaign and simulations with a single-column atmospheric chemistry and meteorological model (SCM). Based on eddy-covariance O3 surface flux observations, we find a median surface resistance on the order of 20,000 s m−1, resulting in a dry deposition velocity of approximately 0.005 cm s−1. This surface resistance is up to an order of magnitude larger than traditionally used values in many atmospheric chemistry and transport models. The SCM is able to accurately represent the yearly cycle, with maxima above 40 ppb in the winter and minima around 15 ppb at the end of summer. However, the observed springtime ozone depletion events are not captured by the SCM. In winter, the modelled PBL O3 budget is governed by dry deposition at the surface mostly compensated by downward turbulent transport of O3 towards the surface. Advection, which is accounted for implicitly by nudging to reanalysis data, poses a substantial, mostly negative, contribution to the simulated PBL O3 budget in summer. During episodes with low wind speed (&amp;lt;5 m s−1) and shallow PBL (&amp;lt;50 m), the 7-day mean dry deposition removal rate can reach up to 1.0 ppb h−1. Our study highlights the importance of an accurate description of dry deposition to Arctic sea ice in models to quantify the current and future O3 sink in the Arctic, impacting the tropospheric O3 budget, which has been modified in the last century largely due to anthropogenic activities.

Retrieval of tropospheric ozone profiles using ground-based MAX-DOAS

In recent years, surface ozone concentrations have increased in many cities in China. Ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a powerful technique for retrieving the profiles of tropospheric trace gases, such as NO2, SO2, and HCHO. However, since the difficulties in deducting the effects of stratospheric ozone, there are few studies on the retrieval of tropospheric ozone profiles using MAX-DOAS measurements. Here, we developed an accurate inversion method to retrieve tropospheric ozone concentrations during the PRIDE-GBA Campaign, wherein the ozone differential slant column densities (DSCDs) were retrieved in QDOAS software using the “time-interpolated zenith spectrum” as the reference spectrum. The tropospheric DSCDs (DSCDstrop) were then calculated by subtracting the simulated stratospheric DSCDs (DSCDsstr, simulated from the SCIATRAN model) from the DSCDs. Tropospheric ozone profiles were retrieved from the DSCDstrop using the optimal estimation method (OEM). The results showed that high values of tropospheric ozone were mainly distributed below 1 km, which is consistent with lidar measurements. In addition, the observed surface ozone concentrations were highly correlated with the in-situ measurements, with correlation coefficients (R) of 0.75 and 0.81, respectively. Combined with the retrieved NO2 and HCHO profiles using the MAX-DOAS measurements, we found that the planetary boundary layer ozone pollution of HeShan Observatory during the PRIDE-GBA Campaign are controlled by the NOx-limited regime. The results of this study indicate that the MAX-DOAS technique has the potential to retrieve tropospheric ozone profiles with high temporal and spatial resolution.

Impacts of land-surface forcing on local meteorology and ozone concentrations in a heavily industrialized coastal urban area

In this study, the Weather Research and Forecasting/Community Multiscale Air Quality (WRF-CMAQ) model was used to investigate the interaction of urban land-surface forcing with local circulations and the impact on boundary layer ozone concentrations in southern Taiwan at an urban-scale resolution. Two simulations were performed with the same emissions but different land cover designations. URBAN was the baseline simulation representing the current urbanized condition, while NO-URBAN replaced all urban grid cells with cropland. The interaction of the sea-breeze with the urban-heat-island (UHI) convergent flow during the daytime in URBAN transports near-surface O3 precursors to the upper planetary boundary layer (PBL). When the UHI convergent flow stalls over the city center, a circulation flow is formed and traps the pollutants at an elevated height, increasing the reaction rate of hydroxyl radical with volatile organic compounds by 2.0–4.0 ppbv h−1 at 1000–1500 m. At nighttime, the deeper boundary layer of URBAN diluted the NOx mixing ratio by ~17 ppbv and weakened the titration effect, contributing to higher O3 by +15 ppbv in the urban area. However, once the daytime vertical mixing diminished, the O3 aloft also diffused downward to the surface level and further degraded the nighttime air quality.

Phase-Resolved Lockdown Features of Pollution Parameters Over an Urban and Adjoining Rural Region During COVID-19

In this study, we investigate the temporal variations in columnar aerosol pollutants and their possible association with the simultaneously measured black carbon (BC) aerosol mass concentration and associated biomass burning (BB) over urban (Delhi) and rural (Panchgaon) sites during the lockdown phases of the COVID-19 pandemic. We also show the impact of lockdown measures on boundary layer ozone and its primary precursors, NO2, and water vapor (H2O), potent greenhouse gases that destroy protective ozone. For this purpose, we used multiple datasets, namely, black carbon (BC) aerosol mass concentration and biomass burning (BB) aerosols using an aethalometer at Amity University Haryana (AUH), Panchgaon, India, and satellite retrievals from NASA’s MODIS and OMI at both the stations. The analysis was conducted during the pre-lockdown period (1–25 March), lockdown 1st phase (25 March–14 April), lockdown 2nd phase (15 April–3 May), lockdown 3rd phase (4–17 May), lockdown 4th phase (18–31 May), and post-lockdown (1–30 June) period in 2020. Our diagnostic analysis shows a substantial reduction in AOD (Delhi: −20% to −80%, Panchgaon: −20% to −80%) and NO2 (Delhi: −10% to −42.03%, Panchgaon −10% to −46.54%) in comparison with climatology (2010–2019) during all four phases of lockdown. The reduction in AOD is attributed to lockdown measures and less transport of dust from west Asia than climatology. Despite a reduction in NO2, there is an increase in the ozone amount (Delhi: 1% to 8% and Panchgaon: 1% to 10%) during lockdown I, II, and III phases. The observed enhancement in ozone may be resultant from the complex photochemical processes that involve the presence of NO2, CO, volatile organic compounds (VOCs), and water vapor. The reduction in AOD and NO2 and enhancement in ozone are stronger at the rural site, Panchgaon than that at the urban site, Delhi.

Model analysis of vertical exchange of boundary layer ozone and its impact on surface air quality over the North China Plain

In addition to photochemical production and horizontal regional transport, surface O3 concentration can also likely be affected by vertical transport, which is not well known so far. The process analysis was conducted by using the Regional Atmospheric Modeling System Community Multiscale Air Quality (RAMS-CMAQ) model to investigate photochemical production and the vertical transport mechanism of boundary-layer O3 during a typical O3 pollution episode in the North China Plain (NCP), and further quantify the contribution of vertical transport to surface O3. The diurnal variations of vertical budgets of O3 and NO2 in the boundary layer at multiple sites showed that there were substantial differences in the vertical distribution of O3 production and transport between urban and suburban/rural areas. In urban areas, surface O3 is consumed by titration reaction to generate NO2, which is then transported to the upper boundary layer and produces O3 by photochemical reaction. With the development of the boundary layer, the upper-layer O3 stored in the residual layer at nighttime can be transported vertically to the surface as the turbulent diffusion intensifies the next morning. While in suburban and rural areas, the vertical transport is relatively weaker because the photochemical formation of O3 occurs in the whole boundary layer, although it decreases slightly with the altitude. Model simulation showed that 20.6–27.9% of urban surface O3 changes in the morning (09:00–10:00 LST) was attributable to the downward transport from the residual layer, while it is 15.0–22.1% at suburban site. The vertical transport from above the boundary layer contributed 24.0–63.6% to daytime urban surface O3 changes, which was weak in suburban areas. Differences and similarities in O3 formation and transport mechanism in urban and suburban regions revealed here highlight the importance of earlier control and regional collaboration.

Observations of iodine monoxide over three summers at the Indian Antarctic bases of Bharati and Maitri

Abstract. Iodine plays a vital role in oxidation chemistry over Antarctica, with past observations showing highly elevated levels of iodine oxide (IO) leading to severe depletion of boundary layer ozone in West Antarctica. Here, we present MAX-DOAS-based (multi-axis differential absorption spectroscopy) observations of IO over three summers (2015–2017) at the Indian Antarctic bases of Bharati and Maitri. IO was observed during all the campaigns with mixing ratios below 2 pptv (parts per trillion by volume) for the three summers, which are lower than the peak levels observed in West Antarctica. This suggests that sources in West Antarctica are different or stronger than sources of iodine compounds in East Antarctica, the nature of which is still uncertain. Vertical profiles estimated using a profile retrieval algorithm showed decreasing gradients with a peak in the lower boundary layer. The ground-based instrument retrieved vertical column densities (VCDs) were approximately a factor of 3 to 5 higher than the VCDs reported using satellite-based instruments, which is most likely related to the sensitivities of the measurement techniques. Air mass back-trajectory analysis failed to highlight a source region, with most of the air masses coming from coastal or continental regions. This study highlights the variation in iodine chemistry in different regions in Antarctica and the importance of a long-term dataset to validate models estimating the impacts of iodine chemistry.

Characteristics of boundary layer ozone and its effect on surface ozone concentration in Shenzhen, China: A case study

In late September 2019, the longest and most extensive ozone (O3) pollution process occurred at Pearl River Delta. Base on the observational data, surface-level O3, vertical distribution characteristics boundary layer O3 as well as its effect on surface-level O3 are thoroughly analyzed. The O3 lidar results showed similar vertical O3 profiles both in pollution episodes and clean periods, from which a high O3 concentration layer between 300 and 500 m and a sub-high O3 concentration layer between 1300 and 1700 m (near the top of the mixing layer) can be found. Besides, the downward O3 transport paths from the high/sub-high O3 concentration layers could be observed along with the boundary layer evolution: At nighttime, large amounts of O3 were effectively stored into the residual layer (RL). Due to the upward development of Mixing layer (ML) in early morning, atmospheric vertical mixing carried the O3 inside the RL down to the surface, which led to a rapid increase in the surface-level O3. The sub-high O3 layer began the downward mixing at noon, and became well-mixed after the boundary layer was fully developed in the afternoon, by which the near surface O3 pollution deteriorated again. Further analysis of the heavy O3 pollution episodes show that, the high O3 concentration inside the RL contributed 54% ± 6% of the surface-level O3 at 9:00 LT and the average contribution of O3 in the sub-high concentration layer to the surface-level O3 at 14:00 LT was 26% ± 9%. Based on the quantitative analysis of the observational data, this paper focus to reveal the importance of the contribution of O3 inside the RL and near the top of the ML to the surface O3.

Continuous multi-component MAX-DOAS observations for the planetary boundary layer ozone variation analysis at Chiba and Tsukuba, Japan, from 2013 to 2019

Ground-based remote sensing using multi-axis differential optical absorption spectroscopy (MAX-DOAS) was used to conduct continuous simultaneous observations of ozone (O3), nitrogen dioxide (NO2), and formaldehyde (HCHO) concentrations at Chiba (35.63° N, 140.10° E, 21 m a.s.l.) and Tsukuba (36.06° N, 140.13° E, 35 m a.s.l.), Japan, for 7 years from 2013 to 2019. These are urban and suburban sites, respectively, in the greater Tokyo metropolitan area. NO2 and HCHO are considered to be proxies for nitrogen oxides (NOx) and volatile organic compounds (VOCs), respectively, both of which are major precursors of tropospheric O3. The mean concentrations below an altitude of 1 km were analyzed as planetary boundary layer (PBL) concentrations. For a more spatially representative analysis around the urban area of Chiba, four MAX-DOAS instruments directed at four different azimuth directions (north, east, west, and south) were operated simultaneously and their data were unified. During the 7-year period, the satellite observations indicated an abrupt decrease in the tropospheric NO2 concentration over East Asia, including China. This suggested that the transboundary transport of O3 originating from the Asian continent was likely suppressed or almost unchanged during the period. Over this time period, the MAX-DOAS observations revealed the presence of almost-constant annual variations in the PBL O3 concentration, whereas reductions in NO2 and HCHO concentrations occurred at rates of approximately 6–10%/year at Chiba. These changes provided clear observational evidence that a decreasing NOx concentration significantly reduced the amount of O3 quenched through NO titration under VOC-limited conditions in the urban area. Under the dominant VOC-limited conditions, the MAX-DOAS-derived concentration ratio of HCHO/NO2 was found to be below unity in all months. Thus, the multi-component observations from MAX-DOAS provided a unique data set of O3, NO2, and HCHO concentrations for analyzing PBL O3 variations.

Vertical distributions of boundary-layer ozone and fine aerosol particles during the emission control period of the G20 summit in Shanghai, China

Vertical observations of ozone (O3) and fine aerosol particles (PM2.5) below 3000 m above ground level were made by an O3 lidar and two hexacopter unmanned aerial system (UAS) platforms to investigate vertical distributions of the boundary-layer O3 and PM2.5 and their effects on surface air quality. Field observations were conducted in Shanghai, China before, during, and after the G20 Summit (Hangzhou) from 23 August to 13 September 2016, when stringent emission control measures were implemented over the Yangtze River Delta region. The results show that surface O3 and PM2.5 concentrations increased evidently during the emission control period due to the significant contribution of transport. Different transport types including regional transport, recirculation transport, and long-range transport were captured in the three stages of the emission control period. Regional transport mainly occurred in the middle and upper boundary layer, leading to positive altitude dependence of the boundary-layer O3 and PM2.5. Recirculation transport mainly occurred in the lower boundary layer, leading to negative altitude dependence of the boundary-layer O3 and PM2.5. Long-range transport of O3 mainly occurred in the lower free troposphere, leading to positive altitude dependence of the boundary-layer O3. Under the influence of northeasterly winds, Shanghai exhibited considerable transport potential of pollutants to Hangzhou during the emission control period. The findings in this study could help to understand complex interactions between different transport types and variations in surface air pollutant concentrations, as well as provide important implications in making regional emission control measures in the future.

Development and utilization of hexacopter unmanned aerial vehicle platform to characterize vertical distribution of boundary layer ozone in wintertime

Vertical observations of ozone play vital roles in understanding various atmospheric chemical processes in the boundary layer, particularly in winter. In this study, we attempted to measure vertical profiles of boundary layer ozone in the winter of 2018 over the Yangtze River Delta region of China, using a hexacopter unmanned aerial vehicle (UAV) platform. A commercial portable ozone monitor mounted in a thermal insulation box was attached to the UAV platform to conduct vertical ozone measurements. The results showed that the UAV platform could effectively capture the vertical variations of boundary layer ozone in wintertime. During the field campaign, surface ozone was in relatively low levels due to weak photochemical production. In the daytime, the ozone was well mixed within the boundary layer. At nighttime, uniform vertical distribution patterns and stratified distribution patterns were frequently obtained in ozone profiles below 500 m. Backward trajectories and wind profiles were used to investigate the horizontal and vertical transport of ozone. The stratified distribution patterns of ozone were closely associated with strong contemporary advection transport of ozone that was accompanied by enhanced winds aloft. Besides, strong wind shear enhanced the downward transport of ozone from the free troposphere into the boundary layer, leading to uniform vertical distribution patterns of boundary layer ozone and the elevated nocturnal surface ozone levels. The results of this study could provide insights into the understanding of the spatial variations and evolution patterns of boundary layer ozone in wintertime and constructing suitable boundary layer schemes in atmospheric chemical models.

Air quality in the Galapagos Islands: A baseline view from remote sensing and in situ measurements

AbstractA characterization of ambient air levels of PM2.5, O3, SO2, NO2 and CO in the Galapagos Islands of Ecuador is presented from in situ and remote sensing observations. PM2.5 was derived from aerosol optical depth (AOD; AERONET) measured at the Universidad San Francisco de Quito, Galapagos Campus (2017–2019). Boundary layer (BL) ozone was obtained from Southern Hemisphere Additional Ozonesondes (SHADOZ) profiles (1998–2016). Background SO2 and pollution events during volcanic eruptions (2005–2018) were estimated from Ozone Monitoring Instrument (OMI) total column measurements through a well‐mixed volume approach. Similarly, ambient NO2 was estimated from OMI data (2012–2019). CO was obtained from Measurement Of Pollution In The Troposphere (MOPITT) observations (2012–2017). The study was complemented using Modern‐Era Retrospective Analysis for Research and Applications (MERRA‐2) reanalysis products and backward trajectory model runs. From the results, baseline levels of the analysed species (PM2.5 = 3.8 μg·m−3, O3 = 17 ppbv, SO2 = 3.6 ppbv, CO = 80 ppbv, NO2 in populated islands = 23 pptv as one year averages) are comparable with other pristine regions, but some factors can cause increased concentrations. First, high tourism seasons (February–April and July–September) raise background PM2.5, NO2 and CO. Furthermore, signals in July–September can be augmented by transport from biomass‐burning regions in the Amazon. This latter factor episodically causes ozone to increase up to 45–75 ppbv (1 hr mean). Lastly, volcanic eruptions raise SO2 up to almost 700 ppbv (24 hr mean) and increase PM2.5 to 29.5 μg·m−3 (1 hr mean). The present study provides for the first time baseline levels of air contaminants in the Galapagos, and identifies specific sources whose effect in time is necessary to monitor given global conditions of vulnerable environmental quality.

Mathematical Model for Studying the Effect of the Atmospheric ‎Boundary Layer on the Surface Ozone Variations at a Coastal ‎Site

Atmospheric Boundary Layer (ABL) height (h) is one of the basic criteria ‎for describing its structure. ABL measurements, parameters and predictions have ‎numerous practical and theoretical implementations as forecast of pollutant ‎concentrations, surface temperature, expansion of disturbance measurements or ‎in climate models and numerical weather prediction. The height of mixing layer ‎is difficult to be measured; therefore, mathematical methods are introduced to ‎calculate this layer and different FORTRAN programs have been developed to ‎define the height of ABL on hourly basis per year. The analysis of the results ‎showed that the variation of the height of the mixing layer for different seasons ‎depends on the type of the dominant stability class and the value of wind speed, ‎where the rise of the mixing layer in winter and autumn months may be referred ‎to increased frequency of stability conditions in the unstable and slightly ‎unstable atmosphere On the other hand, when the stable conditions are dominant, ‎the height of the mixing layer remains smaller. ‎ The boundary layer ozone is a standard contaminant because of its ‎harmful effects on living organisms and plants. It also has an active role in ‎atmospheric chemistry and climate change; therefore, monthly and seasonal ‎variation of the surface ozone O3 concentration and its effects on the ‎atmospheric boundary layer measured for the first time at coastal site in Egypt at ‎the period 2013.‎

An evaluation of the ability of the Ozone Monitoring Instrument (OMI) to observe boundary layer ozone pollution across China: application to 2005–2017 ozone trends

Abstract. Nadir-viewing satellite observations of tropospheric ozone in the UV have been shown to have some sensitivity to boundary layer ozone pollution episodes, but so far they have not yet been compared to surface ozone observations collected by large-scale monitoring networks. Here we use 2013–2017 surface ozone data from China's new Ministry of Ecology and Environment (MEE) network of ∼ 1000 sites, together with vertical profiles from ozonesondes and aircraft, to quantify the ability of tropospheric ozone retrievals from the Ozone Monitoring Instrument (OMI) and to detect boundary layer ozone pollution in China. We focus on summer when ozone pollution in China is most severe and when OMI has the strongest sensitivity. After subtracting the Pacific background, we find that the 2013–2017 mean OMI ozone enhancements over eastern China have strong spatial correlation with the corresponding multiyear means in the surface afternoon observations (R=0.73), and that OMI can estimate these multiyear means in summer afternoon surface ozone with a precision of 8 ppb. The OMI data show significantly higher values on observed surface ozone episode days (&gt;82 ppb) than on non-episode days. Day-to-day correlations with surface ozone are much weaker due to OMI noise and are stronger for sites in southern China (&lt;34∘ N; R=0.3–0.6) than in northern China (R=0.1–0.3) because of weaker retrieval sensitivity and larger upper tropospheric variability in the north. Ozonesonde data show that much of the variability of OMI ozone over southern China in summer is driven by the boundary layer. Comparison of 2005–2009 and 2013–2017 OMI data indicates that mean summer afternoon surface ozone in southern China (including urban and rural regions) has increased by 3.5±3.0 ppb over the 8-year period and that the number of episode days per summer has increased by 2.2±0.4 (as diagnosed by an extreme value model), generally consistent with the few long-term surface records. Ozone increases have been particularly large in the Yangtze River Delta and in the Hubei, Guangxi and Hainan provinces.