Bottom Conditions Research Articles

Geochemical characterization of Upper Cretaceous organic-rich deposits: Insights from the Azraq Basin in Jordan

Cretaceous sedimentary successions in Jordan are among the most promising unconventional global petroleum resources. The Upper Cretaceous deposits in the Azraq Basin in Jordan were analyzed using Rock-Eval pyrolysis, stable carbon isotopes, vitrinite reflectance, and biomarkers, as well as 1D basin modeling. This study aims to evaluate source input, depositional environment, burial history and potential for hydrocarbon generation of the Upper Cretaceous organic-rich deposits in Jordan. The Upper Cretaceous samples exhibit variable source rock potential. Maastrichtian samples are very good, primarily oil-prone, while Campanian and Cenomanian samples range from fair to poor, with Turonian samples showing good petroleum generation potential. Thermal maturity analysis of Cretaceous samples reveals higher maturity in Turonian and Cenomanian samples compared to the thermally immature Maastrichtian and Campanian samples based on the maximum temperature of pyrolytic hydrocarbons generation, vitrinite reflectance, production index and biomarker indicators. The molecular fossils data suggest that the organic matter of these source rocks was primarily of marine phytoplankton origin, with considerable contributions from microbial biomass, and deposited under oxygen-depleted bottom water conditions. Additionally, the resemblance in molecular composition between Cretaceous source rocks and crude oil samples suggests a common origin for the hydrocarbons. The highest contents of organic matter have been recorded at the top of the Maastrichtian and at the bottom of the Turonian sections. These findings correspond with Maastrichtian upwelling deposits in North Africa and the Middle East, as well as with deposits from the Cenomanian-Turonian Oceanic Anoxic Event (OAE2).

Iron redox shuttling and uptake by silicate minerals on the Namibian mud belt

Anoxic marine sediments represent an important source of bioavailable iron (Fe) to the ocean. The highest sedimentary Fe fluxes are observed in open-marine oxygen minimum zones where anoxic bottom waters are in contact with ferruginous surface sediments. Here, sedimentary Fe release, transport and re-deposition (i.e., Fe shuttling) may generate a lateral pattern of sedimentary Fe enrichment and depletion, which can be used to trace redox-related Fe mobility in the paleo-record. However, depending on the balance between terrigenous and authigenic (i.e., shuttle-related) Fe flux, the stability of bottom water redox conditions as well as post-depositional processes of mineral alteration, the sedimentary fingerprint of an Fe redox shuttle may be obscured and difficult to identify.We investigated sedimentary Fe cycling along two transects across the Namibian mud belt with variable terrigenous sedimentation (23°S < 25°S) and during two seasons with opposing bottom water redox conditions (oxic in austral winter versus anoxic to sulfidic in austral summer). On both transects, substantial benthic Fe fluxes up to −50 µmol m−2 d−1 were inferred based on pore water profiles. The magnitude of these fluxes is comparable to those reported for other open-marine oxygen minimum zones. On the transect at 23°S, Fe source areas with ferruginous surface sediments were clearly separated from Fe sink areas with highly sulfidic surface sediments. Therefore, Fe redox shuttling was reflected by a lateral pattern of reactive Fe depletion and enrichment relative to the terrigenous background sedimentation. By contrast, on the transect at 25°S, benthic Fe fluxes were temporally and spatially more variable and surface sediments were ferruginous or only weakly sulfidic. Therefore, sedimentary Fe depletion and enrichment was less pronounced at 25°S. In the Fe sink area at 23°S, hydrogen sulfide was present at the sediment surface during both sampling campaigns and solid phase data suggest that Fe sulfide minerals represented the main burial phase of reactive Fe. By contrast, at 25°S excess Fe was associated with potassium (K) rather than reduced sulfur. While a differing sediment provenance cannot be ruled out entirely, combined evidence from pore water silica profiles, K to Fe stoichiometric relationships and electron microprobe images suggest that laterally derived excess Fe was incorporated into pre-existing and/or authigenic clay minerals during early diagenesis. Iron uptake by clay minerals may be supported by frequent redox oscillations and sediment mixing preventing preservation of Fe sulfide minerals and promoting Fe and K fixation in clay minerals. The burial fluxes of excess Fe associated with sulfide minerals at 23°S and silicate minerals at 25°S were similar. Our findings thus underscore that neoformation or alteration of silicate minerals can be important processes within the low-temperature marine Fe cycle.

Reconstructing the redox environment of the Cambrian Harkless Formation, Nevada, USA: Navigating the effects of iron-rich clay minerals on the iron speciation redox proxy

Understanding the oxygenation of ancient oceans is critical for contextualizing evolutionary events throughout Earth's history. While there are many geochemical proxies available for evaluating paleoredox state, iron speciation is one of the most robust and widely applied recorders of local bottom water redox. The proxy uses a series of sequential extractions which are operationally designed to target redox active iron in different mineral groups, including carbonates, oxides, magnetite, and sulfides. However, clay minerals that contain iron are not specifically targeted but can be important reservoirs of redox active iron. These clay minerals are abundant during many times in Earth's history, so it is critical to understand how they are extracted during iron speciation and their impact on paleoenvironmental interpretations.Here we apply the iron speciation proxy in combination with other geochemical proxies (FeT/Al, Mn enrichments) and mineralogical analyses to determine local bottom water redox conditions during deposition of the early Cambrian Harkless Formation exposed near Gold Point, Nevada, USA. The Harkless Formation contains one of the last occurrences of archaeocyathan reefs before their extinction, thus studying the underlying strata can provide information about the environmental conditions which led to reef development. Iron speciation results indicate oxic to potentially anoxic conditions in the water column. The presence of FeT/Al enrichments, Mn depletion, and the Fe-rich redox sensitive clay minerals chamosite and glauconite suggest intermittent anoxia in the water column and porewaters during some intervals of Harkless deposition. Further, by combining iron speciation extractions with petrographic and x-ray diffraction analyses, we demonstrate that glauconite and chamosite were likely formed at or below the sediment water interface and are also not consistently or fully removed by the standard sequential iron reagents, as noted by previous work.The presence of these authigenic Fe-bearing clay minerals overall results in an underestimation of the proportion of redox active iron during deposition and early sediment diagenesis that may lead to incorrect environmental characterization. We therefore advocate for caution and careful examination of the mineralogy of samples when applying the iron speciation proxy, particularly when authigenic and/or early diagenetic iron-bearing clay minerals are suspected to be present. Based upon these findings, we suggest that the Harkless Formation experienced variable local bottom water redox conditions ranging from oxic to anoxic during deposition. Changes in the relative abundances of chamosite and glauconite may also indicate an increase in oxygenation up section, suggesting that local water column oxygenation played a role in archaeocyathan reef development.

Widespread coastal upwelling along the marginal Yangtze Platform (South China) during the early Cambrian: Implications for hyper-enrichment of organic matter

Early Cambrian Earth history witnessed significant changes in marine environments and biological evolution contemporaneous with extensive accumulation of organic-rich shale. However, major factors controlling hyper-enrichment of organic matter (OM) of lower Cambrian shale deposits remain controversial. Black shale of the lower Cambrian Niutitang Formation (NTT) of the Marginal Yangtze Platform (South China) deposited during the Cambrian middle Age 2 are especially organic-rich, with total organic carbon (TOC) concentrations of as much as 13.0 wt%. Geochemical evidence suggests that cool, dry paleo-climatic conditions that prevailed on the Yangtze Platform during the Cambrian Fortunian-late Age 2, induced vigorous coastal upwelling. Paleo-productivity level assessments indicate that the magnitude of primary productivity contemporaneous with deposition of the NTT shale deposits exceeded that of modern upwelling systems (e.g., Peruvian Margin). The widespread occurrence of phosphate nodules within these deposits and decreased Co-EF × Mn-EF values of associated lower Cambrian black shale successions deposited along the margin of the Yangtze carbonate platform suggest extensive coastal upwelling. Widespread and strong coastal upwelling in tandem with elevated surface water primary productivity and anoxic (even euxinic) bottom water conditions are manifested by deposition of OM hyper-enriched black shale during Cambrian Fortunian to middle Age 2 time. However, weakened seasonal upwelling that appears to have prevailed during the late Cambrian Age 2 was accompanied by accumulation of NTT shale deposits of diminished TOC content. In summary, this study provides robust evidence of extensive coastal upwelling along the Marginal Yangtze Platform during early Cambrian time that favored accumulation of OM hyper-enriched shale. These results help to elucidate the distribution of high-quality lower Cambrian natural gas source rocks in South China.

Variations in deep-sea methane seepage linked to millennial-scale changes in bottom water temperatures ~ 50–6 ka, NW Svalbard margin

During the last glaciation, the northern hemisphere experienced profound millennial-scale changes (termed Dansgaard-Oeschger (DO) events) in atmospheric and oceanic temperatures. In the North Atlantic, the fluctuations resulted in extremely unstable bottom water conditions with bottom water temperatures (BWT) varying up to > 5 °C. We have studied these changes in a core from 1,300 m water depth at Vestnesa Ridge, northwestern Svalbard margin to investigate a possible connection between BWT and seepage of methane from the seafloor covering the period ~ 50–6 ka. Beneath Vestnesa Ridge, gas hydrates containing vast amounts of methane are kept stable due to the high pressure and low temperatures. Release of gas is shown by numerous pockmarks on the seafloor. The pockmarks at 1,300 m water depth are presently inactive, but they bear witness of earlier activity. Our study shows that from ~ 50–6 ka, the core site experienced repeated increases in BWT and in the emissions of gas, both following the pattern of the DO events. This correspondence in time scale indicates that BWT was the primary forcing factor for the variability in methane release. However, the releases were delayed by up to > 1,000 years compared to the initial increase in BWT.

Simulating water-limited potato yields across the Netherlands with (SWAP-)WOFOST: Experimentation, model improvement and evaluation

Water availability explains a large part of the spatial and temporal yield variability of ware potato in the Netherlands. Climate change is projected to lead to greater variability in water availability. Therefore, an accurate simulation of crop yield as a function of water availability is of high importance. Many crop models can simulate water-limited potato yields, but as detailed experimental data on drought and oxygen stress are scarce, models are often not well calibrated and evaluated. We set up a large experiment and an on-farm observational trial to calibrate and evaluate the simulation of water-limited yield of different potato cultivars across the Netherlands. In addition, we investigated the required model complexity to accurately simulate water-limited potato yields. The crop growth model WOFOST was used for simulations either as a single model or coupled with SWAP. Yields were simulated applying either only drought stress or by including both drought and oxygen stress. We employed two methods for simulating oxygen stress in SWAP-WOFOST. The calibration improved accuracy of simulated water-limited yields as demonstrated in our model evaluation. Both on sandy and clayey soils, water-limited yields were best simulated using SWAP-WOFOST while simulating oxygen stress using a process-based method in combination with a rooting density that decreases linearly with rooting depth. On sandy soils, the bottom boundary condition of free drainage was applicable. On clayey soils measured groundwater levels (or soil water pressure heads when measurements are not available) should be used as bottom boundary condition. On sandy soils both WOFOST and SWAP-WOFOST may be used, as results were similar. On clayey soils, WOFOST is less suitable, as it cannot simulate capillary rise. SWAP-WOFOST however has many options and parameters, which can result in large differences in results. Hence, a careful model set up and evaluation is required for each application.

Carbon isotope stratigraphy and biostratigraphy, and associated organic carbon deposition during the Late Cenomanian to Early Turonian in the Tarfaya Basin, Morocco

The Cenomanian-Turonian (C/T) boundary event, also known as Oceanic Anoxic Event 2 (OAE2), is characterised by significant organic carbon preservation and a positive carbon isotope excursion that is recorded globally in sedimentary strata. In this study of the Tarfaya Basin, Morocco, three outcrop sections were logged - at Lagguing East, Tazra, and En-Naila, dated from Late Cenomanian to Early Turonian. New dating, based on ammonites and planktic foraminifera, combined with high-resolution δ13C isotope stratigraphy, yields a more precise delineation of the C/T boundary in the studied section. A total of 99 samples were collected for combined sedimentological, mineralogical, and geochemical analyses to allow a better understand of the palaeoenvironments of deposition and interpret controlling factors on organic enrichment. Five lithofacies have been identified, all indicative of a relative deep marine setting. Variations in lithofacies can be correlated with relative sea level changes, which align with the global eustatic curve.The OAE2 interval comprises black mudstones that signal anoxic conditions, leading to significant organic matter (OM) preservation, even though they appear weathered in the studied section. Notably, organic matter-rich mudstones were evident during the post-OAE2 Early Turonian maximum marine transgression. Trace element enrichment in these organic-rick mudstones indicates that organic matter accumulation was accompanied with increased sea surface productivity and associated with oxygen-depleted bottom water conditions, which facilitated organic matter preservation and enrichment. Upwelling has also been previously described as a process to deliver nutrients to the shelf, enhancing productivity. Some units with depleted organic content are the result of dilution from continental derived clastics. Others may originally have had high TOC, but were influenced by weathering or diagenetic process, changing from the typical black mudstones to yellow in colour. The identified carbon isotopic values and organic carbon enrichment in the C/T strata of the Tarfaya Basin reflect signals of global perturbations in the carbon cycles.

High resolution 3D images of sediment cores as powerful tool for exploring foraminiferal microhabitats

Benthic foraminifera are marine protists largely used as bioindicators and proxies of paleo- environments. Epifaunal species are supposed to live at or above the sediment surface and are therefore used as proxies for bottom water conditions, while infaunal inhabit the sediment column, thus tracing porewater chemistry. Traditional analytical methods based on core slicing, however, have a low resolution that does not allow to precisely characterise the preferential microhabitat(s) of indicator species.In this study we performed microtomographic analyses on an experimental sediment core, to observe the life-position of living foraminifera of two surface-dwelling species Ammonia confertitesta and Haynesina germanica, reported both as epifaunal or shallow infaunal. The images we obtained offered for the first time the possibility to observe each individual in 3D space with a numerical resolution of 13 μm/voxel.The results revealed that the two species are never located above or at the sediment surface and have their preferential microhabitats in a sub-superficial sediment layer constrained in the 0–500 μm interval below the surface. Rapid decrease of abundances below this layer suggests that their microhabitat could be even more specific than previously thought.μCT-scan of sediment cores is also a valuable tool to obtain high-resolution information about foraminiferal ecology. The described method is useful to assess the effective microhabitat of all foraminiferal species that are usually used as proxies for paleorecords, to ensure that the information we can obtain from them is attributable to bottom water or to porewater conditions at a specific sediment depth.

Effect of a harmonic surface pressure on wave propagation over a beach

The objective is to study the harmonic forced wave motion over a beach by a finite Fourier transform technique. The constructed approximate solution has a logarithmic singularity at the shoreline. It accounts for reflexion and local perturbations. Trapping of waves may take place for particular choices of the applied surface pressure excess. The case of a wave incident against a cliff with horizontal bottom is solved exactly. The method deals invariably with a variety of bottom shapes, including the case where there is an additional corrugation of the bottom on a finite interval. Other bottom boundary conditions than impermeability can be treated as well. The results may be of interest in several practical applications, in particular the evaluation of the reflected wave. Numerical applications for a plane sloping beach, a parabolic-type beach and a shelf-type beach are presented and the systems of streamlines have been drawn over and in the proximity of the beach.

Multi-layer non-hydrostatic free-surface flow model with kinematic seafloor for seismic tsunami generation

Earthquake induced tsunamis pose devastating threat to coastal communities worldwide. Accurate description of tsunami generation by kinematic fault rupture is of importance to investigate earthquake events and evaluate tsunami impacts. The paper develops a multi-layer non-hydrostatic model with a kinematic bottom boundary condition and conducts comprehensive validation to examine the model’s capability in resolving seismic tsunami generation. The two-dimensional governing equations of the multi-layer non-hydrostatic free-surface flow system equipped with kinematic seafloor displacement is first introduced in Cartesian coordinates. A combined finite difference and finite volume scheme is utilized to discretize the governing equations with flow variables arranged on a staggered Arakawa C-grid. Application of pressure correction technique to the discretized formulations yields Poisson-type equations from which the non-hydrostatic pressure is solved for the next time step to complete the temporal integration. Based on existing analytical solutions, four groups of tsunami generation cases considering broad ranges of source parameters, including horizontal scale, rise time, and rupture velocity, are designed to demonstrate performance of the proposed non-hydrostatic model with one-, two-, and three-layers as well as the hydrostatic one. Comparison of 59 generation cases including extreme scenarios indicates the non-hydrostatic model performs better than the hydrostatic model in reproducing the entire waveform and predicting the maximum wave amplitude. High modeling accuracy can be achieved through incorporation of more layers. The proposed multi-layer non-hydrostatic model is a powerful tool for investigating earthquake source mechanisms and evaluating coastal tsunami hazards.

Investigation on the thermal performance of a dual driving force heat pipe under different working modes for thermal storage enhancement application

An embedded heat pipe (HP) with dual driving forces for compact and efficient thermal storage application was designed in this paper. To understand the thermal performance of the dual driving force heat pipe (DDFHP) under different heat storage and release conditions, an experiment testing platform was constructed. The influence of heating mode, heating load, and filling ratio (FR) on the working stability, thermal resistance, and effective thermal conductivity of the DDFHP were investigated and analyzed. The results mainly showed that under the bottom heating condition of the DDFHP, the thermal resistance of the DDFHP decreases with increasing heating power when the FR is low, and it first increases and then decreases when the FR is high. Among all the tested heating powers, the thermal resistance can be reduced to as low as 0.039 °C/W. Under the simulated heating conditions of phase change material on the DDFHP, at the same heating power, the thermal resistance of the DDFHP decreases first and then increases with the increase of the FR when the liquid filling height is less than 130 mm. In this case, the optimal FR of the DDFHP is 15 %, and the thermal resistance can be as low as 0.1 °C/W. The present study contributes to future HP applications in thermal storage enhancement.

Study on the safe distance of spatial intersecting tunnel cavern under ground shock

The vertical distance of intersection area is an important factor dominating the service performance of spatial intersecting cavern. To obtain the influence of vertical distance on the dynamic response of orthogonal spatial intersecting caverns under ground shock, the plastic region and peak particle velocity (PPV) distribution are investigated by numerical simulation. A finite-dynamic model is established to simulate the mechanical response of the deeply bureid structure subjected to coupled static and dynamic load, with an artifical boundary condition setting method. The results indicate that as the vertical distance decreases, the plastic region in the intersection area gradually merges, while the bolt support at the lower cavern vault effectively suppresses the destruction of the intersection area. The free surface of the lower cavern vault weakens the bottom support conditions of the upper cavern floor structure, resulting in higher PPV when vertical distance is smaller. Conversely, as vertical distance increases, isolation effect of upper cavern on ground shock weakens, leading to an increase and followed by a decrease in PPV at the lower cavern vault and straight wall. Morever, when vertical distance exceeds than 3 times the cavern characteristic size, the lower cavern exhibits dynamic response characteristics of deeply buried single-cavern. when vertical distance within 3 times, there is significant interaction between caverns with inverse relationship between dynamic axial stress on bolts in intersection area and PPV at lower cavern vault. It is recommended to use comprehensive criteria involving PPV and plastic region distribution to evaluate safety performance for spatial intersecting cavern.

Ebullition dominates methane emissions in stratified coastal waters

Coastal areas are an important source of methane (CH4). However, the exact origins of CH4 in the surface waters of coastal regions, which in turn drive sea-air emissions, remain uncertain. To gain a comprehensive understanding of the current and future climate change feedbacks, it is crucial to identify these CH4 sources and processes that regulate its formation and oxidation. This study investigated coastal CH4 dynamics by comparing water column data from six stations located in the brackish Tvärminne Archipelago, Baltic Sea. The sediment biogeochemistry and microbiology were further investigated at two stations (i.e., nearshore and offshore). These stations differed in terms of stratification, bottom water redox conditions, and organic matter loading. At the nearshore station, CH4 diffusion from the sediment into the water column was negligible, because nearly all CH4 was oxidized within the upper sediment column before reaching the sediment surface. On the other hand, at the offshore station, there was significant benthic diffusion of CH4, albeit the majority underwent oxidation before reaching the sediment-water interface, due to shoaling of the sulfate methane transition zone (SMTZ). The potential contribution of CH4 production in the water column was evaluated and was found to be negligible. After examining the isotopic signatures of δ13C-CH4 across the sediment and water column, it became apparent that the surface water δ13C-CH4 values observed in areas with thermal stratification could not be explained by diffusion, advective fluxes, nor production in the water column. In fact, these values bore a remarkable resemblance to those detected below the SMTZ. This supports the hypothesis that the source of CH4 in surface waters is more likely to originate from ebullition than diffusion in stratified brackish coastal systems.

Sulfide Toxicity as Key Control on Anaerobic Oxidation of Methane in Eutrophic Coastal Sediments.

Coastal zones account for 75% of marine methane emissions, despite covering only 15% of the ocean surface area. In these ecosystems, the tight balance between methane production and oxidation in sediments prevents most methane from escaping into seawater. However, anthropogenic activities could disrupt this balance, leading to an increased methane escape from coastal sediments. To quantify and unravel potential mechanisms underlying this disruption, we used a suite of biogeochemical and microbiological analyses to investigate the impact of anthropogenically induced redox shifts on methane cycling in sediments from three sites with contrasting bottom water redox conditions (oxic-hypoxic-euxinic) in the eutrophic Stockholm Archipelago. Our results indicate that the methane production potential increased under hypoxia and euxinia, while anaerobic oxidation of methane was disrupted under euxinia. Experimental, genomic, and biogeochemical data suggest that the virtual disappearance of methane-oxidizing archaea at the euxinic site occurred due to sulfide toxicity. This could explain a near 7-fold increase in the extent of escape of benthic methane at the euxinic site relative to the hypoxic one. In conclusion, these insights reveal how the development of euxinia could disrupt the coastal methane biofilter, potentially leading to increased methane emissions from coastal zones.

Microbial communities around seeds promote Zostera marina germination

Eelgrass meadows are vital not only for sustaining marine biodiversity as marine ecosystems but also for carbon fixation as blue carbon. However, the national decline in eelgrass meadows in Japan, which was initiated by economic growth in the 1980s, prompted the implementation of conservation measures. This study explored the fundamental techniques of the sediment environment to enhance Zostera marina seed germination rates. We investigated the microbial origin of Zostera marina seeds under anaerobic conditions and assessed their germination efficiency. Anaerobic sediments in the eelgrass meadows were found to increase eelgrass germination rate by 6% more than aerobic sediments. And interestingly, the sulfate-reducing bacteria Desulfovibrionaceae and Sulfurospirillaceae were detected mainly on eelgrass seeds. Our result clearly indicated that the sulfate-reducing bacteria around Zostera marina seeds create anaerobic conditions that promote germination through their sulfate-reducing function. Therefore, when developing new eelgrass meadows, it can be expected to improve germination rates by preparing the sediment environment to facilitate the increase of SRB coexisting with seeds. However, the difference in bottom sediment conditions varies by region, so it is necessary to be careful when adding or removing something. In addition, germination and growth of eelgrass must be considered separately, and factors that promote growth are not described in this work. The result of this study was an important finding for the implementation of Blue Carbon activities to improve sediment quality prior to the creation of eelgrass meadows and can also support eelgrass meadows maintenance after establishment.

Biogeochemical dynamics underlying equilibrium between nitrogen fixation and denitrification and its impact on a coastal marine ecosystem model

Many ecosystem models have chronic issues that result in unrealistic oligotrophic conditions in the shallow coastal regions. This problem is attributed to the poorly resolved bottom boundary condition for ecological tracers; detritus reaching the bottom boundary in shallow water escapes the model domain resulting in continuously decreasing total nitrogen levels. The scaling for the problem is determined by a vertical length scale wd/δ, where wd is detritus sinking speed and δ is remineralization rate. For shallow water depths h≪wd/δ corresponding to shallow marginal coastal ocean regions where loss of nitrogen is significant, ecosystem models predict unrealistic oligotrophic water masses. To alleviate the problem, the classical Nutrient-Phytoplankton-Zooplankton-Detritus (NPZD) model is expanded here to consider denitrification and nitrogen fixation. Internal dynamics of the expanded model are examined through steady-state solutions. The intensity of denitrification, scaled as the ratio between wd/δ and water depth, plays an important role sustaining nitrogen fixers by regulating phosphorus competition with normal phytoplankton. The theoretical equilibriums of the expanded model well represent characteristics of coastal and pelagic ecosystems. The expanded ecosystem model is then fully coupled with a numerical hydrodynamics model and compared with the classical NPZD model. It is shown that unrealistic oligotrophic conditions along the coast predicted by the classical NPZD model are not present when denitrification and nitrogen fixation processes are considered because strong denitrification (loss of nitrogen) in the shallow region enhances nitrogen fixation that compensates the loss.

The Messinian paleoenvironment in the Mediterranean (Monte dei Corvi, Ancona): A comparison with the modern oceanographic conditions

The Messinian was characterized by peculiar biogeochemical dynamics and climate in the Mediterranean region, testified by widespread deoxygenation events (sapropel) and evaporite deposition. To constrain the Mediterranean response to past perturbation it is crucial to understand the current environmental crisis related to climate change. In this regard, benthic and planktic calcareous fossils provide valuable insights into surface and bottom water conditions during deoxygenation events.Here we studied in high resolution 4 sapropel-bearing cycles of the Monte dei Corvi (Ancona, Italy), which recorded the behavior of the Adriatic Deep-Water formation, a major controlling factor for the oxygenation in the modern Eastern Mediterranean. Our analysis unveils fluctuations in planktic and benthic assemblages driven by variations in insolation parameters. Sapropel interbeds deposited during insolation maxima exhibit warm-oligotrophic and Deep Chlorophyll Maximum taxa, suggesting warming and freshening of surface water, leading to weakened Adriatic Deep-Water formation and reduced oxygen delivery to the bottom. Marly limestone/marlstone interbeds exhibit the dominance of cold-eutrophic taxa and an abundance of fecal pellets with monospecific/oligospecific calcareous nannofossils taxa (Umbilicosphaera jafari and Reticulofenestra perplexa), suggesting moderately high salinity and sustained productivity during phases of strong mixing.Comparisons between Messinian and the present-day setting reveal significant differences in the abundance and distribution of calcareous planktic assemblage, mostly due to heightened productivity during the Messinian, a response to restricted conditions that increased the basin's susceptibility to nutrient-delivering runoff. This circumstance played a significant role in the widespread deoxygenation and accumulation of organic carbon during the Messinian.The uncertain trajectory of primary production in the Mediterranean complicates precise predictions of the future oxygen balance. Insights from the Messinian underscore the crucial role of primary productivity in shaping bottom oxygen conditions, emphasizing the necessity for ongoing investigations.

Enrichment mechanism of organic matter and silicon in lower Cambrian shale of the Yangtze Platform

Early Cambrian time witnessed accumulation of high-quality organic-rich siliceous shale deposits that comprise an especially promising shale gas exploration target, especially in China. The present study of the Cambrian Niutitang Formation of the shelf area of the Upper Yangtze Platform utilizes mineralogical and elemental geochemical data to aide in the paleoenvironment reconstruction of these organic-rich deposits. We are especially interested in elucidating organic carbon and silicon enrichment mechanisms of the Niutitang Formation that will benefit shale gas exploration and development of these deposits. The Niutitang Formation can be subdivided into three intervals based on lithology, gamma ray (GR) signature, and TOC abundance. Enriched TOC (average = 6.7%) and nano-size authigenic microcrystalline quartz (Qn) contents of Interval I deposits likely reflect deposition in an environment that experienced persistent euxinic and elevated organic matter delivery associated with enhanced paleoproductivity driven by hydrothermal activity. Interval II shale is interpreted to have accumulated under euxinic-ferruginous conditions that experienced the effects of robust paleoproductivity and diminished terrigenous input related to persistently warm, humid climatic conditions. Enriched TOC (average = 4.9%) and moderate microcrystalline quartz content of these deposits were likely the result of redox conditions and elevated paleoproductivity. Interval III strata appears to have accumulated under oxygenated bottom conditions that experienced moderate paleoproductivity, brackish water and elevated terrigenous detritus input driven by the establishment of cold, dry climatic conditions. The combined results of these conditions are diminished TOC content (average = 0.7%) and enrichment of the sediment in terrestrial quartz. The elevated content of authigenic quartz appears to have diminished the reservoir capacity of Niutitang Formation shale. Interval II organic-rich siliceous shale deposits of Upper Yangtze Platform shelf areas, which have the comparable authigenic microcrystalline quartz content, reservoir performance, and greater organic matter abundance as the rift trough, appear to comprise the stratigraphic horizon with the greatest exploration and development potential. Results of the present study offer theoretical guidance for future shale gas exploration and development efforts in geologically similar regions.

Late Miocene to Early Pliocene paleoceanographic evolution of the Central South Pacific: A deep-sea benthic foraminiferal perspective

The bottom water conditions in the Central South Pacific (CSP) and associated changes in the Lower Circumpolar Deep Water (LCDW) and Antarctic Bottom Water (AABW) under warmer-than-present conditions need to be better understood. These water masses transfer their properties to the major ocean basins. We analyzed Late Miocene to Early Pliocene (5.6–3.6 Ma) marine sediment core sections from the CSP for benthic foraminifera, ice rafted debris (IRD), Ostracoda, planktic foraminifera Orbulina universa abundance, and organic geochemical proxies to assess the bottom water characteristics under warmer-than-present day conditions. A significant increase in IRD abundance between 5.3 and 4.9 Ma marks the Early Pliocene warm phase. The benthic foraminiferal assemblages indicate shifts in bottom water conditions over time in the CSP region. Between 5.6 and 5.3 Ma, predominantly oxygenated bottom water with moderate organic matter flux prevailed. This shifted to suboxic conditions with increased organic matter flux from 5.3 to 4.9 Ma. Subsequently, between 4.9 and 4.4 Ma, bottom water conditions alternated frequently between oxic and suboxic states. Enhanced bottom water formation and inflow of LCDW and AABW in the CSP during 4.4–4.0 Ma promoted oxygenated conditions, accompanied by low organic export flux. However, sluggish bottom water circulation from 4.0 to 3.6 Ma reverted to suboxic conditions, associated with increased carbon burial. Notably, productivity peaked intermittently between 5.3 and 3.6 Ma, as indicated by the occurrence of suboxic species assemblages and increase in the abundance of Orbulina universa, benthic microfauna (ostracods), and other paleoproductivity indicators.

Effect of static compression on near-field tsunami waves: Three-dimensional solution

An analytical solution of three-dimensional surface wave profiles due to arbitrary spatio-temporal disturbance of a circular ocean bottom in a compressible ocean is obtained by incorporating the influence of the static ocean background compression under the assumptions of linearized water wave theory. Time-domain simulations of the surface profile in three dimensions and the pressure distribution within the water column for a circular uniform rise and tilt are shown. The corresponding animation movies depict the temporal evolution of the surface profile and pressure field inside the water column eloquently, which was not shown in earlier literature. The impact of static compression is also discussed through the simulations. A novel analytical expression of the potential function for a generic tilted motion (rmcos(mθ),m∈Z) of the circular ocean floor is derived. An efficient numerical code is developed to find surface elevation and pressure distribution, implementing the inverse Fourier integral as matrix multiplication. Validation is performed for the specific case of a rising flat ocean floor, showing the oscillations due to acoustic-gravity modes. Initially, a simplified problem of a flat rising ocean bottom is solved using the eigenfunction matching method, which involves finding a particular solution for the nonhomogeneous ocean bottom condition and the solution for its homogeneous counterpart. Solutions are obtained using a newly developed inner product between the depth-dependent functions. Later, a Green function technique is used to incorporate the impact of the arbitrary spatio-temporal motion of the circular portion of the ocean bed. The solution obtained from the eigenfunction matching method is utilized to obtain the analytical form of Green’s function and, eventually, an expression of surface elevation and pressure distribution inside the ocean water column.