Abstract The demand for carbon-free fuels such as NH3 and H2 has been growing due to stricter environmental policies on carbon emissions. Since ammonia is easier to store and transport, it is considered an alternative fuel for marine, aviation, and gas turbine industries. However, the narrow flammability, low reactivity, and potential emissions of NOx are important challenges that need to be overcome if ammonia is to be used as a practical fuel for industrial use. Recent works have provided experimental data on the characteristics of NH3 flames under premixed and non-premixed combustion, focusing on flame speed, turbulence-chemistry interaction, and especially the dissociation/cracking of NH3 into H2 and N2. These measurements have encouraged the use of CFD for the simulation and scaling of practical ammonia systems, evaluating the performance of different numerical models for NH3 combustion. In this study, LES is utilized to predict a series of NH3/H2/N2 non-premixed flames stabilized on a bluff body burner. The accuracy of the FGM combustion model combined with LES has been examined, using a commercial CFD solver. The different cracking levels of NH3 into H2 and N2 lead to simulation cases ranging from an H2/N2 flame (i.e., “fully cracked”), to a flame with 50% NH3 (i.e., “half cracked”). The different flame shapes, temperature distributions, and NOx emissions have been simulated, generally matching well experimental data. The developed numerical settings and workflows may be applied to simulating more complex combustors which use NH3 as a fuel.
Read full abstract