Polyester Blends Research Articles

On the use of lignocellulosic hemp fibers to produce biodegradable cost-efficient biocomposites

In this study, the ability of natural hemp fibers (HF) to act as fillers in biodegradable biocomposites has been evaluated by mixing different concentrations of HF with commercially- available biodegradable polyesters, aiming at incorporating the maximum amount of HF to obtain a cost-effective new material in a sustainable approach. Blends of poly(hydroxy‑butyrate) (PHBV) and poly (butylene adipate-co-terephthalate) (PBAT) were used as polymeric matrix. HF were washed and ground before use. They were mainly composed of lignin (̴ 22 %) and carbohydrates (̴ 62–67 %) but a significant amount of proteins (̴ 8.77 %) was also detected. The polymer-HF composites were produced by melt-compounding using mild conditions and shaped as films by compression-molding to obtain test specimens used in the characterization of the biocomposites. The effect of HF loading on the final performance of the biocomposites was investigated. Interestingly, up of 40 % of HF could be incorporated as fillers into the PHBV-PBAT polymeric matrix. The incorporation of HF improved mechanical performance when compared to the polyester blends. In order to reduce its water sensitivity of the composites, food-grade beeswax or carnauba wax were incorporated within the polymeric matrix filled with HF, and the resulting biocomposites showed similar mechanical properties than their counterparts prepared without waxes but displayed significantly higher hydrophobicity.

Accelerated Crystallization and Preferred Formation of a Thermally Stable Crystal Phase in Enantiomeric Blends of Long-Spaced Chiral Polyesters

Accelerated Crystallization and Preferred Formation of a Thermally Stable Crystal Phase in Enantiomeric Blends of Long-Spaced Chiral Polyesters

Polyurethanes Synthesized with Blends of Polyester and Polycarbonate Polyols—New Evidence Supporting the Dynamic Non-Covalent Exchange Mechanism of Intrinsic Self-Healing at 20 °C

Polyurethanes (PUs) synthesized with blends of polycarbonate and polyester polyols (CD+PEs) showed intrinsic self-healing at 20 °C. The decrease in the polycarbonate soft segments content increased the self-healing time and reduced the kinetics of self-healing of the PUs. The percentage of C-O species decreased and the ones of C-N and C=O species increased by increasing the polyester soft segments in the PUs, due to higher micro-phase separation. All PUs synthetized with CD+PE blends exhibited free carbonate species and interactions between the polycarbonate and polyester soft segments to a somewhat similar extent in all PUs. By increasing the polyester soft segments content, the storage moduli of the PUs decreased and the tan delta values increased, which resulted in favored polycarbonate soft segments interactions, and this was related to slower kinetics of self-healing at 20 °C. Although the PU made with a mixture of 20 wt.% CD and 80 wt.% PE showed cold crystallization and important crystallinity of the soft segments, as well as high storage moduli, the intercalation of a small amount of polycarbonate soft segments disturbed the interactions between the polyester soft segments, so it exhibited self-healing at 20 °C. The self-healing of the PUs was attributed to the physical interactions between polycarbonate soft segments themselves and with polyester soft segments, and, to a minor extent, to the mobility of the polymeric chains. Finally, the PUs made with 40 wt.% or more polyester polyol showed acceptable mechanical properties.

Modifying Cassava Starch via Extrusion with Phosphate, Erythorbate and Nitrite: Phosphorylation, Hydrolysis and Plasticization.

Extrusion processing of plasticized cassava starch, a prominent industrial crop, with chemical additives offers a thermo-mechanical approach to modify starch structures through physical and chemical interactions. This research investigates the interaction and morphology of thermoplastic cassava starch (TPS) blended with tetrasodium pyrophosphate (Na4P2O7), sodium tripolyphosphate (Na5P3O10), sodium hexametaphosphate (Na6(PO3)6), sodium erythorbate (C6H7O6Na), and sodium nitrite (NaNO2) via twin-screw extrusion. The effects of these additives on the chemical structure, thermal profile, water absorption, and solubility of the TPS were examined. The high temperature and shearing forces within the extruder disrupted hydrogen bonding at α-(1-4) and α-(1-6) glycosidic linkages within anhydroglucose units. Na4P2O7, Na5P3O10 and Na6(PO3)6 induced starch phosphorylation, while 1H NMR and ATR-FTIR analyses revealed that C6H7O6Na and NaNO2 caused starch hydrolysis. These additives hindered starch recrystallization, resulting in higher amorphous fractions that subsequently influenced the thermal properties and stability of the extruded TPS. Furthermore, the type and content of the added modifier influenced the water absorption and solubility of the TPS due to varying levels of interaction. These modified starch materials exhibited enhanced antimicrobial properties against Escherichia coli and Staphylococcus aureus in polyester blends fabricated via extrusion, with nitrite demonstrating the most potent antimicrobial efficacy. These findings suggest that starch modification via either phosphorylation or acid hydrolysis impacts the thermal properties, morphology, and hydrophilicity of extruded cassava TPS.

Entrapment of Amphipathic Drugs in Core-Shell Polymeric Nanoparticles under Batch Conditions─The Role of Control and Solubility Parameters.

The amphipathic bioactive compounds curcumin, resveratrol, and mitomycin C, which have similar solubility parameter component distributions, have been studied for encapsulation under batch conditions into core-shell nanocarriers composed of external hydrophobically functionalized polyelectrolytes and an inner matrix of polyesters or polyester blends: poly(l-lactide), poly(lactide-co-glycolide), and/or poly(ethylene succinate). Our contribution comprises determining the influence of process parameters on the properties and quality of the final products, namely core-shell nanoparticles loaded with appropriate drugs, according to process analysis technologymanagement. The crucial roles of the organic phase dosing rates and process temperatures were carefully investigated. Moreover, a technically feasible method of removing organic solvents from aqueous dispersions─stripping with inert gas─was employed and evaluated via FT-IR studies. The experiments were supported by the calculation and analysis of solubility parameters (δ) and dispersion (δd), polar (δp), and hydrogen bond (δh) components utilizing HSPiP software. The payload locus and sample morphology were studied via atomic force microscopy and X-ray photoelectron spectroscopy analyses with Ar+ sputtering. It was demonstrated that dosing rates of organic phases not exceeding ca. 0.5 mL/min per 1 L of aqueous dispersion of hydrophobically functionalized polyelectrolytes made it possible to obtain core-shell nanoparticles of ca. 100-150 nm with a very narrow polydispersity (PdI < 0.2). The locus of amphipathic payloads in nanocarriers, mostly within the core polymeric structure, was in good agreement with the results of solubility parameter component studies: water-insoluble polyesters with both polar and nonpolar interactions between chains serve as good host materials for amphipathic drugs.

Environmentally sustainable apparel merchandising of recycled cotton-polyester blended garments: Analysis of consumer preferences and purchasing behaviors

This research work examines how consumer behavior and purchasing pattern are affected by recycled cotton-polyester blended clothing, with a particular emphasis on sustainable apparel merchandising. The use of recycled materials has drawn a lot of attention as environmental sustainability in the fashion business is growing attention. In order to investigate customer behavior, perceptions, preferences and purchasing decisions regarding recycled cotton-polyester blended clothing.This research employed a mixed-methods design that included both qualitative and quantitative methods. For a deeper understanding of the customer attitudes, opinions and motives towards sustainable fashion recycled materials in particular, this phase qualitatively involves a one-on-one interview and focus group discussions based on age, gender social class as well as the level of education. In addition, the study considers aspects such as longevity in use, wear resistance, quality, ease of use and clothing comfort that influence buying decisions. Using data from the qualitative phase as a foundation, the quantitative phase uses surveys given to a broad consumer sample to measure consumer preferences and purchasing pattern for recycled cotton-polyester clothing. This research aims at identifying the key factors that impact the preference of customers and buying behavior for recycled cotton and polyester blends based apparel. Additionally, it aims to assess how well sustainable clothing merchandising techniques work to promote these goods. This study indicates that individuals aged 25–45 from higher social strata and with higher educational attainment exhibit greater awareness and preference for recycled apparel with more than 60 % demonstrating a marked inclination towards these products.

A super-toughened polyethylene naphthalene (PEN) enabled by polyacrylate elastomer with low crosslink density and reactivity

In elastomer toughening of polyester plastics, both the particle size distribution of the elastomer and the interfacial strength between the elastomer and matrix are key factors for toughness. In this work, bi-functional polyacrylate elastomers with controllable crosslinking density and reactivity were designed for enhancing the toughness of polyethylene naphthalene (PEN) matrix. Firstly, the elastomers with crosslinked structure possess increased melt viscosity and endowed wide particle size distribution, which contribute to the construct of thin matrix ligament and make PEN matrix more susceptible to shear-yield. Secondly, the high interfacial strength between elastomer and matrix can facilitate the transfer of external stress from PEN matrix to the elastomer, protecting the matrix from destroying. The resulted PEN blends exhibit an excellent impact resistance of 45.20 kJ/m2 and a high tensile toughness of 3.586 MJ/m3, which are 21.73 times and 47.81 times higher, respectively, than the virgin PEN. The present work may provide an effective approach for designing polyester blends with enhanced impact resistance and tensile toughness.

Date estimation of fabrication and repair of Color garments encouragement banner

The Color Garments Encouragement Banner was designated a Korean Heritage in 2014 to recognize it as the most significant object of the color garments encouragement campaign. However, despite its significance, nothing is known about its manufacture. Therefore, this study attempted to analyze the materials of the banners to estimate when they were manufactured and repaired. The investigation of materials on the banner involved visual examination, literature review, microscopy, SEM–EDS, FT-IR, Py-GC–MS, ICP-MS, and LC–MS. The fabric, patch, and threads comprising the artifact were identified as cotton. FT-IR and Py-GC–MS confirmed that the repair patch was a woven blend of polyester and cotton yarns. EDS analysis indicated that the polyester was treated with titanium delustering. ICP-MS detected high concentrations of chromium that were not used in traditional dyeing techniques. The azo and sulfur compounds were identified by LC–MS analysis. The material layered on the grommet patch was thought to be a mixture of Pb, Ti with CaCO3 and BaSO4. Based on the overall results, the production date of the banner was narrowed down to the late 1920s, and the repair date to the mid-1950s. Although the materials used could not be identified owing to the limitations of the applicable analysis. Nonetheless, it is hoped that the analyses conducted in this study can serve as a scientific foundation for dating modern cultural heritage objects with limited handed-down record and historical documentation.

Hydrolytic-Assisted Fractionation of Textile Waste Containing Cotton and Polyester

Resulting properties of cotton and polyester blends make polycotton the most common fabric in textile industry. Separation technologies are key for the chemical processing of the massive amount of polycotton waste produced worldwide. The very different chemical nature of cellulose and polyethylene terephthalate determines the fractionation strategies to obtain two valuable monomaterial streams. In this work, we propose separation pathways seeking the conversion both polymers. First, polyester was depolymerised into its monomeric units through catalytic alkaline hydrolysis. The combined effect of alkali concentration and the catalyst was analysed to overcome the hydrophobic nature of polyester and optimise its conversion rate minimising the damaged caused to the cellulose chains. Conversion rates up to 80% were reached in a single separation stage with a limited effect of the polymer chain distribution of cellulose which remains a fiber-grade feedstock. Alternatively, cellulose was fully removed by selective dissolution in ionic solvent and subsequent filtration resulting in a spinnable mixture. Finally, enzymatic treatments for the conversion of cellulose into fermentable sugars were studied. Single stage conversions of 65% were achieved after maximizing the enzymatic activity. Structural and spectroscopic analysis showed that crystalline domains of textile-grade cotton limit the enzymatic activity. Optimal fractionation process is, in our view, highly context dependent what conveys to seek a variety of alternatives seeking for chemical processes driven by the ulterior up-cycling of the monomaterial streams

Design and analysis of biodegradable and potentially biobased multiphase systems from starch and co-polyesters

To develop tailored and performing biodegradable multilayer systems with polyester as cap layers and thermoplastic starch (TPS)/polyester blends in the core, several TPS-based blends, with varying formulations and several biodegradable and potentially biobased polyesters, were first elaborated. Poly(butylene adipate-co-terephthalate) (PBAT), poly(butylene succinate) (PBS) and poly(butylene succinate-co-adipate) (PBSA) were tested. The TPS-based blends for the core layer were compatibilized with a multifunctional epoxide styrene-acrylic reactive chain extender. As evidenced by tensile tests, the compatibilization was more effective with blends based on PBAT, probably due to its higher number of reactive chain ends. Multilayer films comprising neat PBAT cap layers and a TPS/PBAT blend, compatibilized or not, as a core layer were then elaborated by coextrusion. Thanks to the PBAT cap layers, the multilayer films had improved thermal stability and water vapor barrier properties, while TPS in the core layer added oxygen barrier properties to the global systems. In connection with the applications, the biocompatibility was also demonstrated through cell growth tests. The suitability of such multilayer films for biodegradable packaging linked to biomedical applications was thereby confirmed.

Sustainability of Blended Textile. Life Cycle Analysis

Textile fibers are derived from natural and artificial fibers and, in some cases, are blended together to ensure optimum properties. Textiles made from cotton and polyester blends currently hold a significant market share as they are relatively inexpensive, offer excellent performance, and have complementary properties. This textile blend is commonly used in everyday apparel. However, the production and consumption of textiles contribute significantly to environmental degradation and greenhouse gas emissions, but the scale of the impact is uncertain and under debate. This is also the case in studies of cotton and polyester blends, as a detailed life cycle inventory of the production of this material is absent in the scientific literature, thus affecting its environmental impact assessment. Therefore, the aim of this study is to fill the knowledge gap by assessing the environmental impacts of cotton and polyester blend production and to establish a comprehensive life cycle inventory for the material. The findings of the study can contribute to a more comprehensive evaluation of the life cycle of cotton and polyester blend textile products and work as a baseline scenario for the environmental impact assessment of various innovative textile recycling technologies. This is especially important as recycling of cotton and polyester blends is currently a major challenge. Additionally, these results can be of practical significance to assist businesses and policy makers in making environmentally informed choices.

Influence of plastic shape on interim fragmentation of compostable materials during composting

Common experience with rotting wooden buildings demonstrates that fragmentation is a necessary natural process during biodegradation. In analogy, the loss of structural integrity of biodegradable plastics during biodegradation produces interim microplastic fragments. It is currently not known which parameters govern fragmentation kinetics: chemical structure, physical shape, and composite layers, or composting conditions may all be relevant. Here we investigated the influence of physical shape on the fragmentation of a polyester blend during laboratory tests simulating industrial composting. Methods previously validated on micronized granules as model shape were applied to shapes that better represent consumer products, such as micronized thin films and shredded plastic-coated paper cups. The peak interim number of detected fragments, which are between 3 and 2000 µm, ranked highest for micronized films, lower for micronized plastic granules, and even lower for coated paper cups. The layered structure of polyester on cellulose may thus have stabilized the biodegrading polyester compound against fragmentation. For thin films, fragment counts dissipated with halftime of 2.5 days, and less than 10–8% of the initially added polyester mass was detected in fragments between 3 and 25 µm at the last sampling time point. The physical shape and multilayer structure of the polymer-containing product were found to be decisive for fragmentation kinetics, indicating that tests on micronized polymer granules might not be representative of the release mechanism of fragments from consumer products containing plastic coatings.

Fabrication of gelatin-polyester based biocomposite scaffold via one-step functionalization of melt electrowritten polymer blends in aqueous phase

The rapid manufacturing of biocomposite scaffold made of saturated-Poly(ε-caprolactone) (PCL) and unsaturated Polyester (PE) blends with gelatin and modified gelatin (NCO-Gel) is demonstrated. Polyester blend-based scaffold are fabricated with and without applying potential in the melt electrowriting system. Notably, the applied potential induces phase separation between PCL and PE and drives the formation of PE rich spots at the interface of electrowritten fibers. The objective of the current study is to control the phase separation between saturated and unsaturated polyesters occurring in the melt electro-writing process and utilization of this phenomenon to improve efficiency of biofunctionalization at the interface of scaffold via Aza-Michael addition reaction. Electron-deficient triple bonds of PE spots on the fibers exhibit good potential for the biofunctionalization via the aza-Michael addition reaction. PE spots are found to be pronounced in which blend compositions are PCL-PE as 90:10 and 75:25 %. The biofunctionalization of scaffold is monitored through CN bond formation appeared at 400 eV via X-ray photoelectron spectroscopy (XPS) and XPS chemical mapping. The described biofunctionalization methodology suggest avoiding use of multi-step chemical modification on additive manufacturing products and thereby rapid prototyping of functional polymer blend based scaffolds with enhanced biocompatibility and preserved mechanical properties. Additionally one-step additive manufacturing method eliminates side effects of toxic solvents and long modification steps during scaffold fabrication.

Eco-friendly surface coating of wool/polyester blend fabric using a combination of montmorillonite and polyquaternium 10: Enhanced flame-retardant performance using layer-by-layer assembly

Wool and polyester blends are sensitive to heat and pose fire hazards. In this study, the flame retardancy of wool/polyester blended fabric was improved by coating montmorillonite (MMT) and polyquaternium-10 (PQ-10) using the layer-by-layer assembly (LBL) method. This was done to confirm the feasibility of combining eco-friendly materials such as MMT and PQ-10 coatings and to secure the flame retardancy of the wool/polyester blend. The phosphate-buffered solution enhanced the intermolecular forces during pretreatment. Scanning electron microscopy and Fourier-transform infrared spectroscopy analyses confirmed the successful deposition of the MMT/PQ-10 combination on the fabric, and the deposition on the fabric surface increased as the number of coating layers increased. The thermogravimetric analysis results showed that the MMT/PQ-10 combination effectively reduced the maximum decomposition temperature, contributing to improved high-temperature thermal stability. Additionally, compared with the untreated fabrics, the coated fabrics exhibited a 38.2% increase in residual substances, and flame-retardant properties enhanced up to 27.3%. As a result of the vertical flame test, the MMT/PQ-10 combination improves the cohesiveness of the fabrics and prevents melt dripping, contributing to the improvement of flame retardancy.

Injection molding of biodegradable polyester blends filled with mineral and sustainable fillers: Performance evaluation

AbstractThis research focuses on the melt processing of biocomposites from a biodegradable polymer blend mixed with hybrid fillers through injection molding technique. An optimized blend ratio (60/40 wt%) poly(butylene succinate‐co‐butylene adipate) (PBSA) and poly(butylene adipate‐co‐terephthalate) (PBAT) demonstrated promising results after blending with a mixture of walnut shell powder (WSP), corn starch and talc in various proportions for use in rigid packaging. The addition of hybrid fillers (i) 10% WSP with 15% talc and (ii) 5% WSP with 5% starch and 15% talc to the polymer blend (60%PBSA/40%PBAT) improved tensile modulus (160% and 162%, respectively) and flexural modulus (147% and 153%, respectively) because of the dispersion of stiffer talc and WSP. Following the addition of fillers, tensile strength of the composites decreased. However, flexural strength improved significantly after filler introduction because of better stress transfer ability. Rheological analysis of filled composites with starch or WSP (25%) depicted similar characteristics of the polymer blend, indicating lower viscosity than hybrid composites. The abundant hydroxyl groups in starch explained the increased water absorption and decreased contact angle compared with other composites. This research's novelty encompasses utilizing low‐cost biomasses with mineral filler into an under‐researched biodegradable polymer blend suitable for single‐use rigid packaging applications.

Effect of papain enzyme surface modification on hydrophilic and comfort properties of polyester/cotton blend fabric

In this study, the authors used an enzyme called papain sourced from the Carica Papaya to improve the comfort and water-absorbing properties of a fabric made from a blend of polyester and cotton (65/35). The experiment was designed using the Box Behnken method to determine the most important variable and the best levels of parameters. The focus was on testing the wettability, moisture regain, and surface characteristics of the material. The results showed that all the comfort properties of the fabric improved after treatment with papain enzyme. After testing different parameters, the best conditions for treating the fabric with papain enzyme were determined to be a temperature of 30 °C, a papain concentration of 14%, and a treatment time of 50 min. Under these optimized conditions, the moisture regain and wettability of the polyester/cotton blend fabric treated with papain enzyme improved to 1.9 ± 0.02% and 6 cm capillary rise (measured with a 2-s drop test and 2-s sinking time) within just 3 min of wicking time. The Polyester/cotton blend fabrics treated with papain enzyme exhibited several noteworthy characteristics, including a significantly reduced susceptibility to fabric pilling (4–5), a limited capacity to attract oily impurities, and a high oil-soil-release capability with a stain removal index of 85%. Additionally, the fabrics showed a one-order-of-magnitude decrease in surface resistivity under normal conditions, with a half-life decay time of 513 s. Observations of the treated fabrics revealed the presence of cracks, grooves, nanostructures, and a high degree of roughness on the surfaces that were treated with papain enzyme. To further evaluate the effects of the lipase enzyme treatment on the fabric properties, several tests were conducted, including Fourier Trasform Infrared spectroscopy (FT-IR), Thermogravimetric Analysis (TGA), Differential scanning calorimetry (DSC), Moisture Regain, Tensile Strength, Stain Repellency, pilling resistance, and Anti-static charge generation.

Development of a Tri-Layered Vascular Construct and In Vitro Evaluation of Endothelization.

Advances in the development of vascular substitutes for small-sized arteries are ongoing because the present grafts do not entirely meet the requirements of native equivalents and are suboptimal in clinical performance. This study aims to develop a tri-layered vascular construct mimicking natural tissue using polyester blends and to investigate its endothelization through in vitro studies as a potential small-caliber vascular graft. The innermost layer is obtained by dip coating as a tubular porous film with a lumen diameter of 3mm and a pore size of ≤8µm. Circumferentially aligned electrospun fiber (diameter 100-800nm) with a deviation angle of 15° are deposited over the porous film forming the intermediate layer. The random electrospun fibers (diameter 100-1100nm) deviating at different angles are wrapped as the outermost layer. The mechanical properties of the tri-layered vascular construct are determined to be 44.80±14.80MPa for Young's modulus and 4.25±0.75MPa for ultimate tensile strength. MTS and cell behavior studies show that the isolated human umbilical cord vein endothelial cells proliferate and line the lumen of the vascular substitute. The vascular construct developed, with its biomimetic architecture, mechanical features, size, and endothelization, can be tested with in vivo studies.

Understanding the Interactions between Soft Segments in Polyurethanes: Structural Synergies in Blends of Polyester and Polycarbonate Diol Polyols.

There are no previous studies on the interactions between polyols of different nature as a model for understanding the interactions between soft segments in PUs. In this study, different blends of two polyols of different natures (polyester-PE, and polycarbonate diol-CD) and similar molecular weights were prepared and their structural, thermal, surface, viscoelastic, and self-adhesion properties were assessed. Different experimental techniques were used: infrared spectroscopy (ATR-IR), differential scanning calorimetry (DSC), X-ray diffraction, thermal gravimetric analysis (TGA), and plate-plate rheology. PE showed a larger number of structural repeating units and a higher number of polar groups than CD, but the carbonate-carbonate interactions in CD were stronger than the ester-ester interactions in PE. The blending of CD and PE imparted synergic structural properties, particularly in the blends containing less than 50 wt.% PE, they were associated with the disrupt of the carbonate-carbonate interactions in CD and the formation of new ester-carbonate and hydroxyl-carbonate interactions. CD + PE blends with less than 50 wt.% PE exhibited higher glass transition temperatures, a new diffraction peak at 2θ = 24°, one additional thermal degradation at 426-436 °C, and a less-steep decline of the storage moduli. Furthermore, the different interactions between the polyol chains in the blends were also evidenced on their surface properties, and all CD + PE blends showed self-adhesion properties which seemed related to the existence of ester-carbonate and carbonate-carbonate interactions.

Sustainable Aspects of Multiple-Use Woven Fabric in the Hospital Environment: Comfort and Textile Dust Generation Perspectives

Textile dust released from hospital textiles is a considerable food source for pathogenic microorganisms and can lead to infections and illness in patients and medical staff. In addition, it often causes malfunctions in sophisticated medical equipment. The structural parameters of the fabric, such as the raw material composition, the thread density and the fabric weave, can influence the amount of dust produced. Friction between threads in a woven fabric plays a crucial role in dust generation, and friction is influenced by the surface structure of fibres, yarns and fabric. Understanding these factors can help in the development of fabrics with lower release of textile dust, which can reduce the risk of spreading infections in healthcare facilities. In this paper, the influence of the washing cycle on the change in morphological properties of fabrics in satin weave made of cotton–polyester blends was investigated. The study showed that as the number of maintenance washing cycles increases, the waviness, roughness and average amplitude of the surface roughness profile of the wove fabrics increases. Damage to the fibres during washing results in dust release, with synthetic fibres releasing less dust than cotton fibres. These results provide important information about the change in fabric properties during the washing process, which may be useful for further research and development of materials for use in a hospital environment.

Preparation and characterisation of polymer blends reinforced with nano-ZnO and study the thermal and electrical properties for industrial applications

Binary blends of unsaturated polyester (70%) and nitrile rubber (NR) (30%) and their composites are prepared. Zinc oxide nanoparticles (ZnONPs) were used as a filler in the hand-lay method. ZnONP weight ratios ranged from 0 to 3 ​wt.%. The ZnONPs were characterised using techniques such as X-ray diffraction (XRD) and scanning electron microscopy (SEM) to examine their crystalline structure and shape. The thermal and dielectric properties of the samples were examined as a function of filler content. Additionally, the theoretical and experimental densities of the nanocomposites were examined using the mixing rule and Archimedes’ principle, respectively. The thermal conductivity and diffusivity values exhibited variations between increasing and decreasing trends as the filler concentrations increased. Among all samples tested, the one containing 2.5% ZnONPs demonstrated the highest thermal conductivity and the lowest diffusivity when compared to the pure blend. As the ZnONP weight ratio increased, the corresponding dielectric constant value rose linearly, while the resistivity decreased linearly. Thermogravimetric analysis (TGA) revealed a significant improvement in the level of char yield and thermal stability of nanocomposites with increasing ZnONP concentration in the matrix.