Black Sand Research Articles

Taxonomic, Physiological, and Biochemical Characterization of Asterarcys quadricellularis AQYS21 as a Promising Sustainable Feedstock for Biofuels and ω-3 Fatty Acids

Asterarcys quadricellularis strain AQYS21, a green microalga isolated from the brackish waters near Manseong-ri Black Sand Beach in Korea, shows considerable potential as a source of bioactive compounds and biofuels. Therefore, this study analyzed the morphological, molecular, and biochemical characteristics of this strain; optimized its cultivation conditions; and evaluated its suitability for biodiesel production. Morphological analysis revealed characteristics typical of the Asterarcys genus: spherical to ellipsoidal cells with pyrenoid starch plates and mucilage-embedded coenobia. Additionally, features not previously reported in other A. quadricellularis strains were observed. These included young cells with meridional ribs and an asymmetric spindle-shaped form with one or two pointed ends. Molecular analysis using small-subunit rDNA and tufA sequences confirmed the identification of the strain AQYS21. This strain showed robust growth across a wide temperature range, with optimal conditions at 24 °C and 88 µmol m−2s−1 photon flux density. It was particularly rich in ω-3 α-linolenic acid and palmitic acid. Furthermore, its biodiesel properties indicated its suitability for biodiesel formulations. The biomass of this microalga may serve as a viable feedstock for biodiesel production and a valuable source of ω-3 fatty acids. These findings reveal new morphological characteristics of A. quadricellularis, enhancing our understanding of the species.

Characterization of Heavy Minerals and Their Possible Sources in Quaternary Alluvial and Beach Sediments by an Integration of Microanalytical Data and Spectroscopy (FTIR, Raman and UV-Vis)

Quaternary stream sediments and beach black sand in north-western Saudi Arabia (namely Wadi Thalbah, Wadi Haramil and Wadi Al Miyah) are characterized by the enrichment of heavy minerals. Concentrates of the heavy minerals in two size fractions (63–125 μm and 125–250 μm) are considered as potential sources of “strategic” accessory minerals. A combination of mineralogical, geochemical and spectroscopic data of opaque and non-opaque minerals is utilized as clues for provenance. ThO2 (up to 17.46 wt%) is correlated with UO2 (up to 7.18 wt%), indicating a possible uranothorite solid solution in zircon. Hafnoan zircon (3.6–5.75 wt% HfO2) is a provenance indicator that indicates a granitic source, mostly highly fractionated granite. In addition, monazite characterizes the same felsic provenance with rare-earth element oxides (La, Ce, Nd and Sm amounting) up to 67.88 wt%. These contents of radionuclides and rare-earth elements assigned the investigated zircon and monazite as “strategic” minerals. In the bulk black sand, V2O5 (up to 0.36 wt%) and ZrO2 (0.57 wt%) are correlated with percentages of magnetite and zircon. Skeletal or star-shaped Ti-magnetite is derived from the basaltic flows. Mn-bearing ilmenite, with up to 5.5 wt% MnO, is derived from the metasediments. The Fourier-transform infrared transmittance (FTIR) spectra indicate lattice vibrational modes of non-opaque silicate heavy minerals, e.g., amphiboles. In addition, the FTIR spectra show O-H vibrational stretching that is related to magnetite and Fe-oxyhydroxides, particularly in the magnetic fraction. Raman data indicate a Verwey transition in the spectrum of magnetite, which is partially replaced by possible ferrite/wüstite during the measurements. The Raman shifts at 223 cm−1 and 460 cm−1 indicate O-Ti-O symmetric stretching vibration and asymmetric stretching vibration of Fe-O bonding in the FeO6 octahedra, respectively. The ultraviolet-visible-near infrared (UV-Vis-NIR) spectra confirm the dominance of ferric iron (Fe3+) as well as some Si4+ transitions of magnetite (226 and 280 nm) in the opaque-rich fractions. Non-opaque heavy silicates such as hornblende and ferrohornblende are responsible for the 192 nm intensity band.

Patterns distribution, concentrations and sources of radioactive elements from black sand in the Red Sea coast, Egypt

In Egypt, the distribution of black sand in various coastal regions has been readily apparent by thorough research. Unfortunately, these investigations did not measure radioactivity in black sand, particularly in the vicinity of the Red Sea. Gamma-ray spectroscopy was used to detect the naturally occurring radioactivity from 238U, 232Th, 40K, and 226Ra in black sand samples from eight locations along the Red Sea coast: Ras Elbehar, Gemsa, Hurghada Elahiaa, Hurghada Titanic, Safaga, Qusier Elsharm Alqbly, Gabal Alrosass, and Marsa Alam. The resultant data were interpolated to represent the spatial distribution. Additionally, the potential rocks sources of radionuclides were geologically mapped to elucidate the relationship between rock components and radioactivity. The results showed that 226Ra, 232Th and238U were higher at samples collected from Ras Elbehar, Hurghada Elahiaa and Hurghada Titanic compared to the other sites. On the other hand, 40K showed the lowest mean value (75.3 ± 3.8 Bq/kg) in Hurghada Titanic samples, while it peaked (563 ± 28 Bq/kg) in Qusier Elsharm Alqbly samples. The interpolated results show notable differences in radioactive amounts between the north and south, which are indicative of several environmental conditions and human activities. Alkaline syenite, syenogranite, older granites (tonalite and granodiorite), and minor acidic volcanic/metavolcanic rocks make up the upstream area of the basin area draining into, for example, the Ras Elbehar locality (highest activity concentrations for 238U (1596 ± 80 Bq/kg) and 226Ra (886 ± 44 Bq/kg)), while alkali-feldspar granite, schist, and shale rocks make up the mid-stream area. The findings provide a basis for scientific forecasting on the impact of synthetic or naturally occurring radioactive isotopes introduced into aquatic environments.

Black sand nanoparticles and heat stress impacts the neurological and oxidative stress indices and splenic-renal histology of Clarias gariepinus

In Egypt, while many studies have focused on the radiometry and mineralogy of black sands, research on their effects on nearby aquatic organisms is rare. This study aimed to assess the combined effects of heat stress (HS) and black sand nanoparticles (BS-NPs) on renal function, antioxidant responses (TAC, SOD, CAT), neuro-stress indicators (AchE, cortisol), and to conduct histopathological investigations in the kidney and spleen tissues of African catfish Clarias gariepinus over a 15-day period to exposure to control, HS (32 °C), BS (6.4 g/kg diet) and HS + BS groups. The outcomes revealed that thermal stress alone showed no significant difference from the control. However, creatinine and uric acid levels were significantly higher in the BS-NPs and HS + BS-NPs groups (p < 0.001). Antioxidant markers (TAC, SOD, and CAT) were substantially reduced across all treated groups (0.05 ≥ p < 0.0001). AchE levels were significantly elevated in BS-NPs and HS + BS-NPs (p < 0.001), while cortisol levels were higher in these groups but not significantly different in HS. Degeneration and necrosis in the white and red pulps, scattered lymphocytes, and increased collagen fiber surrounding blood vessels and the lining of the ellipsoid structure were all evident in the spleen, along with the enlargement of the melanomacrophage centers with big granular, irregular, and brown pigments (hemosiderin). Our study, therefore, provides new insights into how heat stress, an abiotic environmental factor, influences the toxicity of black sand nanoparticles in catfish.

Baseline status of the levels and distribution of rare, noble, and fissionable elements from the Northern Nile Delta black sand deposits

This study examined the composition, distribution, and origins of rare, Noble, and fissionable elements for the first time in black sand deposits from the Northern Delta coastal region. The findings showed that among the elements under investigation, Fe, Ti, Mn, and Sn had the greatest mean levels, while Hf, Cd, and As had the lowest mean amounts. According to the study's elemental composition, black sand is thought to have economic worth for Ti, Zr, Hf, Sn, Ag, and W. The Zr, Co, Cd, Cu, Hf, V, W, and Zn correlation points to the same source origin. It is clear that the accessory mineral composition in the sediments under study especially the heavy ones controls the geochemical patterns of trace elements. The trace element concentrations of interest show a pattern of element variability related to the mineralogy of the sands, as indicated by the principal component analysis and cluster analysis. To explore and exploit heavy minerals in the research region, the study's findings are important.

Extraction and Separation of zirconium using Aliquat 336 from Egyptian black sand

A solvent extraction method has been employed to extract and separate zirconium from the nitric acid medium using 6% tri-caprylmethylammonium chloride (Aliquat 336) [CH3(CH2)7]3N+(CH3) Cl- dissolved in kerosene as diluent. The relevant factors controlling the extraction process of zirconium using Aliquat 336 were studied. These factors include Aliquat 336 concentration, A:O phase ratio, contact time and diluent type. More than 99.6% of Zr was extracted by 6% Aliquat 336 at contact time 10 minutes, phase ratio O:A (v: v) 2:1 and the diluent were kerosene. Third phase formation was studied and dissolving it by using decanol as modifier was also done. Stripping of zirconium from loaded Aliquat 336 has been carried out using 4M H2SO4 as an effective stripping agent. The feasibility of using Aliquat 336 for separation of zirconium was assisted by stripping studies. The loaded zirconium onto Aliquat 336 has been stripped by stripping efficiency 94.18% when using 4M H2SO4 as an efficient eluting agent at 10 minutes contact time and phase ratio O:A (v: v) 1:1.

Precious and Base Metal Minerals in Black Sands of the Egyptian Mediterranean Coast: Mineralogical and Geochemical Attributes

This paper investigates the mineralogical and geochemical characteristics, as well as the possible sources, of gold, silver, platinum group elements (PGE), copper, and lead found in the beach sands along Egypt’s Mediterranean coast. Using scanning electron microscopy and electron probe micro-analysis, this study determines the morphology and micro-chemistry of separated grains to assess their economic potential and how various minerals respond to different transport distances. The analysis reveals that gold grains are of high purity (94.11 to 98.55 wt.%; average 96 wt.% Au) and are alloyed with Ag (1.28–2.32 wt.%) and Cu (0.16–3.15 wt.%). Two types of gold grains were identified, indicating differences in transport distances. Variations in morphology, surface features, inclusion types, rims, and chemistry of the native metals, including gold grains, suggest differences in composition, weathering degree, transport distance, deposit types, and host rocks. The average Ag concentration in gold grains (1.86 wt.%) suggests a link to mesothermal or supergene deposits. Most silver, copper, and lead grains are spherical, with some variations in shape. Silver grains have 71.66–95.34 wt.% Ag (avg. 82.67 wt.%). Copper grains have 92.54–98.42 wt.% Cu (avg. 94.22 wt.%). Lead grains contain 74.22–84.45 wt.% Pb (avg. 79.26 wt.%). The identified platinum group minerals (PGM) belong to the Pt–Fe alloys and sperrylite, both of which are PPGE-bearing minerals. These metals likely originate from the weathering of upstream Nile tributaries surrounded by igneous and metamorphic rocks from Ethiopian and Central African regions, with a minor contribution from the Egyptian Eastern Desert Mountains.

Beach gold transport and aeolian concentration, southern New Zealand

ABSTRACT Aeolian concentration of iron-titanium oxides (black sand) is a common phenomenon on coasts around the world but associated aeolian detrital gold is relatively rare. In contrast, Holocene and active dunes at Waipapa beach on the coast of the southern South Island of New Zealand host aeolian black sand layers with locally abundant finely particulate (<200 µm) gold and platinum, some of which have been mined historically. Aeolian concentration of black sand, gold and platinum is driven by strong prevailing westerly winds (gusts >100 km/h) on annual or decadal time scales. Holocene fluvial recycling of aeolian sands has been important in upgrading the black sand, gold, and platinum contents. Surf concentration of black sand on the beach is minor and merely feeds the aeolian system, and this differs from other beach gold deposits around the world, which are surf-dominated. Most of the Waipapa beach gold (>90%) has flaky morphology with abundant superficial transport-related deformation reflective of fluvial transport, probably down the nearby Mataura River (∼200 km transport) between Miocene and Holocene. Minor distinctive wind-sculpted toroidal gold, and the platinum, arrived from the west (∼300 km transport) via the Waiau River and Foveaux Strait.

LAAN LUNDUYAN: A Volcanic Disaster Resilient Conservation Complex in Albay Biosphere Reserve Through Bionic Architecture

Albay Biosphere Reserve (ABR) aims to conserve biodiversity, support research and recreation, and promote sustainable economic development. However, threats and challenges are present, including a lack of institutionalized biodiversity monitoring systems, a low level of community awareness of ABR, and the looming threat from Mt. Mayon. This research aims to explore the role of bionic architecture in ABR management, while considering biodiversity conservation, addressing the vulnerability of structures in volcanic disasters, and the potential of tourism. To answer this, a descriptive research design with a mixed-method approach was employed to analyze the data gathered from selected barangays in the Mayon Unit of Ligao City. Research findings reveal the potential of bionic architecture for creating a design framework for guiding the development of a volcanic disaster- resilient conservation complex. The framework employs the principle of bionic architecture of incorporat ing the natural ways and processes in biological systems studied in coconut trees towards efficiency, resilience, and adaptability, using its six dimensions: role and patterns, materials, structure, form, function, and process. This proposes architectural features, including energy-efficient and resilient systems, materials such as Albay black sand, and coconut-based products, and key facilities contributing to conservation, and tourism development.

A non-contact solid particle moisture sensor based on near-infrared spectroscopy technology

The detection of moisture content in solid particles has important applications in fields such as biological research, coal mine production, and medicine. This article develops a non-contact solid particle moisture sensor (NcSPMS). NcSPMS uses the multi-light source detection method based on the principle of diffuse reflection absorption to detect the moisture content of solid particles with different particle sizes, distributions and colors. Firstly, the stacked LED light source structure (SLED-LSS) was designed to achieve illumination of LED light source for measurement (M-LED) and the LED light source for reference (R-LED) at the same position and exit angle, eliminating the influence of irregular particle size and distribution on diffuse reflected light intensity. Secondly, the stacked LED array light source structure (SLEDA-LSS) was designed to improve the detection light intensity and enable NcSPMS to detect the moisture content of solid particles of different colors. Thirdly, modulated light technology is used for the transmission of moisture content information. Two modulation frequencies were set to modulate the measurement light source and reference light source, and different intensities of square wave currents were determined to drive the M-LED and R-LED to improve detection accuracy. Fourthly, the FFT-KF data processing method was designed to effectively extract the information of diffuse reflection measurement light intensity. Finally, the function expression of moisture content was obtained through cubic fitting, and the detection of moisture content by NcSPMS was achieved. In order to verify the effectiveness of NcSPMS, the NcSPMS control system was designed. The experimental results show that compared with SLED-LSS, SLEDA-LSS improves measurement accuracy; the different current pairs driving M-LED and R-LED affect the measurement accuracy of NcSPMS; NcSPMS can detect the moisture content of white, yellow, green, red, and black sand particles, with the detection range of 0.10–11.00 %. The relative uncertainty obtained by applying NcSPMS to the detection of nickel ore particles is 4.37 %.

Leaching Efficiency of 238U and 232Th series from Granitic Soils

Granitic soil, a uranium (U) and thorium (Th)-bearing soil body, can be sourced to extract fissionable nuclides through leaching using acidic solutions. Limited research indicates the feasibility of extracting U and Th from granitic sources, necessitating further studies to optimize leaching efficiency and its potential as a fissionable fuel. This study investigates the leaching efficiency of the uranium 238U and thorium 232Th series, as well as 40K, in granitic soil samples. The study utilized a high-purity germanium detector (HPGe) to quantify the activity levels of the 238U and 232Th series and 40K in the studied samples. The black sand deposit and tin-tailing samples were also utilized to benchmark the finding of the leaching efficiency of the uranium 238U and thorium 232Th in granitic samples. The study found that the leaching samples contained low radioactivity levels that were a few to tenth times lower compared to the original samples, with tin-tailing samples exhibiting the highest leaching activity for 238U (630.05 Bq l-1) and 232Th (512.17 Bq l-1) and comparable to granitic soil samples 238U (437.7 Bq l-1) and 232Th (23.9 Bq l-1). Sulfuric acid showed the most efficient leaching reagent ~ up to 23% and 32% for 232Th and 238U, respectively. In comparison, nitric and hydrochloric acids exhibited low leaching efficiencies, ~ 1 – 13%. Overall, granitic soil shows comparable leaching rates to conventional sources of natural uranium nuclear fuel, making it a potential secondary and alternative nuclear fuel source.

Early snowmelt advances flowering phenology and disrupts the drivers of pollinator visitation in an alpine ecosystem

AbstractClimate change is altering interactions among plants and pollinators. In alpine ecosystems, where snowmelt timing is a key driver of phenology, earlier snowmelt may generate shifts in plant and pollinator phenology that vary across the landscape, potentially disrupting interactions. Here we ask how experimental advancement of snowmelt timing in a topographically heterogeneous alpine-subalpine landscape impacts flowering, insect pollinator visitation, and pathways connecting key predictors of plant-pollinator interaction. Snowmelt was advanced by an average of 13.5 days in three sites via the application of black sand over snow in manipulated plots, which were paired with control plots. For each forb species, we documented flowering onset and counted flowers throughout the season. We also performed pollinator observations to measure visitation rates. The majority (79.3%) of flower visits were made by dipteran insects. We found that plants flowered earlier in advanced snowmelt plots, with the largest advances in later-flowering species, but flowering duration and visitation rate did not differ between advanced snowmelt and control plots. Using piecewise structural equation models, we assessed the interactive effects of topography on snowmelt timing, flowering phenology, floral abundance, and pollinator visitation. We found that these factors interacted to predict visitation rate in control plots. However, in plots with experimentally advanced snowmelt, none of these predictors explained a significant amount of variation in visitation rate, indicating that different predictors are needed to understand the processes that directly influence pollinator visitation to flowers under future climate conditions. Our findings demonstrate that climate change-induced early snowmelt may fundamentally disrupt the predictive relationships among abiotic and biotic drivers of plant-pollinator interactions in subalpine-alpine environments.

Exergy, exergo-economic, environmental and sustainability analysis of pyramid solar still integrated hybrid nano-PCM, black sand, and sponge

A sustainable and cost-effective technique for desalinating water with solar energy to alleviate the freshwater scarcity is the solar still. In this study, four different cases including the case-I: conventional solar still (CSS), case-II: CSS with fins and black sand, case-III: CSS with fins, hybrid enhanced nano PCM, black sand and sponges, case-IV: CSS with fins, hybrid enhanced nano PCM, crushed stone and sponges have been comprehensively investigated in terms of thermal, productivity, exergy, economic, environmental and sustainability point of view. The assessments were executed at the Rajshahi (latitude: 24°22′N, longitude: 88°36′E), Bangladesh. Later, the performance case-III was investigated by using river (Padma) water and discolored water, respectively. Average thermal efficiency on daily basis of case-III is about 32.44 % and 6.47 % higher than case-II and case-IV due to the improved heat storing configuration. In addition, cases-II, III, and IV all had exergy efficiency improvements of 18.89 %, 74.75 %, and 53.54 %, correspondingly in comparison to case-I. For cases I, II, III, and IV, the payback periods are 185, 159, 126, and 135 days, accordingly. In cases-I, II, III, and IV, modified SS results in cost-per-litre reductions of 73.5 %, 77.29 %, 81.89 %, and 80.63 %, correspondingly, as compared to market prices. Cases-I, II, III, and IV's energy production factors are 0.137, 0.099, 0.138, and 0.195 yr−1, respectively. The research also supports the claim that adding fins, sponges, black sand, and hybrid enhanced nano-PCM to CSS results in a higher sustainability index.

Study of smelting Egyptian black sand ilmenite by using El Magara coal

Study of smelting Egyptian black sand ilmenite by using El Magara coal

Radionuclides distribution and radiation hazards assessment of black sand separation plant’s minerals: a case study

This study assessed the radioactivity levels and associated risks in the black sand-separated products obtained from the black sand separation plant in Delta, Egypt. A total of sixteen samples were taken from hot spots during and after the separation process. These include water samples and other samples that represent monazite, rutile, zircon, granite, ilmenite, and silica products. The hot spots included the area where the ore was stored. The activity concentrations of 232Th\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^{232}Th$$\\end{document}, 226Ra\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^{226}Ra$$\\end{document}, and 40K\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^{40}K$$\\end{document} were determined in these samples using a p-type HPGe detector. Based on gamma spectrometric analysis, samples of rutile, zircon, and monazite had the highest amounts of radioactivity because they contained the highest NORM’s activity concentrations. In addition, it indicated that the radiological hazard indices of the collected samples were higher than the average world limits for sand texture. These findings suggest that the black sand separation process reveals potential risks to human health and the environment, and therefore, appropriate measures need to be taken to mitigate these risks, especially for the safety of the workers on-site. Reducing the risk associated with those sites should be controlled by implementing the recommendations declared for the series of International Basic Safety Standards of the International Atomic Energy Agency (GSR) Part 3, as affirmed in Document No. 103 of 2007 by the International Commission on Radiological Protection (ICRP) as will be presented in the paper body.

Enhancing water productivity and cost-effectiveness in hemispherical solar stills using sandy beds, reflectors, and a vapor extraction fan

The objective of this study was to enhance the performance of hemispherical solar stills (HSS) through experimental investigations utilizing various types of sand beds as thermal storage materials. The research examined the influence of sand type (yellow and black) and sand bed heights (1, 2, and 3 cm) on the efficacy of HSS. Additionally, the study explored the effects of external reflectors and a vapor extraction fan on the performance of sand-based HSS. The experimental results indicated that HSS using black sand demonstrated superior performance compared to other operating conditions in terms of both productivity and efficiency. Particularly, the most significant improvement in performance for the black sand hemispherical solar still (BSHSS) was observed when employing reflectors and a fan with a sand bed height of 1 cm, resulting in a substantial 154% increase in production, where the production for hemispherical SS and BSHSS + fan and reflectors was 4100 and 10400 mL/m2.day, respectively. Under these optimized conditions, the thermal efficiency of BSHSS + R + F reached 56%. In conclusion, an economic analysis was conducted, revealing that the cost for water treatment was $0.022 per liter for the conventional hemispherical solar still (HSS) and $0.012 per liter for the BSHSS equipped with reflectors and a condenser. These findings represent a significant advancement in enhancing the feasibility and efficiency of solar distillation systems, thereby addressing the global challenges of water scarcity and environmental sustainability.

Effect of variations in concrete quality on the crack width in rigid pavement

Cracks pose a significant issue in rigid pavement, leading to substantial damage. The manual mixing and casting of road pavement concrete underscore the importance of concrete quality as a critical parameter. This study investigates crack behavior by varying concrete quality. Loading is performed statically using line loads, shedding light on the impact of concrete quality on crack development. The concrete to be used has a quality fc' of 15 MPa, 25 MPa, and 35 MPa. The fine aggregate used in this study was Lumajang black sand, while the coarse aggregate used was machine crushed stone, and Portland Composite Cement (PCC) was used in all concrete mixes. The reinforcing steel used had a quality fy of 480 MPa, with a reinforcement ratio of ρ=0.010, which was converted to 5-D16 reinforcement. The subgrade density used to support the specimens had a CBR value of 10 %. Specimen dimensions were 2×0.6×0.2 m for length, width, and thickness. Pavement plates, 30 cm thick, were placed on leveled subgrade soil in a steel box set to achieve a 6 % CBR reading. Hydraulic jacks, monitored by a load cell, applied monotonic static loading with 2 kN intervals, reaching a maximum load of 200 kN. Steel tension and plate settlement were measured using a tension sensor and Linear Variable Differential Transformer (LVDT), respectively. A data logger recorded readings, and crack widths were captured by a digital microscope with 0.01 mm accuracy. Experimental results show that low concrete compressive strength values result in larger crack widths, and vice versa. Cracks also occur at earlier loading of concrete quality fc' 15 MPa. In addition, experiments show that the reinforcement stress value has a significant influence on crack width in specimens with low concrete quality

Occurrence, distribution, and composition of black sand along the Red Sea, Egypt

Black sand along the Red Sea is often composed of volcanic minerals and heavy minerals. The Red Sea region is known for its unique geological features, and black sand beaches can be found in various areas along its shores. The study presents a comprehensive semi-quantitative chemical analysis of black sand samples collected from various locations along the red sea, revealing significant variations in their elemental compositions. The main oxides were identified in each sample, determined through X-ray diffraction (XRD) and X-ray fluorescence (XRF) analyses, indicate diverse mineralogical compositions. The spatial distribution of minerals at each site is depicted through mapping. Additionally, Fourier-transform infrared (FTIR) spectra offer information on the functional groups present in the samples, revealing the existence of hydroxyl groups, aliphatic compounds, and adsorbed water molecules. For Qusier-Elsharm Alqbly, Safaga, Marsa Alam, Gabal Alrosass, Hurghada Titanic, Hurghada Elahiaa, Gemsa, and Ras Elbehar samples, the results highlight the presence of various minerals, such as Quartz, Calcite, Titanium Dioxide, Magnetite, Hematite, Aluminum Oxide, Zirconium Dioxide, Chromium (III) Oxide, and others, providing insights into the geological characteristics of each location. The differences in mineral content among the examined sites are linked to the geological and mineralogical makeup of the source rocks upstream and midstream in the basins that discharge into the surveyed regions. So, variations in black sand concentrations among different locations offer insights into the geological and mineralogical diversity of the studied areas along the Red Sea coast. This study addresses the existing knowledge gap by focusing on the preliminary exploration and description of the occurrence, distribution, and composition of black sand along the Red Sea in Egypt. whereas the results provide valuable insights into the geological diversity of black sand deposits in the surveyed areas, underscoring the need for additional research and interpretation of these variations. Therefore, the in-depth examination of mineralogical composition and crystal structures establishes a foundation for future investigations in the field of geology and earth sciences.

Rare earth elements and radioactive elements in black sands from the Konkan and Malabar coasts of India

ABSTRACT The objective of the present work is to demonstrate the ability of the laser-induced breakdown spectroscopy (LIBS) technique for quick detection and quantification of rare earth elements (REEs) and radioactive elements in the black sands at selected locations of the Konkan coast (Goa) and Malabar coast (Kerala) in India. Several REEs such as Ce, Nd, Sm, Dy, Ho, Tm, Gd, and Th have been detected in the LIBS spectra. Calibration-free LIBS method has been used to calculate the concentration of REEs and radioactive elements. The experimental result shows that the concentration of REEs such as Sm, Dy, Ho, and radioactive element Th is maximum in the sands collected from Thiruvananthapuram (Kerala) beach and minimum in the Baga (Goa) beach. The reliability of the results (qualitative and quantitative) obtained by the LIBS method has been examined by other spectroscopic techniques like XRF and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and found to be in close agreement. The multivariate approach (principal component analysis) has been applied to discern the samples based on their spectral data. Photoacoustic spectroscopy and XRD technique are used to detect compounds/minerals of REEs. The relative hardness, degree of crystallinity (DOC), and crystallite size have been calculated.

Environmental and mineralogical studies on the stream sediments of Baltim–El Burullus coastal plain, North Delta, Egypt

This work is mainly concerned with the effect of anthropogenic activities and natural radioactivity due to the presence of highly radioactive black sand spots, factory construction, and shipping, in addition to other activities like agriculture on human beings. Forty samples were collected along Baltim–El Burullus coastal plain to detect the effect of these problems and determine the suggested solutions. The black sand of the Baltim–El Burullus coastal plain exhibits a considerable amount of economically heavy minerals, their ratio relative to the bulk composition in the investigated samples ranges from 3.18 to 10.5% with an average of 5.45%. The most important of them are magnetite, ilmenite, rutile, leucoxene, garnet, zircon and monazite. The existence of some radioactive-bearing accessory mineral deposits like zircon and monazite led to measuring the naturally occurring radionuclides 226Ra, 232Th and 40K to evaluate the excess lifetime cancer risk (ELCR). The results showed that these concentrations are 19.1 ± 9.73, 14.7 ± 9.53 and 211 ± 71.34 Bq kg−1 were lower than the corresponding reported worldwide average of 35, 45, and 412 Bq kg−1 for each radionuclide (226Ra, 232Th, and 40 K). The gamma hazard indices such as absorbed dose rate (Dair), the annual effective dose (AED), and excess lifetime cancer risk (ELCR) factor were computed in the investigated sediments and all the results were found (Dair = 26.4 nGy h−1, AED = 0.03 mSv year−1, ELCR = 0.0001) to be lower than the values suggested by the United Nations Scientific Committee on the effect of Atomic Research (59 nGy h−1, 0.07 mSv year−1 and 0.0029 for Dair, AED and ELCR, respectively). The study suggests that the black sand is safe to use in various infrastructure applications at Baltim–El Burullus coastal plain. The levels of radioactivity are not high enough to pose a risk to human health.