The development of unique optical materials that provide amplification and lasing in new wavelength ranges is a major scientific problem, the solution of which is becoming the basis for the emergence of new optical technologies, which are primarily targeting the expanding of operating wavelengths in silica glass. In fact, one of the notable advances in the field of fiber optics over the past two decades has been the production of a new type of laser-active fibers (namely bismuth-doped fibers), which has made it possible to cover previously inaccessible (for rare-earth-doped fibers) spectral ranges, in particular O-, E-, S-, and U-telecom bands. The advance in this direction has led to further growth of the technological capabilities in the telecom industry for amplification and generation of optical radiation in various wavelength bands, which will result in the near future to overcoming the problem known as “capacity crunch” by means of expanding the data transmission range. Recently, bismuth-doped fibers have been actively studying in order to improve their characteristics, which would allow for efficient implementation of optical devices based on bismuth-doped fibers (BDFs) with deployed telecommunications systems. This is one of the dynamically developing areas, where progress has already manifested in form of emergence of new achievements, in particular commercially available various types of BDFs, as well as a series of novel fiber-optic amplifiers for the O- and E-bands. In this review, a number of scientific studies that have already led to a noticeable progress in the field of optical properties of BDFs and the practical implementation of optical devices (lasers and amplifiers) based on them are presented and discussed, with much attention to the achievements of recent years.
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